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2020 natural gas LCA appendices Rev1

This collection is the data-centric appendices for the report Life Cycle Analysis of Natural Gas Extraction and Power Generation: U.S. 2020 Emissions Profile. It consists of Appendix A: Additional Modeling Parameters [spreadsheet]; Appendix B: Water Burdens [spreadsheet]; Appendix D: Simulation of Liquids Unloading [python script and spreadsheet]; Appendix E: Detailed GHG Results for All Scenarios [spreadsheet]; Appendix F: Full Inventory Results [spreadsheet]; and Appendix I: Stage-Level Natural Gas Loss and Consumption Rates [spreadsheet]. These results have been updated from the previous version (https://edx.netl.doe.gov/dataset/2020-natural-gas-lca-data-appendices) to correct a modeling error where the same post-processing natural gas composition was used instead of the intended regional compositions.

Appendices↗

A Near-infrared Chemical Inventory of the Atmosphere of 55 Cancri e

We present high-resolution near-infrared spectra taken during eight transits of 55 Cancri e, a nearby low-density super-Earth with a short orbital period (<18 hr). While this exoplanet’s bulk density indicates a possible atmosphere, one has not been detected definitively. Our analysis relies on the Doppler cross-correlation technique, which takes advantage of the high spectral resolution and broad wavelength coverage of our data, to search for the thousands of absorption features from hydrogen-, carbon-, and nitrogen-rich molecular species in the planetary atmosphere. Although we are unable to detect an atmosphere around 55 Cancri e, we do place strong constraints on the levels of HCN, NH{sub 3}, and C{sub 2}H{sub 2} that may be present. In particular, at a mean molecular weight of 5 amu, we can rule out the presence of HCN in the atmosphere down to a volume mixing ratio (VMR) of 0.02%, NH{sub 3} down to a VMR of 0.08%, and C{sub 2}H{sub 2} down to a VMR of 1.0%. If the mean molecular weight is relaxed to 2 amu, we can rule out the presence of HCN, NH{sub 3}, and C{sub 2}H{sub 2} down to VMRs of 0.001%, 0.0025%, and 0.08%, respectively. Our results reduce the parameter space of possible atmospheres consistent with the analysis of Hubble Space Telescope/WFC3 observations by Tsiaras et al. and indicate that if 55 Cancri e harbors an atmosphere, it must have a high mean molecular weight or clouds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Identification of wild areas in southern lower Michigan

An inventory methodology was developed to identify potential wild area sites. A list of site criteria were formulated and tested in six selected counties. Potential sites were initially identified from LANDSAT satellite imagery. A detailed study of the soil, vegetation and relief characteristics of each site based on both high-altitude aerial photographs and existing map data was conducted to eliminate unsuitable sites. Ground reconnaissance of the remaining wild areas was made to verify suitability and acquire information on wildlife and general aesthetics. Physical characteristics of the wild areas in each county are presented in tables. Maps show the potential sites to be set aside for natural preservation and regulation by the state under the Wilderness and Natural Areas Act of 1972.

Habowski, S.↗

Tool for Analysis and Reduction of Scientific Data

The Automated Scheduling and Planning Environment (ASPEN) computer program has been updated to version 3.0. ASPEN as a whole (up to version 2.0) has been summarized, and selected aspects of ASPEN have been discussed in several previous NASA Tech Briefs articles. Restated briefly, ASPEN is a modular, reconfigurable, application software framework for solving batch problems that involve reasoning about time, activities, states, and resources. Applications of ASPEN can include planning spacecraft missions, scheduling of personnel, and managing supply chains, inventories, and production lines. ASPEN 3.0 can be customized for a wide range of applications and for a variety of computing environments that include various central processing units and randomaccess memories. Domain-specific reasoning modules (e.g., modules for determining orbits for spacecraft) can easily be plugged into ASPEN 3.0. Improvements over other, similar software that have been incorporated into ASPEN 3.0 include a provision for more expressive time-line values, new parsing capabilities afforded by an ASPEN language based on Extensible Markup Language, improved search capabilities, and improved interfaces to other, utility-type software (notably including MATLAB).

James, Mark↗

Inventory of forest and rangeland and detection of forest stress

The author has identified the following significant results. Three small scales of CIR photography were interpreted to determine the number of bark beetle-killed trees detected in each of six spot size categories. A procedure was developed to predict the probability of detecting spots in each spot size category and in turn to estimate the number of infestations and dead trees even on the smallest scale. Statistical tests of the data indicated that the linear model did not fit the data and that other models should be tested. As a result of daily monitoring of Black Hills radiometric instruments it was possible to show the spectral energy relationships in the ponderosa pine ecosystems over time. These data have been helpful for comparison with radiance signatures extracted from ERTS-1 bulk 70mm using precision microdensitometry. Effects of atmospheric interference were shown by a 30 percent increase in scene radiance on channel 4 of the satellite imagery. A calibration and scaling technique was developed and tested to enable interpretation of ERTS-1 bulk and precision data for the Atlanta test site. The technique includes calibration of a photographic copy system for the I2S image combiner and the production of scaled overlays of grid coordinate systems, study area locations, and outline maps of county boundaries.

Heller, R. C.↗

Remote sensing of strippable coal reserves and mine inventory in part of the Warrior Coal Field in Alabama

Methods by which estimates of the remaining reserves of strippable coal in Alabama could be made were developed. Information acquired from NASA's Earth Resources Office was used to analyze and map existing surface mines in a four-quadrangle area in west central Alabama. Using this information and traditional methods for mapping coal reserves, an estimate of remaining strippable reserves was derived. Techniques for the computer analysis of remotely sensed data and other types of available coal data were developed to produce an estimate of strippable coal reserves for a second four-quadrangle area. Both areas lie in the Warrior coal field, the most prolific and active of Alabama's coal fields. They were chosen because of the amount and type of coal mining in the area, their location relative to urban areas, and the amount and availability of base data necessary for this type of study.

Joiner, T. J.↗

Tritium Fires: Simulation and Safety Assessment

This is the Sandia report from a joint NSRD project between Sandia National Labs and Savannah River National Labs. The project involved development of simulation tools and data intended to be useful for tritium operations safety assessment. Tritium is a synthetic isotope of hydrogen that has a limited lifetime, and it is found at many tritium facilities in the form of elemental gas (T 2 ). The most serious risk of reasonable probability in an accident scenario is when the tritium is released and reacts with oxygen to form a water molecule, which is subsequently absorbed into the human body. This tritium oxide is more readily absorbed by the body and therefore represents a limiting factor for safety analysis. The abnormal condition of a fire may result in conversion of the safer T 2 inventory to the more hazardous oxidized form. It is this risk that tends to govern the safety protocols. Tritium fire datasets do not exist, so prescriptive safety guidance is largely conservative and reliant on means other than testing to formulate guidelines. This can have a consequence in terms of expensive and/or unnecessary mitigation design, handling protocols, and operational activities. This issue can be addressed through added studies on the behavior of tritium under representative conditions. Due to the hazards associated with the tests, this is being approached mainly from a modeling and simulation standpoint and surrogate testing. This study largely establishes the capability to generate simulation predictions with sufficiently credible characteristics to be accepted for safety guidelines as a surrogate for actual data through a variety of testing and modeling activities.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Two techniques for mapping and area estimation of small grains in California using Landsat digital data

Two techniques have been developed for the mapping and area estimation of small grains in California from Landsat digital data. The two techniques are Band Ratio Thresholding, a semi-automated version of a manual procedure, and LCLS, a layered classification technique which can be fully automated and is based on established clustering and classification technology. Preliminary evaluation results indicate that the two techniques have potential for providing map products which can be incorporated into existing inventory procedures and automated alternatives to traditional inventory techniques and those which currently employ Landsat imagery.

Sheffner, E. J.↗

UWB Technology and Applications on Space Exploration

Ultra-wideband (UWB), also known as impulse or carrier-free radio technology, is one promising new technology. In February 2002, the Federal Communications Commission (FCC) approved the deployment of this technology. It is increasingly recognized that UWB technology holds great potential to provide significant benefits in many terrestrial and space applications such as precise positioning/tracking and high data rate mobile wireless communications. This talk presents an introduction to UWB technology and some applications on space exploration. UWB is characterized by several uniquely attractive features, such as low impact on other RF systems due to its extremely low power spectral densities, immunity to interference from narrow band RF systems due to its ultra-wide bandwidth, multipath immunity to fading due to ample multipath diversity, capable of precise positioning due to fine time resolution, capable of high data rate multi-channel performance. The related FCC regulations, IEEE standardization efforts and industry activities also will be addressed in this talk. For space applications, some projects currently under development at NASA Johnson Space Center will be introduced. These include the UWB integrated communication and tracking system for Lunar/Mars rover and astronauts, UWB-RFID ISS inventory tracking, and UWB-TDOA close-in high resolution tracking for potential applications on robonaut.

Ngo, Phong↗

Addressing Limitations of the Endpoint Slippage Analysis

Some rate of oxidation and reduction side-reactions will inevitably coexist in most rechargeable batteries. While parasitic reduction traps electrons, parasitic oxidation donates electrons to the cell’s inventory and may cause temporary capacity gain. Consequently, capacity measurements can provide unreliable information about the total extent of side-reactions occurring in the cell. The most widely used method to determine the rate of both these parasitic processes involves analyzing the slippage of endpoints, which consists in tracking the termination of cell charge and discharge when data is represented along a cumulative capacity axis. Here, we argue that this approach could lead to inaccuracies when applied to certain systems, which includes Si electrodes in Li-ion batteries and hard carbon in Na-ion batteries. This inaccuracy originates from the smooth nature of the voltage profiles of these materials at low and high alkali-ion content, causing the termination of charge and discharge to be dictated by voltage changes at both the positive and negative electrodes. We analyze this issue in quantitative terms and propose equations that can provide true rates of parasitic processes from experimental endpoint slippage data. This work shows that, in battery science, well-established analytical approaches may not be directly transferrable to new electrode systems.

25 ENERGY STORAGE↗

LACIE analyst interpretation keys

Two interpretation aids, 'The Image Analysis Guide for Wheat/Small Grains Inventories' and 'The United States and Canadian Great Plains Regional Keys', were developed during LACIE phase 2 and implemented during phase 3 in order to provide analysts with a better understanding of the expected ranges in color variation of signatures for individual biostages and of the temporal sequences of LANDSAT signatures. The keys were tested using operational LACIE data, and the results demonstrate that their use provides improved labeling accuracy in all analyst experience groupings, in all geographic areas within the U.S. Great Plains, and during all periods of crop development.

Baron, J. G.↗

International Collaboration in Lunar Exploration

The U.S. Vision for Space Exploration commits the United States to return astronauts to the moon by 2020 using the Ares I Crew Launch Vehicle and Ares V Cargo Launch Vehicle. Like the Apollo program of the 1960s and 1970s, this effort will require preliminary reconnaissance in the form of robotic landers and probes. Unlike Apollo, some of the data NASA will rely upon to select landing sites and conduct science will be based on international missions as well, including SMART-1, SELENE, and Lunar Reconnaissance Orbiter (LRO). Opportunities for international cooperation on the moon also lie in developing lunar exploration technologies. The European Space Agency's SMART-1 orbiter (Figure 1) is making the first comprehensive inventory of key chemical elements in the lunar surface. It is also investigating the impact theory of the moon's formation.'

Morris, K. Bruce↗

Modeling Landslide Susceptibility Over Large Regions with Fuzzy Overlay

Landslide susceptibility mapping is most effective if detailed surface and subsurface information can be combined with authoritative landslide catalogs or a deep understanding of local conditions. However, these types of homogeneous input data and catalogs are frequently not available over large areas. In this study, we model landslide susceptibility in Central America and the Caribbean islands by combining three globally available datasets and one regional dataset with fuzzy overlay. This primarily heuristic model provides the flexibility to test a range of different contributing variables and the capability to compare landslide inventories within the model framework that vary greatly in their size, spatiotemporal scope, and collection methods. We create a regional susceptibility map and evaluate its performance using receiver operating characteristics for both continuous and binned susceptibility values. This susceptibility map forms the basis for a near-real-time landslide hazard assessment system that couples susceptibility with rainfall and soil moisture triggers to estimate potential landslide activity at a regional scale. The application of this susceptibility model at the regional scale provides a foundation for transferring the methodology to other geographic areas.

Landslide↗

Assessment of Stirling Technology Has Provided Critical Data Leading Toward Flight Readiness of the Stirling Converter

The NASA Glenn Research Center is supporting the development of a Stirling converter with the Department of Energy (DOE, Germantown, Maryland) for an advanced Stirling Radioisotope Power System (SRPS) to provide spacecraft onboard electric power for NASA space science missions. A key technology assessment completed by Glenn and DOE has led to the SRPS being identified as a high-efficiency power source for such deep space missions as the Europa Orbiter and the Solar Probe. In addition, the Stirling system is now being considered for unmanned Mars rovers, especially where mission profiles may exclude the use of photovoltaic power systems, such as exploration at high Martian latitudes or for missions of long duration. The SRPS efficiency of over 20 percent will reduce the required amount of radioisotope by more than a factor of 3 in comparison to current radioisotope thermoelectric generators. This significantly reduces radioisotope cost, radiological inventory, and system cost, and it provides efficient use of scarce radioisotope resources. In support of this technology assessment, Glenn conducted a series of independent evaluations and tests to determine the technology readiness of a 55-We Stirling converter developed by Stirling Technology Company (Kennewick, Washington) and DOE. Key areas evaluated by Glenn included: 1) Radiation tolerance of materials; 2) Random vibration testing of the Stirling converter in Glenn's Structural Dynamics Lab to simulate operation in the launch environment; 3) Electromagnetic interference and compatibility (EMI/EMC) of the converter operating in Glenn's EMI lab; Independent failure modes, effects, and criticality analysis, and life and reliability 4. Independent failure modes, effects, and criticality analysis, and life and reliability assessment; and 5) SRPS cost estimate. The data from these evaluations were presented to NASA Headquarters and the Jet Propulsion Laboratory mission office by a joint industry/Government team consisting of DOE, Glenn, and Lockheed Martin Astronautics. This team concluded that there are no technical reasons that would rule out using the Stirling converter for deep space missions. As a direct result of the successful testing at Glenn, the DOE/Stirling Technology Company 55-We Stirling converter has been baselined for the SRPS. Glenn is now continuing an in-house project to assist in developing the Stirling converter for readiness for space qualification and mission implementation. As part of this effort, the Stirling converter will be further characterized under launch environment random vibration testing, methods to reduce converter EMI will be developed, and an independent performance verification will be completed. Converter life assessment and permanent magnet aging characterization tasks are also underway. Substitute organic materials for the linear alternator and piston bearing coatings for use in a high-radiation environment have been identified and have now been incorporated in Stirling converters built by Stirling Technology Company for Glenn. Electromagnetic and thermal finite element analyses for the alternator are also being conducted.

Thieme, Lanny G.↗

Carbon Isotopic Composition of CO2, Evolved During Perchlorate-Induced Reactions in Mars Analog Materials: Interpreting SAM/MSL Rocknest Data

The Sample Analysis at Mars (SAM) Instrument Suite on the Mars Science Laboratory (MSL) Rover Curiosity made its first solid sample evolved gas analysis of unconsolidated material at aeolian bedform Rocknest in Gale Crater. The magnitude of O2 evolved in each run as well as the chlorinated hydrocarbons detected by SAM gas chromatograph/ mass spectrometer (GCMS) [1] suggest a chlorinated oxidant such as perchlorate in Rocknest materials [2]. Perchlorate induced combustion of organics present in the sample would contribute to the CO2 volatile inventory, possibly overlapping with CO2 from inorganic sources. The resulting carbon and oxygen isotopic composition of CO2 sent to the Tunable Laser Spectrometer (TLS) for analysis would represent mixed sources. This work was undertaken to better understand a) how well the carbon isotopic composition ( 13C) of CO2 from partially combusted products represents their source and b) how the 13C of combusted products can be deconvolved from other carbon sources such as thermal decomposition of carbonate.

Stern, J. C.↗

Short Communication: Observation of Initial Burst Release of Fission Gas from High-Burnup UO 2 Nuclear Fuel During Thermal Transient

A system was developed and tested to provide a deeper understanding of the fission gas release kinetics from nuclear fuel during thermal transients. Pressure, temperature, spectral data, and optical images were simultaneously collected during resistive sample heating, and all released gases were collected in liquid nitrogen-cooled charcoal traps. Standup testing was performed with a high-burnup nuclear fuel segment from rod section with an average local burnup of 77 GWd/tU. During heating, the segment released approximately 6 ± 2% of generated fission gas inventory after ramp heating to 460°C. Here, heating ceased when the sample ejected from the holder, as observed by constant imaging.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Monitoring the vernal advancement and retrogradation (green wave effect) of natural vegetation

The author has identified the following significant results. Emphasis has been given to an inventory of land resource types and land use at the ten Great Plains Corridor test sites. A resource and land use classification system was developed which uses available soil survey information and interpretations from NASA obtained high flight aerial photography to locate discrete areas of similar rangeland vegetation. Existing classification systems, even those developed for use with remote sensor data, were found to be inadequate for this project. This system is expected to be of general use for remote sensing related to land use and management. It has specific applicability to any effort aimed at regional use of ERTS-1 MSS digital data products. A preliminary assessment of the relative importance of rangelands in the Great Plains Corridor states indicates that the value of the livestock industry supported by this resource exceeds 23 billion dollars. The development of a Rangeland Feed Conditions index for this region could be used by more than 400,000 farm and ranch operators involved in the production of more than 40% of the nation's beef and much of the country's grain.

Rouse, J. W., Jr.↗

Estimation of tropical forest canopy temperatures, thermal response numbers, and evapotranspiration using an aircraft-based thermal sensor

Thermal infrared Multispectral Scanner (TIMS) data were collected at a resolution of 5 to 10 m from a tropical rain forest over an elevation gradient from 35 to 2700 m in the Braulio Carrillo National Park in Costa Rica. Flight lines were repeated with a 15 to 30 minute time difference for measurement of forest canopy thermal response over time. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture provided inputs to LOWTRAN6 for atmospheric radiance corrections of the TIMS data. Techniques for using calibrated aircraft-based thermal scanner data to examine tropical forest canopy thermal properties are described. Forest canopy temperature changes over time assessed between repeated, duplicated flight lines were combined with estimates of surface radiative energy measurements from towers above the forest canopy to determine temperature spatial variability, calculate Thermal Response Numbers (TRN), and estimate evapotranspiration along the elevation gradient from selected one hectare forest inventory plots.

Luvall, Jeffrey C.↗