Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Waste management”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,333 records · Page 74

Hanford Soil Inventory Model (SIM-v2) Calculated Radionuclide Inventory of Direct Liquid Discharges to Soil in the Hanford Site's 200 Areas

The Hanford soil inventory model (SIM) provides the basic radionuclide and chemical soil inventories from historical liquid discharges to about 400 sites at the Hanford Site. Although liquid discharge inventory for chemicals is part of the SIM implementation, only radionuclide inventory is discussed here since the focus of this ECF is on providing radionuclides inputs for the composite analysis (CA) per DOE Order 435.1, Radioactive Waste Management, requirements. Furthermore, discharged inventories are only estimated for the soluble portions of the liquid discharges to waste sites/waste management areas located on the 200 Area of the Hanford Site (Central Plateau).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Nuclear Fuel Cycle System Simulation Tool Based on High-Fidelity Component Modeling

The DOE is currently directing extensive research into developing fuel cycle technologies that will enable the safe, secure, economic, and sustainable expansion of nuclear energy. The task is formidable considering the numerous fuel cycle options, the large dynamic systems that each represent, and the necessity to accurately predict their behavior. The path to successfully develop and implement an advanced fuel cycle is highly dependent on the modeling capabilities and simulation tools available for performing useful relevant analysis to assist stakeholders in decision making. Therefore a high-fidelity fuel cycle simulation tool that performs system analysis, including uncertainty quantification and optimization was developed. The resulting simulator also includes the capability to calculate environmental impact measures for individual components and the system. An integrated system method and analysis approach that provides consistent and comprehensive evaluations of advanced fuel cycles was developed. A general approach was utilized allowing for the system to be modified in order to provide analysis for other systems with similar attributes. By utilizing this approach, the framework for simulating many different fuel cycle options is provided. Two example fuel cycle configurations were developed to take advantage of used fuel recycling and transmutation capabilities in waste management scenarios leading to minimized waste inventories.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Corrective Action Decision Document/Corrective Action Plan for Corrective Action Unit 577: Area 5 Chromium Containing Waste Disposal Cells, Nevada National Security Site, Nevada

This Corrective Action Decision Document/Corrective Action Plan (CADD/CAP) is for Corrective Action Unit (CAU) 577, “Area 5 Chromium Containing Waste Disposal Cells,” which is located in Area 5 of the Nevada National Security Site (NNSS). CAU 577 includes five low-level waste cells at the Area 5 Radioactive Waste Management Site (RWMS) where buried waste received from Nuclear Fuel Services, Inc. (NFS), was subsequently determined to contain chromium that exceeded the Toxicity Characteristic Leaching Procedure regulatory limit, which would require the waste to carry hazardous waste code D007. To resolve issues related to this alleged violation of hazardous waste regulations, a Settlement Agreement was executed between the Nevada Division of Environmental Protection (NDEP) and the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office on April 25, 2019, which identified agreed-upon mitigation measures. The Settlement Agreement required that the chromium-containing waste received from NFS would be addressed following the closure process laid out in the Federal Facility Agreement and Consent Order (FFACO).

54 ENVIRONMENTAL SCIENCES↗

Mobile phone collection, reuse and recycling in the UK

Highlights: > We characterized the key features of the voluntary UK mobile phone takeback network via a survey. > We identified 3 flows: information; product (handsets and accessories); and incentives. > There has been a significant rise in the number of UK takeback schemes since 1997. > Most returned handsets are low quality; little data exists on quantities of mobile phones collected. > Takeback schemes increasingly divert EoL mobile phones from landfill and enable reuse/recycling. - Abstract: Mobile phones are the most ubiquitous electronic product on the globe. They have relatively short lifecycles and because of their (perceived) in-built obsolescence, discarded mobile phones represent a significant and growing problem with respect to waste electrical and electronic equipment (WEEE). An emerging and increasingly important issue for industry is the shortage of key metals, especially the types of metals found in mobile phones, and hence the primary aim of this timely study was to assess and evaluate the voluntary mobile phone takeback network in the UK. The study has characterised the information, product and incentives flows in the voluntary UK mobile phone takeback network and reviewed the merits and demerits of the incentives offered. A survey of the activities of the voluntary mobile phone takeback schemes was undertaken in 2008 to: identify and evaluate the takeback schemes operating in the UK; determine the target groups from whom handsets are collected; and assess the collection, promotion and advertising methods used by the schemes. In addition, the survey sought to identify and critically evaluate the incentives offered by the takeback schemes, evaluate their ease and convenience of use; and determine the types, qualities and quantities of mobile phones they collect. The study has established that the UK voluntary mobile phone takeback network can be characterised as three distinctive flows: information flow; product flow (handsets and related accessories); and incentives flow. Over 100 voluntary schemes offering online takeback of mobile phone handsets were identified. The schemes are operated by manufacturers, retailers, mobile phone network service operators, charities and by mobile phone reuse, recycling and refurbishing companies. The latter two scheme categories offer the highest level of convenience and ease of use to their customers. Approximately 83% of the schemes are either for-profit/commercial-oriented and/or operate to raise funds for charities. The voluntary schemes use various methods to collect mobile phones from consumers, including postal services, courier and in-store. The majority of schemes utilise and finance pre-paid postage to collect handsets. Incentives offered by the takeback schemes include monetary payments, donation to charity and entry into prize draws. Consumers from whom handsets and related equipment are collected include individuals, businesses, schools, colleges, universities, charities and clubs with some schemes specialising on collecting handsets from one target group. The majority (84.3%) of voluntary schemes did not provide information on their websites about the quantities of mobile phones they collect. The operations of UK takeback schemes are decentralised in nature. Comparisons are made between the UK's decentralised collection system versus Australia's centralised network for collection of mobile phones. The significant principal conclusions from the study are: there has been a significant rise in the number of takeback schemes operating in the UK since the initial scheme was launched in 1997; the majority of returned handsets seem to be of low quality; and there is very little available information on the quantities of mobile phones collected by the various schemes. Irrespective of their financial motives, UK takeback schemes increasingly play an important role in sustainable waste management by diverting EoL mobile phones from landfills and encouraging reuse and recycling. Recommendations for future actions to improve the management of end-of-life mobile phone handsets and related accessories are made.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Finishing Strong in 2011: The Recovery Act at Work at Savannah River Site

American Recovery and Reinvestment Act's highlights and accomplishments for 2011 projects. Covers the latest technology and robotics used for waste management. This video is an overview of the success ARRA brought to the Savannah River Site, the environment, the econonmy, and the surrounding communities.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Sr immobilization in irradiated Portland cement paste exposed to carbonation

Cement based materials are widely used as binding matrices for radionuclides in low and intermediate level waste management applications. We studied the effect of irradiation and carbonation under atmospheric condition on the leaching of Sr from Portland cement paste. Samples were exposed to gamma irradiation or subjected to thermal treatment under either inert or atmospheric conditions. Leaching tests were performed and supplemented by post-leaching characterization including local chemical analysis (LA-ICPMS) crystallographic analysis (XRD), and EPMA imaging. The combination of these methods enabled us to link between the crystallography, texture and composition of the treated samples and their ability to retain Sr ions. Results show that carbonation was the main factor determining the retention of Sr ions, whereas irradiation did not have a significant effect. Moreover, carbonation has a positive effect on the retention of Sr ions in the matrix with the formation of a carbonated zone.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A comparative assessment of waste incinerators in the UK

Highlights: • We evaluate operational municipal solid waste incinerators in the UK. • The supply chain of four case study plants are examined and compared in detail. • Technical, financial and operational data has been gathered for the four plants. • We suggest the best business practices for waste incinerators. • Appropriate strategy choices are the major difficulties for waste to energy plants. - Abstract: The uptake in Europe of Energy from Waste (EfW) incinerator plants has increased rapidly in recent years. In the UK, 25 municipal waste incinerators with energy recovery are now in operation; however, their waste supply chains and business practices vary significantly. With over a hundred more plant developments being considered it is important to establish best business practices for ensuring efficient environmental and operational performance. By reviewing the 25 plants we identify four suitable case study plants to compare technologies (moving grate, fluidised bed and rotary kiln), plant economics and operations. Using data collected from annual reports and through interviews and site visits we provide recommendations for improving the supply chain for waste incinerators and highlight the current issues and challenges faced by the industry. We find that plants using moving grate have a high availability of 87–92%. However, compared to the fluidised bed and rotary kiln, quantities of bottom ash and emissions of hydrogen chloride and carbon monoxide are high. The uptake of integrated recycling practices, combined heat and power, and post incineration non-ferrous metal collections needs to be increased among EfW incinerators in the UK. We conclude that one of the major difficulties encountered by waste facilities is the appropriate selection of technology, capacity, site, waste suppliers and heat consumers. This study will be of particular value to EfW plant developers, government authorities and researchers working within the sector of waste management.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The effect of gender and age structure on municipal waste generation in Poland

Highlights: • An effect of gender and age structure on municipal waste generation was presented. • The waste accumulation index is influenced by a number of unemployed women. • Greater share of women in society contributes to greater waste production. • A model describing the analyzed dependences was determined. - Abstract: In this study the effect of gender and age structure on municipal waste generation was investigated. The data from 10-year period, from 2001 to 2010 year, were taken into consideration. The following parameters of gender and age structure were analyzed: men and woman quantity, female to male ratio, number of working, pre-working and post-working age men/women, number of unemployed men/women. The results have showed a strong correlation of annual per capita waste generation rate with number of unemployed women (r = 0.70) and female to male ratio (r = 0.81). This indicates that waste generation rate is more depended on ratio of men and women that on quantitative size of each group. Using the regression analysis a model describing the dependence between female to male ratio, number of unemployed woman and waste quantity was determined. The model explains 70% of waste quantity variation. Obtained results can be used both to improve waste management and to a fuller understanding of gender behavior.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Combining of different data pools for calculating a reliable POD for real defects

Real defects are essential for the evaluation of the reliability of non destructive testing (NDT) methods, especially in relation to the integrity of components. But in most of the cases the amount of available real defects is not sufficient to evaluate the system. Model-assisted and transfer functions are one way to handle that challenge. This study is focused on a combination of different data pools to create a sufficient amount of data for the reliability estimation. A widespread approach for calculating the Probability of Detection (POD) was used on a radiographic testing (RT) method. The highest contrast to noise ratio (CNR) of each indication is usually selected as the signal in the 'â vs. a' (signal-response) approach for RT. By combining real and artificial defects (flat bottom holes, side drill holes, flat bottom squares, notches, etc) in RT the highest signals are close to each other, but the process of creating and evaluating real defects is much more complex. The solution is seen in the combination of real and artificial data using a weighted least square approach. The weights for real or artificial data were based on the importance, the value and the different detection behavior of the different data. For comparison, the alternative combination through the Bayesian Updating was also applied. As verification, a data pool with a large amount of real data was available. In an advanced approach for evaluating the digital RT data, the size of the indication (perpendicular to the X-ray beam) was introduced as additional information. The signal now consists of the CNR and the area of the indication. The detectability is changing depending on the area of the indication, a fact that was ignored in the previous POD calculations for RT. This points out that a weighted least square approach to pool the data might no longer be adequate. The Bayesian Updating of the estimated parameters of the relationship between the signal field (the area of the indication) and the geometry of the defects is seen as the appropriate model to combine the different defect types in a useful and meaningful way. This work was carried out together with the Finnish company for spent nuclear fuel and waste management - Posiva Oy. The digital RT is one of the NDT methods that might be used for the inspection of the weld of the copper canister to be used for the spent nuclear fuel in the Scandinavian concept of final disposal.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Knowledge-based fault diagnosis system for refuse collection vehicle

The refuse collection vehicle is manufactured by local vehicle body manufacturer. Currently; the company supplied six model of the waste compactor truck to the local authority as well as waste management company. The company is facing difficulty to acquire the knowledge from the expert when the expert is absence. To solve the problem, the knowledge from the expert can be stored in the expert system. The expert system is able to provide necessary support to the company when the expert is not available. The implementation of the process and tool is able to be standardize and more accurate. The knowledge that input to the expert system is based on design guidelines and experience from the expert. This project highlighted another application on knowledge-based system (KBS) approached in trouble shooting of the refuse collection vehicle production process. The main aim of the research is to develop a novel expert fault diagnosis system framework for the refuse collection vehicle.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterisation of imperial college reactor centre legacy waste using gamma-ray spectrometry

Waste characterisation is a principal component in waste management strategy. The characterisation includes identification of chemical, physical and radiochemical parameters of radioactive waste. Failure to determine specific waste properties may result in sentencing waste packages which are not compliant with the regulation of long term storage or disposal. This project involved measurement of intensity and energy of gamma photons which may be emitted by radioactive waste generated during decommissioning of Imperial College Reactor Centre (ICRC). The measurement will use High Purity Germanium (HPGe) as Gamma-ray detector and ISOTOPIC-32 V4.1 as analyser. In order to ensure the measurements provide reliable results, two quality control (QC) measurements using difference matrices have been conducted. The results from QC measurements were used to determine the accuracy of the ISOTOPIC software.

07 ISOTOPE AND RADIATION SOURCES↗

A priori precision estimation for neutron triples counting

The nondestructive assay of Plutonium bearing items for criticality, safety, security, safeguards, inventory balance, process control, waste management and compliance is often undertaken using correlated neutron counting. In particular Multiplicity Shift Register analysis allows one to extract autocorrelation parameters from the pulse train which can, within the framework of a simple interpretational model, be related to the effective {sup 240}Pu spontaneous fission mass present. The effective {sup 240}Pu mass is a weighted sum of the {sup 238}Pu, {sup 240}Pu and {sup 242}Pu masses so if the relative isotopic composition of the Pu can be established from the measured {sup 240}Pu effective mass one can estimate the total Pu mass and also the masses of the individual isotopes, example the fissile species {sup 239}Pu and {sup 241}Pu. In multiplicity counting three counting rates are obtained. These are the Singles, Doubles and Triples rates. The Singles rate is just the gross, totals or trigger rate. The Doubles and Triples rates are calculated from factorial moments of the observed signal triggered neutron multiplicity distributions following spontaneous fission in the item and can be thought of as the rate of observed coincident pairs and coincident triplets on the pulse train. Coincident events come about because the spontaneous fission and induced fission chains taking place in the item result in bursts of neutrons. These remain time correlated during the detection process and so retain information, through the burst size distribution, about the Pu content. In designing and assessing the performance of a detector system to meet a given goal it is necessary to make a priori estimates of the counting precision for all three kinds of rates. This is non-trivial because the counting does not obey the familiar rules of a Poissonian counting experiment because the pulse train has time correlated events on it and the train is sampled by event triggered gates that may overlap. For Singles and Doubles simple approximate analytical empirical rules for how to estimate the variance have been developed guided by theory and refined by experiment. However, for Triples no equivalent rules have been put forward and tested until now. In this work we propose an analytical expression, the CSH relation, for the variance on the Triples count and exercise it against experimental data gathered for Pu items measured in the Los Alamos National Laboratory's Epithermal Neutron Multiplicity Counter (ENMC). Preliminary results are encouraging and reasonable agreement with observation, considered fit for scoping studies, is obtained. We have also looked at the behavior using Monte Carlo simulations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Phase 1 Characterization sampling and analysis plan West Valley demonstration project.

The Phase 1 Characterization Sampling and Analysis Plan (CSAP) provides details about environmental data collection that will be taking place to support Phase 1 decommissioning activities described in the Phase 1 Decommissioning Plan for the West Valley Demonstration Project, Revision 2 (Phase I DP; DOE 2009). The four primary purposes of CSAP data collection are: (1) pre-design data collection, (2) remedial support, (3) post-remediation status documentation, and (4) Phase 2 decision-making support. Data collection to support these four main objectives is organized into two distinct data collection efforts. The first is data collection that will take place prior to the initiation of significant Phase 1 decommissioning activities (e.g., the Waste Management Area [WMA] 1 and WMA 2 excavations). The second is data collection that will occur during and immediately after environmental remediation in support of remediation activities. Both data collection efforts have a set of well-defined objectives that encompass the data needs of the four main CSAP data collection purposes detailed in the CSAP. The main body of the CSAP describes the overall data collection strategies that will be used to satisfy data collection objectives. The details of pre-remediation data collection are organized by WMA. The CSAP contains an appendix for each WMA that describes the details of WMA-specific pre-remediation data collection activities. The CSAP is intended to expand upon the data collection requirements identified in the Phase 1 Decommissioning Plan. The CSAP is intended to tightly integrate with the Phase 1 Final Status Survey Plan (FSSP). Data collection described by the CSAP is consistent with the FSSP where appropriate and to the extent possible.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Request for a Class 1 Permit Modification to the Los Alamos National Laboratory (LANL) Hazardous Waste Facility Permit, EPA ID No. NM0890010515

The following submittal has been prepared by the U.S. Department of Energy and Los Alamos National Security, LLC (collectively the Permittees) to request a modification to the November 2010 Los Alamos National Laboratory (LANL) Hazardous Waste Facility Permit (Permit). This modification has been prepared as a Class 1 permit modification requiring prior approval by the New Mexico Environment Department-Hazardous Waste Bureau (NMEDHWB) (also known as a Class 1* permit modification) as described in the New Mexico Administrative Code, Title 20, Chapter 4, Part 1 (20.4.1.900 NMAC) [incorporating Code of Federal Regulations (CFR), Title 40 §§ 270.42 (a) ]. LANL’s Environmental Protection Agency (EPA) identification number is EPA ID No. NM0890010515. The permit modification includes revisions to Table K-1, SWMUs (Solid Waste Management Units) and AOCs (Areas of Concern) Requiring Corrective Action, which is included in Permit Attachment K, Listings of SWMUs and AOCs. The following summary describes the proposed modification and rationale behind the modification and contains a revised version of the relevant page of Table K-1 incorporating the modification (Attachment 1). The Permittees request that the revised Table K-1 be included in the Permit by the NMED-HWB upon approval of this permit modification request.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Request for a Class 1 Permit Modification to the Los Alamos National Laboratory (LANL) Hazardous Waste Facility Permit, Attachment K EPA ID No. NM0890010515 (Rev. 1)

The following submittal has been prepared by the U.S. Department of Energy and Los Alamos National Security, LLC (collectively the Permittees) to request a modification to the November 2010 Los Alamos National Laboratory (LANL) Hazardous Waste Facility Permit (Permit). This modification has been prepared as a Class 1 permit modification requiring prior approval by the New Mexico Environment Department-Hazardous Waste Bureau (NMEDHWB) (also known as a Class 1 * permit modification) as described in the New Mexico Administrative Code, Title 20, Chapter 4, Part 1 (20.4.1.900 NMAC) [incorporating Code of Federal Regulations (CFR), Title 40 §§ 270.42 (a) ]. LANL's Environmental Protection Agency (EPA) identification number is EPA ID No. NM0890010515. The permit modification includes revisions to Table K-l , SWMUs (Solid Waste Management Units) and AOCs (Areas of Concern) Requiring Corrective Action, which is included in Permit Attachment K, Listings ofSWMUs and AOCs. The following summary describes the proposed modification and rationale behind the modification and contains a revised version of the relevant page of Table K-l incorporating the modification (Attachment 1). The Permittees request that the revised Table K-I be included in the Permit by the NMED-HWB upon approval of this permit modification request. Pits 38 (AOC 54-023) and 39 (AOC 54-024) were recently designated as areas of concern (AOCs) and shall be included in Table K-l of Attachment K, Listings ofSWMUs and AOCs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hanford Site Composite Analysis Technical Approach Description: Hanford Site Disposition Baseline.

The permeability of ground surfaces within the U.S. Department of Energy’s (DOE) Hanford Site strongly influences boundary conditions when simulating the movement of groundwater using the Subsurface Transport Over Multiple Phases model. To conduct site-wide modeling of cumulative impacts to groundwater from past, current, and future waste management activities, a site-wide assessment of the permeability of surface conditions is needed. The surface condition of the vast majority of the Hanford Site has been and continues to be native soils vegetated with dryland grasses and shrubs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Systems Processing Model for Molten Salt Reactors

The chemistry group within the U.S. Department of Energy Molten Salt Reactor Campaign is developing a model for the molten salt reactor system for assessing the suitability of various used fuel processing schemes. In the long run, the developed model is expected to be a tool for better understanding the interplay between the components of the molten salt reactor system including uranium resources, the molten salt reactor, the used fuel processor (e.g., reprocessing plant), and waste management. In this regard, the report proposes a theoretical framework for integrating the various components of the molten salt reactor system. Rather than being buried in implementation details for seemingly heterogeneous components of the reactor system asking for various modeling techniques, this report proposes to approximate and integrate all components with a unified mathematical framework, a discrete-time linear system. An abstracted molten salt reactor system is given as an example to illustrate the effectiveness of the proposed theoretical framework. A fully developed molten salt reactor system model (based on the proposed framework) is expected to be beneficial for various objectives including the transient and equilibrium analysis of fuel cycle scenarios and the identification of potential technology bottlenecks.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗