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At least 1,315 records · Page 73

Numerical Investigation of Susceptor-Catalyst Design for Ethylene Generation in Radio Frequency Based Reactors

Ethylene is the most widely produced petrochemical component in the world. Whether reactors are heated directly or indirectly via steam, manufacturers use economies of scale to overcome inherent thermodynamic inefficiencies when burning fossil fuels. While allowing large-scale operations to use alternative sources of energy and raw materials, new methods of supplying energy to chemical reactor systems can reduce the energy waste produced by conventional processes. One viable method for effectively supplying energy to reactor systems is electromagnetic (EM) induction heating. Using the properties of radio frequency (RF) waves, heterogeneous catalysts can be precisely targeted for heating inside reactors. Site-selective heating can greatly lower the energy requirements of the process by supplying heat to reaction sites while reducing needless heat transfer elsewhere. In this study, a microscale model was used to help create guidelines for susceptors and catalysts to improve ethylene production. The oxidative dehydrogenation of ethane is investigated by utilizing several catalysts and potential catalyst/susceptor combinations, with heat provided by an EM susceptor. Having the susceptors and catalyst function separately results in higher gradients in both heat and mass transfer, which drives transport through the catalyst region, while still providing adequate heating for endothermic reactions. However, using a susceptive core with a catalyst covering produces the maximum ethylene concentration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Mineralogy–Based Anthropogenic Combustion–Iron Emission Inventory

Atmospheric supply of iron can modulate ocean biogeochemistry, due to its key role in global nitrogen and carbon cycles. Current estimates predict up to 20% of global ocean net primary productivity depends on an atmospheric iron source. Using a technology–based methodology, we revise total and soluble anthropogenic iron emissions and resolve iron into its mineral components, which allows modeling mineral–specific atmospheric reactions. We compare different methodologies for representing anthropogenic iron solubility: measured in mild and strong leaches and estimated using a mineralogy basis and identify the emissions that are most affected by such assumptions. The inclusion of metal smelting as an iron source increases iron emissions by up to 10 times higher in the fine aerosol fraction (smaller than 1 μm) than most previous inventories. Different solubility assumptions alter anthropogenic soluble iron emissions and deposition by a factor of 20 and 10, respectively. Using solubilities measured in mild leaches and calculated by mineralogy give 20–30 Gg/yr anthropogenic emissions and 40–50 Gg/yr deposition, while those measured in strong leaches give 80–440 Gg/yr emissions and 200–450 Gg/yr deposition. Here, this range of anthropogenic soluble iron deposition leads to global soluble iron deposition of 1,900–2,300 Gg/yr when dust, wildfires, and atmospheric processing are included, indicating such assumptions can affect global soluble iron supply by about 30%. In regions where marine primary productivity is iron limited, anthropogenic combustion–iron contributes up to half of the atmospheric soluble iron flux to the North Pacific Ocean but supplies less than 5% to the Southern Ocean.

54 ENVIRONMENTAL SCIENCES↗

The Amazon and La Plata River Basins as Moisture Sources of South America: Climatology and Intraseasonal Variability

Abstract Land‐atmosphere interactions are critical for precipitation (PPT) over South America where terrestrial evapotranspiration (ET) constitutes a significant fraction of moisture for rainfall over the ecologically and socio‐economically vital Amazon (AMZ) and La Plata (LPB) river basins. We quantify the contribution of ET from AMZ and LPB to PPT over the continent with a focus on the intraseasonal time scale. Using numerical water tracers embedded in the Weather Research and Forecasting model we track the moisture originating from the two basins. Our findings indicate that approximately 40% of annual rainfall over the eastern foothills of the Andes originates as AMZ ET, and nearly 30% of rainfall over northern Argentina originates as LPB ET. Analysis of moisture transport during both phases of the dominant intraseasonal oscillation pattern over South America reveals an intraseasonal “sloshing” of LPB moisture between the South Atlantic convergence zone (SACZ) and southeastern South America (SESA) regions. AMZ and LPB each supply approximately 6% of moisture for SACZ PPT during periods of intraseasonal enhancement (positive anomalies), highlighting the importance of moisture from the Atlantic Ocean. For the SESA region, LPB supplies 26% of the moisture for PPT during periods of intraseasonal enhancement while AMZ supplies 5%.

54 ENVIRONMENTAL SCIENCES↗

Decision making for implementing non-traditional water sources: a review of challenges and potential solutions

Abstract The effects of climate change, population growth, and future hydrologic uncertainties necessitate increased water conservation, new water resources, and a shift towards sustainable urban water supply portfolios. Diversifying water portfolios with non-traditional water sources can play a key role. Rooftop harvested rainwater (RHRW), atmospheric and condensate harvesting, stormwater, recycled wastewater and greywater, and desalinated seawater and brackish water are all currently utilized and rapidly emerging non-traditional water sources. This review explores the status and trends around these non-traditional water sources, and reviews approaches and models for prioritizing, predicting, and quantifying metrics of concern. The analysis presented here suggests that understanding the challenges of location specific scenarios, socioeconomic knowledge gaps, water supply technologies, and/or water management structure is the crucial first step in establishing a model or framework approach to provide a strategy for improvement going forward. The findings of this study also suggest that clear policy guidance and onsite maintenance is necessary for variable water quality concerns of non-traditional sources like harvested rainwater and greywater. In addition, use of stormwater or reuse of wastewater raises public health concerns due to unknown risks and pathogen levels, thus rapid monitoring technologies and transparent reporting systems can facilitate their adoption. Finally, cost structure of desalination varies significantly around the world, largely due to regulatory requirements and local policies. Further reduction of its capital cost and energy consumption is identified as a hurdle for implementation. Overall, models and process analyses highlight the strength of comparative assessments across scenarios and water supply options.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Large-scale spatially explicit analysis of carbon capture at cellulosic biorefineries

The large-scale production of cellulosic biofuels would involve spatially distributed systems including biomass fields, logistics networks and biorefineries. Better understanding of the interactions between landscape-related decisions and the design of biorefineries with carbon capture and storage (CCS) in a supply chain context is needed to enable efficient systems. Here we analyse the cost and greenhouse gas mitigation potential for cellulosic biofuel supply chains in the US Midwest using realistic spatially explicit land availability and crop productivity data and consider fuel conversion technologies with detailed CCS design for their associated CO 2 streams. Optimization methods identify trade-offs and design strategies leading to systems with attractive environmental and economic performance. Strategic and operational decisions depend on underlying spatial features and are sensitive to biofuel demand and CCS incentives. US CCS incentives neglect to motivate greenhouse gas mitigation from all supply chain emission sources, which leverage spatial interactions between CCS, electricity prices and the biomass landscape.

09 BIOMASS FUELS↗

Critically assessing sodium-ion technology roadmaps and scenarios for techno-economic competitiveness against lithium-ion batteries

Sodium-ion batteries have garnered notable attention as a potentially low-cost alternative to lithium-ion batteries, which have experienced supply shortages and price volatility for key minerals. Here we assess their techno-economic competitiveness against incumbent lithium-ion batteries using a modelling framework incorporating componential learning curves constrained by minerals prices and engineering design floors. We compare projected sodium-ion and lithium-ion price trends across over 6,000 scenarios while varying Na-ion technology development roadmaps, supply chain scenarios, market penetration and learning rates. Assuming that substantial progress can be made along technology roadmaps via targeted research and development, we identify several sodium-ion pathways that might reach cost-competitiveness with low-cost lithium-ion variants in the 2030s. In addition, we show that timelines are highly sensitive to movements in critical minerals supply chains—namely that of lithium, graphite and nickel. Our modelled outcomes suggest that being price advantageous against low-cost lithium-ion variants in the near term is challenging and increasing sodium-ion energy densities to decrease materials intensity is among the most impactful ways to improve competitiveness.

25 ENERGY STORAGE↗

Impact of electric vehicle battery recycling on reducing raw material demand and battery life-cycle carbon emissions in China

The rapid growth of electric vehicles (EVs) in China challenges raw material demand. This study evaluates the impact of recycling and reusing EV batteries on reducing material demand and carbon emissions. Integrating a national-level vehicle stock turnover model with life-cycle carbon emission assessment, we found that replacing nickel-cobalt-manganese batteries with lithium iron phosphate batteries with battery recycling can reduce lithium, cobalt, and nickel demand between 2021 and 2060 by up to 7.8 million tons (Mt) (67%), 12.4 Mt (96%), and 37.2 Mt (93%), respectively, significantly decreasing reliance on import. Moreover, battery recycling coupled with reuse can reduce carbon emissions by up to 6,532-6,864 Mt (36.0-37.9%), depending on four recycling methods employed. However, this reuse strategy delays battery recycling and risks lithium supply shortage, necessitating trade-offs between carbon reduction and material supply. Future technologies, such as lithium-sulfur and all-solid-state batteries, despite their energy efficiency, might exacerbate lithium shortage, underscoring the crucial need for increased lithium supply.

25 ENERGY STORAGE↗

A green closed-loop process for selective recycling of lithium from spent lithium-ion batteries

As the economy started to recover from the COVID pandemic, the price of Li 2 CO 3 skyrocketed to its highest. This situation has aggravated concerns about the supply chain for lithium-ion batteries (LIBs). Recycling spent LIBs is a potential solution to alleviate the bottleneck of the supply chain and prevent environmental pollution, and has attracted lots of attention. However, lithium recycling is generally disregarded because of the complex recycling process and its low recycling efficiency. Here, in this work we developed a sustainable lithium recovery process, which can selectively leach and recover lithium with formic acid before recycling valuable metals. With the reported method, lithium can be 99.8% recovered from layered oxide cathode materials with 99.994% purity. In addition, this lithium recovery process is affordable, compared to the typical hydrometallurgical process, by saving 11.15% per kilogram of spent LIBs. Therefore, this research provided a new solution to eliminating the effects of lithium ions on valuable metal separation and the co-precipitation reaction and precluding the influence of other metal ions on lithium recovery. Finally, this simplified lithium recovery process provides new opportunities for sustainable recycling of LIBs and economical restoration of the lithium supply chain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advanced Permanent Magnet Generator Topologies Using Multimaterial Shape Optimization and 3D Printing: Preprint

A vast majority of utility-scale wind turbine generators in the United States are dependent on foreign- sourced rare-earth permanent magnets that are vulnerable to supply chain uncertainties. Many small wind original equipment manufacturers are motivated to pursue continuous improvements to the generator design to lower the material and production costs and improve performance by lowering cogging torque and increasing the efficiency. Traditional design and manufacturing offer limited opportunities. In this work, we demonstrate advanced design approaches for a 15-kW baseline wind turbine generator by making use of recent progress in three-dimensional (3D) printing of polymer- bonded magnets and, electrical and structural steel. We explore three methods of magnet parametrization using Bezier curves resulting in symmetric, asymmetric and multimaterial magnet designs. We employ a multiphysics approach combining parametric computer-aided design modeling, finite- element analysis and targeted sampling to identify novel designs with more opportunities for reducing rare-earth material, improving efficiency and minimizing cogging torque. The results show that asymmetric-pole design and multimaterial-pole designs offer a greater opportunity to minimize rare-earth magnet materials by up to 35% with similar performance as the baseline generator, suggesting newer opportunities with design freedom beyond traditional limits of symmetry and as allowed by 3D printing.

Bezier curves↗

Repurposing Inactive Oil and Gas Wells for Energy Storage: Maximizing the Potential Via Optimal Drivetrain Control: Preprint

In recent years, there has been a growing emphasis on utilizing energy storage to enhance grid resilience against disruptive events. While renewable energy supply continues to expand, gravity-based solutions like pumped hydro remain dominant in the commercial space. However, their geographical limitations constrain availability, scalability, and increase costs for co-locating solar and wind energy. An alternative approach proposes repurposing idle oil and gas wells located closer to existing grid infrastructure, offering a promising and cost-effective solution. This paper addresses the optimization and control of a regenerative drive system coupled to an interior permanent magnet synchronous machine in a 300-meter well with a 100-Newton weight. The study employs a dynamic MATLAB/Simulink model to simulate the operation of the electric drivetrain system during storage and discharge operations. The results demonstrate an initial round-trip efficiency of 85.9% for the electrical system alone and identify crucial factors for maximizing efficiency. The optimized operation and control of the electromechanical drivetrain system hold great potential for minimizing the levelized cost of storage while maximizing efficiency and revenue generation.

ENERGY STORAGE,ENGINEERING↗

Optimal strategies for a cost-effective and reliable 100% renewable electric grid

This paper explores cost-optimal pathways to 100% renewable power systems for the U.S. building stock. We show that long-duration misalignments of supply and demand, spanning from multi-day to seasonal timescales, present a dominant challenge that must be addressed to meet real-time 100% renewable targets. While long-duration misalignments can be addressed through energy storage, we show that alternative and readily available solutions that are more cost-effective should be considered first. Through a techno-economic analysis, we identify cost-optimal, region-dependent, supply-side, and demand-side strategies that reduce, and in some U.S. regions eliminate, the otherwise substantial capacities and associated costs of long-duration energy storage. Investigated supply-side strategies include optimal mixes of renewable portfolios and oversized generation capacities. Considered demand-side strategies include building load flexibility and building energy efficiency investments. Our results reveal that building energy efficiency measures can reduce long-duration storage requirements at minimum total investment costs. In addition, oversizing and diversifying renewable generation can play a critical role in reducing storage requirements, remaining cost effective even when accounting for curtailed generation. We identify regionally dependent storage cost targets and show that for emerging long-duration energy storage innovations to achieve broad adoption, their costs will need to compete with the decreasing cost of renewables. The findings of this research are particularly important given that most long-duration storage technologies are currently either uneconomical, geologically constrained, or still underdeveloped.

100% renewable↗

Multi-scale planning model for robust urban drought response

Increasingly severe droughts are straining municipal water resources and jeopardizing urban water security, but uncertainty in their duration, frequency, and intensity challenges drought planning and response. We develop the Drought Resilient Interscale Portfolio Planning model (DRIPP) to generate optimal planning responses to urban drought. DRIPP is a generalizable multi-scale framework for optimizing dynamic planning strategies of long-term infrastructure deployment and short-term drought response. It integrates climate and hydrological variability with high-fidelity representations of urban water distribution, available technology options, and demand reduction measures to yield robust and cost-effective water supply portfolios that are location-specific. We apply DRIPP in Santa Barbara, California to assess how least cost water supply portfolios vary under different drought scenarios and identify portfolios that are robust across drought scenarios. In Santa Barbara, we find that drought intensity, not duration or frequency, drives cost increases, reliability risk, and regret of overbuilding infrastructure. Under uncertain drought conditions, a diversified technology portfolio that includes both rapidly deployable, decentralized technologies alongside larger centralized technologies minimizes water supply cost while maintaining high robustness to climate uncertainty.

54 ENVIRONMENTAL SCIENCES↗

Evaluating the Impact of Power Outages on Occupancy Patterns During the 2021 Texas Power Crisis

Large-scale power outages, such as those caused by extreme weather events, have a big impact on human behavior. A short power outage is merely a nuisance for most, and may not change people's locations. An outage that lasts for a few hours can result in spoiled food and medical supplies, and people will have to restock spoiled items. Long outages result in temperatures outside tolerable levels in homes, and may prompt people to acquire supplies, such as generators and gas, or change location. The long outages during Winter Storm Uri in Texas resulted in millions of dollars in property damage due to freezing pipes. This level of damage is expected to result in a sharp increase in supply runs and contractor activity. In this paper, we present a tool to explore differences in visiting patterns before, during, and after power outages. It allows to compare different points of interest like medical facilities, grocery stores, hardware stores, and other types of businesses.

big data↗

An 85 nW IoT Node-Controlling SoC for MELs Power-Mode Management and Phantom Energy Reduction

This paper presents an ultra-low power (ULP) node-controlling system-on-chip (SoC) used for power-mode management and phantom energy reduction of miscellaneous electric loads (MELs). The SoC is powered from a single 2.5 V voltage supply enabled by the integrated power management unit (PMU) and can control up to 16 MELs due to the on-chip 16-channel correlator and the 32b RISC-V microprocessor. To further reduce the system power consumption, two clock domains have been adopted for the correlator and the processor separately. Fabricated in 65-nm CMOS, the measured minimum power consumption of the proposed SoC is only 85 nW at 0.45 V voltage supply and 1 kHz clock frequency. The measured maximum operating frequency can go up to 148 kHz with a 0.55 V supply. An application experiment successfully demonstrates that the SoC controls the power modes of MELs from wake-up to cut-off to save the average power and phantom energy.

power-mode management, phantom energy, phantom pow↗

Building Energy Systems as Behind-the-Meter Resources for Grid Services: Intelligent load control and transactive control and coordination

To mitigate the impacts of climate change, significant reductions in emissions from all sectors of the economy are needed. The electricity generation sector has embarked on an ambitious plan to include renewable generation as part of its decarbonization efforts, and many cities and states are mandating all-electric buildings. While renewable resources will reduce emissions, they are not dispatchable, they vary temporally, and their generation is uncertain. Under these conditions, traditional approaches to managing grid reliability, where supply follows demand, will not be efficient and may not be cost-effective. Further, there is a more efficient alternative for balancing the supply–demand imbalance and for absorbing variability and uncertainty of renewable energy using distributed energy resources (DERs) as opposed to reserve generation. Because buildings consume more than 75% of total U.S. annual electricity consumption, behind-the-meter (BTM) DERs have a load flexibility of 77 GW of power and 90 GWh of virtual energy storage capacity nationwide (Kalsi, 2017). Therefore, some portion of the supply–demand imbalance can be met by these DERs at a lower cost compared to business-as-usual solutions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The Effect of Prosumer Duality on Power Market: The Effect of Market Regulation

Electricity prosumers are energy subsystems that not only consume, but also produce electricity. They are present in distribution level networks as traditional utility customers who have installed distributed energy resources. They are also present in transmission level networks as large conglomerates own both generation assets and large industrial loads. Previous work on the economics of prosumers has demonstrated that prosumers in a market have incentives to behave more competitively compared to producers and consumers in traditional markets. This paper further explores the behavior of prosumers and their response to market policies including the allocation of network losses and the impact of net metering. We extend a Cournot model of a dual prosumer and find that prosumers respond with higher supply quantities if network losses are allocated to demand base. They respond with lower supply quantities if network losses are allocated to supply base. Allocating network losses to demand base also causes equilibrium prices to decline. Markets where prosumers first satisfy their own load and then sell the balance of electricity to the grid have lower quantities and higher prices compared to markets where prosumers buy and sell at locational marginal price.

Tsybina, Eve↗

A High-Voltage High-Current Benchtop Test Stand for Solid-State Switch Testing at the SNS

Solid-state switches already replaced thyratrons in the SNS extraction kicker power supplies, offering improved efficiency and reliability. However, recent supply chain disruptions, combined with a self-firing issue, led us to explore alternative solutions. A vendor-developed MOS-Gated Thyristor switch was introduced but ultimately failed during testing. To investigate the failure and assess possible improvements, a benchtop test stand was constructed to evaluate the performance of a single stage board. This test stand features a Pulse Forming Network (PFN) that operates at 6 kV and 6 kA, with a repetition rate exceeding 60 Hz, simulating real operational conditions. By utilizing this setup, we seek to gain a better understanding of the failure mechanisms, refine the switch designs, and ultimately develop a more reliable alternative for the extraction kicker power supplies.

Bullman, Austin [ORNL]↗

Optimal Power Management for Large-Scale Battery Energy Storage Systems via Bayesian Inference

Large-scale battery energy storage systems (BESS) have found ever-increasing use across industry and society to accelerate clean energy transition and improve energy supply reliability and resilience. However, their optimal power management poses significant challenges: the underlying high-dimensional nonlinear nonconvex optimization lacks computational tractability in real-world implementation, and the uncertainty of the exogenous power demand makes exact optimization difficult. This paper presents a new solution framework to address these bottlenecks. The solution pivots on introducing power-sharing ratios to specify each cell’s power quota from the output power demand. To find the optimal power-sharing ratios, we formulate a nonlinear model predictive control (NMPC) problem to achieve power-loss-minimizing BESS operation while complying with safety, cell balancing, and power supply-demand constraints. We then propose a parameterized control policy for the power-sharing ratios, which utilizes only three parameters, to reduce the computational demand in solving the NMPC problem. This policy parameterization allows us to translate the NMPC problem into a Bayesian inference problem for the sake of 1) computational tractability, and 2) overcoming the nonconvexity of the optimization problem. We leverage the ensemble Kalman inversion technique to solve the parameter estimation problem. Concurrently, a low-level control loop is developed to seamlessly integrate our proposed approach with the BESS to ensure practical implementation. This low-level controller receives the optimal power-sharing ratios, generates output power references for the cells, and maintains a balance between power supply and demand despite uncertainty in output power. We conduct extensive simulations and experiments on a 20-cell prototype to validate the proposed approach.

Battery energy storage systems (BESSs)↗