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At least 1,333 records · Page 74
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NASA NTRS1989

Spectral shifts of methane lines in collisions with hydrogen, helium, nitrogen, and argon

Pressure-induced shifts of rotational-vibrational lines in CH4 have been measured at very high spectral resolution in the R-branch of the 3nu(3) overtone. The colliding gases were H2, He, N2, and Ar. Results are presented as functions of rotational and tetrahedral quantum numbers. Mean values (in 0.001/cm per torr) for the R0-R6 multiplets are -0.01109 (CH4-H2), +0.00547 (opposite sense) (CH4-He), -0.01990 (CH4-N2), and -0.02126 (CH4-Ar).

Fox, Kenneth↗
NASA NTRS1990

Mass fractionation of noble gases in diffusion-limited hydrodynamic hydrogen escape

The theory of mass fractionation by hydrogen is presently extended to atmospheres in which hydrogen is not the major constituent. This theoretical framework is applied to three different cases. In the first, it is shown that the fractionation of terrestrial atmospheric neon with respect to mantle neon is explainable as a consequence of diffusion-limited hydrogen escape from a steam atmosphere toward the end of the accretion process. In the second, the anomalously high Ar-38/Ar-36 ratio of Mars is shown to be due to hydrodynamic fractionation by a vigorously escaping and very pure hydrogen wind. In the last case, it is speculated that the currently high Martian D/H ratio emerged during the hydrodynamic escape phase which fractionated Ar.

Zahnle, Kevin↗
NASA NTRS1990

Transformation of vector magnetograms and the problems associated with the effects of perspective and the azimuthal ambiguity

Off-center vector magnetograms which use all three components of the measured field provide the maximum information content from the photospheric field and can provide the most consistent potential field independent of the viewing angle by defining the normal component of the field. The required transformations of the magnetic field vector and the geometric mapping of the observed field in the image plane into the heliographic plane have been described. Here we discuss the total transformation of specific vector magnetograms to detail the problems and procedures that one should be aware of in analyzing observational magnetograms. The effect of the 180-deg ambiguity of the observed transverse field is considered as well as the effect of curvature of the photosphere. Specific results for active regions AR 2684 (September 23, 1980) and AR 4474 (April 26, 1984) from the Marshall Space Flight Center Vector magnetograph are described which point to the need for the heliographic projection in determining the field structure of an active region.

Gary, G. Allen↗
NASA NTRS1990

Nonpotential magnetic fields at sites of gamma-ray flares

The relation between the degree of nonpotentiality of photospheric magnetic fields and the occurrence of gama-ray flares is examined to determine whether there are special signatures of the stressed fields for this type of flare. Observations of the flares in the active region of April 1984 (AR 4474) are analyzed, showing that the big flare initiated at the location on the magnetic neutral line where the field deviated the most from a potential field. The nonpotential signatures of AR 4474 are compared with those of four other regions. The results suggest that gamma-ray flares are associated with strongly nonpotential fields that extend over relatively larger lengths of the magnetic neutral line that the fields associated with flares that do not produce gamma-ray events.

Hagyard, M. J.↗
NASA NTRS1990

Solar coronal Ar/Fe and Ne/Mg abundance ratios derived from ultraviolet forbidden line spectra

An Ar/Fe abundance ratio of 0.031 + or - 35 percent and an upper limit of 0.4 to the Ne/Mg abundance ratio are determined for solar coronal active regions using solar spectra. Forbidden lines occur at 1324.45 A for Mg V, 1349.38 A for Fe XII, 1375.98 A for Ca XV, and 1392.12 A for Ar XI. The unobserved Ne V line is predicted to fall at 1574.68 A. These abundance ratios are consistent with lower abundances of Ne and Ar in the corona relative to low first ionization potential elements.

Doschek, G. A.↗
NASA NTRS1990

A model for the production of cosmogenic nuclides in chondrites

A model is presented for calculating the production rates of cosmic-ray-produced He, Ne, and Ar as well as Be-10, Al-26, and Mn-53 in chondrites of variable size and shape. The predictions of this model are compared with published data for the meteorites ALH78084, St. Severin, and Keyes. The agreement is found to be about 5 percent for the concentrations of Be-10, Ne-21, Ne-22, Ar-38, and Mn-53, and to be better than 1 percent for the Ne-22/Ne-21 ratios. The correlation between P(Be-10)/P(Ne-21) and Ne-22/Ne-21 ratios is experimentally verified over a wide range of irradiation conditions.

Graf, TH.↗
NASA NTRS1991

Probable age of Autolycus and calibration of lunar stratigraphy

Ar-39 - Ar-40 analyses of three petrographically distinct, shocked Apollo 15 KREEP (i.e., high K, rare earth element, P, and other trace element contents) basalt samples demonstrate that a major impact event affected all three samples at about 2.1 Ga. The Copernican System craters Aristillus and Autolycus are to the north. Autolycus, the older of the two, is in a particularly appropriate terrain and is the most likely source of the 2.1 Ga heating and delivery event. With this calibration point, and if Autolycus really is a Copernican crater, the Copernican System lasted twice as long as has previously been suggested. Furthermore, the moon was not subjected to a constant cratering rate over the past 3 billion years; the average rate in the preceding Eratosthenian must have been twice that in the Copernican.

Ryder, G.↗
NASA NTRS1991

Searching for Crisium Basin ejecta - Chemistry and ages of Luna 20 impact melts

Chemical (INAA) and chronological (Ar-40 - Ar-39) analyses of six Luna 20 impact melts are performed, and these are compared to the results of Podosek et al. (1973), commonly taken to be representative of the Crisium Basin impact. At least two chemical groups of impact melts are identified. One is interpreted as melts derived from the local crust by craters over the last 3.9 Ga. Another group, which includes one of the samples dated by Podosek et al. (1973), is chemically and chronologically (3.85 + or - 0.02 Ga) indistinguishable from Apollo 17 samples interpreted as Serenitatis impact melts, and hence could be melt formed by that event and deposited at the Luna 20 site. One sample (22023,3,F) has a well-defined age of 3.895 + or - 0.017 Ga, and is chemically similar to, but distinct from, impact melts from other basins. This sample, and its chemistry and age are tentatively identified with the Crisium Basin impact. Whether the age of the Crisium impact is given by 22023,3,F, the samples analyzed by Podosek et al. (1973), or neither, it is clear that Crisium impact melt is not abundant in the Luna 20 collection.

Swindle, T. D.↗
NASA NTRS1991

A reevaluation of the solar-wind sputtering rate on the lunar surface

Knowledge of the retention efficiency for solar-wind-implanted Ar-36 in lunar surface material and measurement of the Ar-36 concentration in a sputtered surface make it possible to calculate an upper limit to the effective sputtering rate at which that surface has been eroded. On the basis of data for 71501 plagioclase and the glass of rock 12054, a value is derived for the sputter-erosion rate equal to less than 0.0024 + or - 0.001 A/yr, in good agreement with the limit of less than 0.0035 A/yr previously calculated by Zinner et al. (1977).

Kerridge, J. F.↗
NASA NTRS1991

Argon adsorption and the lunar atmosphere

The results of Ar adsorption experiments on a terrestrial labradorite and lunar rock 15415 crushed in vacuo are reported. The experiments were designed to test lunar atmosphere simulation models for the behavior of Ar on the lunar surface, as determined from the Apollo 17 mass spectrometer results. These models (Hodges, 1980, 1982) used a single adsorption potential to characterize the surfaces of lunar soil grains, with the result that high (6-7 kcal/mol) heats of adsorption were inferred. The present experimental results show that very high adsorption potentials are indeed associated with fresh mineral surfaces, but that these energetic surfaces occupy only small fractions of the total surface area. Nonetheless, these small fractions of surface, if they can be maintained in the lunar regolith in steady-state condition, could be sufficient to account for the Apollo 17 mass spectrometer observations.

Bernatowicz, T. J.↗
NASA NTRS1991

Modeling the Orion nebula as an axisymmetric blister

The ionized gas in the Orion nebula is examined by means of axisymmetric modeling that is based on observational data from the ionized, neutral, and molecular regions. Nonsymmetrical features are omitted, radial dependence from the Trapezium is assumed, and azimuthal symmetry in the plane of the sky is used. Stellar properties and abundances of certain elements are described, and these data are used to compare the present axisymmetric-blister model to a previous spherical model. Strong singly-ionized emission that are visible near the Trapezium are found to originate in the ionization-bounded region in the dense Trapezium zone. The model can be more tightly constrained by adding near-IR data on noncentral zones for (Ar II), (AR III), (Ne II), and (S IV). The quadrant with the 'bar' creates an nonsymmetry that influences the observational data, and the model can therefore be improved with the additional data.

Rubin, R. H.↗
NASA NTRS1991

Revived interest in the lunar atmosphere

The recent discoveries of Na and K in the lunar atmosphere are emphasized in a review of lunar atmospheric observations which identifies possible directions of research. Observations are briefly reviewed through the Apollo era which identified the atmosphere as a surface-boundary exosphere, and identified atmospheric constituents included He and Ar which rose and fell by a factor of 20 during the lunar diurnal cycle. Ar-36 and -40 were also identified as were the sources of ionospheric source and sink processes including the solar EUV flux. Na and K are discussed which were identified in a study of the spectroscopic ring effect, and the effects of elemental interaction with the lunar surface can be approximated in laboratory experiments. Observations and measurements of the lunar surface are important for the continued investigation of lunar and other planetary mechanisms.

Morgan, Thomas H.↗
NASA NTRS1991

Macromolecular recognition: Structural aspects of the origin of the genetic system

Theoretical simulation of prebiotic chemical processes is an invaluable tool for probing the phenomenon of the evolution of life. Using computational and modeling techniques and guided by analogies from present day systems, we seek to understand the emergence of the genetic apparatus, enzymatic catalysis and protein synthesis under prebiotic conditions. Modeling of the ancestral aminoacyl-tRNA-synthetases (aRS) may provide important clues to the emergence of the genetic code and the protein synthetic machinery. The minimal structural requirements for the catalysis of tRNA aminoacylation are being explored. A formation of an aminoacyl adenylate was studied in the framework of ab initio molecular orbital theory. The role of individual residues in the vicinity of the TyrRS active site was examined, and the effect of all possible amino acids substitutions near the active site was examined. A formation of aminoacyl tRNA was studied by the molecular modeling system SYBYL with the high resolution crystallographic structures of the present day tRNA, aRS's complexes. The ultimate goal is to propose a simple RNA segment that is small enough to be build in the primordial chemical environment but maintains the specificity and catalytic activity of the contemporary RNA enzyme. To understand the mechanism of ribozyme catalyzed reactions, ab initio and semi-empirical (ZINDO) programs were used to investigate the reaction path of transphosphorylation. A special emphasis was placed on the possible catalytic and structural roles played by the coordinated magnesium cation. Both the inline and adjacent mechanisms of transphosphorylation were studied. The structural characteristics of the target helices, particularly a possible role for the G-T pair, is also studied by a molecular dynamics (MD) simulation technique.

Rein, Robert↗
NASA NTRS1991

Automation of closed environments in space for human comfort and safety

The results of the second year of a three year design project on the automation of the Environmental Control and Life Support System (ECLSS) of the Space Station Freedom (SSF) are presented. The results are applicable to other space missions that require long duration space habitats. A description of conceptual controls which are developed for the Water Recovery and Management (WRM) Subassembly is given. Mathematical modeling of the Air Revitalization (AR) Subassembly is presented. The work done by the Kansas State University NASA/USRA interdisciplinary student design team is concluded with a discussion of the expert system which was developed for the AR Subassembly.

Source record↗
NASA NTRS1990

Studies in general aviation aerodynamics

The Department of Aerospace Engineering at the University of Maryland has completed a research study for NASA Langley on the application of drooped leading edges to high aspect wings. The experimental study conducted for this grant was a natural extension of work previously conducted at NASA Ames, the University of Michigan, NASA Langley and the University of Maryland. Previous research had shown that wing planform modifications (commonly referred to as drooped leading edge mods) could have a significant effect on reducing or eliminating the stall/spin characteristics of General Aviation (GA) aircraft. All aircraft studied in the earlier work had relatively low aspect ratio wings (AR = 6). Since future GA aircraft will feature higher aspect ratio wings, the obvious question was: how well will the dropped leading edge work on higher aspect ratio wings? The focus of the current study was to examine the effectiveness of the drooped leading edge modifications to higher aspect ratio wings with AR = 9 to 12.

Winkelmann, Allen E.↗
NASA NTRS1992

Volatile tracers of Martian atmospheric evolution: Present measurement status and requirements for future investigations

One of the most significant contributions to the detailed characterization of the molecular, atomic, and isotopic composition of the Martian atmosphere came from the Viking mass spectrometer experiments. Measurement of the abundance of the noble gases Ne, Ar, Kr, and Xe, as well as major molecular species was achieved together with some of the important isotopic compositions such as N-15/N-14, Ar-36/Ar-40, and others. The isotopic characterization, a key element to an understanding of atmospheric evolution, advanced further with recent measurements of the deuterium/hydrogen (D/H) ratio from HDO as well as the detailed study of gases contained in meteorites thought to be Martian origin.

Mahaffy, Paul↗
NASA NTRS1991

Numerical investigation on Benard instability in a finite liquid layer

A numerical procedure for directly simulating the Benard-Marangoni instabilities (B-M-I) in a bounded liquid layer is presented in this paper. The procedure consists of applying a finite amplitude disturbance to the basic static state, and then integrating the Navier-Stokes equations to determine whether the disturbance will die down or will reach a state of finite-strength steady convection. The critical Marangoni number (Mac) for the onset of B-M-I can thus be determined and can be correlated as a function of the aspect ratio (Ar), Prandtl number (Pr), and Rayleigh number (Ra). The Biot number (B) between the liquid and the air is analyzed to approximate the heat transfer condition along the free surface. A 2D calculation is performed to investigate the effect of various initial disturbances, and the Mac is determined for Ar = 2, Ra = 0, and Pr = 0.7. Current results show that disturbances of different nature and amplitude have little effect on Mac. The Mac determined in this study also clearly demonstrates the dominant effect of the sidewalls.

Duh, J. C.↗
NASA NTRS1992

State-to-state rotational energy-transfer measurements in the nu(2) = 1 state of ammonia by infrared-infrared double resonance

The state-resolved rotational (R-R, R-T) energy transfer in (N-14)H3 (for NH3-NH3 and NH3-Ar collisions) was studied using an IR double-resonance laser spectroscopic technique. Measurements of both the total rate of depopulation by collisions, and the rates of transfer into specific final rovibrational states (v,J,K) were performed using time-resolved tunable diode laser absorption spectroscopy. A kinetic master-equation analysis of time-resolved level populatons was carried out, yielding state-to-state rate constants and propensity rules for NH3-NH3 and NH3-Ar collisions.

Abel, Bernd↗