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At least 1,333 records · Page 74
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Stagnation-point heat transfer correlation for ionized gases

Based on previous laminar boundary-layer solutions for argon, xenon, nitrogen, and air, it is shown that the effect of gas ionization on stagnation-point heat transfer can be correlated with the variation of the frozen Prandtl number across the boundary layer. A formula is obtained for stagnation-point heat transfer in a noble gas and is shown to be valid from the low-temperature range to the region of strong ionization. It is concluded that the considered effect can be well correlated by the 0.7 power of the Prandtl-number ratio across the boundary layer.

Bade, W. L.↗
NASA NTRS1975

Electron impact ionization of Io's sodium emission cloud

The geometry of the sodium cloud associated with Io (Jupiter I) indicates that the lifetime of the neutral sodium atoms is an order of magnitude less than the photoionization lifetime. We suggest that ionization by thermal plasma electrons in the Jovian magnetosphere is the dominant Na loss process. Using plasma densities deduced from Pioneer 10 measurements, the lifetime and density distributions are calculated for Na and other species which may be present in the cloud around Io. Electron ionization of Na is found to be an order of magnitude faster than photoionization, in agreement with the lifetime deduced from Na cloud observations.

Carlson, R. W.↗
NASA NTRS1976

Further studies of ionization in interstellar clouds

Interferometric scans of the interstellar 7699-A line of K I or of the D1 line of Na I are reported for 14 stars. Along with results obtained recently by others for the column densities of H I, H2, or Na I toward a larger number of stars, these results are added to a previous compilation of such data, and are used to reanalyze the relations among the well-correlated K I, Na I, and total hydrogen column densities. The estimated depletion factors of both K and Na are about 3 to 4. Alternatively, the fractional ionization will be at least 0.0009 in these relatively low-density clouds if the K and Na abundances are not to exceed their solar values. Photoionization of the heavy elements by starlight can account for the greater part of this ionization if interstellar carbon is undepleted. The influence of temperature effects and of gas-phase chemical reactions on the approximately quadratic variations of the K I and Na I column densities with the total hydrogen column density is discussed.

Hobbs, L. M.↗
NASA NTRS1975

Shock tube study of ionization rates of NaCl-contaminated argon

Spectrally resolved radiometry and a microwave technique were used to measure the electron density, electron temperature, and concentration, and the concentration of sodium atoms in the weakly ionized region behind a shock wave in an argon shock tube. It is shown that the observed increase in the ionization rate is due to electron detachment of negative chlorine ions produced from sodium chloride vapor contained as an impurity in the argon gas. The observed behavior of the electron temperature in time and the reactions controlled by the electron temperature are analyzed in the light of the impurity reaction scheme.

Scheneider, C.-P.↗
NASA NTRS1976

Ionization by energetic electrons in the midlatitude nighttime E region

Observations of the electron density profile and flux of energetic electrons obtained in two rocket flights at Wallops Island near midnight are presented. The ionization rates of the upper E region deduced from the electron density profiles are found to support the dependence on Kp established in previous observation. Calculations of the ionization rates using the observed electron fluxes show agreement with the values derived from the electron density profiles.

Smith, L. G.↗
NASA NTRS1977

Angular distribution of Auger electrons due to 3d-shell ionization of krypton

Cross sections for electron impact ionization of krypton due to ejection of a 3rd shell electron have been calculated using screened hydrogenic and Hartree-Slater wave functions for target atom. While the total ionization cross sections in the two approximations are within 10% of each other, the Auger electron angular distribution, related to cross sections for specific magnetic quantum numbers of the 3rd electrons, is widely different in the two approximations. The angular distribution due to Hartree-Slater approximation is in excellent agreement with measurement. The physical reason for the discrepancies in the two approximations is explained.

Omidvar, K.↗
NASA NTRS1976

Calculations of molecular ionization energies using a self-consistent-charge Hartree-Fock-Slater method

A numerical-variational method for performing self-consistent molecular calculations in the Hartree-Fock-Slater (HFS) model is presented. Molecular wavefunctions are expanded in terms of basis sets constructed from numerical HFS solutions of selected one-center atomlike problems. Binding energies and wavefunctions for the molecules are generated using a discrete variational method for a given molecular potential. In the self-consistent-charge (SCC) approximation to the complete self-consistent-field (SCF) method, results of a Mulliken population analysis of the molecular eigenfunctions are used in each iteration to produce 'atomic' occupation numbers. The simplest SCC potential is then obtained from overlapping spherical atomlike charge distributions. Molecular ionization energies are calculated using the transition-state procedure; results are given for CO, H2O, H2S, AlCl, InCl, and the Ni5O surface complex. Agreement between experimental and theoretical ionization energies for the free-molecule valence levels is generally within 1 eV. The simple SCC procedure gives a reasonably good approximation to the molecular potential, as shown by comparison with experiment, and with complete SCF calculations for CO, H2O, and H2S.

Rosen, A.↗
NASA NTRS1977

Angular distribution of Auger electrons due to 3d-shell impact ionization of krypton

Cross sections for electron impact ionization of krypton due to ejection of a 3d-shell electron have been calculated using screened hydrogenic and Hartree-Slater wavefunctions for the target atom. While the total ionization cross sections in the two approximations are within 10% of each other, the Auger electron angular distribution, related to cross sections for specific magnetic quantum numbers of the 3d electrons, are widely different in the two approximations. The angular distribution due to the Hartree-Slater approximation is in excellent agreement with measurement. The physical reason for the discrepancies in the two approximations is explained.

Omidvar, K.↗
NASA NTRS1977

Ionization fronts as phase transitions

Model weak D-type ionization fronts have been constructed which include the effects of magnetic pressure and H I coolants. Ly-alpha cooling is found to suppress the high-temperature peak of 15,000 to 20,000 K found in earlier models. Ionization fronts are found to be closely related to phase transitions.

Hill, J. K.↗
NASA NTRS1977

Detection of forbidden S III fine-structure emission in ionized nebulae

The 3P2-3P1 fine-structure line of doubly ionized sulfur has been detected at 534.41 + or - 0.03 kaysers in the spectra of NGC 7027, BD +30 deg 3639, and G333.6-0.2. The abundance of S(2+) and the electron density are discussed. The ionization of G333.6-0.2 is lower than expected from its luminosity.

Greenberg, L. T.↗
NASA NTRS1977

Field ionization device used for measuring the pulse height defect of He/+/ in silicon

A neutral particle detector using field ionization and liquid-nitrogen-cooled solid state detectors has been developed to investigate the pulse height defect of low energy He(+) ions in silicon. The field ionization tip is fabricated from a short length of tungsten wire; a typical detector is of the surface-barrier Si type with a thin Au window and low capacitance (about 15 pF); the assembly is mounted in a cylindrical vacuum chamber which is pumped to about 10 to the -6th torr. As an example, pulse height distributions for He(+) and H(+) taken at tip bias of 25.7 kV are presented. The detected energy of the H and He ions are studied as a function of the actual energies of accelerated ions, for a detector having a gold front conducting surface layer of 32 micrograms/sq cm.

Curtis, C. C.↗
NASA NTRS1977

Double ionization of CO2 by photon impact

Double ionization of CO2 by photon impact from the double-ionization threshold at energies of 36.2 eV (342 A) to 110 eV (113 A) has been observed. The ratio of doubly to singly charged ions shows a linear rise with photon energy for approximately 15 eV above the threshold and reaches a constant value of about 2% between 67 and 110 eV.

Samson, J. A. R.↗
NASA NTRS1977

Results of ionization measurements in the middle atmosphere

Positive-ion electrical-conductivity measurements, which are now performed with 4-cm diameter meteorological rocket payloads, provide a simple means of monitoring the NO concentration in the mesosphere, as well as the ionization variability. A wavelike dynamical structure is observed at low latitudes. Parachute-borne Gerdien mobility analyzers show, in addition, ion mobility spectra which spread from much greater to much less than that expected for simple gas-phase ions in the mesosphere and also indicate an ion clustering chain in the stratosphere. Large particulate ions apparently form in the daytime and grow very large at night. An instrument combining the mobility analyzer with a flashing source of ionizing radiation could be used as an NO(x) spectrometer.

Croskey, C. L.↗
NASA NTRS1978

Quantum mechanical theory of collisional ionization in the presence of intense laser radiation

The paper presents a quantum mechanical formalism for treating ionizing collisions occurring in the presence of an intense laser field. Both the intense laser radiation and the internal electronic continuum states associated with the emitted electrons are rigorously taken into account by combining discretization techniques with expansions in terms of electronic-field representations for the quasi-molecule-plus-photon system. The procedure leads to a coupled-channel description of the heavy-particle dynamics which involves effective electronic-field potential surfaces and continua. It is suggested that laser-influenced ionizing collisions can be studied to verify the effects of intense laser radiation on inelastic collisional processes. Calculation procedures for electronic transition dipole matrix elements between discrete and continuum electronic states are outlined.

Bellum, J. C.↗
NASA NTRS1978

Low energy ionizing collisions between N2 and CO beam molecules and CO, N2, NO, CH4, and CO2 target molecules

Absolute total negative charge production cross sections for N2 + CO, CO + N2, CO + CO, N2 + NO, N2 + CH4, and N2 + CO2 collisions are reported, and a simple model of collisions is discussed. The cross sections were measured to within about 1 eV of their thresholds. Specific reaction channels were investigated by referring to mass spectrometric identification of the product ions scattered in the forward direction, and these product ion identifications were used to explain characteristic structures in the total charge production cross sections in the near-threshold regions. The extent of the importance of dissociative ionization and 'simple' ionization in the studied collisions at low energy is considered, and charge transfer cross sections for (CO)+ + CO, CO(+) + CH4, and N2(+) + CH4 are presented.

Utterback, N. G.↗
NASA NTRS1978

Electrical structure and ionizable constituent measurements

In-situ stratospheric ions showed typical characteristics. A Krypton lamp created large numbers of additional ions of remarkably high mobility with a product of number density and ionization cross section of the ionizable constituent(s) greater than 10 cm to the 9th power per cm.

Hale, L. C.↗
NASA NTRS1979

The influence of ionization events on atmospheric ozone

Atmospheric ionization events can modify the concentration of neutral species in the stratosphere and mesosphere. In particular, ozone is destroyed because of the production of significant quantities of odd nitrogen and hydrogen compounds which react photochemically to destroy ozone. Direct evidence of ozone depletion comes from data taken during and following two solar flares generating large fluxes of 10-100 Mev protons, which bombarded the polar stratosphere and mesosphere. Observations of ozone taken during X-ray emission by solar flares and energetic electron precipitation during aurorae indicates ozone destruction above 50 km by ionization produced odd hydrogen. Lightning is apparently a large contributor to the tropospheric odd nitrogen budget. Ion propulsion induced dumping of the inner proton radiation belt represents a human activity which may influence stratospheric NOx.

Aikin, A. C.↗
NASA NTRS1979

Variational description of the positive column with two-stem ionization

The ionization balance in diffusion dominated discharges which depends on both one and two step ionization processes is considered. The Spenke diffusion equation (D sq delta n + neutrino n + sq kn =0) describing such conditions is solved by the Rayleigh-Ritz variational method. Simple analytic approximations to the density profile, and the similarity relation between neutrino,k,D and the discharge dimensions, are derived for planar and cylindrical geometry, and compared with exact computations for certain limiting cases.

Crawford, F. W.↗