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NASA NTRS2002

Optical Properties of Thin Film Molecular Mixtures

Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling the degree of molecular mixing, the solar selective coatings can be tailored to have the combined properties of high solar absorptance, alpha, and low infrared emittance, epsilon. On orbit, these combined properties would simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. Mini-satellites equipped with solar collectors coated with these cermet coatings may utilize the captured heat energy to power a heat engine to generate electricity, or to power a thermal bus that directs heat to remote regions of the spacecraft. Early work in this area identified the theoretical boundary conditions needed to operate a Carnot cycle in space, including the need for a solar concentrator, a solar selective coating at the heat inlet of the engine, and a radiator. A solar concentrator that can concentrate sunlight by a factor of 100 is ideal. At lower values, the temperature of the solar absorbing surface becomes too low for efficient heat engine operation, and at higher values, cavity type heat receivers become attractive. In designing the solar selective coating, the wavelength region yielding high solar absorptance must be separated from the wavelength region yielding low infrared emittance by establishing a sharp transition in optical properties. In particular, a sharp transition in reflectance is desired in the infrared to achieve the desired optical performance. For a heat engine operating at 450C, a sharp transition at 1.8 micrometers is desired. The radiator completes the heat flow through the Carnot cycle. Additional work has been done supporting the use of molecular mixtures for terrestrial applications. Sputter deposition provides a means to apply coatings to the tubes that carry a working fluid at the focus of trough-style collectors. Sputtering offers considerable flexibility in coating conditions, including a wide variety of metal and dielectric targets. Coating designs range from simple two or three layer coatings to complex coatings that are purposely graded to be metal-rich at their base and oxide-rich at their surface in order to yield the desired solar selective properties. In these cermet coatings, molecular islands of metal are thought to be embedded in a three dimensional matrix of dielectric. Recent work has identified the use of custom made ion beam sputter deposition targets to produce coatings containing molecular mixtures of metal and dielectric. The targets are cylindrical and the surface consists of a gradually changing composition of metal and dielectric. Rotating the cylinder under the beam during ion beam sputter deposition yields a coating that is a molecular mixture of metal and dielectric, with the composition changing through the thickness of the coating. The optical properties of these coatings are not only dependent on their thickness and chemical composition, but are also dependent on the extent of the through thickness gradient established during deposition. This paper presents a summary of the optical properties of several thin film molecular mixtures designed as solar selective coatings. Optical performance is first identified as a function of wavelength, from the ultraviolet to the visible and infrared. Coating composition, thickness, and gradient from metal to dielectric also play an important role. Additional work for future activities is also identified.

Jaworske, Donald A.↗

NASA NTRS2001

Observation and Analysis of Jovian and Saturnian Satellite Mutual Events

The main goal of this research was to acquire high time resolution photometry of satellite-satellite mutual events during the equatorial plane crossing for Saturn in 1995 and Jupiter in 1997. The data would be used to improve the orbits of the Saturnian satellites to support Cassini mission requirements, and also to monitor the secular acceleration of Io's orbit to compare with heat flow measurements.

Tholen, David J.↗

NASA NTRS2002

Ultramafic Terranes and Associated Springs as Analogs for Mars and Early Earth

Putative extinct or extant Martian organisms, like their terrestrial counterparts, must adopt metabolic strategies based on the environments in which they live. In order for organisms to derive metabolic energy from the natural environment (Martian or terrestrial), a state of thermodynamic disequilibrium must exist. The most widespread environment of chemical disequilibrium on present-day Earth results from the interaction of mafic rocks of the ocean crust with liquid water. Such environments were even more pervasive and important on the Archean Earth due to increased geothermal heat flow and the absence of widespread continental crust formation. The composition of the lower crust and upper mantle of the Earth is essentially the-same as that of Mars, and the early histories of these two planets are similar. It follows that a knowledge of the mineralogy, water-rock chemistry and microbial ecology of Earth's oceanic crust could be of great value in devising a search strategy for evidence of past or present life on Mars. In some tectonic regimes, cross-sections of lower oceanic crust and upper mantle are exposed on land as so-called "ophiolite suites." Such is the case in the state of California (USA) as a result of its location adjacent to active plate margins. These mafic and ultramafic rocks contain numerous springs that offer an easily accessible field laboratory for studying water/rock interactions and the microbial communities that are supported by the resulting geochemical energy. A preliminary screen of Archaean biodiversity was conducted in a cold spring located in a presently serpentinizing ultramafic terrane. PCR and phylogenetic analysis of partial 16s rRNA, sequences were performed on water and sediment samples. Archaea of recent phylogenetic origin were detected with sequences nearly identical to those of organisms living in ultra-high pH lakes of Africa.

Blake, David↗

NASA NTRS2001

The Evolution of the Martian Hydrosphere: Implications for the Fate of a Primordial Ocean and the Current State of the Northern Plains

In this paper we consider the hydraulic and thermal conditions that gave rise to the elevated source regions of the Late Hesperian outflow channels and explore their implications for the evolution of the Martian hydrosphere. We find that if the outflow channel floodwaters were derived from a subpermafrost aquifer, then it implies that, throughout the planet's first billion years of evolution, as much as one third of its surface was covered by standing bodies of water and ice. Following the development of the global dichotomy, the bulk of this water would have existed as an ice-covered ocean in the northern plains. We demonstrate that the progressive crustal assimilation of this early surface reservoir of H2O (punctuated by possible episodes of less extensive flooding) was a natural consequence of the planet's subsequent climatic and geothermal evolution-potentially cycling the equivalent of a km-deep global ocean of water through the atmosphere and subsurface every approx. 10(exp 9) years. In response to the long-term decline in planetary heat flow, the progressive coldtrapping of H2O into the growing cryosphere is expected to have significantly depleted the original inventory of groundwater-a development that could well explain the apparent decline in outflow channel activity observed during the Amazonian. Although primarily a theoretical analysis, our findings appear remarkably consistent with the geomorphic and topographic evidence that Mars once possessed a primordial ocean and that a substantial relic of that body continues to survive as massive ice deposits within the northern plains. Confirmation of the presence of such deposits, combined with the potential detection of a global-scale groundwater system, would provide persuasive support for the validity of this analysis.

Clifford, Stephen M.↗

NASA NTRS2003

Geophysical Probes of the Icy Satellites of Jupiter

This paper presents a discussion on the structure and dynamic processes of the interiors of the icy satellites of Jupiter. Although such measurements as global gravity and magnetic fields, high precision altimetry and radar sounding can be made from the Jupiter Icy Moons Orbiter (JIMO) satellite, there are certain seismic and heat flow measurements which must be made from the surface to clearly understand the geophysics of a planet such as Jupiter. The possibility of a geophysical probe that can be released into orbit about a satellite to return potential field data for a sufficient period of time is discussed.

Banerdt, W. B.↗

NASA NTRS2003

Effect of Varying Crustal Thickness on CHAMP Geopotential Data

To determine the effect of crustal thickness variation on satellite-altitude geopotential anomalies we compared two regions of Europe with vastly different values, Central/Southern Finland and the Pannonian Basin. Crustal thickness exceeds 62 km in Finland and is less than 26 km in the Pannonian Basin. Heat-flow maps indicate that the thinner and more active crust of the Pannonian Basin has a value nearly three times that of the Finnish Svecofennian Province. Ground based gravity mapping in Hungary shows that the free-air gravity anomalies across the Pannonian Basin are near 0 to +20 mGal with shorter wavelength anomalies from +40 to less than +60 mGal and some 0 to greater than -20 mGal. Larger anomalies are detected in the mountainous areas. The minor value anomalies can indicate the isostatic equilibrium for Hungary (the central part of the Pannonian Basin). Gravity data over Finland are complicated by de-glaciation. CHAMP gravity data (400 km) indicates a west-east positive gradient of greater than 4 mGal across Central/Southern Finland and an ovoid positive anomaly (approximately 4 mGal) quasi-coincidental with the magnetic anomaly traversing the Pannonian Basin. CHAMP magnetic data (425 km) reveal elongated semicircular negative anomalies for both regions with South-Central Finland having larger amplitude (less than -6 nT) than that over the Pannonian Basin, Hungary (less than -5 nT). In both regions subducted oceanic lithosphere has been proposed as the anomalous body.

Taylor, P. T.↗

NASA NTRS2003

Mars: Always Cold, Sometimes Wet?

A synthesis of a diverse suite of observations of H2O-related landforms that are possible Mars analogs from terrestrial polar regions (Devon Island in the Arctic; the Dry Valleys of Antarctica) put into question any requirement for extended episode(s) of warm and wet climate in Mars past. Geologically transient episodes of localized H2O cycling, forced by exogenic impacts, enhanced endogenic heat flow, and/or orbit-driven short-term local environmental change under an otherwise cold, low pressure (=10(exp 2) mbar) global climate, may be sufficient to account for the martian surface's exposed record of aqueous activity. A Mars that was only sometimes locally warm and wet while remaining climatically cold throughout its history is consistent with results (difficulties) encountered in modeling efforts attempting to support warm martian climate hypotheses. Possible analogs from terrestrial cold climate regions for the recent gully features on Mars also illustrate how transient localized aqueous activity might, under specific circumstances, also occur on Mars under the present frigid global climatic regime.

Lee, Pascal↗

NASA NTRS2003

Effect of Varying Crustal Thickness on CHAMP Geopotential Data

Tn determine the effect of crustal thickness variation on satellite-altitude geopotential anomalies we compared two regions of Europe with vastly different values, South and Central Finland and the Pannonian Basin. In our study regions, crustal thickness exceeds 44 km in Finland and is less than 26 km in the Pannonian Basin. Heat-flow data indicate that the thinner and more active crust of the Pannonian Basin has a value nearly three times that of the Finnish Svecofennian Province. An ovoid positive CHAMP gravity anomaly (-4 mGal) is quasi-coincidental with the CHAMP magnetic anomaly traverses the Pannonian Basin while ground based gravity mapping in Hungary shows that the free-air gravity anomalies across the Pannonian Basin are near 0 to +20 mGal with shorter wavelength anomalies from +40 to less than +60 mGal and some 0 to greater than -20 mGal. Larger anomalies are detected in the mountainous areas. The minor value anomalies can indicate the isostatic equilibrium for Hungary (the central part of the Pannonian Basin). Gravity data over Finland bear overprint of de-glaciation. CHAMP gravity data indicates a west-east positive gradient of less than 4 mGal across South and Central Finland. CHAMP magnetic data (400 km) reveal elongated semi-circular negative anomalies for both regions with South-Central Finland having larger amplitude (less than -6 nT) than that over the Pannonian Basin, Hungary (less than -5 nT). In the latter subducted oceanic lithosphere has been proposed as the anomalous body.

Taylor, Patrick T.↗

NASA NTRS2004

Lava Lakes on Io: New Perspectives from Modeling

Ionian paterae are a class of volcanic feature that are characterized by irregular craters with steep walls, flat floors, and arcuate margins that may or may not exhibit nesting. Loki (310 W, 12 N) is Io's largest patera at approx.200 km in diameter (Figure 1), and may account for 15% of Io's total heat flow. Earth-based infrared data, as well as information collected using the Galileo Near-Infrared Mapping Spectrometer (NIMS) and the Photopolarimeter Radiometer (PPR) have been used to interpret Loki s eruption style. Debate continues over whether Loki s occasional (periodic or not) temperature increases are due to an overturning lava lake within the patera, or to an eruption of surface flows on the patera floor. Interpretation of model results and comparisons with active terrestrial lava lakes suggest that Loki behaves quite differently from active lava lakes on Earth, and that surface flows (rather than an overturning lava lake) are a more likely explanation of Loki's thermal brightening.

Gregg, Tracy K. P.↗

NASA NTRS2003

Records of our Early Biosphere Illuminate our Origins and Guide our Search for Life Beyond Earth

A scientific "mission of exploration to early Earth" will help us chart the distribution of life elsewhere. We must discriminate between attributes of biospheres that are universal versus those attributes that represent principally the outcomes of long-term survival specifically on Earth. In addition to the basic physics and chemistry of matter, the geologic evolution of rocky habitable planets and their climates might be similar elsewhere in the Universe. Certain key agents that drive long-term environmental change (e.g., stellar evolution, impacts, geothermal heat flow, tectonics, etc.) can help us to reconstruct ancient climates and to compare their evolution among populations of Earth- like planets. Early Earth was tectonically more active than today and therefore it exhaled reduced chemical species into the more oxidized surface environment at greater rates. This tectonic activity thus sustained oxidation-reduction reactions that provided the basis for the development of biochemical pathways that harvest chemical energy ("bioenergetics"). Most examples of bioenergetics today that extract energy by reacting oxidized and reduced chemicals in the environment were likely more pervasive among our microbial ancestors than are the presently known examples of photosynthesis. The geologic rock record indicates that, as early as 3.5 billion years ago (3.5 Ga), microbial biofilms were widespread within the coastal environments of small continents and tectonically unstable volcanic islands. Non oxygen-producing (non-oxygenic) photosynthesis preceded oxygenic photosynthesis, but all types of photosynthesis contributed substantially to the long-term increase in global primary biological productivity. Evidence of photosynthesis is tentative by 3.5 Ga and compelling by 2.7 Ga. Evidence of oxygenic photosynthesis is strong by 2.7 Ga and compelling by 2.3 Ga. These successive innovations transformed life from local communities that survived principally by catalyzing chemical equilibration to a globally dominant agent that created and sustained widespread chemical disequilibria in the environment and shallow crust. Major biogeochemical perturbations ca. 2.3 to 2.0 Ga, 1.3 Ga, and also 0.8 to 0.6 Ga, contributed to the irreversible oxidation of the global environment and perhaps also triggered evolutionary innovations (e.g., the development of multi-cellular biota) that became the foundations of our modern biosphere. Understanding the nature and timing of this ascent of life is crucial for discerning our o m beginnings. This understanding also empowers OUT search for the origins, evolution and distribution of life elsewhere in our solar system and beyond.

DesMarais, David J.↗

NASA NTRS2003

Optical Properties of Thin Film Molecular Mixtures

Jaworske, Donald A.↗

NASA NTRS2004

Saturn's Rings, the Yarkovsky Effects, and the Ring of Fire

The dimensions of Saturn's A and B rings may be determined by the seasonal Yarkovsky effect and the Yarkovsky-Schach effect; the two effects confine the rings between approximately 1.68 and approximately 2.23 Saturn radii, in reasonable agreement with the observed values of 1.525 and 2.267. The C ring may be sparsely populated because its particles are transients on their way to Saturn; the infall may create a luminous Ring of Fire around Saturn's equator. The ring system may be young: in the past heat flow from Saturn's interior much above its present value would not permit rings to exist.

Rubincam, David Parry↗

NASA NTRS2004

Overview of the GRC Stirling Convertor System Dynamic Model

A Stirling Convertor System Dynamic Model has been developed at the Glenn Research Center for controls, dynamics, and systems development of free-piston convertor power systems. It models the Stirling cycle thermodynamics, heat flow, gas, mechanical, and mounting dynamics, the linear alternator, and the controller. The model's scope extends from the thermal energy input to thermal, mechanical dynamics, and electrical energy out, allowing one to study complex system interactions among subsystems. The model is a non-linear time-domain model containing sub-cycle dynamics, allowing it to simulate transient and dynamic phenomena that other models cannot. The model details and capability are discussed.

Lewandowski, Edward J.↗

NASA NTRS2005

Development of Detectability Limits for On-Orbit Inspection of Space Shuttle Wing Leading Edge

At the conclusion of the Columbia Accident Investigation, one of the recommendations of the Columbia Accident Investigation Board (CAIB) was that NASA develop and implement an inspection plan for the Reinforced Carbon-Carbon (RCC) system components of the Space Shuttle. To address these issues, a group of scientists and engineers at NASA Langley Research Center proposed the use of an IR camera to inspect the RCC. Any crack in an RCC panel changes the thermal resistance of the material in the direction perpendicular to the crack. The change in thermal resistance can be made visible by introducing a heat flow across the crack and using an IR camera to image the resulting surface temperature distribution. The temperature difference across the crack depends on the change in the thermal resistance, the length of the crack, the local thermal gradient, and the rate of radiation exchange with the environment. This paper describes how the authors derived the minimum thermal gradient detectability limits for a through crack in an RCC panel. This paper will also show, through the use of a transient, 3-dimensional, finite element model, that these minimum gradients naturally exist on-orbit. The results from the finite element model confirm that there are sufficient thermal gradient to detect a crack on 96% of the RCC leading edge.

Stephan, Ryan A.↗

NASA NTRS1996

Transient Analysis Used to Study Thermal Radiation Effects in Single and Composite Semitransparent Layers

In a continuing in-house program at the NASA Lewis Research Center, analytical and numerical methods are being developed to apply radiative analysis to predict transient temperature distributions and heat flows in partially transmitting materials. Results have been obtained for a single plane layer, and a transient analysis is being developed for a two-layer composite where each layer has a different refractive index. Because the ceramic refractive indices are larger than one, internal reflections are produced at the surfaces and at the internal interface. Reflections tend to distribute energy within a layer, and this affects the transient temperature distributions.

Source record↗

NASA NTRS1997

Thermal Radiation Effects Analyzed in Translucent Composite and Thermal Barrier Coating

Ceramic parts and coatings are needed to withstand high temperatures in advanced aircraft engines. In hot environments, such as in the combustion chambers of these engines, infrared and visible radiation can penetrate into some ceramics and heat them internally. The internal temperatures depend on radiative effects combined with heat conduction, and on convection and radiation at the material boundaries. Since engine temperatures are high, radiant emission can be large from within translucent parts and coatings, and this must be included in the analysis. Transient and steady-state behavior are both important. During a transient, radiant penetration provides more rapid internal heating than conduction alone, and the temperature distributions are usually considerably different than for steady-state conditions; this can produce transient thermal stresses. Analytical and numerical methods are being used at the NASA Lewis Research Center to predict transient temperatures and heat flows in translucent materials. A transient analysis was done for a composite of two translucent layers. The layer refractive indices were larger than 1, producing internal reflections at the boundaries and at the internal interface. In addition, steady-state results were computed for a two-layer composite with one layer opaque. The results were used to assess the importance of internal radiation in a zirconia thermal barrier coating on a cooled metal wall. Since the radiative transfer equations are rather complex, especially when internal scattering is included, approximate methods are being investigated that might be convenient for computer design programs. An approximate two-flux method was used and verified by comparisons with solutions that used exact radiative transfer relations. The two-flux equations include scattering without increasing solution difficulty.

Siegel, Robert↗

NASA NTRS2001

Light Microscopy Module: An On-Orbit Microscope Planned for the Fluids and Combustion Facility on the International Space Station

The Light Microscopy Module (LMM) is planned as a fully remotely controllable on-orbit microscope subrack facility, allowing flexible scheduling and control of fluids and biology experiments within NASA Glenn Research Center's Fluids and Combustion Facility on the International Space Station. Within the Fluids and Combustion Facility, four fluids physics experiments will utilize an instrument built around a light microscope. These experiments are the Constrained Vapor Bubble experiment (Peter C. Wayner of Rensselaer Polytechnic Institute), the Physics of Hard Spheres Experiment-2 (Paul M. Chaikin of Princeton University), the Physics of Colloids in Space-2 experiment (David A. Weitz of Harvard University), and the Low Volume Fraction Colloidal Assembly experiment (Arjun G. Yodh of the University of Pennsylvania). The first experiment investigates heat conductance in microgravity as a function of liquid volume and heat flow rate to determine, in detail, the transport process characteristics in a curved liquid film. The other three experiments investigate various complementary aspects of the nucleation, growth, structure, and properties of colloidal crystals in microgravity and the effects of micromanipulation upon their properties. Key diagnostic capabilities for meeting the science requirements of the four experiments include video microscopy to observe sample features including basic structures and dynamics, interferometry to measure vapor bubble thin film thickness, laser tweezers for colloidal particle manipulation and patterning, confocal microscopy to provide enhanced three-dimensional visualization of colloidal structures, and spectrophotometry to measure colloidal crystal photonic properties.

Doherty, Michael P.↗

NASA NTRS2002

Light Microscopy Module: On-Orbit Microscope Planned for the Fluids Integrated Rack on the International Space Station

The Light Microscopy Module (LMM) is planned as a remotely controllable, automated, on-orbit facility, allowing flexible scheduling and control of physical science and biological science experiments within the Fluids Integrated Rack (FIR) on the International Space Station. Initially four fluid physics experiments in the FIR will use the LMM the Constrained Vapor Bubble, the Physics of Hard Spheres Experiment-2, Physics of Colloids in Space-2, and Low Volume Fraction Entropically Driven Colloidal Assembly. The first experiment will investigate heat conductance in microgravity as a function of liquid volume and heat flow rate to determine, in detail, the transport process characteristics in a curved liquid film. The other three experiments will investigate various complementary aspects of the nucleation, growth, structure, and properties of colloidal crystals in microgravity and the effects of micromanipulation upon their properties.

Motil, Susan M.↗