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At least 1,315 records · Page 73

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NASA NTRS1979

Structure and electrical activity of planar defects in EFG ribbons

Optical, electron beam induced current (EBIC), and transmission electron microscopy were used to study the structure and electrical activity of planar defects in EFG silicon. What appears to be twin boundaries by both optical microscopy plus etching, and by EBIC are in reality systems of microtwins, some of which are only a few atomic lattice planes thick. The electrical activity of planar defects appears to be correlated with emission of dislocations especially at termination points. Impurity effects may also play a role. Twin boundaries per se appear not to be electrically active.

Ast, D. G.↗

DOE OSTI2023

Nanostructure‐Derived Antireflectivity in Leafhopper Brochosomes

Understanding how insect‐derived biomaterials interact with light has led to new advances and interdisciplinary insights in entomology and physics. Leafhoppers are insects that coat themselves with highly ordered biological nanostructures known as brochosomes. Brochosomes are thought to provide a range of protective properties to leafhoppers, such as hydrophobicity and antireflectivity, which has inspired the development of synthetic brochosomes that mimic their structures. Despite recent progress, the high antireflective properties of brochosome structures are not fully understood. Herein, a combination of experiments and computational modeling is used to understand the structure‐, material‐, and polarization‐dependent optical properties of brochosomes modeled on the geometries found in three leafhopper species. The results qualitatively represent that light interference interaction with nanostructures naturally occurring in brochosomes is responsible for the spectral tuning and the asymmetric line shape of the reflectance spectra. Whereas prior work has focused on the computational modeling of idealized pitted particles, this work shows that light–matter interactions with brochosome structures can be tuned by varying the geometry of their cage‐like nanoscale features and by changing the arrangement of multiparticle assemblies. Broadly, this work establishes principles for the guided design of new optically active materials inspired by these unique insect nanostructures.

Banerjee, Progna↗

DOE OSTI2022

Defect Structure in Quantum-Cutting Yb3+-Doped CsPbCl3 Perovskites Probed by X-Ray Absorption and Atomic Pair Distribution Function Analysis

Ytterbium-doping in all-inorganic lead-halide perovskites (CsPb(Cl1-xBrx)3) generates novel properties including quantum cutting and narrow line emission, making these materials attractive spectral down-converters for solar photovoltaics. The relationship between this optical efficiency and the defect structure(s) associated with Yb3+ dopants within perovskites is not well understood. Various charge-neutral doping motifs have previously been proposed and studied computationally, including clusters involving two substitutional Yb3+ ions charge-compensated by a single local Pb2+ vacancy. Near-band-edge defect states associated with such motifs are believed to play an important mechanistic role in quantum cutting itself. Here, we report the results of X-ray absorption and X-ray total-scattering measurements on ytterbium-doped CsPbCl3. XANES shows that the dopant oxidation state is exclusively Yb3+, and a combination of Yb L3 and Pb L3 EXAFS shows that this Yb3+ substitutes exclusively at Pb2+ sites, where it adopts a pseudo-octahedral [YbCl6]3- coordination environment. Shell-by-shell fits to the data show a short Yb-Cl bond distance of 2.58 Å compared to the Pb-Cl bond distance of 2.83 Å. We confirm this finding by X-ray pair distribution function analysis, which also shows evidence of additional Pb2+ vacancy formation induced by Yb3+ doping. We evaluate whether this is the primary mechanism of charge compensation using simulated EXAFS and pair distribution function data for several computed defect structures. Together, these results resolve the local dopant structures and charge-compensation mechanisms in lanthanide-doped all-inorganic lead-halide perovskites, and, as such, significantly advance the understanding of structure-function relationships in this important class of materials.

Kluherz, Kyle (ORCID:0000000279865167)↗

NASA NTRS1995

Technology for Space Optical Interferometry

The Micro-Precision Control/Structure Interaction (CSI) program at JPL is chartered to develop the structures and control technology needed for sub-micron level stabilization of future optical space systems. The extreme dimensional stability required for such systems derives from the need to maintain the alignment and figure of critical optical elements to a small fraction (typically 1/20th to 1/50th) of the wavelength of detected radiation (about 0.5 micron for visible light, 0.1 micron for ultraviolet light). This requirement is common to a broad class of optical sysetms. The challenge for CSI arises when such systems become large, with spatially distributed optical elements mounted on lightweight, flexible structure. This paper will present an overview of the approach that is being taken by JPL's CSI program to address this challenge. In particular, the paper will discuss the application of CSI technology to a specific example of a future large optical space mission. Experimental demonstration of the technology on ground-based testbeds will also be presented.

structures↗

DOE OSTI2022

Efficient and interpretable graph network representation for angle-dependent properties applied to optical spectroscopy

Abstract Graph neural networks are attractive for learning properties of atomic structures thanks to their intuitive graph encoding of atoms and bonds. However, conventional encoding does not include angular information, which is critical for describing atomic arrangements in disordered systems. In this work, we extend the recently proposed ALIGNN (Atomistic Line Graph Neural Network) encoding, which incorporates bond angles, to also include dihedral angles (ALIGNN-d). This simple extension leads to a memory-efficient graph representation that captures the complete geometry of atomic structures. ALIGNN-d is applied to predict the infrared optical response of dynamically disordered Cu(II) aqua complexes, leveraging the intrinsic interpretability to elucidate the relative contributions of individual structural components. Bond and dihedral angles are found to be critical contributors to the fine structure of the absorption response, with distortions that represent transitions between more common geometries exhibiting the strongest absorption intensity. Future directions for further development of ALIGNN-d are discussed.

36 MATERIALS SCIENCE↗

NASA NTRS2006

Daytime Use of Astronomical Telescopes for Deep-Space Optical Links

Tests at the 200-inch Hale Telescope on Palomar Mountain have demonstrated this telescope's ability to withstand considerable thermal stress, and subsequently produce remarkably unaffected results. During the day of June 29,2005, the Hale telescope dome was left open, and the telescope was exposed to outside air and direct sunlight for 8 hours. During this time, portions of the telescope structure in the telescope's optical path experienced temperature elevations of 30 C, while the primary mirror experienced unprecedented heating of over 3 C. The telescope's measured blind pointing accuracy after this exposure was not noticeably degraded from the measurements taken before exposure. More remarkably, the telescope consistently produced stellar images which were significantly better after exposure of the telescope (1.2 arcsec) than before (1.6 arcsec), even though the conditions of observation were similar. This data is the first step in co-opting astronomical telescopes for daytime use as astronomical receivers, and supports the contention that deleterious effects from daytime exposure of the telescope can be held to an acceptable level for interleaved communications and astronomy.

telescope heat↗

DOE OSTI2023

Direct Visualization of Localized Vibrations at Complex Grain Boundaries

Abstract Grain boundaries (GBs) are a prolific microstructural feature that dominates the functionality of a wide class of materials. The functionality at a GB results from the unique atomic arrangements, different from those in the grain, that have driven extensive experimental and theoretical studies correlating atomic‐scale GB structures to macroscopic electronic, infrared optical, and thermal properties. In this work, a SrTiO 3 GB is examined using atomic‐resolution aberration‐corrected scanning transmission electron microscopy and ultrahigh‐energy‐resolution monochromated electron energy‐loss spectroscopy, in conjunction with density functional theory. This combination enables the correlation of the GB structure, nonstoichiometry, and chemical bonding with a redistribution of vibrational states within the GB dislocation cores. The new experimental access to localized GB vibrations provides a direct route to quantifying the impact of individual boundaries on macroscopic properties.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Origin of Intrinsically Low Thermal Conductivity in a Garnet-Type Solid Electrolyte: Linking Lattice and Ionic Dynamics with Thermal Transport

Understanding thermal transport in solid electrolytes is essential for improving the performance, reliability, and safety of all-solid-state batteries. Garnet-type lithium-ion conductors are promising candidates for solid electrolytes, yet their thermal-transport mechanisms remain poorly understood. Here, we connect the lattice and ion dynamics of single-crystal garnet-type Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 to its intrinsically low thermal conductivity. Our study reveals that the single crystals grown by the floating-zone method exhibit remarkably low glasslike thermal conductivity. Using first-principles calculations and inelastic-neutron-scattering measurements, we identify both the acoustic and numerous optical phonon modes, which stem from the complex crystal structure of the material. Notably, a low-energy optical branch exhibits an avoided crossing with acoustic phonons near 7 meV. These optical modes can enhance the scattering of heat-carrying acoustic phonons and reduce thermal conductivity. Furthermore, the calculated Grüneisen parameters are large, especially for the vibrational modes around 6 meV, indicating strong anharmonicity, with a noticeable contribution from lithium-ion vibrations. A two-channel thermal-transport model is employed to describe the weak temperature dependence of the thermal conductivity, which can be attributed to the substantial contribution of diffuson transport facilitated by the abundance of optical phonons and intrinsic anharmonicity. These results offer valuable insights into the thermal transport in a broad class of ionic conductors of interest for energy conversion and storage applications.

Ab initio calculations↗

NASA NTRS1990

Non-steller light from high-redshift radiogalaxies

With the aid of a new IRCAM image of 3C356, researchers question the common assumption that radiosource-stimulated starbursts are responsible for the extended optical emission aligned with radio structures in high-redshift radiogalaxies. They propose an alternative model in which the radiation from a hidden luminous quasar is beamed along the radio axis and illuminates dense clumps of cool gas to produce both extended narrow emission line regions and, by Thomson scattering, extended optical continua. Simple observational tests of this model are possible and necessary if we are to continue to accept that the color, magnitude and shape evolution of radiogalaxies are controlled by the active evolution of stellar populations.

Rawlings, Steve↗

DOE OSTI2023

Visible-telecom tunable dual-band optical isolator based on dynamic modulation in thin-film lithium niobate

Optical isolators are an essential component of photonic systems. Current integrated optical isolators have limited bandwidths due to stringent phase-matching conditions, resonant structures, or material absorption. Here, we demonstrate a wideband integrated optical isolator in thin-film lithium niobate photonics. We use dynamic standing-wave modulation in a tandem configuration to break Lorentz reciprocity and achieve isolation. We measure an isolation ratio of 15 dB and insertion loss below 0.5 dB for a continuous wave laser input at 1550 nm. In addition, we experimentally show that this isolator can simultaneously operate at visible and telecom wavelengths with comparable performance. Isolation bandwidths up to ∼100 nm can be achieved simultaneously at both visible and telecom wavelengths, limited only by the modulation bandwidth. Our device’s dual-band isolation, high flexibility, and real-time tunability can enable novel non-reciprocal functionality on integrated photonic platforms.

Shah, Manav↗

DOE OSTI2023

Computationally-driven discovery of second harmonic generation in EuBa 3 (B 3 O 6 ) 3 through inversion symmetry breaking

Nonlinear optical (NLO) crystals with superior properties are significant for advancing laser technologies and applications. Introducing rare earth metals to borates is a promising and effective way to modify the electronic structure of a crystal to improve its optical properties in the visible and ultraviolet range. In this work, we computationally discover inversion symmetry breaking in EuBa 3 (B 3 O 6 ) 3 , which was previously identified as centric, and demonstrate noncentrosymmetry via synthesizing single crystals for the first time by the floating zone method. We determine the correct space group to be P 6¯. The material has a large direct bandgap of 5.56 eV and is transparent down to 250 nm. The complete anisotropic linear and nonlinear optical properties were also investigated with a d 11 of ∼0.52 pm/V for optical second harmonic generation. Further, it is Type I and Type II phase matchable. This work suggests that rare earth metal borates are an excellent crystal family for exploring future deep ultraviolet (DUV) NLO crystals. It also highlights how first principles computations combined with experiments can be used to identify noncentrosymmetric materials that have been wrongly assigned to be centrosymmetric.

He, Jingyang (ORCID:0000000238863659)↗

NASA NTRS1980

Improved optics for an ultracentrifuge

Ultracentrifuge is important tool in study of polymers, biomolecules, and cell structures. In typical ultracentrifuge rotor supports pair of optically matched vials; one contains sample mixed in solvent, and other is reference that contains only solvent. Doubleslit optical system, transverse to rotor, creates interference pattern on photographic plate each time vials pass through optics. Medium in sample vial displaces interference maximums such that shift gives measurement of density distribution along length of sample.

Miller, C. G.↗

NASA NTRS2014

Aeroelastic Control of a Segmented Trailing Edge Using Fiber Optic Strain Sensing Technology

Currently, design of aircraft structures incorporate a safety factor which is essentially an over design to mitigate the risk of structure failure during operation. Typically this safety factor is to design the structure to withstand loads much greater than what is expected to be experienced during flight. NASA Dryden Flight Research Centers has developed a Fiber Optic Strain Sensing (FOSS) system which can measure strain values in real-time. The Aeroelastics Lab at the AERO Institute is developing a segmented trailing edged wing with multiple control surfaces that can utilize the data from the FOSS system, in conjunction with an adaptive controller to redistribute the lift across a wing. This redistribution can decrease the amount of strain experienced by the wing as well as be used to dampen vibration and reduce flutter.

aeronautics↗

NASA NTRS1988

Monolithic electro-optic modulator array

A PIN GaAlAs diode structure is provided with parameters for index guiding of light in a single mode. The index of refraction of the central layer I (which in practice may be lightly doped .pi. or .nu.) is greater than the p- and n-layers to create a slab waveguide in the transverse direction. Stripe contacts define separate waveguide channels that are separated electrically and optically by implanting protons or etching grooves between the stripe contacts in the upper layer. Separate reverse biasing voltages may be applied to the stripe contacts for modulation of the light in proportions to the voltage, either with absorption modulation, if the light wavelength is within about 500.ANG. of the bandgap of the .pi.-material, or phase-delay modulation, if the wavelength is separated from the bandgap of the .pi.-material by at least 900.ANG..

Robinson, Deborah L.↗

NASA NTRS2008

Developing Optimized Trajectories Derived from Mission and Thermo-Structural Constraints

In conjunction with NASA and the Department of Defense, the Johns Hopkins University Applied Physics Laboratory (JHU/APL) has been investigating analytical techniques to address many of the fundamental issues associated with solar exploration spacecraft and high-speed atmospheric vehicle systems. These issues include: thermo-structural response including the effects of thermal management via the use of surface optical properties for high-temperature composite structures; aerodynamics with the effects of non-equilibrium chemistry and gas radiation; and aero-thermodynamics with the effects of material ablation for a wide range of thermal protection system (TPS) materials. The need exists to integrate these discrete tools into a common framework that enables the investigation of interdisciplinary interactions (including analysis tool, applied load, and environment uncertainties) to provide high fidelity solutions. In addition to developing robust tools for the coupling of aerodynamically induced thermal and mechanical loads, JHU/APL has been studying the optimal design of high-speed vehicles as a function of their trajectory. Under traditional design methodology the optimization of system level mission parameters such as range and time of flight is performed independently of the optimization for thermal and mechanical constraints such as stress and temperature. A truly optimal trajectory should optimize over the entire range of mission and thermo-mechanical constraints. Under this research, a framework for the robust analysis of high-speed spacecraft and atmospheric vehicle systems has been developed. It has been built around a generic, loosely coupled framework such that a variety of readily available analysis tools can be used. The methodology immediately addresses many of the current analysis inadequacies and allows for future extension in order to handle more complex problems.

Lear, Matthew H.↗

NASA NTRS1973

Electric field and fine structure in aurora.

Simultaneous rocket measurements of electric field and optical aurora during a weak PCA event are presented. The aurora consisted of faint structures superposed on a homogeneous glow, and on-board photometers showed that the rocket passed through two discrete auroral forms. These enhanced auroral emissions coincided with variations in the dc electric field and an increase in the ac field. A detailed comparison between electric fields and optical emissions shows that the relation is quite complex. The results are compared with earlier electric field and optical auroral measurements.

Maseide, K.↗

NASA NTRS1994

IUE spectra and optical imaging of the oxygen-rich supernova remnant N132D

We present new optical Charge Coupled Devices (CCD) interference filter imagery and International Ultraviolet Explorer (IUE) spectroscopy for the oxygen-rich supernova remnant N132D in the Large Magellanic Cloud. The optical images show a wealth of structure, and comparison with an archival Einstein High Resolution Imager (HRI) X-ray image shows that a few optical features have X-ray counter-parts, but in general there is little correlation between X-ray and optical features. The IUE spectra at two positions show strong lines of carbon and oxygen, with lines of neon, magnesium, silicon, and helium also present and variable in relative intensities. We use optical data for N132D from Dopita & Tuohy (1984) with our UV observations to compare with shock models (both with and without thermal conduction) and X-ray photoionization model calculations. While none of the model fits is entirely satisfactory, the generally weak UV emission relative to optical disagrees with the general character of shock model predictions and indicates that photoionization is the dominant excitation mechanism for the UV/optical emission. This conclusion is similar to what was found for E0102 - 7219, the oxygen-rich remnant in the Small Magellanic Cloud. We derive rough abundances for the emitting material in N132D, compare to stellar nucleosynthesis models, and discuss the implications for its precursor. A precursor near 20 solar mass is consistent with the data.

Blair, William P.↗

NASA NTRS2006

Reducing Stray Light To Characterize Nirspec Subsystems: The Focal Plane Array And Micro-Shutter Array

The James Webb Space Telescope (JWST) is an infrared, space-based telescope scheduled for launch in 2013. JWST includes four scientific instruments, including the Near Infrared Spectrometer (NIRSpec), which operates in the wavelength range from 0.6 to 5 microns. NASA/Goddard Space Flight Center (GSFC) is responsible for two NIRSpec subsystems: the detector subsystem, with its focal plane array (FPA), and the micro-shutter subsystem, with its micro-shutter array (MSA). The FPA is comprised of two side-by-side Rockwell Scientific HgCdTe 2kx2k detectors, with detectors and readout electronics optimized for low noise. The MSA is a GSFC developed micro-electro-mechanical system (MEMS) that serves as a programmable slit mask, allowing NIRSpec to obtain simultaneous spectra of >100 objects in a single field of view. We present the optical characterization test plan of the FPA. The test plan is driven by many requirements: cryogenic operating temperature, a flight-like beam shape, and multi-wavelength photon flux from 1 to 60,000 per second, thus low stray light is critical. We use commercial optical modeling software to predict stray light effects at the FPA. We also present the optical contrast test plan of the MSA. Since each individual shutter element operates in on/off fashion, the most important optical metric is contrast. The MSA structure is designed to minimize stray and scattered light, and the test setup reduces stray light such that the optical contrast requirement is met.

Connelly, Joseph A.↗