Radiofrequency recombination lines
RF spectral recombination lines from atomic level transitions, discussing populations, H lines, electron temperature, density and emission and formation
Dupree, A. K.↗
SEARCH · Engineering Papers
Results for “ELECTRON TRANSITION”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Theoretical and experimental studies in ultraviolet solar physics
The processes and parameters in atomic and molecular physics that are relevant to solar physics are investigated. The areas covered include: (1) measurement of atomic and molecular parameters that contribute to discrete and continous sources of opacity and abundance determinations in the sun; (2) line broadening and scattering phenomena; and (3) development of an ion beam spectroscopic source which is used for the measurement of electron excitation cross sections of transition region and coronal ions.
Parkinson, W. H.↗
New fine structure cooling rate
One of the dominant electron cooling processes in the ionosphere is caused by electron impact induced fine structure transitions among the ground state levels of atomic oxygen. This fine structure cooling rate is based on theoretical cross sections. Recent advances in the numerical cross section determinations to include polarization effects and more accurate representations of the atomic target result in new lower values. These cross sections are employed in this paper to derive a new fine structure cooling rate which is between 40% and 60% of the currently used rate. A new generalized formula is presented for the cooling rate (from which the fine structure cooling rate is derived), valid for arbitrary mass and temperature difference of the colliding particles and arbitrary inelastic energy difference.
Hoegy, W. R.↗
New fine structure cooling rate
One of the dominant electron cooling processes in the ionosphere is caused by electron impact induced fine structure transitions among the ground state levels of atomic oxygen. This fine structure cooling rate is based on theoretical cross sections. Recent advances in the numerical cross section determinations to include polarization effects and more accurate representations of the atomic target result in new lower values. These cross sections are employed in this paper to derive a new fine structure cooling rate which is between 40% and 60% of the currently used rate. A new generalized formula is presented for the cooling rate (from which the fine structure cooling rate is derived), valid for arbitrary mass and temperature difference of the colliding particles and arbitrary inelastic energy difference.
Hoegy, W. R.↗
Propagation of cosmic rays in extragalactic radio sources
A model of extragalactic radio sources is considered which assumes that relativistic electrons carry energy from the central galaxy to the radio lobes and also emit the radio waves. It is suggested that the radio emission is confined to an axis because electrons propagate parallel to the magnetic field more readily than perpendicular to it and that symmetric radio lobes appear on this axis because electrons are deposited at supercoherent transitions far from the central galaxy, where they propagate diffusively. The slow drift velocities that characterize this propagation are shown to explain the secondary structure between the main lobes and to establish a relationship between double sources and galactic radio trails.
Earl, J. A.↗
An atomic model for neutral and singly ionized uranium
A model for the atomic levels above ground state in neutral, U(0), and singly ionized, U(+), uranium is described based on identified atomic transitions. Some 168 states in U(0) and 95 in U(+) are found. A total of 1581 atomic transitions are used to complete this process. Also discussed are the atomic inverse lifetimes and line widths for the radiative transitions as well as the electron collisional cross sections.
Maceda, E. L.↗
Spectrophotometry of Comet West
Postperihelion observations of Comet West (1975n = 1976 VI) have been made with a Fourier transform spectrometer at heliocentric distances from 0.57 to 1.68 AU. Measurements were made of the emission bands of C2, CN, C3, CH, and NH2, as well as the emission lines of Na D and forbidden (O I), and the flux in the continuum in nine different bandpasses. Several ratios of the band strengths of CN have been used to determine the two free parameters in the fluorescence equilibrium model of CN of Danks and Arpigny (1973). From the values of the parameters it is inferred that the vibrational transition probability for the ground electronic state is between 0.025 and 0.075 per sec and that the ratio of oscillator strengths between the (0-0) bands of the violet and red systems is between 25 and 30. When corrected for field-of-view effects, NH2 shows no systematic variation in abundance relative to C2 while CH shows a small increase. The cometary continuum is found to be slightly redder than the solar continuum, consistent with results for other bright, dusty comets. The equivalent width of the Delta u = 0 sequence of C2 shows a marked decrease at r(H) = 1.2 AU.
Ahearn, M. F.↗
Atomic calculations for Ca XVII - UV and X-ray lines
Doschek et al. (1977) have pointed out the importance of the Ca XVII UV lines as an electron density diagnostic. Energy levels, transition probabilities, and collision strengths, are presently obtained for the 2s2, 2s 2p, 2p2, 2s 3s, 2s 3p, and 2s 3d configurations of Ca XVII, and the theoretical intensity ratios for the UV and X-ray lines are compared with observed intensities in solar flare spectra. Inconsistencies are indicated in the analysis of UV data, and discrepancies between observed and theoretical intensity ratios indicate that further studies are required. New identifications are suggested in the X-ray wavelength region.
Bhatia, A. K.↗
On the long-tail solar wind electron velocity distribution
The role of the log-normal distribution in the description of the high-energy tail of the electron velocity distribution in the solar wind plasma is examined. Specifically, it is shown that the core-halo solar wind distribution function can be understood in terms of a simple phenomenological model of general applicability in which the core has a Maxwellian or normal distribution and the halo a log-normal distribution. In the presence of structures in the interplanetary medium capable of interacting with the electrons, the model predicts a transition at the highest velocities to a secondary halo distribution.
Shlesinger, Michael F.↗
Weld-Bead Shaver
Hand-held power tool shaves excess metal from inside circumference of welded duct. Removes excess metal deposited by penetration of tungsten/inert-gas weld or by spatter from electron-beam weld. Produces smooth transition across joint. Easier to use and not prone to overshaving. Also cuts faster, removing 35 in. (89 cm) of weld bead per hour.
Guirguis, Kamal↗
Rovibrational intensities and electric dipole moment function of the X2 Pi hydroxyl radical
Recent work aimed at determining the absolute rovibrational transition intensities for the ground electronic state of the hydroxyl radical is reviewed. Two new sets of Fourier transform emission spectra of OH are described which were recorded at the University of Paris and at the Kitt Peak National Solar Observatory.
Chackerian, C., Jr.↗
Multifrequency emission from hot ion disks
The discovery of a large number of gamma-emitting active galactic nuclei (AGNs) by the EGRET instrument on the Compton Gamma Ray Observatory (CGRO) has spawned a lot of theoretical interest in the high-energy and multifrequency emission from these objects. Since most of them show evidence for relativistic outflow, jet models have received most of the attention so far. However, the presence of soft photons at the center of the active nucleus and the resulting Compton drag make it difficult to produce the observed amount of MeV/GeV emission. We explore hot, two-temperature accretion disks around Kerr black holes as an alternative to relativistic beam models for the production of the high-enerty emission. The decay of neutral pions created in the hot region produces photons with energies up to several hundred MeV. Relativistic pairs created as a result of charged pion decays produce additional inverse-Compton radiation in the range of approx. 1 keV-4 MeV if the pairs are exposed to UV radiation, or in the range of approx. 40 keV-150 MeV if the pairs are exposed to soft X-rays. This suggests that high-energy flares in AGNs may be triggered by changes in the disk structure (such as phase transitions or the development of electron scattering coronae) that temporarily shield the hot inner region from UV photons emitted at larger radii, thereby reducing the optical depth for MeV/GeV gamma-rays. Stochastic processes may also play a role in accelerating the utrarelativistic electrons responsible for producing the highest energy (GeV) emission.
Maisack, Michael↗
NASA Spinoff Article: Automated Procedures To Improve Safety on Oil Rigs
On May 11th, 2013, two astronauts emerged from the interior of the International Space Station (ISS) and worked their way toward the far end of spacecraft. Over the next 51/2 hours, the two replaced an ammonia pump that had developed a significant leak a few days before. On the ISS, ammonia serves the vital role of cooling components-in this case, one of the station's eight solar arrays. Throughout the extravehicular activity (EVA), the astronauts stayed in constant contact with mission control: every movement, every action strictly followed a carefully planned set of procedures to maximize crew safety and the chances of success. Though the leak had come as a surprise, NASA was prepared to handle it swiftly thanks in part to the thousands of procedures that have been written to cover every aspect of the ISS's operations. The ISS is not unique in this regard: Every NASA mission requires well-written procedures-or detailed lists of step-by-step instructions-that cover how to operate equipment in any scenario, from normal operations to the challenges created by malfunctioning hardware or software. Astronauts and mission control train and drill extensively in procedures to ensure they know what the proper procedures are and when they should be used. These procedures used to be exclusively written on paper, but over the past decade, NASA has transitioned to digital formats. Electronic-based documentation simplifies storage and use, allowing astronauts and flight controllers to find instructions more quickly and display them through a variety of media. Electronic procedures are also a crucial step toward automation: once instructions are digital, procedure display software can be designed to assist in authoring, reviewing, and even executing them.
traclabs↗
Orientation Effects in Two-Phase Microgap Flow
The high power density of emerging electronic devices is driving the transition from remote cooling, which relies on con-duction and spreading, to embedded cooling, which extracts dissipated heat on-site. Two-phase microgap coolers employ the forced flow of dielectric fluids undergoing phase change in a heated channel within or between devices. Such coolers must work reliably in all orientations for a variety of applications (e.g., vehicle-based equipment), as well as in microgravity and high-g for other applications (e.g., spacecraft and aircraft). The lack of acceptable models and correlations for orientation- and gravity-independent operation has limited the use of two-phase coolers in such applications. Previous research has revealed that gravita-tional acceleration plays a diminishing role in establishing flow regimes and transport rates as the channel size shrinks, but there is considerable variation among the proposed microscale criteria and limited research on two-phase flows in low aspect ratio mi-crogap channels. Reliable criteria for achieving orientation- and gravity-independent flow boiling would enable emerging sys-tems to exploit this thermal management technique and streamline the technology development process. As a first step toward understanding the effect of gravity on two-phase microgap flow and transport, in the present effort the authors have studied the effect of evaporator orientation and mass flux on near-saturated flow boiling of HFE7100 in a 1.01 mm tall by 13.0 mm wide by 12.7 mm long microgap channel. Orientation-independence, defined as achieving similar critical heat fluxes, heat transfer coefficients, and flow regimes across evaporator orientations, was achieved for mass fluxes of 400 kg/m2-s and greater. The present results are compared to pub-lished criteria for achieving gravity-independence.
orientation↗
Orientation Effects in Two-Phase Microgap Flow
The high power density of emerging electronic devices is driving the transition from remote cooling, which relies onconduction and spreading, to embedded cooling, which extracts dissipated heat on-site. Two-phase microgap coolersemploy the forced flow of dielectric fluids undergoing phase change in a heated channel within or between devices. Such coolers must work reliably in all orientations for a variety of applications (e.g., vehicle-based equipment), as well as in microgravity and high-g for other applications (e.g., spacecraft and aircraft). The lack of acceptable models andcorrelations for orientation- and gravity-independent operation has limited the use of two-phase coolers in suchapplications. Previous research has revealed that gravitational acceleration plays a diminishing role in establishing flow regimes and transport rates as the channel size shrinks, but there is considerable variation among the proposed microscale criteria and limited research on two-phase flows in low aspect ratio microgap channels. Reliable criteria for achieving orientation- and gravity-independent flow boiling would enable emerging systems to exploit this thermal management technique and streamline the technology development process.
orientation↗
Gravity Effects in Two-Phase Microgap Flow
The high power density of emerging electronic devices is driving the transition from remote cooling, which relies on conduction and spreading, to embedded cooling, which extracts dissipated heat on-site. Two-phase microgap coolers employ the forced flow of dielectric fluids undergoing phase change in a heated channel within or between devices. Such coolers must work reliably in all orientations for a variety of applications (e.g., vehicle-based equipment), as well as in microgravity and high-g for aerospace applications, but the lack of acceptable models and correlations for orientation- and gravity-independent operation has limited their use. Reliable criteria for achieving orientation- and gravity-independent flow boiling would enable emerging systems to exploit this thermal management technique and streamline the technology development process. As a first step toward understanding the effect of gravity in two-phase microgap flow and transport, in an earlier effort, the authors studied the effects of evaporator orientation, mass flux, and heat flux on flow boiling of HFE7100 in a 1.01 mm tall by 13.0 mm wide by 12.7 mm long microgap channel. Orientation-independence, defined as achieving similar critical heat fluxes, heat transfer coefficients, and flow regimes across orientations, was achieved for mass fluxes of 400 kg/sq.m-s and greater (corresponding to a Froude number of about 0.8). In the present effort, the authors have studied the effects of gravity, mass flux, and subcooling on flow boiling of HFE7100 in a 0.17 mm tall by 13.0 mm wide by 12.7 mm long microgap channel. The Flow Boiling in Microgap Coolers payload experienced about three minutes of weightlessness and shorter periods of high-g (up to about 5 g) during two recent flights aboard the Blue Origin New Shepard reusable launch vehicle. The results from the flight experiments will be presented and compared with published criteria for achieving gravity-independence.
Robinson, Franklin L.↗
Ba₁₋ₓSrₓFeO₃₋ᵧ as an Improved Oxygen Carrier for Chemical Looping Air Separation: A Computational and Experimental Study
Chemical looping air separation (CLAS) is a promising method to generate pure carbon-dioxide from fuel combustion with a pure oxygen stream, which is produced through the capture, and targeted release, of oxygen from the atmosphere using a solid oxide carrier. The performance of this process depends on the redox characteristics of the oxide carrier. Using experimental oxygen-temperature-programmed desorption (TPD) and thermogravimetric analysis (TGA), the study shows that Ba₀․₇₅Sr₀․₂₅FeO₃ has improved oxygen storage capacity (OSC), oxidation, and reduction kinetics over pristine SrFeO₃ at temperatures ranging from 300-500 °C. The redox energetics computed by using first-principles density functional theory (DFT) calculations also depict the measured trend establishing it as an important descriptor of the measured performance. The Ba₁₋ₓSrₓFeO₃₋ᵧ depicts a Sr-substitution and oxygen stoichiometry induced structural phase transition from hexagonal at low temperatures to pseudo-cubic phase with higher OSC up to T=400 °C. Also, the mechanism leading to this structural phase transition is identified by performing electronic and vibrational structural calculations. This presentation was given on March 8, 2024 at the APS March Meeting in Minneapolis, MN.
Acharya, Shree Ram↗
Ultrafast photochemistry of gas-phase transition metal carbonyls
Organometallic photochemistry lies at the heart of photochemical energy conversions in applications such as photocatalysis, photovoltaic cells, and luminescent materials. Thus, understanding how metal and ligand interactions in organometallic complexes modify electronic excited-state properties and reactivity has been the subject of intense studies for decades. Transition metal carbonyls [M n (CO) m ] have long served as prototypical organometallic complexes for understanding metal–ligand bonding and photochemistry and have been studied extensively in solution, matrices, and the gas phase on time scales ranging from femtoseconds to microseconds and longer. This review chronicles the past two and a half decades of efforts in understanding the ultrafast (sub-nanosecond) dynamics of transition metal carbonyls in the gas phase, where complicating solvent influences are absent and multiple experimental probes and high-level electronic structure theory can come together to yield rich information on the intricate interplay of electronic and structural dynamics. This review first lays the groundwork by briefly describing the electronic structure of transition metal carbonyls and introducing the various ultrafast techniques that have been applied to study their unimolecular dynamics. We then provide a detailed historical account on the ultrafast photochemistry of iron pentacarbonyl, nickel tetracarbonyl, and transition metal hexacarbonyls and decacarbonyls, putting the more recent ultrafast studies in the context of prior investigations. In conclusion, we end this review with an outlook on open questions and future possibilities.
Core level spectroscopy↗