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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,333 records · Page 74
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Energy Storage Data Reporting in Perspective—Guidelines for Interpreting the Performance of Electrochemical Energy Storage Systems

Due to the tremendous importance of electrochemical energy storage, numerous new materials and electrode architectures for batteries and supercapacitors have emerged in recent years. Correctly characterizing these systems requires considerable time, effort, and experience to ensure proper metrics are reported. Many new nanomaterials show electrochemical behavior somewhere in between conventional double-layer capacitor and battery electrode materials, making their characterization a non-straightforward task. It is understandable that some researchers may be misinformed about how to rigorously characterize their materials and devices, which can result in inflation of their reported data. Additionally, this is not uncommon considering the current state of the field nearly requires record breaking performance for publication in high-impact journals. Incorrect characterization and data reporting misleads both the materials and device development communities, and it is the shared responsibility of the community to follow rigorous reporting methodologies to ensure published results are reliable to ensure constructive progress. This tutorial aims to clarify the main causes of inaccurate data reporting and to give examples of how researchers should proceed. The best practices for measuring and reporting metrics such as capacitance, capacity, coulombic and energy efficiencies, electrochemical impedance, and the energy and power densities of capacitive and pseudocapacitive materials are discussed.

25 ENERGY STORAGE↗
DOE OSTI2021

Dual-Ion Intercalation and High Volumetric Capacitance in a Two-Dimensional Non-Porous Coordination Polymer

Intercalation is a promising ion-sorption mechanism for enhancing the energy density of electrochemical capacitors (ECs) because it offers enhanced access to the electrochemical surface area. It requires a rapid transport of ions in and out of a host material, and it must occur without phase transformations. Materials that fulfil these requirements are rare; those that do intercalate almost exclusively cations. Herein, we show that Ni3(benzenehexathiol) (Ni 3 BHT), a non-porous two-dimensional (2D) layered coordination polymer (CP), intercalates both cations and anions with a variety of charges. Whereas cation intercalation is pseudocapacitive, anions intercalate in a purely capacitive fashion. The excellent EC performance of Ni3BHT provides a general basis for investigating similar dual-ion intercalation mechanisms in the large family of non-porous 2D CPs.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Electrochemical Capacitance Traces with Interlayer Spacing in Two‐dimensional Conductive Metal–Organic Frameworks

Abstract Electrically conductive metal–organic frameworks (MOFs) are promising candidates for electrochemical capacitors (EC) for fast energy storage due to their high specific surface areas and potential for redox activity. To maximize energy density, traditional inorganic pseudocapacitors have utilized faradaic processes in addition to double‐layer capacitance. Although conductive MOFs are usually comprised of redox active ligands which allow faradaic reactions upon electrochemical polarization, systematic studies providing deeper understanding of the charge storage processes and structure‐function relationships have been scarce. Here, we investigate the charge storage mechanisms of a series of triazatruxene‐based 2D layered conductive MOFs with variable alkyl functional groups, Ni 3 (HIR 3 ‐TAT) 2 (TAT=triazatruxene; R=H, Et, n ‐Bu, n ‐Pent). Functionalization of the triazatruxene core allows for systematic variation of structural parameters while maintaining in‐plane conjugation between ligands and metals. Specifically, R groups modulate interlayer spacing, which in turn shifts the charge storage mechanism from double‐layer capacitance towards pseudocapacitance, leading to an increase in molar specific capacitance from Ni 3 (HIH 3 ‐TAT) 2 to Ni 3 (HIBu 3 ‐TAT) 2 . Partial exfoliation of Ni 3 (HIBu 3 ‐TAT) 2 renders redox active ligand moieties more accessible, and thus increases the dominance of faradaic processes. Our strategy of controlling charge storage mechanism through tuning the accessibility of redox‐active sites may motivate further design and engineering of electrode materials for EC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Suppression of Weakly-Damped Torsional Oscillations in Autonomous Power Systems

Variants are considered for suppression of weakly-damped vibration effects caused by the first critical frequency of torsional oscillations of a gas-turbine unit in the autonomous electric power system of an oil and gas field. It is shown that torsional oscillations can be suppressed with the aid both of a reactive power source installed at the field power system, consisting of a controlled shunt reactor (CSR) and a static capacitor battery, and of an auxiliary active RLC filter, when using in both cases auxiliary control loops of torsional deviation as well as its first and second derivatives. A methodology has been developed for simultaneous coordination of the settings of any regulation system based on a numerical optimization, which permits selecting the characteristics of control loops of the source of reactive power and active RLC filter that are optimal from the point of view of suppressing torsional oscillations.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2018

Developments of Highly Multiplexed, Multi-chroic Pixels for Balloon-Borne Platforms

We present our work to develop and characterize low thermal conductance bolometers that are part of sinuous antenna multi-chroic pixels (SAMP). We use longer, thinner and meandered bolometer legs to achieve 9 pW/K thermal conductance bolometers. We also discuss the development of inductor–capacitor chips operated at 4 K to extend the multiplexing factor of the frequency domain multiplexing to 105, an increase of 60% compared to the factor currently demonstrated for this readout system. This technology development is motivated by EBEX-IDS, a balloon-borne polarimeter designed to characterize the polarization of foregrounds and to detect the primordial gravity waves through their B-mode signature on the polarization of the cosmic microwave background. EBEX-IDS will operate 20,562 transition edge sensor bolometers spread over 7 frequency bands between 150 and 360 GHz. Balloon and satellite platforms enable observations at frequencies inaccessible from the ground and with higher instantaneous sensitivity. This development improves the readiness of the SAMP and frequency domain readout technologies for future satellite applications.

42 ENGINEERING↗
DOE OSTI2018

Effect of High-Gradient Magnetic Field on Electrical Property of Carbon Nanotube-Polypyrrole Composite; Nanotube Separation Mechanism

High- and low-gradient magnetic fields are produced by resistor-inductor-capacitor (RLC) discharge apparatuses. The maximum magnetic field is 12.5 Tesla with 1-ms pulse duration. Multiwall carbon nanotube–polypyrrole composite is prepared. The samples are exposed to high- and low-gradient magnetic fields. To understand the behavior of carbon nanotubes (CNTs) in high-gradient magnetic fields (HGMFs), we theoretically calculated the equivalent magnetic susceptibility of a CNT in the gradient magnetic field. We found that the gradient force which is exerted on a CNT could be repellent or absorbent depending on the parallel and perpendicular susceptibilities of the CNT, as well as on the initial orientation of the CNT with respect to magnetic field direction. Four-probe studies show that the electrical conductivity of CNT composites decreases after exposure to a high-gradient magnetic field. Microscopic observation of the electrical current profile of composites reveals rearrangement of CNTs under HGMF.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Effect of High Magnetic Pulse Iteration on Electrical Property of CNT-Polypyrrole Composite: Alignment Mechanism

In this work, a pulsed magnetic field of 10 T with a duration of 1.5 ms is produced by a resistor-inductor-capacitor (RLC) discharge system. A carbon nanotube-polypyrrole (CNT-PPy) composite (9 wt%) is prepared. The influence of the pulsed magnetic field iteration on the alignment of CNTs embedded in polymer matrix is observed (up to 60 pulses). The microstructure of the magnetically aligned composites is probed by scanning probe microscopy technique. The behavior of a CNT in a magnetic field is theoretically studied, and the equivalent magnetic susceptibility for an anisotropic CNT is calculated. The theory of CNT alignment in a magnetic field is discussed. We found that the perpendicular diamagnetism of a CNT results in its alignment in a magnetic field. We showed that the magnetic torque, which is applied to a CNT, depends on the perpendicular and parallel susceptibilities of the CNT as well as on its initial orientation with respect to the magnetic direction. After exposure to magnetic pulses, the electrical property of the composites is enhanced. The results show that there is a positive correlation between the electrical conductance of CNTs and the number of applied pulses (for 30 pulses). Fourier transform infrared spectroscopy technique is used to control the polymer structure during the experiment. Our theoretical finding reveals the limited capacity of CNT’s alignment in magnetic fields.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Characteristics of the Magnetic Resonance WPT System Applying a Frequency Converter

Recently, studies on the commercialization of magnetic resonance wireless power transfer (WPT) systems are underway domestically and internationally. The magnetic resonance WPT technology enables power transmission between transmitter and receiver coils with the same resonance frequency. If the resonance frequencies of the transmitter coil and receiver coil are different, the efficiency of the WPT will rapidly decrease. Various organizations, such as A4WP, have been striving to standardize resonance frequencies, but the countries around the world are sticking to their own distinctive standards based on the frequency bands available in their territories. Therefore, each country uses a slightly different resonance frequency band. In this paper, a frequency converter that enables WPT when the transmitter and receiver coils have different resonance frequencies is proposed. The frequency converter consists of two coils, and its structure is very simple. The two coils transmit power using the magnetic induction method, and frequency variation is possible using variable capacitors. It was confirmed from the experiment that WPT is possible even if the resonance frequencies of the transmitter and receiver coils are different.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Imaginary resistor based Parity-Time symmetry electronics dimers

An approach of fabricating Parity-Time symmetry electronic dimers circuits is demonstrated using an imaginary resistor Z whose impedance is frequency independent. Remarkably, the dynamic rate equations of the coupled oscillators so-called ZRC dimers, uniquely consist of first order partial differential equations which result in a 2 ×2 effective Hamiltonians commuting with the joint Parity-Time (PT) operator. The method helps in describing two groups of PT symmetry electronics. The first group has an eigenspectrum that displays a single spontaneous PT transition or a thresholdless (THL) PT transition. The second group is a PT transitionless normal mode spectrum with essentially negative values of capacitors. The dynamics indicate that the system exhibits high frequencies propagation when operation is done before the thresholdless point is reached. The transitionless regime indicates an equilibrium point in the coupling for which the system turns to be conservative regardless the gain/loss values, and beyond which the gain/loss remarkably decays/amplifies wave. In addition, we observe a value of gain/loss above which there is a limitation of signal amplification.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Small-Size High-Current Generators for X-Ray Backlighting

The paper deals with the soft X-ray backlighting based on the X-pinch as a powerful tool for physical studies of fast processes. Proposed are the unique small-size pulsed power generators operating as a low-inductance capacitor bank. These pulse generators provide the X-pinch-based soft X-ray source (hν = 1–10 keV) of micron size at 2–3 ns pulse duration. The small size and weight of pulse generators allow them to be transported to any laboratory for conducting X-ray backlighting of test objects with micron space resolution and nanosecond exposure time. These generators also allow creating synchronized multi-frame radiographic complexes with frame delay variation in a broad range.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Synthesis of Flexible Graphene/Polymer Composites for Supercapacitor Applications

In this paper, the graphene was synthesized using biocompatible cellulosic component from onions. Onion epidermal cells were chosen as raw material. During heating at high temperature, the bonding among atoms in material was rearranged and forms two-dimensional hexagonal carbon layer (graphene). The characterization of synthesized graphene was done by x-ray diffractometer, Raman spectrometer and field emission scanning electron microscopy, respectively. An attempt has been taken to form the capacitors with two different current collector electrodes, anticipating the performance of the supercapacitors. The observed capacitance values as-obtained for Al and Au current collector were 1.3 μF and 6.08 μF, respectively. However, when thermally exfoliated graphene was used as an electrode on Al and Au current collector, the capacitance value was drastically increased and found to be 1.6 and 41.25 μF, respectively.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Convex quadratic relaxations for mixed-integer nonlinear programs in power systems

Here, this paper presents a set of new convex quadratic relaxations for nonlinear and mixed-integer nonlinear programs arising in power systems. The considered models are motivated by hybrid discrete/continuous applications where existing approximations do not provide optimality guarantees. The new relaxations offer computational efficiency along with minimal optimality gaps, providing an interesting alternative to state-of-the-art semidefinite programming relaxations. Finally, three case studies in optimal power flow, optimal transmission switching and capacitor placement demonstrate the benefits of the new relaxations.

42 ENGINEERING↗
DOE OSTI2023

Correlation between cation order/disorder and the electrocaloric effect in the MLCCs of complex perovskite ferroelectrics

The physical properties (dielectric, ferroelectric, piezoelectric, etc.) of complex perovskite ferroelectrics depend on the degree of order/disorder and the scale of the ordered domains. In this study, the electrocaloric (EC) properties of three representative complex perovskite ferroelectrics, Pb(Mg 1/3 Nb 2/3 )O 3 -8PbTiO 3 (PMN-8PT), 1mol% Sm-doped Pb(Mg 1/3 Nb 2/3 )O 3 -8PbTiO 3 (1S-PMN-8PT) and Pb(Sc 1/2 Ta 1/2 )O 3 (PST) are evaluated. Multi-layer ceramic capacitors (MLCCs) with identical structural configurations were fabricated for these three compounds, and their EC properties were characterized by direct measurement using a thermocouple. The EC temperature change of PMN-8PT, 1S-PMN-8PT and PST MLCCs under 20 V μm –1 at room temperature were found to be 1.42 K, 1.54 K, and 3.10 K, respectively. X-ray diffraction and high-resolution transmission electron microscopy data suggests that the high EC performance of PST is related to the ordering of B-site cations (Sc 3+ and Ta 5+ ) with the ordering parameter S = 0.82 and a long coherence length of ~100 nm, such that the sample transitioned from a relaxor ferroelectric to a normal ferroelectric. Furthermore, these results provide pathway towards design of high performance EC materials required for solid state refrigeration and air-conditioning technologies.

36 MATERIALS SCIENCE↗
DOE OSTI2014

A generalized multi-dimensional mathematical model for charging and discharging processes in a supercapacitor

A generalized three dimensional computational model based on unied formulation of electrode- electrolyte-electrode system of a electric double layer supercapacitor has been developed. The model accounts for charge transport across the solid-liquid system. This formulation based on volume averaging process is a widely used concept for the multiphase ow equations ([28] [36]) and is analogous to porous media theory typically employed for electrochemical systems [22] [39] [12]. This formulation is extended to the electrochemical equations for a supercapacitor in a consistent fashion, which allows for a single-domain approach with no need for explicit interfacial boundary conditions as previously employed ([38]). In this model it is easy to introduce the spatio-temporal variations, anisotropies of physical properties and it is also conducive for introducing any upscaled parameters from lower length{scale simulations and experiments. Due to the irregular geometric congurations including porous electrode, the charge transport and subsequent performance characteristics of the super-capacitor can be easily captured in higher dimensions. A generalized model of this nature also provides insight into the applicability of 1D models ([38]) and where multidimensional eects need to be considered. In addition, simple sensitivity analysis on key input parameters is performed in order to ascertain the dependence of the charge and discharge processes on these parameters. Finally, we demonstarted how this new formulation can be applied to non-planar supercapacitors

Single Domain↗
DOE OSTI2016

Fabrication and applications of copper sulfide (CuS) nanostructures

This review article presents different fabrication procedures (under the headlines of solvothermal routes, aerosol methods, solution methods and thermolysis), and applications (photocatalytic degradation, ablation of cancer cells, electrode material in lithium ion batteries and in gas sensing, organic solar cells, field emission properties, super capacitor applications, photoelectrochemical performance of QDSCs, photocatalytic reduction of organic pollutants, electrochemical bio sensing, enhanced PEC characteristics of pre-annealed CuS film electrodes) of copper sulfide (Covellite). - Highlights: • This review article presents the synthesis and applications of copper sulfide. • CuS has been used over the years for different applications in nanoscience. • Different synthetic protocols are followed for their preparation which help in the possible modifications in the morphology of CuS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

High energy storage properties of (Ni1/3Nb2/3)4+ complex-ion modified (Ba0.85Ca0.15)(Zr0.10Ti0.90)O3 ceramics

Highlights: • BCZT-xNN ceramics showed single phase perovskite structure without an obvious second phase after adding NN, and exhibited both good temperature (−55 to 160 °C) and frequency (10{sup 2}–10{sup 7} Hz) stability. • The highest energy storage density can reach 0.66 J/cm{sup 3} and the energy efficiency is 88.1% was achieved in x = 0.3. • The environmental friendly (lead-free) BCZT-xNN ceramics are good candidate for application in energy storage devices. • This paper also developes a new method to obtain high energy storage density and efficiency of ceramic capacitor, which aims to adjust the T{sub c} of ceramics far below room temperature. - Abstract: In this study, paraelectric ceramics, (Ba{sub 0.85}Ca{sub 0.15})(Zr{sub 0.10}Ti{sub 0.90}){sub 1-x}(Ni{sub 1/3}Nb{sub 2/3}){sub x}O{sub 3,} abbreviated as BCZT-xNN (with x = 0.1, 0.2, 0.3, 0.4) were prepared via a solid-state reaction method. By introducing a B-site complex-ion, (Ni{sub 1/3}Nb{sub 2/3}){sup 4+}, the Curie temperature of the ceramic could be reduced to below room temperature. The effects of this B-site (Ni{sub 1/3}Nb{sub 2/3}){sup 4+} complex-ion substitution on the phase structure, surface microstructure as well as the dielectric, ferroelectric, and energy storage properties of the ceramic were systematically investigated. After adding NN, BCZT-xNN shows a single phase perovskite structure without evidence of a second phase . In addition, we observed high stability with respect to both temperature (−55 to 160 °C) and frequency (10{sup 2}–10{sup 7} Hz). Doping with NN produces slim polarization-electric field hysteresis loops and enhanced energy storage properties, while the efficiency decreases. When x = 0.3, the highest energy storage density reached 0.66 J/cm{sup 3} for a high electric field (20 kV/mm), and the respective energy efficiency was 88.1%. These properties indicate that the environmental friendly BCZT-xNN ceramics are promising candidates for commercial energy storage devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Enhanced temperature-stable dielectric properties in oxygen annealed 0.85(K0.5Na0.5)NbO3-0.15SrZrO3 ceramic

Highlights: • Prepared O{sub 2}-annealed KNN-15SZ could meet the EIA X8R specification. • Oxygen annealing resulted in different variation of T{sub m} of cores and shells. • Variation of T{sub m} related to decrease of oxygen vacancies and diffusion of KNN. • Enhanced dielectric temperature stability attributed to change of PNRs size. - Abstract: The structure, morphology and dielectric properties of the oxygen annealed (O{sub 2}-annealed) and untreated (as-prepared) 0.85(K{sub 0.5}Na{sub 0.5}) NbO{sub 3}-0·15SrZrO{sub 3} (KNN-15SZ) ceramics were investigated. The temperature dependence of dielectric permittivity shows two diffuse dielectric peaks associated with duplex core-shell structure, leading to relatively stable dielectric permittivity in a wide temperature range. Interestingly, the O{sub 2}-annealed sample with the operating temperature range of −104 °C–157 °C could meet the EIA X8R specification, which is superior to the as-prepared one (−98 °C–130 °C) for the EIA X7R specification. Furthermore, the dielectric contribution from cores and shells of both samples was divided by the Lorentz fitting. The relation between relaxation frequency and temperature of both samples obeyed the Vogel-Fulcher law. This finding could pave a possible way to modify dielectric temperature stability for multilayer ceramic chip capacitors applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗