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NASA NTRSDate not supplied

The GeoGLOWS Project: Essential Water Variables and Observations – Expected Value Chain, Products, Examples

Essential Water Variables (EWV) were developed over the last decade to ensure that key datasets were made available for closing the global water budget, and addressing the many international actions that require water data. Satellite, surface, and numerical model data all have a role in providing EWVs, and it is a key point that these data must be merged and then fed into decision support applications to answer all the needs of the panoply of user communities. The more specialized the applications become, the higher the demand for development and maintenance resources. Some examples of applications include the NASA Goddard Giovanni, which provides on-line data access and simple analysis; the Global Flood Monitor, which focuses on precipitation-driven flooding; the NASA Landslide Hazard Assessment for Situational Awareness, which similarly treats landslides; and the Global Streamflow Forecasting Project, which provides multiple decision support interfaces, as well as a general toolkit for building new interfaces.

Essential Water Variables↗
NASA NTRS1973

Lunar composition from Apollo orbital measurements.

Several spectrometers carried in the Service Module of the Apollo 15 and Apollo 16 spacecraft were employed for the compositional mapping of the lunar surface. The observations involved the measurements of secondary (fluorescent) X-rays, gamma-rays and alpha particle emissions. A large scale compositional map of over 20 percent of the lunar surface was obtained for the first time. It was possible to demonstrate interesting chemical differences between the mare and the highlands, to find specific areas of high radioactivity and to learn something about the composition of the moon's hidden side.

Adler, I.↗
NASA NTRS1985

Ground Reflectance Measurements from Thematic Mapper Data

Satellite radiance data are measures of solar radiation that has been reflected by the Earth's surface and scattered and absorbed by atmospheric gases and aerosols. Of concern to geologists are the surface reflectance and the degrading effects on surface resolution and albedo contrast introduced by atmospheric phenomena. The objects of this research have been to: (1) provide an empirical relationship between scanner radiance and ground reflectance allowing interpretation of the satellite data in terms of the surface parameter, and (2) assess the precision with which surface spectral reflectance may be recovered from LANDSAT-4 TM data in the presence of perturbing atmospheric and instrumental factors. The approach is field-oriented, and utilizes ground observations of surface spectral reflectance with portable spectrometers and radiometers to develop the required empirical relationships.

Conel, J. E.↗
NASA NTRS2013

Dual-Polarization, Multi-Frequency Antenna Array for use with Hurricane Imaging Radiometer

Advancements in common aperture antenna technology were employed to utilize its proprietary genetic algorithmbased modeling tools in an effort to develop, build, and test a dual-polarization array for Hurricane Imaging Radiometer (HIRAD) applications. Final program results demonstrate the ability to achieve a lightweight, thin, higher-gain aperture that covers the desired spectral band. NASA employs various passive microwave and millimeter-wave instruments, such as spectral radiometers, for a range of remote sensing applications, from measurements of the Earth's surface and atmosphere, to cosmic background emission. These instruments such as the HIRAD, SFMR (Stepped Frequency Microwave Radiometer), and LRR (Lightweight Rainfall Radiometer), provide unique data accumulation capabilities for observing sea surface wind, temperature, and rainfall, and significantly enhance the understanding and predictability of hurricane intensity. These microwave instruments require extremely efficient wideband or multiband antennas in order to conserve space on the airborne platform. In addition, the thickness and weight of the antenna arrays is of paramount importance in reducing platform drag, permitting greater time on station. Current sensors are often heavy, single- polarization, or limited in frequency coverage. The ideal wideband antenna will have reduced size, weight, and profile (a conformal construct) without sacrificing optimum performance. The technology applied to this new HIRAD array will allow NASA, NOAA, and other users to gather information related to hurricanes and other tropical storms more cost effectively without sacrificing sensor performance or the aircraft time on station. The results of the initial analysis and numerical design indicated strong potential for an antenna array that would satisfy all of the design requirements for a replacement HIRAD array. Multiple common aperture antenna methodologies were employed to achieve exceptional gain over the entire spectral frequency band while exhibiting superb VSWR (voltage standing wave ratio) values. Element size and spacing requirements were addressed for a direct replacement of the thicker, lower-performance, stack ed patch antenna array currently employed for the HIRAD application. Several variants to the multiband arrays were developed that exhibited four, equally spaced, high efficiency, "sweet spot" frequency bands, as well as the option for a high-performance wideband array. The 0.25-in. (≈6.4- mm) thickness of the antenna stack-up itself was achieved through the application of specialized antenna techniques and meta-materials to accomplish all design objectives.

Little, John↗
NASA NTRS2014

Improved Satellite Retrievals of NO2 and SO2 over the Canadian Oil Sands and Comparisons with Surface Measurements

Satellite remote sensing is increasingly being used to monitor air quality over localized sources such as the Canadian oil sands. Following an initial study, significantly low biases have been identified in current NO2 and SO2 retrieval products from the Ozone Monitoring Instrument (OMI) satellite sensor over this location resulting from a combination of its rapid development and small spatial scale. Air mass factors (AMFs) used to convert line-of-sight "slant" columns to vertical columns were re-calculated for this region based on updated and higher resolution input information including absorber profiles from a regional-scale (15 km × 15 km resolution) air quality model, higher spatial and temporal resolution surface reflectivity, and an improved treatment of snow. The overall impact of these new Environment Canada (EC) AMFs led to substantial increases in the peak NO2 and SO2 average vertical column density (VCD), occurring over an area of intensive surface mining, by factors of 2 and 1.4, respectively, relative to estimates made with previous AMFs. Comparisons are made with long-term averages of NO2 and SO2 (2005-2011) from in situ surface monitors by using the air quality model to map the OMI VCDs to surface concentrations. This new OMI-EC product is able to capture the spatial distribution of the in situ instruments (slopes of 0.65 to 1.0, correlation coefficients of greater than 0.9). The concentration absolute values from surface network observations were in reasonable agreement, with OMI-EC NO2 and SO2 biased low by roughly 30%. Several complications were addressed including correction for the interference effect in the surface NO2 instruments and smoothing and clear-sky biases in the OMI measurements. Overall these results highlight the importance of using input information that accounts for the spatial and temporal variability of the location of interest when performing retrievals.

surface concentration↗
NASA NTRS1997

Auger Spectroscopy of Hydrogenated Diamond Surfaces

An energy shift and a change of the line shape of the carbon core-valence-valence Auger spectra are observed for diamond surfaces after their exposure to an electron beam, or annealing at temperatures higher then 950 C. The effect is studied for both natural diamond crystals and chemical-vapor-deposited diamond films. A theoretical model is proposed for Auger spectra of hydrogenated diamond surfaces. The observed changes of the carbon Auger line shape are shown to be related to the redistribution of the valence-band local density of states caused by the hydrogen desorption from the surface. One-electron calculation of Auger spectra of diamond surfaces with various hydrogen coverages are presented. They are based on self-consistent wave functions and matrix elements calculated in the framework of the local-density approximation and the self-consistent linear muffin-tin orbital method with static core-hole effects taken into account. The major features of experimental spectra are explained.

Krainsky, I. L.↗
DOE OSTI2019

Bulk Fermi surface of the Weyl type-II semimetallic candidate NbIrTe 4

Recently, a new group of layered transition-metal tetra-chalcogenides was proposed via first-principles calculations to correspond to a new family of Weyl type-II semimetals with promising topological properties in the bulk as well as in the monolayer limit. In this paper, we present measurements of the Shubnikov-de Haas (SdH) and de Haas-van Alphen effects under high magnetic fields for the type-II Weyl semimetallic candidate NbIrTe 4 .We find that the angular dependence of the observed Fermi surface extremal cross-sectional areas agree well with our density functional theory (DFT) calculations supporting the existence ofWeyl type-II points in this material. Although we observe a large and nonsaturating magnetoresistivity in NbIrTe 4 under fields all the way up to 35 T, Hall-effect measurements indicate that NbIrTe 4 is not a compensated semimetal. The transverse magnetoresistivity displays a fourfold angular dependence akin to the so-called butterfly magnetoresistivity observed in nodal line semimetals. Finally, we conclude that the magnetoresistivity and its unconventional angular dependence are governed by the topography of the Fermi surface and the resulting anisotropy in effective masses and in carrier mobilities.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Air-sea fluxes and surface layer turbulence around a sea surface temperature front

The observed effects of sharp changes in sea surface temperature (SST) on the air-sea fluxes, surface roughness, and the turbulence structure in the surface layer and the marine atmospheric boundary layer are discussed. In situ flux and turbulence observations were carried out from three aircraft and two ships within the FASINEX framework. Three other aircraft used remote sensors to measure waves, microwave backscatter, and lidar signatures of cloud tops. Descriptions of the techniques, intercomparison of aircraft and ship flux data, and use of different methods for analyzing the fluxes from the aircraft data are described. Changing synoptic weather on three successive days yielded cases of wind direction both approximately parallel and perpendicular to a surface temperature front. For the wind perpendicular to the front, wind over both cold-to-warm and warm-to-cold surface temperatures occurred. Model results consistent with the observations suggest that an internal boundary layer forms at the SST.

Friehe, C. A.↗
DOE OSTI2016

The effect of charging rate on the graphite electrode of commercial lithium-ion cells: A post-mortem study

Increased charging rates negatively affect the lifetime of lithium-ion cells by increasing cell resistance and reducing capacity. This work is a post-mortem study of 18650 cells subjected to charge rates of 0.7-, 2-, 4-, and 6-C. For cells charged at 0.7-C to 4-C, this performance degradation is primarily related to surface film thickness with no observable change in surface film chemical composition. However, at charge rates of 6-C, the chemical composition of the surface film changes significantly, suggesting that this change is the reason for the sharper increase in cell resistance compared to the lower charge rates. In addition, we found that surface film formation was not uniform across the electrode. Surface film was thicker and chemically different along the central band of the electrode “jelly roll”. This result is most likely attributable to an increase in temperature that results from non-uniform electrode wetting during manufacture. As a result, this non-uniform change further resulted in active material delamination from the current collector owing to chemical changes to the binder for the cell charged at 6-C.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2019

Hillock formation in co-deposited thin films of immiscible metal alloy systems

Hillocks are protruding sections of a surface that can influence the electronic and mechanical properties of a thin film. In monolithic films, these hillocks are formed due to thermally induced stress gradients during deposition. In this study, the surface morphology of co-sputtered immiscible Cu-X (X is a body centered cubic (BCC) group V or VI metal) thin films is characterized to elucidate the conditions that lead to hillock formation. Cu-Ta and Cu-Mo-Ag films were co-deposited with physical vapor deposition (PVD) magnetron sputtering at 25, 400, 600, and 800°C. A significant number of homogeneously distributed surface hillocks were observed only in the 600 and 800°C films. High-angle annular dark field (HAADF) cross-sectional imaging revealed significant Cu agglomerations underneath the protruding features. For the Cu-Ta films, the Cu was enveloped in a Cu-Ta nanocrystalline matrix. For Cu-Mo-Ag, the Cu was surrounded by Mo-Ag concentration modulations. While thermal stress gradients arise during deposition of immiscible metal films, biaxial stress calculations and literature cases reveal that they are not solely responsible for hillock formation. The observed morphologies align with a surface diffusion kinetic model that evaluates diffusion length of adatoms during deposition as a function of deposition temperature. Finally, this indicates a phase separation driving force paired with the constituent elements’ dissimilar mobilities at elevated deposition temperatures contribute to the presence of hillocks.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Comparison of thermal oxidation and plasma oxidation of 4H-SiC (0001) for surface flattening

The thermal oxidation and water vapor plasma oxidation of 4H-SiC (0001) were investigated. The initial oxidation rate of helium-based atmospheric-pressure plasma oxidation was six times higher than that of thermal oxidation. The oxide-SiC interface generated by plasma oxidation became flatter with increasing thickness of the oxide, whereas the interface generated by thermal oxidation was atomically flat regardless of the oxide thickness. Many pits were generated on the thermally oxidized surface, whereas few pits were observed on the surface oxidized by plasma. After the oxide layer generated plasma oxidation was removed, an atomically flat and pit-free SiC surface was obtained.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Electronic structure of non-centrosymmetric PtBi2 studied by angle-resolved photoemission spectroscopy

Using high-resolution angle-resolved photoemission spectroscopy (ARPES), we have systematically studied the electronic structure of non-centrosymmetric PtBi2 with a layered structure. Through photon energy dependent measurements, the surface state and the bulk state were identified. Consistent with the non-centrosymmetric structure, different surface states were observed on opposite PtBi2(001) surfaces. Experimental bulk bands agree nicely with first-principle calculations. By combining ARPES and calculations, energy bands that contribute to triply degenerate point fermion were all detected. We also suggest that there are “canted” tube-like Fermi surfaces that might cause strong anisotropy in electronic transportation in non-centrosymmetric PtBi2.

Jiang, Wenxiang (ORCID:000000020524259X)↗
DOE OSTI2018

Colors of Centaurs observed by the Subaru/Hyper Suprime-Cam and implications for their origin

Abstract Centaurs have orbits between Jupiter and Neptune and are thought to originate from the trans-Neptunian region. Observations of surface properties of Centaurs and comparison with those of trans-Neptunian objects (TNOs) would provide constraints on their origin and evolution. We analyzed imaging data of nine known Centaurs observed by the Hyper Suprime-Cam (HSC) installed on the Subaru Telescope with the g- and i-band filters. Using the data available in the public HSC data archive, as well as those obtained by the HSC Subaru Strategic Program (HSC-SSP) by the end of 2017 June, we obtained the g − i colors of the nine Centaurs. We compared them with those of known TNOs in the HSC-SSP data obtained by T. Terai et al. (2018, PASJ, 70, S40). We found that the color distribution of the nine Centaurs is similar to that of those TNOs with high orbital inclinations, but distinct from those TNOs with low orbital inclinations. We also examined correlations between the colors of these Centaurs and their orbital elements and absolute magnitude. The Centaurs’ colors show a moderate positive correlation with semi-major axis, while no significant correlations between the color and other orbital elements or absolute magnitude were found for these Centaurs. On the other hand, recent studies on Centaurs with larger samples show interesting correlations between their color and absolute magnitude or orbital inclination. We discuss how our data fit in these previous studies, and also discuss implications of these results for their origin and evolution.

Sakugawa, Haruka↗
NASA NTRS1973

Position from gravity

Procedures for obtaining position from surface gravity observations are reviewed and their relevance assessed in the context of the application of modern geodetic techniques to programs of Earth and ocean physics. Solutions based on the use of surface layer techniques, the discrete value approach, and the development from Green's theorem are stated in summary, the latter being extended to order e cubed in the height anomaly. The representation of the surface gravity field which is required in order that this accuracy may be achieved is discussed. Interim techniques which could be used in the absence of such a representation are also outlined.

Mather, R. S.↗
NASA NTRS1974

Atlas of lunar radar maps at 70-cm wavelength

The intensity distribution of lunar radar echoes has been mapped for two-thirds of the earth-visible lunar surface at a wavelength of 70 cm. The depolarizing effects of the lunar surface were observed by simultaneously receiving the radar echoes in opposite polarizations. These echoes were mapped with areal resolutions of 25-100 sq km. Mapping with this resolution confirmed that the young craters have enhanced returns. A few craters were found to have enhanced echoes only from their rims. Backscattering differences were also observed between various areas within a mare, between different highland areas, and between maria and adjacent highlands. These scattering differences were interpreted with a simple model, which assumed that the surface backscattered with varying amounts of quasi-specular and diffuse power. Only an increase in the diffuse power was needed to give the numerical values of the enhancements.

Thompson, T. W.↗
NASA NTRS1977

Fretting of AISI 9310 and selected fretting resistant surface treatments

Fretting wear experiments were conducted with uncoated AISI 9310 mating surfaces, and with combinations incorporating a selected coating to one of the mating surfaces. Wear measurements and SEM observations indicated that surface fatigue, as made evident by spallation and surface crack formation, is an important mechanism in promoting fretting wear to uncoated 9310. Increasing humidity resulted in accelerated fretting, and a very noticeable difference in nature of the fretting debris. Of the coatings evaluated, aluminum bronze with a polyester additive was most effective at reducing wear and minimizing fretting damage to the mating uncoated surface, by means of a selflubricating film that developed on the fretting surfaces. Chromium plate performed as an effective protective coating, itself resisting fretting and not accelerating damage to the uncoated surface.

Bill, R. C.↗
NASA NTRS1977

Fretting of AISI 9310 and selected fretting resistant surface treatments

Fretting wear experiments were conducted with uncoated AISI 9310 mating surfaces, and with combinations incorporating a selected coating to one of the mating surfaces. Wear measurements and SEM observations indicated that surface fatigue, as made evident by spallation and surface crack formation, is an important mechanism in promoting fretting wear to uncoated 9310. Increasing humidity resulted in accelerated fretting, and a very noticeable difference in nature of the fretting debris. Of the coatings evaluated, alumimum bronze with a polyester additive was most effective at reducing wear and minimizing fretting damage to the mating uncoated surface, by means of a self-lubricating film that developed on the fretting surfaces. Chromium plate performed as an effective protective coating, itself resisting fretting and not accelerating damage to the uncoated surface.

Bill, R. C.↗