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At least 1,315 records · Page 73

Formation of ncl-Si in the Amorphous Matrix a-SiO{sub x}:H Located near the Anode and on the Cathode, Using a Time-Modulated DC Plasma with the (SiH{sub 4}–Ar–O{sub 2}) Gas Phase (C{sub O{sub 2}} = 21.5 mol %)

The formation of ncl-Si in the amorphous matrix a-SiO{sub x}:H using a time-modulated DC plasma at an elevated oxygen content of C{sub O{sub 2}} = 21.5 mol % in a gas mixture of (SiH{sub 4}–Ar–O{sub 2}) is investigated. Plasma modulation implies the repeated (n = 180) switching on (for t{sub on} = 5, 10, 15 s) and switching off (for t{sub off} = 5, 10, 15 s) of the magnet coil of the DC magnetron. The effect of self-induction is used to enhance the processes of SiH{sub 4} dissociation, the formation of Si nanoparticles, and the ionization of oxygen and ncl-Si flows towards the electrodes. The samples are located both on an electrically isolated substrate holder near the anode and on the cathode (beyond its erosion zone). These experiments show that the shape of the dependences of the photoluminescence intensity I{sub PL}{sup ncl−Si} on the wavelength Λ are identical for all pairs of samples on the anode and cathode. When the t{sub on} value is small (t{sub on} = 5 s), the difference in the sample location only slightly affects the infrared (IR) spectra. At longer times t{sub on} (≥10 s) and a short time t{sub off} (5 s), the amorphous matrix located on the cathode is enriched with oxygen (as compared with that near the anode). The optimal plasma-modulation parameters are found to be t{sub off}/t{sub on} = 5, 10, 15/10 and t{sub off}/t{sub on} = 5, 10/15; under these conditions, the amorphous matrix has a “perfect structure” and is transparent to radiation, and the I{sub PL}{sup ncl−Si} value is the largest in the range λ ≈ 0.75–0.9 μm.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Acoustic vibrations in integrated electro-optic modulators on substrates of lithium niobate

The processes of the excitation of acoustic vibrations and their influence on the optical signals in integrated electro-optic modulators on substrates of lithium niobate have been investigated. The resonant frequencies of the excitation of substrate vibrational modes have been determined. It has been shown that acoustic vibrations can make a significant contribution to the modulator transfer characteristic at frequencies up to several hundred megahertz, which should be taken into account when using the modulators at low frequencies, for example, as a part of fiber-optic sensors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electrochemically modulated single-molecule localization microscopy for in vitro imaging cytoskeletal protein structures

A new concept of electrochemically modulated single-molecule localization super-resolution imaging is developed. Applications of single-molecule localization super-resolution microscopy have been limited due to insufficient availability of qualified fluorophores with favorable low duty cycles. The key for the new concept is that the “On” state of a redox-active fluorophore with unfavorable high duty cycle could be driven to “Off” state by electrochemical potential modulation and thus become available for single-molecule localization imaging. The new concept was carried out using redox-active cresyl violet with unfavorable high duty cycle as a model fluorophore by synchronizing electrochemical potential scanning with a single-molecule localization microscope. The two cytoskeletal protein structures, the microtubules from porcine brain and the actins from rabbit muscle, were selected as the model target structures for the conceptual imaging in vitro. The super-resolution images of microtubules and actins were obtained from precise single-molecule localizations determined by modulating the On/Off states of single fluorophore molecules on the cytoskeletal proteins via electrochemical potential scanning. Importantly, this method could allow more fluorophores even with unfavorable photophysical properties to become available for a wider and more extensive application of single-molecule localization microscopy.

electrochemical modulation↗

Effects of Soiling of Photovoltaic Modules and Systems in Brazil’s Climate Zones

This research presents a methodology for quantifying soiling loss in p-Si and CdTe photovoltaic modules through measurements from soiling stations installed in Belo Horizonte (-19.92° S, -43.99° W), Porto Alegre (-30.05° S, -51.17° W), Brotas de Macaúbas (12.0011° S, -42.6303° W), and Macapá (0.0356° N, -51.0705° W), in Brazil. The electrical parameters measured from photovoltaic modules are compared with precipitation data collected in the same location, with the objective of evaluating the behavior of the soiling ratio during the dry periods. Mathematical models determined the SRatio and SRate for each site (in compliance with the IEC-61324-1 monitoring standard [1]). The SRatio for short-circuit current and maximum power data from the modules were evaluated and compared, characterizing the potential effects of uniform and non-uniform soiling. In addition, a method for analyzing energy-production data of PV systems in order to extract the soiling rate was developed and is presented. The gravimetric soiling densities (mg/m2) was determined using the modeling by Coello and Boyle [2] and these are compared to data collected using the Figgis soiling microscope [3].

climate zone↗

Influence of Impurities in Module Packaging on Potential-Induced Degradation

Chemical compounds were added into crystalline silicon cell mini modules, including in the encapsulant, interfaces, and glass, to determine their effect on potential-induced degradation (PID). Fe, either in the glass or at the glass/encapsulant interface, was found to be correlated with increased PID, but the difference in module power loss was not statistically significant compared to controls. Additions of Cu, Cr, Pb, Sn, Ag, and Na compounds to either the encapsulant or at the glass/encapsulant interface did not appear correlated with PID. Lock-in thermography on bare cells affected by PID removed from the mini modules show highly localized areas of junction breakdown, and SIMS analysis indicates localized impurities as well, though a spatial relation between the two was not established. Deposition of a conductive layer on the front surface of the cell, either with semitransparent Ta or Poly 3,4-ethylenedioxythiophene (PEDOT), eliminated PID when the cells were stressed at -1000 V bias, 50°C, with the glass face grounded for 140 h.

14 SOLAR ENERGY↗

2013 PV Module Reliability Workshop: February 26-27, 2013, Golden, CO [Slides]

NREL's Photovoltaic (PV) Module Reliability Workshop (PVMRW) brings together PV reliability experts to share information, leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology--both critical goals for moving PV technologies deeper into the electricity marketplace. NREL’s PVMRW is unique in its requirement that all participating companies share at least one presentation (either oral or poster). In most cases, participation from each company is limited to two people. These requirements greatly increase information sharing: If everyone shares a little information, everyone takes home a lot of information. In 2013, the PVMRW was designed to be a regional meeting of the International PV Module Quality Assurance Task Force, first of its kind for the Americas. This regional meeting also had substantial international participation. The workshop agenda mirrored the organization of the Task Force, with a session for each of Task Groups 2 through 5. Each Task Group presented a status report of their discussions and highlighted a small number of technical presentations describing studies related to that Task Group. In addition, the participants presented about 65 posters on topics directly or indirectly related to the work of the four Task Groups. Most of the participants shared their presentations for public posting; this document is a compilation of these. The success of the workshop is a direct result of the participants’ willingness to share their results.

14 SOLAR ENERGY↗

User's Manual for Data for Validating Models for PV Module Performance

This user's manual describes performance data measured for flat-plate photovoltaic (PV) modules installed in Cocoa, Florida, Eugene, Oregon, and Golden, Colorado. The data include PV module current-voltage curves and associated meteorological data for approximately one-year periods. These publicly available data are intended to facilitate the validation of existing models for predicting the performance of PV modules, and for the development of new and improved models. For comparing different modeling approaches, using these public data will provide transparency and more meaningful comparisons of the relative benefits.

14 SOLAR ENERGY↗

Cooperative effort between Consorcio European Spallation Source--Bilbao and Oak Ridge National Laboratory spallation neutron source for manufacturing and testing of the JEMA-designed modulator system

The JEMA modulator was originally developed for the European Spallation Source (ESS) when Spain was under consideration as a location for the ESS facility. Discussions ensued and the Spallation Neutron Source Research Accelerator Division agreed to form a collaboration with ESS-Bilbao (ESS-B) consortium to provide services for specifying the requirements for a version of the modulator capable of operating twelve 550 kW klystrons, monitoring the technical progress on the contract with JEMA, installing and commissioning the modulator at SNS, and performing a 30 day full power test. This work was recently completed, and this report discusses those activities with primary emphasis on the installation and testing activities.

43 PARTICLE ACCELERATORS↗

PACT Module Design Acceptance Criteria (Industry)

For the PACT center to both develop testing protocols and provide service to the metal halide perovskite (MHP) PV community, PACT will seek modules (mini and full-sized) for testing purposes. To ensure both safety and high-quality samples PACT publishes acceptance criteria to define the minimum characteristics of modules the center will accept for testing. These criteria help to ensure we are accepting technologies that are compatible with our technical facilities and testing equipment and can transition to large scale commercial manufacturing. This module design acceptance criteria document is for industry partners and is different from the acceptance criteria for research partners (academia, national laboratories) partners.

14 SOLAR ENERGY↗

Durable Module Materials (DuraMAT) Consortium (Final Technical Report)

The DuraMAT Consortium brings together DOE national lab and university research capabilities with the photovoltaic (PV) and supply-chain industries to accelerate a sustainable, just, and equitable transition to zero carbon electricity generation by 2035 through our five core objectives: development of a central data resource for PV modules, multi-scale and multi-physics modeling, disruptive acceleration science, forensic tools for fielded modules, and materials solutions for more durable, reliable, and resilient modules.

14 SOLAR ENERGY↗

Task 12 PV Sustainability - Life Cycle Assessment of Crystalline Silicon Photovoltaic Module Delamination with Hot Knife Technology

The objective of this study is to complete a life cycle assessment (LCA) of a novel technology that separates the crystalline silicon (c-Si) photovoltaic (PV) module front glass from the backsheet using hot knife technology. This is known to be the most challenging step in module recycling, where the choice of delamination approach can determine the process selection for the next steps of the recycling process, the economic value of the recovered materials, and environmental performance. The life cycle inventory (LCI) reported here is based on primary data from the technology manufacturer. Different LCIs are established following the cut-off approach and the end-of-life (EOL) approach. The environmental impacts of the hot knife delamination process are analysed based on six indicators, and the main contributors to delamination efforts are identified. For the EOL approach, the potential environmental benefits from the recovered materials are compared to the environmental impacts caused by the delamination process. The functional unit of this analysis is the delamination of 1 kg of used framed c-Si PV modules at the place of installation.

14 SOLAR ENERGY↗

Next Generation Solid Oxide Fuel Cell Module Development

The overall objective of this project was to develop a transformative Solid Oxide Fuel Cell (SOFC) building block configuration comprised of multi-stack arrays that can be utilized in large-scale power plants. This transformative design signified the benefits of lower performance degradation coupled with improved reliability, low cost, smaller packaging for easier transport and installation, and improved maintenance and field serviceability characteristics. The project goal was to design and fabricate a scalable hot module for housing an array of SOFC stacks and to demonstrate the characteristics of the module gas distribution, insulation and instrumentation, and DC power take-off. The approach was to validate the design of a stack prototype scalable to megawatt (MW) class systems using FuelCell Energy’s Compact SOFC Architecture (CSA) stacks. The scope of work was intended to design, build, and test a compact and low-cost multi-stack sub-module with flexibility to house CSA stacks and scalable to 350 kW which could ultimately be deployed in construction of MW-class systems.

20 FOSSIL-FUELED POWER PLANTS↗

Magnetically Modulated Heat Transport in a Global Simulation of Solar Magneto-convection

We present results from a global MHD simulation of solar convection in which the heat transported by convective flows varies in-phase with the total magnetic energy. The purely random initial magnetic field specified in this experiment develops into a well-organized large-scale antisymmetric component undergoing hemispherically synchronized polarity reversals on a 40 year period. A key feature of the simulation is the use of a Newtonian cooling term in the entropy equation to maintain a convectively unstable stratification and drive convection, as opposed to the specification of heating and cooling terms at the bottom and top boundaries. When taken together, the solar-like magnetic cycle and the convective heat flux signature suggest that a cyclic modulation of the large-scale heat-carrying convective flows could be operating inside the real Sun. We carry out an analysis of the entropy and momentum equations to uncover the physical mechanism responsible for the enhanced heat transport. The analysis suggests that the modulation is caused by a magnetic tension imbalance inside upflows and downflows, which perturbs their respective contributions to heat transport in such a way as to enhance the total convective heat flux at cycle maximum. Potential consequences of the heat transport modulation for solar irradiance variability are briefly discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Evolution of Spin, Orbital, and Superorbital Modulations of 4U 0114+650

We report a systematic analysis of the spin, orbital, and superorbital modulations of 4U 0114+650, a high-mass X-ray binary that consists of one of the slowest spinning neutron stars. Using the dynamic power spectrum, we found that the spin period varied dramatically and is anticorrelated with the long-term X-ray flux variation that can be observed using the Rossi X-ray Timing Explorer ASM, Swift BAT, and the Monitor of All-sky X-ray Image. The spin-up rate over the entire data set is consistent with previously reported values; however, the local spin-up rate is considerably higher. The corresponding local spin-up timescale is comparable to the local spin-up rate of OAO 1657−415, indicating that 4U 0114+650 could also have a transient disk. Moreover, the spin period evolution shows two ∼1000-day spin-down/random-walk epochs that appeared together with depressions of the superorbital modulation amplitude. This implies that the superorbital modulation was closely related to the presence of the accretion disk, which is not favored in the spin-down/random-walk epochs because the accretion is dominated by the direct wind accretion. The orbital period is stable during the entire time span; however, the orbital profile significantly changes with time. We found that the depth of the dip near the inferior conjunction of the companion is highly variable, which disfavors the eclipsing scenario. Moreover, the dip was less obvious during the spin-down/random-walk epochs, indicating its correlation with the accretion disk. Further monitoring in both X-ray and optical bands could reveal the establishment of the accretion disk in this system.

79 ASTRONOMY AND ASTROPHYSICS↗

( Cloud Atlas Cloud Atlas): discovery of patchy clouds and high-amplitude rotational modulations in a young, extremely red L-type brown dwarf

Condensate clouds fundamentally impact the atmospheric structure and spectra of exoplanets and brown dwarfs, but the connections between surface gravity, cloud structure, dust in the upper atmosphere, and the red colors of some brown dwarfs remain poorly understood. Rotational modulations enable the study of different clouds in the same atmosphere, thereby providing a method to isolate the effects of clouds. Here, we present the discovery of high peak-to-peak amplitude (8%) rotational modulations in a low-gravity, extremely red (J−K {sub s} = 2.55) L6 dwarf WISEP J004701.06+680352.1 (W0047). Using the Hubble Space Telescope (HST) time-resolved grism spectroscopy, we find a best-fit rotational period (13.20 ± 0.14 hr) with a larger amplitude at 1.1 μm than at 1.7 μm. This is the third-largest near-infrared variability amplitude measured in a brown dwarf, demonstrating that large-amplitude variations are not limited to the L/T transition but are present in some extremely red L-type dwarfs. We report a tentative trend between the wavelength dependence of relative amplitude, possibly proxy for small dust grains lofted in the upper atmosphere, and the likelihood of large-amplitude variability. By assuming forsterite as a haze particle, we successfully explain the wavelength-dependent amplitude with submicron-sized haze particle sizes of around 0.4 μm. W0047 links the earlier spectral and later spectral type brown dwarfs in which rotational modulations have been observed; the large amplitude variations in this object make this a benchmark brown dwarf for the study of cloud properties close to the L/T transition.

79 ASTRONOMY AND ASTROPHYSICS↗

Challenge to Move from 'One Size Fits All' to PV Modules the Customer Needs: Preprint

Historically, PV companies requested a single qualification test for a single product. As the market has grown, there have been increasing opportunities for companies to differentiate their products while still maintaining high manufacturing volumes of each product. At the same time, as PV is deployed in an increasingly broad range of conditions, modules need to be able to withstand a wide rangeof stresses. In some cases, targeting a specific deployment condition may allow reduction of product cost. Realizing this opportunity will require the ability to confidently predict long-term performance based on accelerated tests and known weather conditions. By working together, the community can most quickly develop tests that identify which products perform well under which conditions. Thispaper discusses some of the challenges of predicting long-term PV performance, including the wide range of stresses that may be encountered, the variability of the stresses from moment to moment, the complexity of some degradation mechanisms, and the dependence of accelerated testing on module geometry. The paper also describes two international projects that deal with location-specificdurability evaluation and long-term module performance.

14 SOLAR ENERGY↗

Outdoor PV Module Degradation of Current-Voltage Parameters: Preprint

Photovoltaic (PV) module degradation rate analysis quantifies the loss of PV power output over time and is useful for estimating the impact of degradation on the cost of energy. An understanding of the degradation of all current-voltage (I-V) parameters helps to determine the cause of the degradation and also gives useful information for the design of the system. This study reports on datacollected from 12 distinct mono- and poly-crystalline modules deployed at the National Renewable Energy Laboratory (NREL) in Golden, Colorado. Most modules investigated showed < 0.5%/year decrease in maximum power due to short-circuit current decline.

14 SOLAR ENERGY↗

A Stability of LCLS Linac Modulators

Information concerning to a stability of LCLS RF linac modulators is allocated in this paper. In general a 'pulse-to-pulse' modulator stability (and RF phase as well) is acceptable for the LCLS commission and FEL programs. Further modulator stability improvements are possible and approaches are discussed based on our experimental results.

43 PARTICLE ACCELERATORS↗