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Localized strain profile in surface electrode array for programmable composite multiferroic devices

In this work, we investigate localized in-plane strains on the microscale, induced by arrays of biased surface electrodes patterned on piezoelectrics. Particular focus is given to the influence that adjacent electrode pairs have on one another to study the impact of densely packed electrode arrays. We present a series of X-ray microdiffraction studies to reveal the spatially resolved micrometer-scale strain distribution. The strain maps with micrometer-scale resolution highlight how the local strain profile in square regions up to 250 x 250 lm 2 in size is affected by the surface electrodes that are patterned on ferroelectric single-crystal [Pb(Mg 1/3 Nb 2/3 )O 3 ] x -[PbTiO 3 ] 1-x . The experimental measurements and simulation results show the influence of electrode pair distance, positioning of the electrode pair, including the angle of placement, and neighboring electrode pair arrangements on the strength and direction of the regional strain. Our findings are relevant to the development of microarchitected strain-mediated multiferroic devices. The electrode arrays could provide array-addressable localized strain control for applications including straintronic memory, probabilistic computing platforms, microwave devices, and magnetic-activated cell sorting platforms.

42 ENGINEERING↗

Tests of Dark MACHOs: lensing, accretion, and glow

Dark matter could take the form of dark massive compact halo objects (dMACHOs); i.e., composite objects that are made up of dark-sector elementary particles, that could have a macroscopic mass from the Planck scale to above the solar mass scale, and that also admit a wide range of energy densities and sizes. Concentrating on the gravitational interaction of dMACHOs with visible matter, we map out the mass-radius parameter space that is consistent with gravitational lensing experiments, as well as anisotropies of the cosmic microwave background (CMB) based on the spherical accretion of matter onto a dMACHO in the hydrostatic approximation. For dMACHOs with a uniform-density mass profile and total mass in the range of ~ 10 -12 - 10 M , we find that a dMACHO could explain 100% of the dark matter if its radius is above ≈ 3 times the Einstein radius of the lensing system. For a larger mass above 10 M , a dMACHO with radius above ~ 1×10 8 cm×(M/100 M ) 9/2 is consistent with CMB observables. For a lighter dMACHO with mass below ~ 10 -12 M , there still is not a good experimental probe. Finally, we point out that heavier dMACHOs with masses ~ 0.1 M may be observed by X-ray and optical telescopes if they reside at rest in a large molecular cloud, nearby to our solar system, and accrete ordinary matter to emit photons.

79 ASTRONOMY AND ASTROPHYSICS↗

Topsoil bulk geochemical compositions - An updated harmonized global dataset

Mineral weathering is a key biogeochemical process because of the capacity of minerals to stabilize organic matter. However, predicting soil weathering status across large spatial areas still isn’t possible due to a lack of global data and theoretical frameworks. To address this knowledge gap, multiple global datasets of bulk topsoil geochemical compositions have been harmonized using R. These datasets document topsoil bulk geochemical compositions across five continents (n = ~16,000 observations). Source data for these observations include the EuroGEOSurveys Geochemical Baseline Database (FOREGS), the US Geological Survey National Geochemical Database (NASGLP), the Geochemical Atlas of Australia (GAA), the US Geological Survey Alaska Geochemical Database (AGD84), the National Cooperative Soil Survey (NCSS), the European Geochemical Mapping of Agricultural Soil (GEMAS), Ecorespira-Amazon (ERA), the New Zealand Geochemical Baseline Survey (NZ_GBS), and the African Soil Information Service (AFSIS). Major elements observed include Aluminum (Al), Calcium (Ca), Iron (Fe), Potassium (K), Magnesium (Mg), Sodium (Na), Titanium (Ti), Manganese (Mn), Phosphorus (P), Carbon (C), and Sulfur (S). This data package includes the harmonized dataset itself, and the R scripts necessary to harmonize these datasets, in addition to metadata that describes all columns, files, and databases used in this project. Methods & Sampling Step 1 – Databases of geochemical data identified This study aimed to leverage existing measurements of topsoil geochemical data. Databases were first identified and deemed appropriate for inclusion if they were measuring soils and performed these measurements on the <2mm soil fraction. Databases such as NCSS and AGD84 needed more post processing to include in the database and this was done using the NCSS_datamerge_031626 R file and Alaska_USGSmerge_031626 R file, respectively. Step 2 – Database harmonization Once appropriate databases were identified, they were harmonized for ease of analysis using the R script Database_Harmonization_031826. This included removing columns from original datasets that would not be used in analysis (removed columns are noted in the code). Then, data cleaning procedures specific to each dataset were undertaken. This includes standardizing columns to include units and adding metadata columns regarding procedures for analyzing specific elements. Functions for standardizing measurements and units are outline in R files: calculate element_mg_kg_031626, calculate_oxide_wt_perc_031626, change_oxide_caps_031626, and conv_2_numeric_031626. This also included adding a unique identifier for each sample to identify it with its respective database (see CD_ID in data dictionary). Geographic information: Data reflect a compilation of datasets collected globally. Geographic areas covered by each of the datasets include: - EuroGEOSurveys Geochemical Baseline Database (FOREGS) - European continent - North American Soil Geochemical Landscapes (NASGLP) - continental United States and limited parts of Canada (see database key for more details) - National Geochemical Survey of Australia (GAA) - Australia - Alaska geochemical database (AGDB4) - Alaska - National Cooperative Soil Survey (NCSS) - Global measurements, but concentrated in the continental United States - Geochemical data for arable land and land under permanent grass cover in continental Europe (GEMAS) - continental Europe - Ecorespira-Amazon (ERA) - Geochemical data from the Amazon basin - Geochemical baseline data for New Zealand (NZGBS) - New Zealand - Geochemical data collected across continental Africa (AfSIS) - Measurements across Africa

EARTH SCIENCE > LAND SURFACE > SOILS↗

Precise Compositional Characterization of Plutonium Alloys by Electron Probe Microanalysis

Key Takeaway Points: • Unlike most other materials, the precise compositional analysis of plutonium, including compounds and alloys, is riddled by numerous difficulties that are unique to the element, including the high atomic number and radioactive nature. There’s work to be done! • Radioactive materials require special handling to ensure precise compositions can be measured by EPMA. • Mean Atomic Number background corrections are limited due to high average atomic number. • Mass Absorption Coefficients are unknown for most light elements. Quantification relies upon calibration curves. • Principal Component Analysis could be a useful tool to improve interpretation of complicated, multiple element X-ray maps.

Maner, IV, James L.↗

Cybersecurity Workforce Training for SMR Integration into Distribution Grids: A Competency Framework and Containerized Hands-On Lab for the SMR/DER/Microgrid Boundary

Small modular reactors (SMRs) and microreactors are entering the U.S. distribution grid as synchronous generation on feeders designed for loads and inverter-based distributed energy resources (DERs). No existing cybersecurity training program addresses this intersection of nuclear operations, DER management, and operational technology security. As subcontractor to Iowa State University on the CyDERMS Center, Argonne analyzed the relevant standards and training landscape, translated the resulting gaps into a twelve-objective competency framework across distribution-operator and graduate-analyst role tracks, and built a containerized training lab using a ∼400-bus composite grid model behind a realistically simulated Modbus TCP SCADA stack. The analysis isolates the balance-of-plant / energy-management-system (BOP/EMS) boundary as the critical jurisdictional seam where, as of March 2026, neither NRC nor NERC CIP cleanly claims cybersecurity responsibility for distribution-connected SMRs. The framework maps each objective across NIST CSF 2.0, ISA/IEC 62443, NIST NICE Task–Knowledge–Skill statements, and NRC RG 5.71 awareness-and-training controls. The training lab implements operator-recognition assessment scenarios spanning grid-side disturbances and telemetry-layer anomalies.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

LANDSAT 4 investigations of Thematic Mapper and Multispectral Scanner applications

Structural and stratigraphic characteristics of the Drum Mountains in Utah were obtained using LANDSAT 5 TM data that were digitally enhanced using band ratioing, principal components analysis, and spatial filtering techniques. Color ratioing composite images proved most useful for distinguishing between and identifying exposure of hyroxly bearing hydrothermally altered inclusive rocks and bleached contact metamorphic rocks dominated by calc-silicate mineral assemblages. The amount and detail of geologic information interpreted from TM images is more significant than that from MSS and in geologic maps. Enhanced LANDSAT 5 TM data also identified and mapped hydrothermal alteration and distinguished between altered and unaltered limonitic assemblages in the Tonopath, Nevada quadrangle.

Lauer, D. T.↗

FE-SEM, FIB and TEM Study of Surface Deposits of Apollo 15 Green Glass Volcanic Spherules

Surface deposits on lunar pyroclastic green (Apollo 15) and orange (Apollo 17) glass spherules have been attributed to condensation from the gas clouds that accompanied fire-fountain eruptions. The fire fountains cast molten lava high above the lunar surface and the silicate melt droplets quenched before landing producing the glass beads. Early investigations showed that these deposits are rich in sulfur and zinc. The deposits are extremely fine-grained and thin, so that it was never possible to determine their chemical compositions cleanly by SEM/EDX or electron probe x-ray analysis because most of the excited volume was in the under-lying silicate glass. We are investigating the surface deposits by TEM, using focused ion beam (FIB) microscopy to extract and thin the surface deposits. Here we report on chemical mapping of a FIB section of surface deposits of an Apollo green glass bead 15401using the ultra-high resolution JEOL 2500 STEM located at NASA Johnson Space Center.

Ross, Daniel K.↗

Nondestructive Testing As a Tool in the Space Shuttle Columbia Accident Investigation

Nondestructive testing (NDT) played a crucial role in determining the Columbia tragedy's cause. Over 84,000 pieces of debris were recovered; hundreds were subsequently subjected to NDT and materials analysis. Visual NDT of the debris revealed localized areas of damage such as erosion, excessive heating, knife edging and mechanical damage. Three-dimensional reconstructions were made of the left wing leading edge, utilizing a tripod-mounted laser scanning head and focused laser beam, and an advanced topometric optical scanner (ATOS) with digital white light to scan complex-shaped debris, producing monochrome 3-D models. Texture mapping provided a means to capture true colors of the debris and superimpose them on the scanned images. Uniform deposits were found over large portions of debris, obscuring underlying materials. To determine what was beneath, inverse radiography was enlisted. The radiographs guided investigators to where samples should be taken. To ascertain compositions, these samples were subjected to analytical testing, including energy dispersive X-ray spectroscopy and electron microprobe analysis. This combination of visual evidence, radiography, virtual reconstruction, and materials analysis allowed the forensic scientists to verify that a breach occurred in the leading edge of the left wing, the path the plasma followed, and the sequence of events that led to the loss.

McDanels, Steve↗

New Insights Into Aristarchus Crater With LRO LAMP Far-Ultraviolet Observations

Aristarchus crater is a Copernican-age impact crater well known for its high-albedo ejecta blanket and nearby flow features rich in pyroclastic materials. The Lyman Alpha Mapping Project (LAMP) is a far-ultraviolet (FUV) spectrograph (57–197 nm) on board the Lunar Reconnaissance Orbiter (LRO). LAMP data identified Aristarchus crater as having a high Off-band (155–184 nm) to On-band (130–155 nm) albedo (Off/On) ratio, providing new insight into the mineral composition of the area. Previous LAMP observations of bright crater rays and lunar swirls show that regions of high Off/On-band ratios may indicate highly feldspathic compositions. In this study we use LAMP data to understand FUV compositional signatures at Aristarchus. We investigate four well-characterized regions of interest around Aristarchus crater, and we compare Off/On-band ratios at Aristarchus crater to laboratory-derived ratios of several endmembers such as anorthite and olivine. We further analyze LAMP FUV spectra alongside near-infrared spectra from the Moon Mineral Mapper (M3) on board Chandrayaan-1 to characterize the mineralogy in several regions of interest. We find that LAMP Off/On-band ratios are able to distinguish between plagioclase feldspars and minerals such as quartz and mafic-dominated compositions. The LAMP Off/On-band ratios at Aristarchus are higher than previously reported ratios for plagioclase-rich regions, suggesting that the composition is unique to Aristarchus. Spectra from LAMP and M 3 both show that the central peak and high-albedo ejecta around Aristarchus contain shocked, possibly alkalic, plagioclase feldspar.

Elizabeth Czajka↗

Variations in chemical composition of Apollo 15 mare basalts

Chemical analyses of 30 different Apollo 15 mare basalts were examined to evaluate the effects of closure on the pearson moment correlation coefficient. It is shown possible to describe the Apollo 15 mare basalts in terms of an opaque, an olivine/pyroxene, an anorthite, and a KREEP component, if significant correlations are identified using the expected correlations as null values. Using Q-mode cluster analysis and nonlinear mapping, it is possible to recognize three groups of the mare basalts, groups 1 and 2 belonging to the olivine normative basalt cluster and group 3 to the quartz normative cluster.

Butler, J. C.↗

Coordinated Mineralogical and Isotopic Analysis of a Cosmic Symplectite Identified in a Stardust Terminal Particle

Comet Wild-2 samples returned by the Stardust spacecraft contain a chemically diverse mixture of material, underscoring the complex nature of comets. Studies of entire Stardust aerogel tracks afford the opportunity to examine the fine-grained particle fragments distributed along the length of the track as well as the terminal particles. Previous TEM characterization of a terminal particle (TP) in track #147 revealed a symplectically intergrown iron sulfide and oxide assemblage. Mineralogically similar assemblages, known as cosmic symplectites (COS, formerly termed "new-PCP"), have only been identified in the primitive carbonaceous chondrite Acfer 094. Meteoritic COS have isotopically heavy O compositions (delta (sup 17), O-18 = 180per mille) that point to interactions with early solar system primordial water. In this study we report mineralogical and O isotopic measurements of the Wild-2 COS assemblage. Experimental: Track #147 is a "bulbous"-type track (4600 microns long) containing 7 terminal particles. The TPs were removed from the track, embedded in epoxy, and ultramicrotomed. A JEOL 2500SE 200 keV field-emission scanning-transmission electron microscope was used to obtain quantitative elemental maps and detailed mineralogical characterization. Following TEM analysis, two thin sections of TP4 (12 microns) were analyzed for O isotopes by raster ion imaging with the JSC NanoSIMS 50L. All three O isotopes were measured simultaneously using electron multipliers. San Carlos olivine grains were used as isotopic standards. Results and Discussion: The COS in the Wild-2 track #147 TP4 sample consists of symplectically intergrown pentlandite and nanocrystalline maghemite which coexists with high-Ca pyroxene with Na and Cr (kosmochlor component). This kosmochlor component could have a nebular origin and be precursors to type II chondrules in ordinary chondrites. Yet pentlandite is not a stable phase in the nebula. The COS in Acfer 094 also consists of pentlandite, but contains magnetite [4] rather than the more oxidized maghemite observed in the Wild-2 COS. The Acfer 094 COS display heavy O isotopic compositions that are the result of sulfidization and oxidation of Fe, Ni-metal grains and sulfides by O-17- and O-18-rich water in the solar nebula or possibly on the parent body. The O isotopic composition of the Wild-2 COS, however, is indistinguishable from terrestrial, indicating it was not altered by the same primordial aqueous reservoir as the Acfer 094 COS. The alteration could have occurred on the parent body by isotopically equilibrated ice. The mineralogy and petrography of Wild-2 samples suggests an incomplete or nascent hydration process. In future work we will analyze S isotopes in the track #147 TP4 COS and search for additional COS in Stardust samples.

Nguyen, A. N.↗

Transmission Electron Microscopy of Itokawa Regolith Grains

Introduction: In a remarkable engineering achievement, the JAXA space agency successfully recovered the Hayabusa space-craft in June 2010, following a non-optimal encounter and sur-face sampling mission to asteroid 25143 Itokawa. These are the first direct samples ever obtained and returned from the surface of an asteroid. The Hayabusa samples thus present a special op-portunity to directly investigate the evolution of asteroidal sur-faces, from the development of the regolith to the study of the effects of space weathering. Here we report on our preliminary TEM measurements on two Itokawa samples. Methods: We were allocated particles RA-QD02-0125 and RA-QD02-0211. Both particles were embedded in low viscosity epoxy and thin sections were prepared using ultramicrotomy. High resolution images and electron diffraction data were ob-tained using a JEOL 2500SE 200 kV field-emission scanning-transmission electron microscope. Quantitative maps and anal-yses were obtained using a Thermo thin-window energy-dispersive x-ray (EDX) spectrometer. Results: Both particles are olivine-rich (Fo70) with μm-sized inclusions of FeS and have microstructurally complex rims. Par-ticle RA-QD02-0125 is rounded and has numerous sub-μm grains attached to its surface including FeS, albite, olivine, and rare melt droplets. Solar flare tracks have not been observed, but the particle is surrounded by a continuous ~50 nm thick, stuctur-ally disordered rim that is compositionally similar to the core of the grain. One of the surface adhering grains is pyrrhotite show-ing a S-depleted rim (~8-10 nm thick) with nanophase Fe metal grains (<5 nm) decorating the outermost surface. The pyrrhotite displays a complex superstructure in its core that is absent in the S-depleted rim. Particle RA-QD02-0211 contains solar flare particle tracks (~2x109 cm-2) and shows a structurally disordered rim ~100 nm thick. The track density corresponds to a surface exposure of ~103-104 years based on the track production rate of [1]. The dis-ordered rim is nanocrystalline with minor amorphous material between crystalline domains. Quantitative element maps show the outermost ~10 nm of the disordered rim is Si-rich. Discussion and Conclusions: Both particles record the ef-fects of space weathering processes on Itokawa. Noguchi et al. [2] proposed that the disordered rims they observed on Itokawa particles largely result from solar wind radiation damage and we arrive at a similar conclusion for the two particles we analyzed. The microstructure of the S-depleted layer on the pyrrhotite grain in RA-QD02-0125 is similar to that observed in troilite irradiated with ~1018 4 kV He+ [3, 4]. Prolonged irradiation has also been shown to disorder pyrrhotite such that the superstructure reflec-tions are lost [5].

Keller, Lindsay P.↗

Autonomous discovery of emergent morphologies in directed self-assembly of block copolymer blends

The directed self-assembly (DSA) of block copolymers (BCPs) is a powerful approach to fabricate complex nanostructure arrays, but finding morphologies that emerge with changes in polymer architecture, composition, or assembly constraints remains daunting because of the increased dimensionality of the DSA design space. Here, we demonstrate machine-guided discovery of emergent morphologies from a cylinder/lamellae BCP blend directed by a chemical grating template, conducted without direct human intervention on a synchrotron x-ray scattering beamline. This approach maps the morphology-template phase space in a fraction of the time required by manual characterization and highlights regions deserving more detailed investigation. These studies reveal localized, template-directed partitioning of coexisting lamella- and cylinder-like subdomains at the template period length scale, manifesting as previously unknown morphologies such as aligned alternating subdomains, bilayers, or a “ladder” morphology. This work underscores the pivotal role that autonomous characterization can play in advancing the paradigm of DSA.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

TRACE Input Modernization

This work presents a Tom’s Obvious Minimal Language (TOML)-based representation of input for the US Nuclear Regulatory Commission’s TRAC/RELAP Advanced Computational Engine (TRACE) thermal hydraulics code. Implemented using the Workbench Analysis Sequence Processor (WASP), the approach maps traditional TRACE input structures to a hierarchical format composed of named parameters, typed values, and native data collections. The resulting representation preserves TRACE’s existing modeling capabilities while providing a modern, structured interface for model development and management. WASP further extends TOML through a file import directive that supports modular model composition and reusable input organization. In addition, WASP provides extended array data entry convenience with various data repeat and interpolation capabilities. Examples of the new TOML syntax are provided for major TRACE input categories, including hydraulic components, heat structures, control systems, and trip logic. The TOML representation establishes a foundation for improved validation, tooling, automation, and model maintainability while remaining compatible with existing TRACE workflows. To facilitate migration to the TOML-based input format, the TRACE executable now supports conversion of native TRACE input into an intermediate JSON representation. A Python utility subsequently transforms the JSON data into an equivalent TOML model. Lastly, the TRACE executable now supports execution using TOML-formatted input.

Lefebvre, Robert A. [Oak Ridge National Laboratory↗

A composition and thickness model for lunar impact crater and basin deposits

A model was developed for determining the composition and thicknesses of continuous deposits of large lunar impact craters and basins. Results of a photogeologic study and topographic analysis of continuous deposits of the lunar crater Delisle, which support the model, show that numerous secondary craters and crater chains with concentric dunes on their uprange rims occur well within the mapped deposits. At any given radius from Delisle, the secondary craters are of equal freshness and not vastly different in size, but with increasing radius they become better defined. The upper surface of the continuous deposits reaches the level of the pre-existing mare surface well within the mapped boundary of the deposits.

Morrison, R. H.↗

Design of a Particle Beam Satellite System for Lunar Prospecting

One potential use for neutral particle beam (NPB) technology is as an active orbital probe to investigate the composition of selected locations on the lunar surface. Because the beam is narrow and can be precisely directed, the NPB probe offers possibilities for high resolution experiments that cannot be accomplished using passive techniques. Rather, the combination of both passive and active techniques can be used to provide both full-coverage mapping (passively) at low resolution (tens of kilometers) and high-resolution information for discrete locations of special interest. A preliminary study of NPB applicability for this dual-use application was recently conducted. The study was completed in Feb. 1993. A novel feature was the consideration of the use of a Russian launch vehicle (e.g., the Proton). The use of other Russian space hardware and capabilities was also encouraged. This paper describes the lunar prospector system design. Other researchers discuss the issues and opportunities involving lunar scientific experimentation using an NPB. The NPB lunar prospector utilizes a modified design of the Far Field Optics Experiment (FOX). Like the Earth-orbiting FOX, the core capability of the NPB lunar prospector will be a pulsed RF LINAC that produces a 5-MeV proton beam that is projected to the target with a 30-micro-r beam divergence and a 10-micro-r beam-pointing accuracy. Upon striking the lunar surface, the proton beam will excite characteristic radiation (e.g., X-rays) that can be sensed by one or more detectors on the NPB platform or on a separate detector satellite.

Berwald, D. H.↗

Mapping and monitoring changes in vegetation communities of Jasper Ridge, CA, using spectral fractions derived from AVIRIS images

An important application of remote sensing is to map and monitor changes over large areas of the land surface. This is particularly significant with the current interest in monitoring vegetation communities. Most of traditional methods for mapping different types of plant communities are based upon statistical classification techniques (i.e., parallel piped, nearest-neighbor, etc.) applied to uncalibrated multispectral data. Classes from these techniques are typically difficult to interpret (particularly to a field ecologist/botanist). Also, classes derived for one image can be very different from those derived from another image of the same area, making interpretation of observed temporal changes nearly impossible. More recently, neural networks have been applied to classification. Neural network classification, based upon spectral matching, is weak in dealing with spectral mixtures (a condition prevalent in images of natural surfaces). Another approach to mapping vegetation communities is based on spectral mixture analysis, which can provide a consistent framework for image interpretation. Roberts et al. (1990) mapped vegetation using the band residuals from a simple mixing model (the same spectral endmembers applied to all image pixels). Sabol et al. (1992b) and Roberts et al. (1992) used different methods to apply the most appropriate spectral endmembers to each image pixel, thereby allowing mapping of vegetation based upon the the different endmember spectra. In this paper, we describe a new approach to classification of vegetation communities based upon the spectra fractions derived from spectral mixture analysis. This approach was applied to three 1992 AVIRIS images of Jasper Ridge, California to observe seasonal changes in surface composition.

Sabol, Donald E., Jr.↗

Near-Infrared Spectroscopy and Spectral Mapping of Jupiter and the Galilean Satellites: Results from Galileo's Initial Orbit

The Near Infrared Mapping Spectrometer performed spectral studies of Jupiter and the Galilean satellites during the June 1996 perijove pass of the Galileo spacecraft. Spectra fora5-micrometer hotspot on Jupiter are consistent with the absence of a significant watercloud above 8 bars and with a depletion of water compared to that predicted for solar composition, corroborating results from the Galileo probe. Great Red Spot (GRS) spectral images show that parts of this feature extend upward to 240 millibars, although considerable altitude-dependent structure is found within it. A ring of dense clouds surrounds the GRS and is lower than it by 3 to 7 kilometers. Spectra of Callisto and Ganymede reveal a feature at 4.25 micrometers, attributed to the presence of hydrated minerals or possibly carbon dioxide on their surfaces. Spectra of Europa's high latitudes imply that fine-grained water frost overlies larger grains. Several active volcanic regions were found on lo, with temperatures of 420 to 620 kelvin and projected areas of 5 to 70 square kilometers.

Carlson, R.↗