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At least 1,333 records · Page 74

Phase lock acquisition for sampled data PLLs using the sweep technique

Simulation results of the swept-acquisition performance of residual carrier phase-locked loops (PLLs) are reported. The loops investigated are sampled data counterparts of the continuous time type II and III loops currently in use in Deep Space Network receivers. It was found that sweep rates of 0.2 B(sub L)(2) to 0.4 B(sub L)(2) Hz/s can be used, depending on the loop parameters and loop signal-to-noise ratio (SNR), where B(sub L) is the one-sided loop noise bandwidth. Type III loops are shown to be not as reliable as type II loops for acquisition using this technique, especially at low SNRs.

Aguirre, S.↗

H II regions and the abundance properties of spiral galaxies

We investigate the relationships between the characteristic oxygen abundance, the radial abundance gradient, and the macroscopic properties of spiral galaxies by examining the properties of individual H II regions within those galaxies. Our observations of the line flux ratio (O II) lambda lambda 3726, 3729 + (O III) lambda lambda 4959, 5007)/H beta for 159 H II regions in 14 spiral galaxies are combined with published data to provide a sample of 39 disk galaxies for which (O II) + (O III)/H beta has been measured for at least five H II regions. We find that the characteristic gas-phase abundances and luminosities of spiral galaxies are strongly correlated. This relationship maps almost directly onto the luminosity-metallicity relationship of irregular galaxies and is also quite similar to that found for elliptical and dwarf spheroidal galaxies. Within our sample of spirals, a strong correlation between characteristic abundance and Hubble type also exists. The correlation between luminosity and Hubble type complicates the issue, but we discuss several interpretations of the correlations. The relationship between circular velocity and characteristic abundance is also discussed. We find that the slopes of the radial abundance gradients, when expressed in units of dex/isophotal radius, do not significantly correlate with either luminosity or Hubble type. However, the hypothesis that both early and very late type spirals have shallower gradients than intermediate spirals is consistent with the data. We find suggestive evidence that the presence of a bar induces a flatter gradient and also briefly discuss whether abundance gradients are exponential, as is usually assumed. We investigate the properties of individual H II regions in a subset of 42 regions for which we have spectra that cover almost the entire spectral range from 3500 to 9800 A. We use those data to estimate the densitites and ionizing spectra within the H II regions. We confirm that the ionizing spectrum hardens with increasing radius and decreasing abundance. We find no correlation between the ionization parameter and either radius or abundance, but this may be due to significant scatter introduced by the simple conversion of line ratios to ionization parameter.

Zaritsky, Dennis↗

Thermodynamic constraints on the textural evolution of eucrite, EET 90020

Basaltic eucrites, which are possibly parts of the Vestan crust, formed as either lava flows or intrusions, and can offer insights into early crust formation. However most eucrites have experienced thermal metamorphism, which exacerbates the challenges of understanding these samples. A variety of petrogenetic models such as, partial melting of a primitive source, fractional crystallization of magmas emplaced in a primitive crust, and/or partial melting of a eucritic source coupled with melt mixing and assimilation have been proposed in order to explain observed petrologic and chemical characteristics of eucrites. EET 90020 is an unbrecciated eucrite that has experienced significant thermal metamorphism, with temperatures of metamorphic equilibration calculated to be ~840-1040°C. Its petrologic history remains contentious, in part due to differences in trace element analyses [10,17, this work], which has led to multiple metamorphic interpretations [8,10-11]. Here, we combined petrologic observations, chemical analyses, and thermodynamic modeling, to interpret micro-domain textures identified in EET 90020 and better constrain its petrologic history. Ultimately, the development of such textures is a direct result of the geologic processes operating on a young Vesta or similar asteroid. Sample description: We identified three textural domains in EET 90020 (Figure 1); (I) A coarse grain domain with granoblastic plagioclase and pyroxene, (II) a medium grain domain with curved grain boundaries between plagioclase and pyroxene, and (III) a fine grain domain dominated by tridymite that fills in interstitial space between spherical plagioclase. Major element chemistry in phases is consistent across domains. Pyroxene have distinctive high Ca lamellae (Wo40.92En28.1Fs31.0) forming from the low-Ca pigeonite host (Wo3.5En33.7Fs62.8). There are small amounts of fayalitic olivine along pyroxene/oxide grain boundaries, where pyroxenes have reacted with ilmenite/chromite clasts. Plagioclase is anorthitic (Avg ~An88), with little variation (An86-92.5). Trace element bulk rock analyses were collected via ICP-MS and individual mineral analyses with LA-ICP-MS (Figure 2). The bulk sample has an observable enrichment in light rare earth elements, with a notable depletion in Eu. Plagioclase is enriched in LREEs, depleted in HREEs, and has a positive Eu anomaly while pyroxene is enriched in HREEs with a negative Eu anomaly. Variations in trace element analyses is likely influenced by the presence of phosphates because are highly enriched in REEs and have a dramatic effect on the bulk domain compositions. Thermodynamic modeling: The software package, Perple_X, was used to calculate mineral phase equilibria over a range of conditions using a Gibbs free energy minimization approach [12]. Models used all major/minor elements except P2O5. Thermodynamic properties from [13] were used to constrain endmember phase stabilities. Activity models were used to describe mixing in phases with solid solution. Isochemical P-T phase diagrams were constructed for the bulk thin section, and the coarse, medium and fine grain domain compositions. Domain compositions were determined using microprobe analyses of phases identified in each domain and observed modal mineral abundancies. Thermodynamically stable pyroxene compositions were extracted from model results and compared to pyroxene compositions collected via EMPA, allowing us to calculate temperatures for metamorphic equilibrium. Results: Results that use the coarse domain composition (Fig. 3a) demonstrate overlap at T ~ 1020°C indicating high T equilibration. There was no overlap for the medium and fine grain domains, or the bulk composition (e.g., Fig. 3b) indicating that these are not equilibrium assemblages. These results were replicated using data from [8,20]. Discussion: The disequilibrium results from the bulk rock, fine grain and medium grain models imply that EET 90020 was modified during and/or after peak metamorphism (open system behavior). However, this is in contrast to the coarse domain where it appears as if equilibrium was maintained. We suggest that this conflict is explained by highly localized equilibrium occurring at millimeter length-scales, which has been observed in terrestrial metamorphism where aqueous fluid infiltrate [14] or melt loss occurs [15]. It is unlikely that aqueous alteration was significant in modifying the bulk composition of EET 90020, because it lacks hydrated minerals. However, the presence of melt is supported by the presence of an abundance of curved grain boundaries and spherical grains in the medium and fine grain domains This contrasts the coarse domain, where grain boundaries are angular. Given the evidence for disequilibrium in the medium and fine grain domains, it would be inappropriate to draw additional conclusions about textural evolution using thermodynamic models of those domains. However, modeling results of the coarse grain domain, where equilibrium was maintained, can provide useful insights into the geologic evolution of EET 90020. We approximate maximum metamorphic temperatures, using the Ca component in pyroxene, at ~1020°C (Fig. 4), which is consistent with previous two-pyroxene thermometry [11]. At this temperature, up to 10 vol % melt can be produced in the coarse grain domain, which is at the boundary of minimum melt needed in order to segregate and form a melt network [16]. Tridymite and plagioclase would be the first minerals to melt out during heating starting ~990°C. This is consistent with the observed melt textures formed by tridymite and plagioclase in the fine grain domain. We suggest that a partial melting model best explains the textural development of EET 90020. Upon heating, melt generated was either trapped, resulting in no net change in the localized rock composition, or migrated, resulting in disequilibrium between pyroxene and the surrounding matrix. A positive Eu anomaly in plagioclase indicates that all of the plagioclase was melted previously. This is consistent with previous studies that have suggested that EET 90020 represents a residual eucrite that experienced partial melting and subsequent melt loss [8]. We speculate that partial melting could have occurred when EET 90020 was heated in the asteroid’s lower crust or adjacent to an intrusion [7]. Future work will study other, texturally heterogeneous samples to see if EET 90020 presents a unique circumstance or whether crustal partial melting was ubiquitous on the eucrite asteroid.

Eucrites↗

DFT-based investigation of solvation of Nd(III)/Yb(III) cations in room-temperature ionic-liquid

We report a DFT study on the solvation of bare rare-earth (RE) cations [Nd(III) and Yb(III)] in the room-temperature ionic-liquid (RTIL) based on 1,3-dimethyl-imidazolium + , PF 6 - , [MMI][PF 6 ]. In the present article, we aim to investigate whether the chosen RTIL can preferentially solvate any of the RE cations under study. First, the RTIL binding to the RE cation is studied in the gas phase, and then explored with continuum solvation model employing RTIL parameters. First, we considered the formation of the first solvation shell, where the PF 6 - anions directly bond with the Ln(III) cation. We then further surrounded the first solvation shell with [MMI]+ cations to form the second solvation shell. The stability of PF 6 - coordinated complexes is studied by calculating the binding energy values. The number of PF 6 - anions for both Ln(III) cations starts with three ligands and goes until the maximum binding energy in the RTIL medium is reached. The coordination number and binding modes of PF 6 - depend on the size of the RE cation. Comparing the binding energy values between the RE cations for the first solvation shell complexes, it is noticed that Yb-complexes have relatively greater binding energy than Nd-complexes. We have further performed a Boltzmann population analysis to find out the most dominant conformer among each category of PF 6 - coordinated complexes. A study using Natural Population Analysis shows that after complexation with PF 6 - the charge on the Yb-centers lower to a greater extent than Nd-centers, implying stronger bonding between Yb and PF 6 - , which is in harmony with the binding energy analysis. Overall, the computational investigation provides an in-depth understanding of the complexation phenomena of RE cations in RTIL, which can be useful for the practical separation of RE cations using RTIL.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation of the impacts of gamma radiolysis on an advanced TALSPEAK separation

Here, the advanced TALSPEAK process is a selective solvent extraction that utilizes 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) to separate lanthanide elements from trivalent actinides, which are held back in the aqueous phase by N-hydroxylethyl-N,N’,N’-ethylenediamine triacetic acid (HEDTA) buffered by citric acid. Gamma irradiation of an experiment containing Eu(III) and Am(III) as representative lanthanide and actinide elements resulted in higher distribution ratios of both and separation factors which decreased in an exponential fashion with increasing dose. Analysis of the reagents showed that the HEDTA concentration also decreased in an exponential fashion, strongly suggesting that degradation was correlated with loss of separation selectivity. In contrast, the concentration of citrate was unaffected, and while the concentration of HEH[EHP] did decrease, its dose-dependent kinetic profile indicated that it was not limiting partitioning. A second set of experiments were conducted using a citrate concentration that was 7.5 X higher, with the expectation that citrate would protect the HEDTA by scavenging radiolytically formed OH radicals. HEDTA degradation was significantly mitigated at higher gamma doses, but the Eu-Am separation was worse than in the low citrate experiments, presumably because at the high citrate concentrations, the Eu-citrate complexes formed in abundances competitive with the Am complexes, and are more effectively held back in the aqueous phase.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Constraints in the Remediation of Uranium Former Uranium Mining Sites - 19586

Uranium mining and milling legacy sites still exist all over the world. Financial constraints play a key role in constraining the remediation of these sites, but a series of other factors must also be considered. The IAEA has been assisting its Member States in moving forward their remediation projects, and more specifically the Central Asian region has received dedicated attention in this aspect. In association with other international organisations such as the European Commission and European Bank of Reconstruction and Development among others in the scope of the CGULS initiative (Coordination Group of Uranium Legacy Sites), a series of activities have been put in place to assist the countries in that region. Through its Technical Cooperation Department, the IAEA has also supported other Member States to manage their legacies. The IAEA CIDER Project (Constraints in Decommissioning and Environmental Remediation) in its first phase investigated possible constraint to implementation of both decommissioning and environmental remediation projects, and collected successful experiences and lessons learned from remediation projects all over the world. It started with a survey in which almost 30 Member States participated. Constraints were examined in three main areas: i) Institutional Aspects (regulatory and policy); ii) Technological and iii) Social. These results have been published in a dedicated report available in the IAEA web page (also called the CIDER Baseline Report). Under the request of participating Member States, a second phase of CIDER has been initiated with a more focused (action oriented) character. In this regard experts developed a framework for helping countries in need under two major areas: Strategy Development and Implementation and Stakeholder Engagement Support. Two other initiatives under CIDER Phase II consisted of the Enhanced Capacity Building in Environmental Remediation (the so-called School of Environmental Remediation) and a database depicting the sites in and in need of remediation in a global perspective. This paper is intended to present and promote some aspects of the methodology conceived in CIDER Phase II to help countries establish remediation strategies that will facilitate overcoming some of the barriers mentioned above. Furthermore, it aims to discuss aspects that might be improved in the assistance provided by international organisations to countries in need of developing remediation projects, pointing out to some of the documented causes for not achieving more robust results. It is expected that the combination of different tools to share good practices e.g. web-based tools, e-Learning, webinars in addition to face-to-face training events, may enhance the chances of successful implementation of remediation of legacy sites, including former uranium production sites. This initiative opens a wide avenue for cooperation while providing a platform to bring together practitioners, regulators, contractors, funding organisations to enhance the support to be provided. By working together, more effective and sustainable results can be achieved and remediation of such sites implemented in a timely, safe and cost-effective way. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Collider and gravitational wave complementarity in exploring the singlet extension of the standard model

We present a dedicated complementarity study of gravitational wave and collider measurements of the simplest extension of the Higgs sector: the singlet scalar augmented Standard Model. We study the following issues: (i) the electroweak phase transition patterns admitted by the model, and the proportion of parameter space for each pattern; (ii) the regions of parameter space that give detectable gravitational waves at future space-based detectors; and (iii) the current and future collider measurements of di-Higgs production, as well as searches for a heavy weak diboson resonance, and how these searches interplay with regions of parameter space that exhibit strong gravitational wave signals. We carefully investigate the behavior of the normalized energy released during the phase transition as a function of the model parameters, address subtle issues pertaining to the bubble wall velocity, and provide a description of different fluid velocity profiles. On the collider side, we identify the subset of points that are most promising in terms of di-Higgs and weak diboson production studies while also giving detectable signals at LISA, setting the stage for future benchmark points that can be used by both communities.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Physics Based Model for Cryogenic Chilldown and Loading. Part III: Correlations

In this report we discuss the details of the correlations used to recognize flow patterns and predict frictional losses, heat and mass transfer in the cryogenic two phase flow. The emphasis are put on the formulation of the correlation problem in terms of concise parametric and functional spaces allowing for efficient online search of the model parameters and accurate prediction of the phenomena observed during cryogenic loading. A special attention is paid to the discussion of the correlation dependence on the gravity. In this context the physics of stability, friction, and boiling in the two-phase flow that underlies the required correlations is discussed.

two-phase flow↗

Reduction of Hg(II) by Fe(II)-Bearing Smectite Clay Minerals

Aluminosilicate clay minerals are often a major component of soils and sediments and many of these clays contain structural Fe (e.g., smectites and illites). Structural Fe(III) in smectite clays is redox active and can be reduced to Fe(II) by biotic and abiotic processes. Fe(II)-bearing minerals such as magnetite and green rust can reduce Hg(II) to Hg(0); however, the ability of other environmentally relevant Fe(II) phases, such as structural Fe(II) in smectite clays, to reduce Hg(II) is largely undetermined. We conducted experiments examining the potential for reduction of Hg(II) by smectite clay minerals containing 0–25 wt% Fe. Fe(III) in the clays (SYn-1 synthetic mica-montmorillonite, SWy-2 montmorillonite, NAu-1 and NAu-2 nontronite, and a nontronite from Cheney, Washington (CWN)) was reduced to Fe(II) using the citrate-bicarbonate-dithionite method. Experiments were initiated by adding 500 µM Hg(II) to reduced clay suspensions (4 g clay L−1) buffered at pH 7.2 in 20 mM 3-morpholinopropane-1-sulfonic acid (MOPS). The potential for Hg(II) reduction in the presence of chloride (0–10 mM) and at pH 5–9 was examined in the presence of reduced NAu-1. Analysis of the samples by Hg LIII-edge X-ray absorption fine structure (XAFS) spectroscopy indicated little to no reduction of Hg(II) by SYn-1 (0% Fe), while reduction of Hg(II) to Hg(0) was observed in the presence of reduced SWy-2, NAu-1, NAu-2, and CWN (2.8–24.8% Fe). Hg(II) was reduced to Hg(0) by NAu-1 at all pH and chloride concentrations examined. These results suggest that Fe(II)-bearing smectite clays may contribute to Hg(II) reduction in suboxic/anoxic soils and sediments.

58 GEOSCIENCES↗

Study on the kinetics and mechanism of Am(III) with TODGA

The removal of minor actinides (mainly Am, Cm and Np) from the high-level waste would remarkably reduce the necessary storage time. Recently developed, a tridentate ligand, N,N,N',N'-tetraoctyl diglycolamide (TODGA), has been identified as one of the most powerful extractants being considered for the partitioning of trivalent actinides and lanthanides. In the present paper, the extraction kinetics behavior of Am(III) in TODGA/n-dodecane-HNO{sub 3} system has been studied, dependent on various parameters such as the stirring speed, the interfacial area, the extractant concentration in n-dodecane, the extracted ions concentration, the acidity of aqueous phase and the temperature. The results show that: the extraction process is controlled by diffusion mode under 130 rpm of stirring speed and by chemical reaction mode above 150 rpm. The extraction rate equation is given in the paper and the apparent extraction rate constant of Am(III) by TODGA/n-dodecane in 170 rpm and at 25 Celsius degrees is k=(24.2±3.4)*10{sup -3} mol{sup -2.18}*L{sup 2.18}*min{sup -1}*cm. The initial extraction rate of Am(III) by TODGA/n-dodecane at 170 r/min and 25 Celsius degrees increases with increasing temperature, and the apparent active energy is calculated to be E{sub a}=(25.94±0.98) kJ/mol.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Comparison of the Solubility Products of Layered Me(II)–Al(III) Hydroxides Based on Sorption Studies with Ni(II), Zn(II), Co(II), Fe(II), and Mn(II)

The precipitation of mixed metal–aluminum-layered double hydroxides (Me(II)–Al(III)-LDH)) may be an important control of the solubility of Mn(II), Fe(II), Ni(II), Zn(II), and Co(II) in soils, but assessment of this process is hindered by a lack of thermodynamic data. Here, we determined the solubility products (Ksp) of the Me(II)–Al(III)-LDHs formed by these metals based on long-term Me(II)–γAl2O3 sorption studies complemented with X-ray absorption spectroscopy (XAS) measurements. The LDH phases had the chemical formula Me(II)2/3Al1/3(OH)2Cl1/3. Solubility products were derived as Ksp = (Me2+)aq2/3(Al3+)aq1/3(OH−)aq2(Cl−)aq1/3, where brackets represent aqueous activity values determined from the equilibrium solution chemistry of the sorption samples. The Ksps are metal-dependent, with values increasing by two orders of magnitude in the order Ni(II) < Zn(II) < Co(II) < Fe(II) < Mn(II). Comparison to the solubility of β-Me(OH)2 suggests considerable thermodynamic preference of Me(II)–Al(III)-LDH over β-Me(OH)2 in soil environments and reveals a linear relation between the log-transformed Ksp values of Me(II)–Al(III)-LDH and β-Me(OH)2. Solubility plots suggest that Ni(II)–, Zn(II)–, and Co(II)–Al(III)-LDH may form in metal-polluted soils. Fe(II)–Al(III)-LDH may occur in riparian soils undergoing reduction, but precipitation of Mn(II)–Al(III)-LDH appears unlikely as it requires [Mn2+]aq much higher than commonly encountered in reducing soils. Additional thermodynamic and field studies are needed to further assess the importance of Me(II)–Al(III)-LDHs in soils and related geochemical systems.

Bhattacharya, Lasita↗

Microstructure-dependent rate theory model of defect segregation and phase stability in irradiated polycrystalline LiAlO 2

We report gamma lithium aluminate (LiAlO 2 ) is a breeder material for tritium and is one of key components in a tritium-producing burnable absorber rod (TPBAR). Dissolution and precipitation of second phases such as LiAl 5 O 8 and voids are observed in irradiated LiAlO 2 . Such microstructure changes cause the degradation of thermomechanical properties of LiAlO 2 and affect tritium retention and release kinetics, and hence, the TPBAR performance. In this work, a microstructure-dependent model of radiation-induced segregation (RIS) has been developed for investigating the accumulation of species and phase stability in polycrystalline LiAlO 2 structures under irradiation. Three sublattices (i.e. [Li, Al, V] I [O, V o ] II [Li i , Al i , O i , V i ] III ), and concentrations of six diffusive species (i.e. Li; vacancy of Li or Al at [Li, Al, V] I sublattice, O vacancy at [O, V o ] II sublattice, and Li, Al and O interstitials at [Li i , Al i , O i , V i ] III interstitial sublattices; are used to describe spatial and temporal distributions of defects and chemistry. Microstructure-dependent thermodynamic and kinetic properties including the generation, reaction, and chemical potentials of defects and defect mobility are taken into account in the model. The parametric studies demonstrated the capability of the developed RIS model to assess the effect of thermodynamic and kinetic properties of defects on the segregation and depletion of species in polycrystalline structures and to explain the phase stability observed in irradiated LiAlO 2 samples. The developed RIS model will be extended to study the precipitation of LiAl 5 O 8 and voids and tritium retention by integrating the phase-field method.

36 MATERIALS SCIENCE↗

Impulsive phase of solar flares

The present understanding of the impulsive phase of a solar flare, characterized by short-duration bursts of impulsive hard X-ray, EUV, optical and radio emission indicating the release of energetic electrons is reviewed. Observations of the spectral distribution of impulsive hard X-ray bursts and of Type III and radio continuum bursts are presented and interpreted in terms of energetic electron distributions, and impulsive EUV, XUV, soft X-ray and optical observations, which provide a lower limit to total energy release during the impulsive phase, are discussed. The role of energetic electrons in exciting the hard X-ray, EUV and microwave emissions is considered, and thin-target, thick-target, partial-precipitation and thermal models of impulsive phase electron acceleration are evaluated in light of the observations. It is noted that available data do not allow discrimination between a thermal or a nonthermal electron distribution, on which depends the proportion of flare energy supplied by the energetic electrons, and that data favors models which permit at least partial electron precipitation. Future observational and theoretical work is indicated.

Kane, S. R.↗

Programmable Phase Selection between Altermagnetic and Noncentrosymmetric Polymorphs of MnTe on InP via Molecular Beam Epitaxy

Phase selecting nearly degenerate crystalline polymorphs during epitaxial growth can be challenging yet critical to targeting physical properties for specific applications. Here, we establish how phase selectivity of altermagnetic and noncentrosymmetric polymorphs of MnTe can be programmed by subtle changes to the surface of lattice-matched InP substrates in molecular beam epitaxy growth. Bulk altermagnetic MnTe is thermodynamically stable in the hexagonal NiAs-structure and is synthesized here on the polar (111)A surface (In-terminated) of InP, while the noncentrosymmetric, cubic ZnS-structure with wide band gap (>3 eV), which epitaxially matches III–V materials, is stabilized on the (111)B surface (P-terminated). Electron microscopy, X-ray photoemission spectroscopy, and reflection high-energy electron diffraction indicate that phase selection is triggered at the interface and proceeds along the growing surface. First-principles calculations suggest that interfacial termination and strain have a significant effect on the interfacial energy; stabilizing the NiAs polymorph on the In-terminated surface and the ZnS structure on the P-terminated surface. Here, selectively grown, high-quality, phase pure films of both MnTe polymorphs will enable our understanding of the novel properties of these materials, thereby facilitating their use in new applications ranging from spintronics to microelectronic devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Temperature dependence of the photoluminescence polarization of ordered III-V semiconductor alloys

We studied the linear polarization of the photoluminescence (PL) emission of atomically ordered GaInAsP and GaInP alloys with different ordering parameters in the temperature range from 10 to 300 K. The epitaxial layers of these alloys were grown on GaAs and Ge (001) substrates by metal organic vapor phase epitaxy. The polarization of the PL emission propagating along different crystallographic axes depends on the value of biaxial strain in the layer and changes with temperature. We calculated the PL polarization patterns for different propagation directions as a function of biaxial strain using an existing model developed for ternary atomically ordered III-V alloys. Comparing the calculated PL polarization patterns with those obtained experimentally, we separated the variation of the PL polarization due to change of biaxial strain with temperature.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Simultaneous imaging and diffraction in the dynamic diamond anvil cell

The ability to visualize a sample undergoing a pressure-induced phase transition allows for the determination of kinetic parameters, such as the nucleation and growth rates of the high-pressure phase. For samples that are opaque to visible light (such as metallic systems), it is necessary to rely on x-ray imaging methods for sample visualization. Here, we present an experimental platform developed at beamline P02.2 at the PETRA III synchrotron radiation source, which is capable of performing simultaneous x-ray imaging and diffraction of samples that are dynamically compressed in piezo-driven diamond anvil cells. This setup utilizes a partially coherent monochromatic x-ray beam to perform lensless phase contrast imaging, which can be carried out using either a parallel- or focused-beam configuration. The capabilities of this platform are illustrated by experiments on dynamically compressed Ga and Ar. Melting and solidification were identified based on the observation of solid/liquid phase boundaries in the x-ray images and corresponding changes in the x-ray diffraction patterns collected during the transition, with significant edge enhancement observed in the x-ray images collected using the focused-beam. These results highlight the suitability of this technique for a variety of purposes, including melt curve determination.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗