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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,333 records · Page 74
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Research on Orbital Plasma-Electrodynamics (ROPE)

Since the development of probe theory by Langmuir and Blodgett, the problem of current collection by a charged spherically or cylindrically symmetric body has been investigated by a number of authors. This paper overviews the development of a fully three-dimensional particle simulation code which can be used to understand the physics of current collection in three dimensions and can be used to analyze data resulting from the future tethered satellite system (TSS). According to the TSS configurations, two types of particle simulation models were constructed: a simple particle simulation (SIPS) and a super particle simulation (SUPS). The models study the electron transient response and its asymptotic behavior around a three dimensional, highly biased satellite. The potential distribution surrounding the satellite is determined by solving Laplace's equation in the SIPS model and by solving Poisson's equation in the SUPS model. Thus, the potential distribution in space is independent of the density distribution of the particles in the SUPS model but it does depend on the density distribution of the particles in the SUPS model. The evolution of the potential distribution in the SUPS model is described. When the spherical satellite is charged to a highly positive potential and immersed in a plasma with a uniform magnetic field, the formation of an electron torus in the equatorial plane (the plane in perpendicular to the magnetic field) and elongation of the torus along the magnetic field are found in both the SIPS and the SUPS models but the shape of the torus is different. The areas of high potential that exist in the polar regions in the SUPS model exaggerate the elongation of the electron torus along the magnetic field. The current collected by the satellite for different magentic field strengths is investigated in both models. Due to the nonlinear effects present in SUPS, the oscillating phenomenon of the current collection curve during the first 10 plasma periods can be seen (this does not appear in SIPS). From the parametric studies, it appears that the oscillating phenomenon of the current collection curve occurs only when the magnetic field strength is less than 0.2 gauss for the present model.

Wu, S. T.↗
NASA NTRS1995

Spatial and Temporal Distribution of Ion Engine Accelerator Grid Erosion

Structural failure of the accelerator grid in two-grid ion optics due to charge exchange ion erosion is considered one of the dominant failure modes for ion engines. A detailed examination of three accelerator grids used in long duration tests of inert gas ion thrusters was undertaken to characterize the radial mass loss distribution, the local distribution of mass loss in the erosion pattern and how it varies as the pattern evolves. The results show significant broadening of the radial profile compared to what is expected in space with significant variations from grid to grid. The local distribution of mass loss and how it varies with increasing total mass loss in the erosion pattern was also found to differ considerably among the three grids. The results indicate that the details of the erosion geometry cannot be ignored when generalizing test results or modeling grid failure to calculate useful engine service life.

Ion Engine↗
DOE OSTI2025

Dimensional Control in Phase-Pure Coevaporated Quasi-2D Ruddlesden–Popper Structures

Fast, uncontrolled crystallization with several competing pathways makes solution-processing of phase-pure quasi-two-dimensional (quasi-2D) metal halide Ruddlesden–Popper thin films challenging. Typically, solution-processing results in the formation of different structural phases with varying dimensionality ranging from 2D, to quasi-2D, and 3D, introducing bandgap disorder and inhibiting charge transport. In this work, we eliminate interactions between precursor salts and solvents by using controlled thermal coevaporation to grow quasi-2D thin films that show high phase purity and narrow phase distribution. We study the structural landscape using synchrotron-based X-ray scattering and charge-carrier dynamics using ultrafast pump–probe spectroscopy. We then demonstrate a strategy to control the crystallographic phase of the film through phosphonic acid-based surface modification. We use density functional theory to study the interactions between propylphosphonic acid and the organic precursors and find that the interactions of loosely bound phosphonic acid molecules with evaporated precursors, followed by the migration of phosphonic acids through the deposited thin film, dictate the film structure between 2D and quasi-2D phases. These findings introduce new solvent-free methods for the fabrication of phase-pure quasi-2D Ruddlesden–Popper thin films and control phase selectivity across different dimensional (2D and quasi-2D) structures.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Dual Tunability for Uncatalyzed N‐Alkylation of Primary Amines Enabled by Plasma‐Microdroplet Fusion

Abstract The fusion of non‐thermal plasma with charged microdroplets facilitates catalyst‐free N‐alkylation for a variety of primary amines, without halide salt biproduct generation. Significant reaction enhancement (up to >200×) is observed over microdroplet reactions generated from electrospray. This enhancement for the plasma‐microdroplet system is attributed to the combined effects of energetic collisions and the presence of reactive oxygen species (ROS). The ROS (e.g., O 2 ⋅ − ) act as a proton sink to increase abundance of free neutral amines in the charged microdroplet environment. The effect of ROS on N‐alkylation is confirmed through three unique experiments: (i) utilization of radical scavenging reagent, (ii) characterization of internal energy distribution, and (iii) controls performed without plasma, which lacked reaction acceleration. Establishing plasma discharge in the wake of charged microdroplets as a green synthetic methodology overcomes two major challenges within conventional gas‐phase plasma chemistry, including the lack of selectivity and product scale‐up. Both limitations are overcome here, where dual tunability is achieved by controlling reagent concentration and residence time in the microdroplet environment, affording single or double N‐alkylated products. Products are readily collected yielding milligram quantities in eight hours. These results showcase a novel synthetic strategy that represents a straightforward and sustainable C−N bond‐forming process.

Chemistry↗
NASA NTRS1987

Observations of spatial distribution of energetic O(3+), O(4+), and O(5+) ions in the magnetosphere

L profiles of ions with intermediate charge states (O(5+), O(4+), and O(3+) are presented and compared with those of O(+), O(2+), and O(6+) ions in order to determine their possible sources of origin. The L profiles exhibit broad maxima located at L = 6-7 for O(3+) and O(4+) and L = 7-8 for O(5+) ions during periods of low to medium geomagnetic activity. With increasing Kp, the flux versus L distributions extend further earthward and the maxima move to slightly lower L values. While the flux decrease earthward of the maximum is very steep, the gradual decrease outward of the maximum becomes flatter with increasing charge state. These results suggest that O(3+), O(4+), and O(5+) ions are produced predominantly by charge exchange processes, and that the O(4+) and O(5+) ions are produced from the solar wind-originating O(6+).

Kremser, G.↗
DOE OSTI2023

Fast Charging Infrastructure for Electrifying Road Trips to and from National Parks in the Western United States

National parks in the Western United States draw over 80 million visitors every year, and most visitors rely on personal cars for their road trips (or long-distance travels). Travel to national parks represents distinct travel demand, as they are typically located in remote areas necessitating long-distance trips. This study investigates the quantity and locations of on-route fast charging infrastructure needed by 2030 to enable seamless travel to/from national parks using electric vehicles in seven target states in the region, employing unprecedented high-resolution spatial and temporal analysis. We find that the required number of fast charging ports for on-route charging infrastructure ranges from 1,200 to 22,000, depending on different assumptions of key input parameters - vehicle electrification rate, charging behavior, average gap between charging stations, port utilization rate, and towing trailers. Our analysis also indicates that electrical load for on-route fast charging infrastructure would peak in the afternoon, in the range of 70-400 MW, varying with the key input parameters. This study illustrates how different input parameters result in different degrees of impact on various aspects of charging infrastructure. We also examine the characteristics of projected charging infrastructure in terms of land use type, relationship with traffic volume, size of stations, and other variables.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Development of planar P-type point contact germanium detectors for low-mass dark matter searches

The detection of low-energy deposition in the range of sub-eV through ionization using germanium (Ge) with a bandgap of ~ 0.7 eV requires internal amplification of the charge signal. This can be achieved through high electric field that accelerates charge carriers, which can then generate more charge carriers. The minimum electric field required to generate internal charge amplification is derived for different temperatures. We report the development of a planar point contact Ge detector in terms of its fabrication and the measurements of its leakage current and capacitance as a function of applied bias voltage. With the determination of the measured depletion voltage, the field distribution is calculated using GeFiCa, which predicts that the required electric field for internal charge amplification can be achieved in proximity to the point contact. The energy response to an Am-241 source is characterized and discussed. We conclude that such a detector with internal charge amplification can be used to search for low-mass dark matter.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1980

Electric power processing, distribution, management and energy storage

Power distribution subsystems are required for three elements of the SPS program: (1) orbiting satellite, (2) ground rectenna, and (3) Electric Orbiting Transfer Vehicle (EOTV). Power distribution subsystems receive electrical power from the energy conversion subsystem and provide the power busses rotary power transfer devices, switchgear, power processing, energy storage, and power management required to deliver control, high voltage plasma interactions, electric thruster interactions, and spacecraft charging of the SPS and the EOTV are also included as part of the power distribution subsystem design.

Giudici, R. J.↗
DOE OSTI2023

Physics basis for the Wisconsin HTS Axisymmetric Mirror (WHAM)

The Wisconsin high-temperature superconductor axisymmetric mirror experiment (WHAM) will be a high-field platform for prototyping technologies, validating interchange stabilization techniques and benchmarking numerical code performance, enabling the next step up to reactor parameters. A detailed overview of the experimental apparatus and its various subsystems is presented. WHAM will use electron cyclotron heating to ionize and build a dense target plasma for neutral beam injection of fast ions, stabilized by edge-biased sheared flow. At 25 keV injection energies, charge exchange dominates over impact ionization and limits the effectiveness of neutral beam injection fuelling. This paper outlines an iterative technique for self-consistently predicting the neutral beam driven anisotropic ion distribution and its role in the finite beta equilibrium. Beginning with recent work by Egedal et al. ( Nucl. Fusion , vol. 62, no. 12, 2022, p. 126053) on the WHAM geometry, we detail how the FIDASIM code is used to model the charge exchange sources and sinks in the distribution function, and both are combined with an anisotropic magnetohydrodynamic equilibrium solver method to self-consistently reach an equilibrium. We compare this with recent results using the CQL3D code adapted for the mirror geometry, which includes the high-harmonic fast wave heating of fast ions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Solvent-mediated carboxylic acid diammonium spacer for synthesizing FA-based 2D Dion–Jacobson perovskites toward efficient solar cells

Two-dimensional (2D) perovskites are promising for photovoltaic applications due to their outstanding optical properties and better environmental stability compared to three-dimensional (3D) perovskites. Unlike 2D Ruddlesden–Popper (RP) perovskites, which use monovalent ammonium spacers, Dion–Jacobson (DJ) perovskites employ divalent organic spacers that enhance structural stability by mitigating weak van der Waals interactions. However, the random phase distribution and disorder crystal orientation in 2D DJ perovskites create deep quantum wells, hindering charge transfer and reducing short-circuit current density (J SC ) and overall photovoltaic performance. This study introduces an organic diammonium, 1,4-butanediamine diacetate (BDAAc 2 ), to replace the traditional halide spacer 1,4-butanediamine iodide (BDADI 2 ). This substitution regulates perovskites crystallization dynamics, reducing compositional disorder and random phase distribution, thus improving the quality of the perovskite films. The robust coordination interactions between BDAAc 2 and the perovskite inorganic framework lead to an ordered [PbX 6 ] 4− arrangement, suppressing the formation of complex intermediate phases and significantly enhancing δ phase crystallinity in the intermediate film. This results in a high yield of high-quality α phase. Consequently, the resulting 2D DJ perovskite solar cells based on BDAFA 3 Pb 4 (I 0.9 Br 0.1 ) 13 achieve a higher power conversion efficiency of 16.41% and an elevated J SC of 20.46 mA cm −2 .

14 SOLAR ENERGY↗
DOE OSTI2021

Holistic Numerical Calibration of the iMESA Electrostatic Analyzer

A drifted Maxwellian velocity distribution is the most common model used to interpret the data from low-energy charged-particle instruments onboard spacecraft that are used to investigate the ambient plasma environment in the low Earth orbit (LEO). An original method is presented for determining the flow parameters (density, temperature, and flow energy) of such a distribution from the output of the integrated miniaturized electrostatic analyzer, which has been successfully flown on several LEO missions. Rather than attempting to deconvolve from the on-orbit data the analyzer’s response to an ideal, monoenergetic input, numerical simulation is used to predict and parameterize the response of the device to an input distribution that includes an isotropic, non-zero temperature, yielding a straightforward method for extracting the flow parameters from the spacecraft data. The method is computationally simple enough to be incorporated into a robust algorithm suitable for rapid batch processing or real-time analysis of data.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Enabling high rate capability, low internal resistance, and excellent cyclability for vanadium redox flow batteries utilizing ultrafast laser-structured graphite felt

The electrochemical performance of vanadium redox flow batteries (VRFBs) was enhanced via laser-patterned graphite felt (GF) electrodes. The laser-structured GF electrodes engineered via preparing a series of well-ordered microscopic channel structures with an average width of 200 μm, creating a three-dimensional carbon framework. The ultrafast laser patterning increased the porosity by 10%, as compared to pristine electrode. The analysis of the overpotential distribution using electrochemical impedance spectroscopy revealed that the electrode polarization involving charge transfer and diffusion resistance is strongly alleviated with the aid of carbon micro-perforation. The advanced design of laser-structured GF electrode also exhibits high rate capability, low internal resistance, and excellent cyclability. The improved performance was attributed to the synergistic effect involving (i) high electrochemically active surface area for rapid electrochemical reactions (i.e., V(II)/V(III) and V(IV)/V(V) redox couples) and (ii) excellent transport properties for facile electron/ion/species transport. The micro-scale channels created with the laser-ablation technique act as capillary structures and enabled homogeneous and rapid wetting of GF electrodes as formulated with the classical Washburn equation. The VRFB equipped with the laser-structured GF electrodes delivered a high discharge capacity with exceptional capacity retention upon extended cycling (>84.9%). In conclusion, accordingly, the design of laser-structured electrode paves the pathway towards finely tuning the electrode internal microstructure for improved cyclability, durability, and capacity retention in various electrochemical energy storage/conversion devices (e.g. all-vanadium redox flow batteries).

25 ENERGY STORAGE↗
DOE OSTI2026

A comparison of the dielectric function for p-point water models

We compute the longitudinal dielectric function ɛl(k) for p-point water models, p = 3 (SPC/E, TIP3P), p = 4 (TIP4P-EW, OPC), and p = 5 (TIP5P-E) from the charge–charge fluctuation function SZZ(k), obtained from two methods: average of the charge in k-space (method:sum) and from the pair distribution function in Fourier space (method:integral). The latter requires a continuation to small k-values, which we thoroughly discuss. We conclude with a detailed comparison of the longitudinal dielectric function for the different p-point models and its main characteristics: small k and large k limits, position of the poles, and its (complex) zeros.

Shevy, Noah [Ames National Laboratory, Department ↗
NASA NTRS1971

Thin electrostatically self-focusing electron streams.

Study of 30 to 380 microampere, 50 to 550 V, 1 to 2 mm, electrostatically self-focusing electron streams (50 cm long) drifting through mercury vapor (at 50 microtorr to 2 millitorr) in a tube with a radius of 6.6 cm. The inside surface of the tube is coated with a transparent layer whose resistivity is 50 ohm-cm per centimeter. In order to determine the charged-particle densities and the potential profile in and around the beam without disturbing the system, a multigrid electrostatic charged particle energy analyzer was used to study separately the energy distributions of both ions and electrons ejected radially from the beam. The results show two energy groupings for electrons. The energy distribution of the high-energy group is produced by ionizing collisions between beam electrons and neutral gas atoms; a group of flow-energy electrons becomes trapped in the potential well within and around the beam, subsequently escaping by collisional mechanisms.

Mccorkle, R. A.↗
NASA NTRS1984

Interactions between satellites and plasma

The interactions of a spacecraft with the surrounding, streaming plasma were determined by the following effects: the fade out of the plasma in the wake of the probe, the emission of photoelectrons and secondary electrons, the differential charging of the surface of the probe, and a spatial potential distribution in the vicinity of the space probe. These effects and their importance are discussed and following plasma conditions are considered: (1) geostationary satellite orbits; (2) in the solar wind (HELIOS mission); and (3) in the ionosphere at an altitude of 250 km (the projected OSV on Spacelab). The fundamental models are reviewed.

Isensee, U.↗
NASA NTRS1987

The effect of a sector boundary crossing on the cometary dust tail

Recognizing that gains in the cometary dust tail are electrically charged, the effect of an interplanetary sector boundary crossing on grain distribution is studied. Specifically, Halley's comet around the time of encounter by the GIOTTO and VEGA 1 and 2 spacecraft in March 1986 is considered. The smallest dust particles are strongly effected, and the projection of their distributions in a plane containing the sun-comet axis and normal to the orbital plane shows a wavy appearance. Also, since reversals in the interplanetary magnetic field occur with a periodicity of 5 to 10 days, the spacecraft, which follow 3 to 4 days apart, are likely to encounter entirely different dust distributions at the lower end of the mass spectrum.

Horanyi, M.↗
NASA NTRS1990

Ensemble Monte Carlo characterization of graded Al(x)Ga(1-x)As heterojunction barriers

The current-voltage characteristics of graded Al(x)Ga(1-x)As heterojunction barriers were investigated using a self-consistent ensemble Monte Carlo method. Results are presented for barriers with two doping levels (10 to the 15th/cu cm and 10 to the 17th/cu cm) and two barrier heights (100 and 265 meV). It was found that the lower barrier structure exhibited little rectification at room temperature at both doping levels, while the higher barrier exhibited considerable rectification. The structures with the lower doping value exhibited a smaller current in both forward and reverse regions, due to space-charge effect. The results of studies of the energy and momentum distribution functions along the barrier indicate that the assumption of drifted Maxwellian distribution used in energy-momentum models is not justified for Gamma valley electrons.

Kamoua, R.↗
NASA NTRS1992

Hypervelocity impact effects on solar cells

One of the space hazards of concern is the problem of natural matter and space debris impacting spacecraft. In addition to mechanical damage, impact velocities greater than 5 km/sec can produce shock induced ionization effects with resultant surface charging and complex chemical interactions. The upper limit of the velocity distribution for these particles is on the order of 70 km/sec. The second source of particulate matter is due to the presence of man and the machinery needed to place satellites in orbit. This 'man made' component of the space debris consists of waste, rocket exhaust, and debris caused by satellite break-up. Most of the particles are small. However as the size increases, debris purposefully thrown overboard such as garbage and human waste, combined with paint chips, plastic, wire fragments, bolts, etc., become formidable hazards which completely dominate the distribution function for some orbits. These larger fragments can produce penetration and spalling of the thick metallic structures associated with spacecraft. The particles most often encountered are aluminum oxide, associated with fuel residue, and paint chips. These debris types can have a wide range of particle sizes. It has been stated that the design of spacecraft will have to take the debris evolution into account and provide additional suitable armor for key components in the near future. The purpose of this work was to subject samples from solar power arrays, one of the key components of any spacecraft, to a debris flux typical of what might be found in space, and measure the degradation of the power panels after impact.

Rose, M. Frank↗