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Dynamics of vegetative cytoplasm during generative cell formation and pollen maturation in Arabidopsis thaliana

Ultrastructural changes of pollen cytoplasm during generative cell formation and pollen maturation in Arabidopsis thaliana were studied. The pollen cytoplasm develops a complicated ultrastructure and changes dramatically during these stages. Lipid droplets increase after generative cell formation and their organization and distribution change with the developmental stage. Starch grains in amyloplasts increase in number and size during generative and sperm cell formation and decrease at pollen maturity. The shape and membrane system of mitochondria change only slightly. Dictyosomes become very prominent, and numerous associated vesicles are observed during and after sperm cell formation. Endoplasmic reticulum appears extensively as stacks during sperm cell formation. Free and polyribosomes are abundant in the cytoplasm at all developmental stages although they appear denser at certain stages and in some areas. In mature pollen, all organelles are randomly distributed throughout the vegetative cytoplasm and numerous small particles appear. Organization and distribution of storage substances and appearance of these small particles during generative and sperm cell formation and pollen maturation are discussed.

Non-NASA Center↗

Coherent Frequency Reference System for the NASA Deep Space Network

The NASA Deep Space Network (DSN) requires state-of-the-art frequency references that are derived and distributed from very stable atomic frequency standards. A new Frequency Reference System (FRS) and Frequency Reference Distribution System (FRD) have been developed, which together replace the previous Coherent Reference Generator System (CRG). The FRS and FRD each provide new capabilities that significantly improve operability and reliability. The FRS allows for selection and switching between frequency standards, a flywheel capability (to avoid interruptions when switching frequency standards), and a frequency synthesis system (to generate standardized 5-, 10-, and 100-MHz reference signals). The FRS is powered by redundant, specially filtered, and sustainable power systems and includes a monitor and control capability for station operations to interact and control the frequency-standard selection process. The FRD receives the standardized 5-, 10-, and 100-MHz reference signals and distributes signals to distribution amplifiers in a fan out fashion to dozens of DSN users that require the highly stable reference signals. The FRD is also powered by redundant, specially filtered, and sustainable power systems. The new DSN Frequency Distribution System, which consists of the FRS and FRD systems described here, is central to all operational activities of the NASA DSN. The frequency generation and distribution system provides ultra-stable, coherent, and very low phase-noise references at 5, l0, and 100 MHz to between 60 and 100 separate users at each Deep Space Communications Complex.

Tucker, Blake C.↗

LLNL Kimberlina 1.2 NUFT Simulations June 2018 (v2)

This dataset contains the output 6,000, 3-dimensional reactive multi-phase flow and transport aquifer simulations of brine and CO2 leakage into a protective aquiver in California’s San Joaquin Valley and input data files detailing the geologic mesh, aquifer physical properties and CO2 and brine injection rates. This data set was generated as an ongoing effort with the US DOE National Risk Assessment Partnership (NRAP) to evaluate the effectiveness of monitoring techniques to detect brine and CO2 leakage from legacy wells into underground sources of drinking water overlaying a CO2 storage reservoir. Each simulation contains a unique set of input parameters, generated stochastically. The outputs consist of these upper three geologic layers (from top): the Etchegoin, Macoma-Chanac, Santa Margarita-McLure formations. These simulations span the several distances (1, 3 and 6 km or wells W31-0.2, W31-0.5 and W31-1.0, respectively) from the CO2 injector, initiated from bottom hole pressure and saturation to calculate wellbore leakage from the storage reservoir, with low and high regional groundwater gradients and wellbore leakage into 5 leaky nodes. The dataset includes 1,000 unique simulations for each distance, which each contain a unique aquifer heterogeneity, aquifer and caprock permeability, and two model generations are included with a high permeability (prod07) and hybrid permeability (prod09). The range of permeability distributions is listed in Table 1. Each model generation consists of 3,000 simulations. Included in the dataset are the leakage rates determined from 2D wellbore models which utilize the pressure and CO2 saturation from LBL's reservoir simulations, NUFT mesh files with distributed lithology, NUFT rocktab files which describe the material properties for the geologic layers and the NUFT input files and post-processed output 'ntab' files. Each ntab file contains spatial (rows) and temporal (columns) model output tables for each model cell, the locations (x,y,z) and dimensions for each cells (dx, dy, dz). Table 1. Permeability distribution ranges for prod07 and prod09 model generations Geologic Layer: Permeability Range (log10 m^2) prod07 prod09 Etchegoin -12.92 to -10.92 -13.70 to -11.44 Macoma-Chanac -12.72 to -10.72 -13.50 to -11.24 Santa Margarita-McLure -12.70 to -10.70 -13.48 to -11.22 The input files used to generate the model include which are included in the dataset are: Time series of CO2 leakage input into the model (ex: Q_brn.W31-0.2.sim1000.layers123.tab) Time series of CO2 leakage input into the model (ex: Q_CO2.W31-0.2.sim1000.layers123.tab) Physical properties of the aquifer materials detailing the aquifer porosity, solid density, partitioning coefficients, permeabilities and van-Genuchten parameters detailed in a NUFT rocktab file: (ex: sim1000.usnt.rocktab) Numerical mesh and geologic data assigned to each model cell detailed in a NUFT genmsh format (ex: sim1000.mesh_k16.prod07.trans.genmsh) The primary output parameters are: pH (use absolute value) Change in TDS (mg/kg) Change in Pressure (Pa) Change CO2 gas saturation (fraction range 0.0-1.0) for example, the directory /p/lscratchh/mansoor1/nrap/kimberlina/prod09/mainfiles/sim1000/W31- 0.2 contains: sim1000.W31-0.2.trans.pH.red.ntab sim1000.W31-0.2.no_bg.trans.TDS.red.ntab sim1000.W31-0.2.usnt.P.deltabg.red.ntab sim1000.W31-0.2.usnt.CO2_sat.deltabg.red.ntab Each row in the NTAB files consist of model output per numerical grid cell. Each output file contains 33 columns (variables), including the information of numerical records, geologic location and sizes and the simulated parameter values over time. The first 13 variables are about numerical records and relative geologic information for a simulation grid: 1. index: simulation index 2. i: the ith grid of x-axis 3. j: the ith grid of y-axis 4. k: the ith grid of z-axis 5. element_ref: element reference 6. nuft_ind: nuft index 7. x: grid location in the x axis direction 8. y: grid location in the y axis direction 9. z: grid location in the z axis direction 10. dx: grid length in the x axis direction 11. dy: grid length in the y axis direction 12. dz: grid length in the z axis direction 13. volume: volume of the simulation grid The remainder (14, 15, 16...) variables are the simulated parameter values over time, take Pressure as an example, are: 14. 0.0y: initial pressure per cell. 15. 10.0y: simulated pressure at the end of the 10th year. 16. 20.0y: simulated pressure at the end of the 20th year. ... (repeated for every 10 years until 200 years)... The model extends 10,000 m, 5,000 m and 1,411 m in the x,y and z dimensions, respectively. The mesh consists of 164,832 cells with mesh dimensions of 101 x 51 x 32 (nx, ny, nz), with cell dimensions ranging from 100 m laterally (along x and y-axis) and model layers are as designated in the z-axis: Layer 1: atmosphere (1e-30 m thick) Layer 2: upper caprock (10 m thick) Layers 3-13: Etchegoin (536.23 m thck) Layers 14-27: Macoma-Chanac (679.04 m thick) Layers 28-32: Santa Margarita-McLure (185.94 m thick) The wellbore is placed along node i=51, j=26, and extends vertically along 5 nodes from the top to the bottom of the model. Special instructions when extracting files: Each Gzip archive (ex: prod07.sim1000-sim00099.tar.gz) contains 100 simulations. Gzip archives should be transferred into base directories (ie. In Linux: mkdir prod07; mv prod07.*.tar.gz prod07/.) before extracting, or files will be overwritten. Each sub-simulation tree should have the following file structure pattern (using the linux 'tree' command): |-- prod07 | |-- sim0001 | |-- W31-0.2 | | |-- Q_brn.W31-0.2.sim0001.layers123.tab | | |-- Q_co2.W31-0.2.sim0001.layers123.tab | | |-- sim0001.W31-0.2.no_bg.trans.TDS.red.ntab | | |-- sim0001.W31-0.2.trans.pH.red.ntab | | |-- sim0001.W31-0.2.usnt.CO2_sat.deltabg.red.ntab | | |-- sim0001.W31-0.2.usnt.P.deltabg.red.ntab | |-- W31-0.5 | | |-- Q_brn.W31-0.5.sim0001.layers123.tab | | |-- Q_co2.W31-0.5.sim0001.layers123.tab | | |-- sim0001.W31-0.5.no_bg.trans.TDS.red.ntab | | |-- sim0001.W31-0.5.trans.pH.red.ntab | | |-- sim0001.W31-0.5.usnt.CO2_sat.deltabg.red.ntab | | |-- sim0001.W31-0.5.usnt.P.deltabg.red.ntab | |-- W31-1.0 | | |-- Q_brn.W31-1.0.sim0001.layers123.tab | | |-- Q_co2.W31-1.0.sim0001.layers123.tab | | |-- sim0001.W31-1.0.no_bg.trans.TDS.red.ntab | | |-- sim0001.W31-1.0.trans.pH.red.ntab | | |-- sim0001.W31-1.0.usnt.CO2_sat.deltabg.red.ntab | | |-- sim0001.W31-1.0.usnt.P.deltabg.red.ntab | |-- sim0001.mesh_k16.prod07.trans.genmsh Disclaimer This document was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor Lawrence Livermore National Security, LLC, nor any of their employees makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government or Lawrence Livermore National Security, LLC. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States government or Lawrence Livermore National Security, LLC, and shall not be used for advertising or product endorsement purposes. Lawrence Livermore National Laboratory is operated by Lawrence Livermore National Security, LLC, for the U.S. Department of Energy, National Nuclear Security Administration under Contract DE-AC52-07NA27344. This report was reviewed and released as LLNL-MI-753464.

aquifer↗

Impact of High Penetration Distributed Energy Resources on the Bulk Electric System

The growth of distributed energy resources (DERs), mostly generation using intermittent renewable energy sources, along with the retirement of central generation (mostly conventional power plants using fossil-fuel-based resources) has implications for the steady-state and dynamic performance of the bulk electric system (BES). Among the DERs connected to the distribution system, photovoltaic (PV) systems are the most prevalent and have been installed at an increasing rate. Until recently, the penetration levels of DERs have not been high enough to create significant impacts on the reliability and security of power system operation. However, in recent years, the penetration levels of DERs have risen to a level that their impacts on the bulk electric system should be considered in a detailed fashion in planning and operations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A Review of Behind-the-Meter Solar Generation Modeling and Forecasting

Solar photovoltaic systems largely integrated within the distribution grid are operated 'behind-the-meter' and power generation cannot be directly monitored by most utilities. The increasing penetration of behind-the-meter solar photovoltaic systems can deter efficient network and market operations due to variability and uncertainty in net load, which is exacerbated by limited visibility and the difficulty in analyzing the hosting capacity. Risk introduced by behind-the-meter solar contributions may hinder reliable and secure grid operations due to biased system monitoring and forecasts. Accurate behind-the-meter estimations, together with capacity and specification forecasts, thus play a key role in balancing supply and demand and this article reviews the pertinent literature, identifying key characteristics and predictive methods for efficient behind-the-meter solar photovoltaic generation. Forecasting is central to methods herein. The fundamental characteristics of behind-the-meter solar forecasting, including which methods are applicable for scenario-driven use cases, are driven by the metrics most useful for system-wide performance evaluation. To this aim, the literature is reviewed with a focus on forecasting applications for aggregate, regional behind-the-meter generation useful to bulk system and utility operations. As distinguished from net load forecasting, subtleties in these coincident tasks are explored before concluding with recommendations for current practice and future implementations.

behind-the-meter↗

A Distributed Trajectory-Oriented Approach to Managing Traffic Complexity

In order to handle the expected increase in air traffic volume, the next generation air transportation system is moving towards a distributed control architecture, in which ground-based service providers such as controllers and traffic managers and air-based users such as pilots share responsibility for aircraft trajectory generation and management. While its architecture becomes more distributed, the goal of the Air Traffic Management (ATM) system remains to achieve objectives such as maintaining safety and efficiency. It is, therefore, critical to design appropriate control elements to ensure that aircraft and groundbased actions result in achieving these objectives without unduly restricting user-preferred trajectories. This paper presents a trajectory-oriented approach containing two such elements. One is a trajectory flexibility preservation function, by which aircraft plan their trajectories to preserve flexibility to accommodate unforeseen events. And the other is a trajectory constraint minimization function by which ground-based agents, in collaboration with air-based agents, impose just-enough restrictions on trajectories to achieve ATM objectives, such as separation assurance and flow management. The underlying hypothesis is that preserving trajectory flexibility of each individual aircraft naturally achieves the aggregate objective of avoiding excessive traffic complexity, and that trajectory flexibility is increased by minimizing constraints without jeopardizing the intended ATM objectives. The paper presents conceptually how the two functions operate in a distributed control architecture that includes self separation. The paper illustrates the concept through hypothetical scenarios involving conflict resolution and flow management. It presents a functional analysis of the interaction and information flow between the functions. It also presents an analytical framework for defining metrics and developing methods to preserve trajectory flexibility and minimize its constraints. In this framework flexibility is defined in terms of robustness and adaptability to disturbances and the impact of constraints is illustrated through analysis of a trajectory solution space with limited degrees of freedom and in simple constraint situations involving meeting multiple times of arrival and resolving a conflict.

Idris, Husni↗

Predictive and Cooperative Voltage Control with Probabilistic Load and Solar Generation Forecasting

This paper proposes predictive cooperative voltage control method in a power system with high penetration of photovoltaic (PV) units. Cooperative distributed control of the reactive power output of PV inverters is coordinated with operation of voltage regulators (VRs) to maintain system voltages within an appropriate bandwidth. Probabilistic forecasting of the solar power generation and the loads is applied to estimate voltage changes which, in turn, are used to set the VR tap positions for preventing large voltage fluctuations with the lowest risk considering the voltage distribution estimation. The fine tuning of voltage adjustment is achieved by cooperative control of PV inverters to maintain a uniform voltage profile across the system. The proposed method is tested on the modified IEEE 123-node test feeder with high PV penetration using real insolation data and with constant loads replaced by several different load profiles. Simulation results demonstrate the effectiveness of the coordinated approach for voltage control with cooperative PV and predictive VR controls taking into account probabilistic load and solar power forecasts.

Cooperative Control↗

PacWave Grid Integration Study: Transient and Dynamic Conditions (Final Report)

This report describes the results of PSCAD simulations that were performed in 2020 to assess the impacts of PacWave generation on CLPUD's 12.47-kV distribution and 69-kV subtransmission systems. PacWave South (PacWave) is a wave energy test facility planned by Oregon State University. PacWave shore facilities will be located south of Seal Rock on the Oregon coast. PacWave is expected to be operational in 2022 and will connect up to 10 MW of generation to CLPUD's Seal Rock distribution feeder.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Initial Uncertainty Analysis of Carbon Tetrachloride Contamination and Remediation in the Ringold A and Lower Mud Units at the Central Plateau

The long-term effectiveness of groundwater cleanup at the Hanford Site Central Plateau depends on predictive models that can capture key uncertainties in contaminant fate and transport. Carbon tetrachloride (CCl 4 ), a persistent and toxic compound, presents particular challenges due to variability in degradation rates, uncertainty in initial plume distribution, and subsurface heterogeneity. These uncertainties directly influence plume persistence, migration pathways, and remedy performance, and thus must be systematically evaluated to support long-term remediation planning. To address these gaps, a large-scale Monte Carlo analysis was conducted using the Plateau to River (P2R) model framework. The modeling approach parameterized three primary uncertainty factors: (1) degradation rate, (2) initial plume distribution, and (3) hydraulic conductivity. Degradation was represented as a first-order process, with half-lives ranging from 70 to 700 years. Initial plume distributions were created using a geostatistical simulation method (sgsim), which generates many equally plausible versions of how contaminants might be distributed underground. From this, 100 different scenarios were mapped onto the P2R grid. Variability in hydraulic conductivity was represented in a similar way, with 100 scenarios each for the Ringold Lower Mud and Ringold A units (layers 6 and 7), based on fitted exponential variograms and conditioned to well data. In total, more than 1000 realizations were simulated to assess plume behavior under uncertainty. Results demonstrate that degradation kinetics exert the strongest control over plume persistence: Shorter half-lives produced rapid mass reduction, while longer half-lives yielded persistent plumes with limited attenuation. A nonlinear response was observed, with steep mass reductions at half-lives greater than 200 years and near-linear declines beyond this threshold, reflecting interactions between degradation and pumping. The initial plume distribution strongly influenced early transport patterns, with broader sources generating larger plume footprints, although pump-and-treat operations constrained plume migration to managed areas. By comparison, hydraulic conductivity variability in the Ringold units had only a secondary influence, modifying spreading behavior without altering the dominant migration pathways governed by source configuration and hydraulic controls. Overall, the analysis highlights that uncertainty in degradation rate and initial plume configuration are the primary drivers of variability in plume predictions, while conductivity heterogeneity plays a limited role. These findings underscore the need for improved site-specific data on degradation processes and source characterization to enhance the reliability of long-term performance assessments and to better inform remedial decision-making at the Central Plateau.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Noise and Emissions Assessment of the N3-X Transport

Analytical predictions of certification noise and exhaust emissions for NASA's N3-X - a notional, hybrid wingbody airplane - are presented in this paper. The N3-X is a 300-passenger concept transport propelled by an array of fans distributed spanwise near the trailing edge of the wingbody. These fans are driven by electric motors deriving power from twin generators driven by turboshaft engines. Turboelectric distributed hybrid propulsion has the potential to dramatically increase the propulsive efficiency of aircraft. The noise and exhaust emission estimates presented here are generated using NASA's conceptual design systems analysis tools with several key modifications to accommodate this unconventional architecture. These tools predict certification noise and the emissions of oxides of nitrogen by leveraging data generated from a recent analysis of the N3-X propulsion system.

Berton, Jeffrey J.↗

Distributed Traffic Complexity Management by Preserving Trajectory Flexibility

In order to handle the expected increase in air traffic volume, the next generation air transportation system is moving towards a distributed control architecture, in which groundbased service providers such as controllers and traffic managers and air-based users such as pilots share responsibility for aircraft trajectory generation and management. This paper presents preliminary research investigating a distributed trajectory-oriented approach to manage traffic complexity, based on preserving trajectory flexibility. The underlying hypotheses are that preserving trajectory flexibility autonomously by aircraft naturally achieves the aggregate objective of avoiding excessive traffic complexity, and that trajectory flexibility is increased by collaboratively minimizing trajectory constraints without jeopardizing the intended air traffic management objectives. This paper presents an analytical framework in which flexibility is defined in terms of robustness and adaptability to disturbances and preliminary metrics are proposed that can be used to preserve trajectory flexibility. The hypothesized impacts are illustrated through analyzing a trajectory solution space in a simple scenario with only speed as a degree of freedom, and in constraint situations involving meeting multiple times of arrival and resolving conflicts.

Idris, Husni↗

Electric field distribution in a non-self-sustained RF discharge with ionization generated by Ns discharge pulses

Abstract Electric field in a capacitively coupled, non-self-sustained RF discharge nitrogen plasma with external ionization generated by high-voltage ns pulses has been measured by ps Electric field induced second harmonic generation (EFISH). The measurements are made both in the bulk of the plasma and in the sheaths, using the absolute calibration by the Laplacian field between two plane electrodes. The results are compared with the kinetic modeling calculations. The RF electric field in the sheaths is significantly higher compared to that in the plasma, due to the displacement of the electrons by the drift oscillations and the resultant plasma self-shielding. However, the kinetic modeling predictions indicate that the electron impact ionization in the sheaths is largely ineffective, due to the low electron density. The reduction of the electric field in the plasma by the self-shielding in the sheaths is moderate, such that the energy is coupled to the plasma by the below-breakdown RF field. The peak RF field in the plasma is in the range of 15–25 Td, indicating the efficient vibrational excitation of N 2 by electron impact. The modeling predictions suggest that the targeted vibrational excitation of molecular species in a non-self-sustained RF discharge with external ionization is scalable to high pressures, electron densities, and discharge powers. The present approach can be extended to the vibrational excitation of other molecular species where the vibrational relaxation is relatively slow, such as CO, CO 2 , and H 2 .

Physics↗

Life Cycle Emissions Factors for Electricity Generation Technologies

This dataset consists of a table containing the distribution of literature estimates of greenhouse gas emissions for the following electricity generation and storage technologies: biopower, coal, concentrating solar power, geothermal, hydrogen storage, hydropower, lithium-ion battery storage, natural gas, nuclear, ocean, oil, photovoltaic, pumped-storage hydropower, and wind. Quartile estimates of life cycle emissions factors in units of grams of carbon dioxide equivalent per kilowatt hour of generation (g CO2e/kWh) are provided for the following life cycle stages: one-time upstream, ongoing combustion, ongoing non-combustion, one-time downstream, and total. Literature estimates were compiled by the LCA Harmonization study and subsequent updates, as detailed in the factsheet which accompanies this dataset, https://www.nlr.gov/docs/fy21osti/80580.pdf .

01 COAL, LIGNITE, AND PEAT↗

Augmenting Conceptual Design Trajectory Tradespace Exploration with Graph Theory

Within conceptual design changes occur rapidly due to a combination of uncertainty and shifting requirements. To stay relevant in this fluid time, trade studies must also be performed rapidly. In order to drive down analysis time while improving the information gained by these studies, surrogate models can be created to represent the complex output of a tool or tools within a specified tradespace. In order to create this model however, a large amount of data must be collected in a short amount of time. By this method, the historical approach of relying on subject matter experts to generate the data required is schedule infeasible. However, by implementing automation and distributed analysis the required data can be generated in a fraction of the time. Previous work focused on setting up a tool called multiPOST capable of orchestrating many simultaneous runs of an analysis tool assessing these automated analyses utilizing heuristics gleaned from the best practices of current subject matter experts. In this update to the previous work, elements of graph theory are included to further drive down analysis time by leveraging data previously gathered. It is shown to outperform the previous method in both time required, and the quantity and quality of data produced.

Dees, Patrick D.↗

Augmenting Conceptual Design Trajectory Tradespace Exploration with Graph Theory

Within conceptual design changes occur rapidly due to a combination of uncertainty and shifting requirements. To stay relevant in this fluid time, trade studies must also be performed rapidly. In order to drive down analysis time while improving the information gained by these studies, surrogate models can be created to represent the complex output of a tool or tools within a specified tradespace. In order to create this model however, a large amount of data must be collected in a short amount of time. By this method, the historical approach of relying on subject matter experts to generate the data required is schedule infeasible. However, by implementing automation and distributed analysis the required data can be generated in a fraction of the time. Previous work focused on setting up a tool called multiPOST capable of orchestrating many simultaneous runs of an analysis tool assessing these automated analyses utilizing heuristics gleaned from the best practices of current subject matter experts. In this update to the previous work, elements of graph theory are included to further drive down analysis time by leveraging data previously gathered. It is shown to outperform the previous method in both time required, and the quantity and quality of data produced.

Dees, Patrick D.↗

Adaptive Metropolis Sampling with Product Distributions

The Metropolis-Hastings (MH) algorithm is a way to sample a provided target distribution pi(z). It works by repeatedly sampling a separate proposal distribution T(x,x') to generate a random walk {x(t)}. We consider a modification of the MH algorithm in which T is dynamically updated during the walk. The update at time t uses the {x(t' less than t)} to estimate the product distribution that has the least Kullback-Leibler distance to pi. That estimate is the information-theoretically optimal mean-field approximation to pi. We demonstrate through computer experiments that our algorithm produces samples that are superior to those of the conventional MH algorithm.

Wolpert, David H.↗

3DGRAPE/AL User's Manual

This document is a users' manual for a new three-dimensional structured multiple-block volume g generator called 3DGRAPE/AL. It is a significantly improved version of the previously-released a widely-distributed programs 3DGRAPE and 3DMAGGS. It generates volume grids by iteratively solving the Poisson Equations in three-dimensions. The right-hand-side terms are designed so that user-specific; grid cell heights and user-specified grid cell skewness near boundary surfaces result automatically, with little user intervention. The code is written in Fortran-77, and can be installed with or without a simple graphical user interface which allows the user to watch as the grid is generated. An introduction describing the improvements over the antecedent 3DGRAPE code is presented first. Then follows a chapter on the basic grid generator program itself, and comments on installing it. The input is then described in detail. After that is a description of the Graphical User Interface. Five example cases are shown next, with plots of the results. Following that is a chapter on two input filters which allow use of input data generated elsewhere. Last is a treatment of the theory embodied in the code.

Sorenson, Reese L.↗

Selective Depolymerization for Sculpting Polymethacrylate Molecular Weight Distributions

Chain-end reactivation of polymethacrylates generated by reversible-deactivation radical polymerization (RDRP) has emerged as a powerful tool for triggering depolymerization at significantly milder temperatures than those traditionally employed. In this study, we demonstrate how the facile depolymerization of poly(butyl methacrylate) (PBMA) can be leveraged to selectively skew the molecular weight distribution (MWD) and predictably alter the viscoelastic properties of blended PBMA mixtures. By mixing polymers with thermally active chain ends with polymers of different molecular weights and inactive chain ends, the MWD of the blends can be skewed to be high or low by selective depolymerization. This approach leads to the counterintuitive principle of the “destructive strengthening” of a material. As a result, we demonstrate, as a proof of concept, the encryption of information within polymer mixtures by linking Morse code with the MWDs before and after selective depolymerization, allowing for the encoding of data within blends of synthetic macromolecules.

36 MATERIALS SCIENCE↗