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NASA NTRS2013

Improvements of VIIRS and MODIS Solar Diffuser and Lunar Calibration

Both VIIRS and MODIS instruments use solar diffuser (SD) and lunar observations to calibrate their reflective solar bands (RSB). A solar diffuser stability monitor (SDSM) is used to track the SD on-orbit degradation. On-orbit observations have shown similar wavelength-dependent SD degradation (larger at shorter VIS wavelengths) and SDSM detector response degradation (larger at longer NIR wavelengths) for both VIIRS and MODIS instruments. In general, the MODIS scan mirror has experienced more degradation in the VIS spectral region whereas the VIIRS rotating telescope assembly (RTA) mirrors have seen more degradation in the NIR and SWIR spectral region. Because of this wavelength dependent mirror degradation, the sensor's relative spectral response (RSR) needs to be modulated. Due to differences between the solar and lunar spectral irradiance, the modulated RSR could have different effects on the SD and lunar calibration. In this paper, we identify various factors that should be considered for the improvements of VIIRS and MODIS solar and lunar calibration and examine their potential impact. Specifically, we will characterize and assess the calibration impact due to SD and SDSM attenuation screen transmission (uncertainty), SD BRF uncertainty and onorbit degradation, SDSM detector response degradation, and modulated RSR resulting from the sensor's optics degradation. Also illustrated and discussed in this paper are the calibration strategies implemented in the VIIRS and MODIS SD and lunar calibrations and efforts that could be made for future improvements.

VIIRS↗
NASA NTRS2016

Reactive Orthotropic Lattice Diffuser for Noise Reduction

An orthotropic lattice structure interconnects porous surfaces of the flap with internal lattice-structured perforations to equalize the steady pressure field on the flap surfaces adjacent to the end and to reduce the amplitude of the fluctuations in the flow field near the flap end. The global communication that exists within all of the perforations provides the mechanism to lessen the pressure gradients experienced by the end portion of the flap. In addition to having diffusive effects (diffusing the incoming flow), the three-dimensional orthogonal lattice structure is also reactive (acoustic wave phase distortion) due to the interconnection of the perforations.

Khorrami, Mehdi R.↗
NASA NTRS2016

ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) - Merging Observations and Laboratory Data

The Diffuse Interstellar Bands (DIBs) are a set of ~500 absorption bands that are detected in the spectra of stars with interstellar clouds in the line of sight. DIBs are found from the NUV to the NIR in the spectra of reddened stars spanning different interstellar environments in our local, and in other galaxies. DIB carriers are a significant part of the interstellar chemical inventory. They are stable and ubiquitous in a broad variety of environments and play a unique role in interstellar physics/chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics, and astrophysical modeling of line-of-sights. PAHs are among the molecular species that have been proposed as DIB carriers. We will present an assessment of the PAH-DIB model in view of the progress and the advances that have been achieved over the past years through a series of studies involving astronomical observations of DIBs, laboratory simulation of interstellar analogs for neutrals and ionized PAHs, theoretical calculations of PAH spectra and the modelization of diffuse and translucent interstellar clouds. We will present a summary of what has been learned from these complementary studies, the constraints that can now be derived for the PAHs as DIB carriers in the context of the PAH-DIB model and how these constraints can be applied to the EDIBLES project. The spectra of several neutral and ionized PAHs isolated in the gas phase at low temperature have been measured in the laboratory under experimental conditions that mimic interstellar conditions and are compared with an extensive set of astronomical spectra of reddened, early type stars. The comparisons of astronomical and laboratory data provide upper limits for the abundances of specific neutral PAH molecules and ions along specific lines-of-sight. Something that is not attainable from infrared observations alone. We present the characteristics of the laboratory facilities, MIS and COSmIC, that have been developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. MIS stands for Matrix Isolation Spectroscopy, a well-proven technique for isolating cold molecular species in inert solid environments. COSmIC stands for Cosmic Simulation Chamber. It combines a supersonic free jet expansion with discharge plasma and high-sensitivity cavity ringdown spectroscopy and time-of-flight mass spectrometry detection tools for the generation and the detection of cold, isolated gas-phase molecules and ions under experimental conditions that closely mimic interstellar conditions. The column densities of the individual neutral PAH molecules and ions probed in these surveys are derived from the comparison of these unique laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for unambiguous quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

astrophysics↗
NASA NTRS2015

Superthermal Electron Magnetosphere-Ionosphere Coupling in the Diffuse Aurora in the Presence of ECH Waves

There are two main theories for the origin of the diffuse auroral electron precipitation: first, pitch angle scattering by electrostatic electron cyclotron harmonic (ECH) waves, and second, by whistler mode waves. Precipitating electrons initially injected from the plasma sheet to the loss cone via wave-particle interaction processes degrade in the atmosphere toward lower energies and produce secondary electrons via impact ionization of the neutral atmosphere. These secondary electrons can escape back to the magnetosphere, become trapped on closed magnetic field lines, and deposit their energy back to the inner magnetosphere. ECH and whistler mode waves can also move electrons in the opposite direction, from the loss cone into the trap zone, if the source of such electrons exists in conjugate ionospheres located at the same field lines as the trapped magnetospheric electron population. Such a situation exists in the simulation scenario of superthermal electron energy interplay in the region of diffuse aurora presented and discussed by Khazanov et al. (2014) and will be quantified in this paper by taking into account the interaction of secondary electrons with ECH waves.

Coupling↗
NASA NTRS1973

Lidar Measurements of On-Shore Wind Diffusion

The concept to place electric power generating stations on the oceans off the coast of the United States has instilled new efforts in research for improved understanding of the diffusion properties of the atmosphere in the ocean-air interface. The Atomic Energy Commission has instigated a program by the Meteorology Group at Brookhaven National Laboratory to investigate the low level, on-shore wind systems that dominate many of the coastal regions. Analytical techniques and specialized instrumentation from previous studies at Brookhaven are being used in this new program. The Brookhaven Lidar system is used to measure some of the physical properties of the oil-fog plume originating from a portable smoke generator on a boat off the coast. The oil-fog plume is used as a tracer which can be observed, photographed and measured to determine the diffusive power of the atmosphere associated with the ocean-air interface and the discontinuities found in the ocean-land boundary. This paper will describe the program rather briefly and the oil-fog scattering measurements that have been made with the Lidar system.

Brown, R. M.↗
NASA NTRS2014

On-Orbit Performance of MODIS Solar Diffuser Stability Monitor

Moderate Resolution Imaging Spectroradiometer (MODIS) is currently operated on both the Terra and Aqua spacecraft. It collects data in 20 reflective solar bands (RSB) and 16 thermal emissive bands. MODIS RSB calibration is reflectance based via an on-board solar diffuser (SD). On-orbit changes in the SD bidirectional reflectance factor are tracked by an onboard solar diffuser stability monitor (SDSM). The SDSM functions as an independent ratioing radiometer with nine filtered detectors, covering wavelengths in the visible (VIS) and near-infrared (NIR) spectral regions. A brief overview of SDSM design functions, on-orbit operations, and performance for both Terra and Aqua MODIS is provided. In addition to the SD on-orbit degradation at different wavelengths, the changes in SDSM detector responses and their potential impact on tracking SD on-orbit degradation are examined. After more than 12 years of on-orbit operation, Aqua MODIS SD has shown degradation varying from 0.6% at 0.94 microns to 19.0% at 0.41 microns. Due to more frequent solar exposure and longer operation time, the Terra MODIS SD has experienced a much larger degradation, varying from 2.3% at 0.94 microns to 48.0% at 0.41 microns. For both Terra and Aqua MODIS, the SD has experienced more degradation at shorter wavelengths. Meanwhile, the SDSM detector responses have also experienced wavelength-dependent degradation. The largest change in the SDSM detector responses, however, occurred at longer NIR wavelengths. Since launch, the SDSM systems on both Terra and Aqua MODIS have continued their nominal operations, enabling critical parameters to be derived in support of the RSB on-orbit calibration. The calibration strategies developed for and lessons learned from MODIS SDSM operations, and a preliminary performance comparison with the S-NPP VIIRS SDSM are discussed.

MODIS↗
NASA NTRS2016

Ion-Scale Structure in Mercury's Magnetopause Reconnection Diffusion Region

The strength and time dependence of the electric field in a magnetopause diffusion region relate to the rate of magnetic reconnection between the solar wind and a planetary magnetic field. Here we use approximately 150 milliseconds measurements of energetic electrons from the Mercury Surface, Space Environment, GEochemistry, and Ranging (MESSENGER) spacecraft observed over Mercury's dayside polar cap boundary (PCB) to infer such small-scale changes in magnetic topology and reconnection rates. We provide the first direct measurement of open magnetic topology in flux transfer events at Mercury, structures thought to account for a significant portion of the open magnetic flux transport throughout the magnetosphere. In addition, variations in PCB latitude likely correspond to intermittent bursts of approximately 0.3 to 3 millivolts per meter reconnection electric fields separated by approximately 5 to10 seconds, resulting in average and peak normalized dayside reconnection rates of approximately 0.02 and approximately 0.2, respectively. These data demonstrate that structure in the magnetopause diffusion region at Mercury occurs at the smallest ion scales relevant to reconnection physics.

Gershman, Daniel J.↗
NASA NTRS2016

Electron Energization and Mixing Observed by MMS in the Vicinity of an Electron Diffusion Region During Magnetopause Reconnection

Measurements from the Magnetospheric Multiscale (MMS) mission are reported to show distinct features of electron energization and mixing in the diffusion region of the terrestrial magnetopause reconnection. At the ion jet and magnetic field reversals, distribution functions exhibiting signatures of accelerated meandering electrons are observed at an electron out-of-plane flow peak. The meandering signatures manifested as triangular and crescent structures are established features of the electron diffusion region (EDR). Effects of meandering electrons on the electric field normal to the reconnection layer are detected. Parallel acceleration and mixing of the inflowing electrons with exhaust electrons shape the exhaust flow pattern. In the EDR vicinity, the measured distribution functions indicate that locally, the electron energization and mixing physics is captured by two-dimensional reconnection, yet to account for the simultaneous four-point measurements, translational invariant in the third dimension must be violated on the ion-skin-depth scale.

Chen, Li-Jen↗
NASA NTRS2016

MODIS Solar Diffuser On-Orbit Degradation Characterization Using Improved SDSM Screen Modeling

The Solar Diffuser (SD) is used for the MODIS reflective solar bands (RSB) calibration. An on-board Solar Diffuser Stability Monitor (SDSM) tracks the degradation of its on-orbit bi-directional reflectance factor (BRF). To best match the SDSM detector signals from its Sun view and SD view, a fixed attenuation screen is placed in its Sun view path, where the responses show ripples up to 10%, much larger than design expectation. Algorithms have been developed since the mission beginning to mitigate the impacts of these ripples. In recent years, a look-up-table (LUT) based approach has been implemented to account for these ripples. The LUT modeling of the elevation and azimuth angles is constructed from the detector 9 (D9) of SDSM observations in the MODIS early mission. The response of other detectors is normalized to D9 to reduce the ripples observed in the sun-view data. The accuracy of all detectors degradation estimation depends on how well the D9 approximated. After multiple years of operation (Terra: 16 years; Aqua: 14 years), degradation behavior of all detectors can be monitored by their own. This paper revisits the LUT modeling and proposes a dynamic scheme to build a LUT independently for each detector. Further refinement in the Sun view screen characterization will be highlighted to ensure the degradation estimation accuracy. Results of both Terra and Aqua SD on-orbit degradation are derived from the improved modeling and curve fitting strategy.

Chen, H.↗
NASA NTRS2017

High Temperature Characteristics of Pt/TaSi2/Pt/W and Pt/Ti/W Diffusion Barrier Systems for Ohmic Contacts to 4H-SiC

The degradation of ohmic contacts to 4H-SiC pressure sensors over time at high temperature is primarily due to two failure mechanisms: migrating bond pad Au and atmospheric O toward the ohmic contact SiC interface and the inter-metallic mixing between diffusion barrier systems (DBS) and the underlying ohmic contact metallization. We investigated the effectiveness of Pt/TaSi2/Pt/W (DBS-A) and Pt/Ti/W (DBS-B) in preventing Au and O diffusion through the underlying binary Ti/W or alloyed W50:Ni50 ohmic contacts to 4H-SiC and the DBS ohmic contact intermixing at temperature up to 700 C.

Platinum↗
NASA NTRS2017

The Diffuse Interstellar Bands: Solving a Century Old Problem

The Diffuse Interstellar Bands (DIBs) are a set of apporoximately 500 absorption bands that are seen in the spectra of reddened stars (i.e., stars obscured by the presence of interstellar clouds in their line of sight). The first DIBs were detected in the visible over a century ago. Diffuse Interstellar Bands are now detected from the near ultraviolet to the near infrared in the spectra of reddened stars spanning a variety of interstellar environments in our local, and in other galaxies. Although DIB carriers are a significant part of the interstellar chemical inventory as they account for a noticeable fraction of the interstellar extinction, the nature of their carriers is still unknown over a century after the detection of the first bands. DIB carriers are stable and ubiquitous in a broad variety of interstellar environments and play a unique role in interstellar physics and chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics and astrochemistry, quantum chemistry calculations and astrophysical modeling of line-of-sights. In this review, we'll present and discuss the current state of this perplexing problem. We'll review the progress and the failures that have been encountered in the long quest for the identification of the carriers of these ubiquitous interstellar bands.

Molecules in Space↗
NASA NTRS2017

Thermophysical Properties of Cold and Vacuum Plasma Sprayed Cu-Cr-X Alloys, NiAl and NiCrAlY Coatings: Electrical and Thermal Conductivity, Thermal Diffusivity, and Total Hemispherical Emissivity - Part 1

This two-part paper reports the thermophysical properties of several cold and vacuum plasma sprayed monolithic Cu and Ni-based alloy coatings. Part I presents the electrical and thermal conductivity, thermal diffusivity, and total hemispherical emissivity data while Part II reports the specific heat capacity data for these coatings. Metallic copper alloys, stoichiometric NiAl and NiCrAlY coatings were fabricated by either the cold sprayed or the vacuum plasma spray deposition processes for thermal property measurements between 77 and 1223 K. The temperature dependencies of the thermal conductivities, thermal diffusivities, electrical conductivities and total hemispherical emissivities of these cold and vacuum sprayed monolithic coatings are reported in this paper. The electrical and thermal conductivity data correlate reasonably well for Cu-8%Cr-1%Al, Cu-23%Cr-5%Al and NiAl in accordance with the Wiedemann-Franz (WF) law although a better fit is obtained using the Smith-Palmer relationship. The Lorentz numbers determined from the WF law are close to the theoretical value.

Raj, S. V.↗
NASA NTRS2017

Kinetic Monte Carlo Simulations of Oxygen Diffusion in Environmental Barrier Coating Materials

Ceramic Matrix Composite (CMC) materials are of interest for use in next-generation turbine engine components, offering a number of significant advantages, including reduced weight and high operating temperatures. However, in the hot environment in which such components operate, the presence of water vapor can lead to corrosion and recession, limiting the useful life of the components. Such degradation can be reduced through the use of Environmental Barrier Coatings (EBCs) that limit the amount of oxygen and water vapor reaching the component. Candidate EBC materials include Yttrium and Ytterbium silicates. In this work we present results of kinetic Monte Carlo (kMC) simulations of oxygen diffusion, via the vacancy mechanism, in Yttrium and Ytterbium disilicates, along with a brief discussion of interstitial diffusion.

Good, Brian S.↗
NASA NTRS2017

Magnetospheric Multiscale Mission Observations of the Outer Electron Diffusion Region

This paper presents Magnetospheric Multiscale mission (MMS) observations of the exhaust region in the vicinity of the central reconnection site in Earth's magnetopause current sheet. High-time-resolution measurements of field and particle distributions enable us to explore the fine structure of the diffusion region near the X line. Ions are decoupled from the magnetic field throughout the entire current sheet crossing. Electron jets flow downstream from the X line at speeds greater than the E by B drift velocity. At or around the magnetospheric separatrix, large-amplitude electric fields containing field-aligned components accelerate electrons along the magnetic field toward the X line. Near the neutral sheet, crescent-shaped electron distributions appear coincident with (1) an out-of-plane electric field whose polarity is opposite to that of the reconnection electric field and (2) the energy transfer from bulk kinetic to field energy. The observations indicate that MMS passed through the edge of an elongated electron diffusion region (EDR) or the outer EDR in the exhaust region.

Hwang, K.-J.↗
NASA NTRS2018

Three-Dimensional, Space-Dependent Mesoscale Diffusivity: Derivation and Implications

Recently, we presented a parameterization of an arbitrary tracer 3D mesoscale flux that describes both diabatic and adiabatic regimes without using arbitrary tapering functions. However, we did not parameterize the mesoscale diffusivity, which is the subject of this work. A key difference between the present and previous diffusivity parameterizations is that in the latter, the two main ingredients, mesoscale drift velocity and eddy kinetic energy, were not parameterized but determined using present data, which deprives the models of predictive power. Since winds, stratification, etc., are predicted to change in the future, use of these parameterizations to study future climate scenarios becomes questionable. In this work, we parameterize drift velocity and eddy kinetic energy (vertical–horizontal components), which we first assess with data [WOCE, TOPEX/Poseidon (T/P), and North Atlantic Tracer Release Experiment (NATRE)] and then use in a coarse-resolution stand-alone ocean code under Coordinated Ocean-Ice Reference Experiment I (CORE-I) forcing. We present results for the global ocean temperature and salinity, Atlantic overturning circulation, meridional heat transport, and Drake Passage transport, which we compare with several previous studies. The temperature drift is less than that of five of seven previous OGCMs, and the salinity drift is among the smallest in those studies. The predicted winter Antarctic Circumpolar Current mixed layer depths (MLDs) are in good agreement with the data. Predicting the correct MLD is important in climate studies since models that predict very deep mixed layers transfer more of the radiative perturbation to the deep ocean, reducing surface warming (and vice versa).

Eddies; Mesoscale processes; Mixing; Ocean models;↗
NASA NTRS2019

Low Energy Precipitating Electrons in the Diffuse Aurorae

Auroral electron precipitation is often classified into three categories: diffuse, monoenergetic,and broadband. However, some precipitating electrons do not fit any of the three categories, which areassumed to be "diffuse" electrons for convenience. Many of these nonconforming electrons exhibit highfluxes at low energies. Most studies assume that the precipitating electrons originate from themagnetosphere. However, this primary precipitation is only the first step in the formation of the electronprecipitation. The primary precipitation creates secondary electrons and both electron populations bouncemany times between the conjugate points. Thus, the full electron precipitation consists of not only theprimary but the Multiply Reflected Primary and Secondary (MRPS) electrons. The MRPS electrons aremodeled with Superthermal Electron Transport model. The modeldata comparisons suggest that the lowenergy electrons in the nonconforming precipitating electrons can be attributed to MRPS electrons.

Wing, Simon↗
NASA NTRS2019

Comparison of MODIS Solar Diffuser Stability Monitor Calibration Results for Different Operational Configurations

The MODIS instruments on the Terra and Aqua spacecraft use a sunlit solar diffuser (SD), with an optional SD attenuation screen (SDS), to calibrate the reflective solar bands. A solar diffuser stability monitor (SDSM) is used to track the SD reflectance degradation on orbit, by taking a ratio of the detector response when viewing the SD compared to the response when viewing the sun. The MODIS SDSMs have been operated both with and without the SDS in place. The SDSMs have also been operated in both a fixed and an alternating mode. In the alternating mode, the SDSM detectors view the SD, sun, and a dark background in an alternating pattern with the view changing on every MODIS scan within a single orbit. In the fixed mode, the SDSM detectors are fixed on the sun view for one orbit, and then are fixed on the SD view for the following orbit. This paper reviews the history of the SDSM operational configurations used throughout the MODIS missions and discusses the differences in the SD degradation results, which may be due to differences in sun-satellite geometry, SD signal level, and stray light effects. We highlight Aqua SDSM results from two recent dates in October 2017 and July 2019, where both the fixed and alternating mode calibrations were run on the same day, providing clear examples of the calibration differences. Additionally, we show how mixing the results from calibrations done with and without the SDS for Aqua MODIS can provide more stable results.

Twedt, Kevin A.↗
NASA NTRS2020

How Magnetically Conjugate Atmospheres and the Magnetosphere Participate in the Formation of Low‐Energy Electron Precipitation in the Region of Diffuse Aurora

The electron precipitation in the region of the diffuse aurora should be considered as a two‐step process (Khazanov et al., 2017, https://doi.org/10.1002/2016GL072063). The first one is the interaction of plasma sheet electrons with electrostatic electron cyclotron and/or whistler waves, moving those electrons into the loss cone to precipitate in both magnetically conjugate atmospheres. The second step is the interaction of these electrons with the ionosphere and atmosphere via their elastic and nonelastic collisions and reflection (backscatter) of degraded electrons back to magnetosphere and conjugate ionospheres. This paper presents the results of a newly developed scenario of non steady‐state electron precipitation dynamics that accounts for magnetosphere‐ionosphere‐atmosphere energy interplay over the entire energy range of the plasma sheet electron population and their affiliated secondary electrons. It also studies how both magnetically conjugate auroral regions work together with the magnetosphere in the formation of electron precipitation in the region of the diffuse aurora with the energy range coverage from 1 eV up to 10 keV.

George V Khazanov↗