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At least 1,315 records · Page 73

The Low-Mass Limit: Dark Matter Detectors with eV-Scale Energy Resolution

The SuperCDMS SNOLAB experiment will be a 20-kg scale Si and Ge direct dark matter detection experiment designed to probe down to 300 MeV in dark matter (DM) mass through DM-nucleus scattering and 500 keV in DM electron scattering. In order to reach these low masses with appreciable sensitivity to dark matter, it needs to achieve very low energy resolution ($\le 10$ ev) for nuclear recoils in both detector materials, which will be achieved using a new detector design and operating mode, CDMS HV. This detector is designed to operate at a bias of 100V to convert charges liberated in our detector targets to into phonon energy in order to resolve individual electron-hole pairs. This has never before been achieved in a kg-scale detector. In this thesis, I cover three elements of the design of the CDMS HV detectors. I discuss the detector physics controlling how charges and phonons are generated in our detector crystals, comparing theory to results of recent experiments carried out at Stanford. I move on to describe the operating principles of our phonon-mediated charge readout, as well as the design of the CDMS HV detector. I then describe the performance tests of early CDMS HV prototypes in conjunction with the SuperCDMS SNOLAB electronics, and discuss the path towards achieving single electron-hole pair resolving detectors at the kg-scale given the performance obtained thus far. As a result of these tests, we were able to refine our noise and sensor dynamics models, and develop new metrics for diagnosing non-ideal sources of noise to aid in reducing coupling of the external environment to our detectors. In order to study the microphysics of phonon and charge production in our target crystals, we fabricated a number of gram-scale devices with various sensor designs in order to separate sensor and environmental effects from intrinsic crystal properties. These devices provided the first successful demonstrating of using voltage to amplify charge energ y by production of phonons (the Neganov-Trofimov-Luke effect! ) in order to resolve electron-hole pairs, and opened up a new regime of dark matter and photon science at the gram-scale that we are just beginning to explore. A first dark matter search was carried out with one of these gram-scale devices, producing world-leading limits on electron-recoiling dark matter between 0.5 and 5 MeV in dark matter mass for multiple form factors. This device achieved a phonon resolution of 10~eV, allowing a single gram-day of exposure to rival kg-days of exposure in the competing liquid-noble based electron-recoil search.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Polarization Experiments with Electromagnetic Probes (Final Technical Report)

The grant started in 1989 and finished on 31 July, 2018. The PI (Vina Punjabi) with many Norfolk State University (NSU) undergraduate students, and several research associates have been involved in many research activity during this period. NSU is primarily a minority institution. The PI has worked with one or two students every year, most of the students involved in her research went on to graduate schools to pursue degrees in physics, applied physics or engineering. One of the most important goal of the PI’s research activity has been involving NSU physics undergraduate students in forefront nuclear and particle physics research. (List of students and research associates is given in Appendix I). Over the years the PI, students and research associates participated in many research activity, however there are two main projects where the PI has been involved as one of the project leader. (1) Investigation of the structure of the deuteron at Saturne national lab in Saclay, France and at Laboratory of High Energy (LHE), part of the Joint Institute of Nuclear Research (JINR) lab in Dubna, Russia. (2) Measurement of the ratio of electric to magnetic form factors of the proton , GEp/GMp at Jefferson Lab, to study the internal structure of the proton.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Modular Controllable Transformers (MCT)

Large Power Transformers (LPTs) are at the heart of the electricity infrastructure and are critical pieces in today’s grid. Aging assets, long turn-around times, transportation delays and dependence on foreign manufacturing for these components have created conditions for points of failure across the system. Moreover, there is no available dynamic control on these passive sections of the grid. For all the automation embedded on the low voltage side of the low voltage side of the system there is absolutely no flexibility on the high voltage side. Changes in power flow patterns are brought about by altering dispatch patterns for generators which requires a coordinated effort and is often time consuming. Traditional FACTS based approaches such as UPFC or HVDC light involve massive modifications to the existing infrastructure. Recent instances of physical attacks on LPTs and the slow recovery process associated with fixing or replacing these damaged units has created an increased awareness for this issue. LPT designs are highly customized owing to specific field requirements. Long lead times coupled with transportation delays make procuring and installing LPTs a lengthy process. In an attempt to minimize the recovery time following an LPT failure, transformer manufacturers have developed mobile transformer units. These units typically consist of either a single-phase or three-phase transformer mounted on a truck and characterized by compact form factors. By reducing the assembly time and transport time these units offer a fast and temporary solution to LPT failures. Several efforts led by DOE, Edison Electric Company (EEI) and North American Electric Reliability Corporation (NERC) have led to the RecX program. RecX transformers consist of single phase transformers transported on specialized assemblies to enable fast restoration and minimal installation time. NERC and EEI have instituted transformer sharing programs like Spare Equipment Database (SED) as well as Spare Transformer Equipment Database (STEP) which encourage utilities to maintain and share a fleet of LPTs. Mobile transformers are typically limited to less than 100 MVA to enable transportation on a trailer. Also, the efficiency of mobile transformer units and RecX transformers is lower since they are temporary solutions. The ideal replacement solution would be one that could utilize a set of standardized transformers while incorporating flexibility to influence metrics like power flow, apparent impedance and voltage profiles. In view of these issues the team at Georgia Tech proposed a concept called Modular Controllable Transformers (MCTs). This project was commissioned as a part of DOE’s Transformer Resiliency and Advance Component (TRAC) program. The approach consists of splitting one large unit rated upwards of 100 MVA with smaller modular, standardized units. Each of these smaller units are augmented with a converter to add power flow, voltage and impedance control. Splitting the power level into multiple units has two important implications. By making smaller units, the transportation times can be reduced drastically. Moreover, even though these units have very specific impedance and other parameters, the augmented converters can make it emulate the unit being replaced. Thus, faster replacement times and added controls are achieved making this an extremely resilient approach. In the event of one modular units failure, the other two controllable units can operate in the most resilient fashion keeping the net system overloads to a minimum. Moreover, for the same probability of failure only a fraction of the system capacity is lost. The converter is augmented on to the tertiary winding of the transformer making it retrofittable in the field without massive modifications to the system. The material proposed in this report highlights design considerations to minimize recovery time as well as results displaying overall improvement in resiliency. The cost analysis of this approach shows significant savings compared to UPFC and HVDC lite based approaches. Extensive analysis was conducted on numerous aspects of this project over the course of this project. Simulation studies were conducted to prove the 5MVA converter design. Challenging BIL constraints and transient issues were addressed over the course of this project. Simulations on EMTP platform presented in consequent sections were used to finely tune the control for the same. A final design for a back-to-back 5MVA neutral-point-clamped (NPC) converter was completed in this project. Furthermore, switching components like high power IGBTs from IXYS Westcode Press-Pack series and ABB Stackpack series were identified for this application. These devices exhibit a blocking voltage of 6.5 kV and a nominal collector current of 900 A. Potential housing options as well as existing commercial option were identified for this converter design. A 56 MVA modular transformer unit was designed with Delta Star Inc. with consultation and inputs from all project members. The transformer cooling systems were chosen to be Oil Natural Air Forced (ONAF) to optimize ease of transport. A full Product Requirement Document (PRD) for the converter and the transformer was generated. The team also investigated key aspects of resiliency and how to quantify the same. A metric was developed to analyze resiliency and numerous simulation cases were presented. Increased (N-1) resiliency and outage resistance was showcased through simulation on the Texas Large scale power system. Dynamic control capabilities were also showcased on numerous system level simulations. An IEEE 30 bus system was used to show the ability of the MCT approach to reduce line congestion. Power flow control; a part of the MCTs abilities, showcased a 29% reduction in transformer loading on the same system. Full control over tie line flows was demonstrated on a modified IEEE 13 bus system. Dynamic LTC capabilities were shown through simulation and were compared to traditional LTCs. Furthermore, the ability of the MCTs to alter apparent transformer impedance was simulated to promote standardization of modular transformer units while retaining the ability to emulate a varied range of impedance characteristics. Thus granular control over power flow, voltages, impedances and was presented. Regulatory analysis conducted by Oak Ridge National Laboratory (ORNL) further bolstered the efficacy of the MCT approach and verified the added resiliency achieved due to this approach. As a conclusion, it was proved that the resilience improvement obtained from using the MCT approach is justified by just one failure in a 30-year period. This means that the benefits obtained from using the MCT approach far outweigh the cost of setting this approach up. As a part of the future efforts, the team is proposing building a (12.47-24) kV/400 kVA scaled down unit to control 5MVA of power flows. Emphasis would be laid on using commercial components to speed up the build of these units. Further the actual transport of the modular transformer unit would be a part of this operation and would provide insight into transportation issues. The approach shows much promise and adds key dynamic control on passive sub transmission and transmission sectors.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Prototype Ceramic High Efficiency Particulate Air Filter Testing and Filter Media Development for Nuclear Facility Ventilation

This report summarizes recent and past related Ceramic HEPA Filter activity for this NNSA NSR&D project and on-going plans for FY18 and FY19 work as presently planned. Prior work has evaluated concepts for a ceramic HEPA filter including ceramic support materials, filter media including electrospun filter media, and metal housing designs to accommodate the conservative temperature performance target of up to 500°C. This has been supported by modelling efforts discussed with nuclear facility system engineers and their management. The temperature and time-at-temperature are based on conservative, bounding temperatures from fire analysis presented as a draft EFCOG best practice paper for nuclear facility safety analysis. The overall goal is to improve safety of DOE nuclear facilities during fire scenarios by developing improved filtration technology including increasing performance while reducing pressure drop. Ceramic filtration technology can provide robust, passive mitigation against radiological releases. The goal of the ceramic HEPA filter is to provide a robust HEPA filter that provides increased temperature performance in an equivalent form factor (size and shape) that is similar to existing conventional HEPA filters used in facilities. Once qualified for use in facilities, the benefit of a ceramic HEPA filters could simplify and reduce safety and support system costs, as well as considerably lower life-cycle costs. Installation, monitoring, and maintenance of active fire suppression systems, as well as other related systems, are a considerable on-going cost to nuclear facilities. Reducing the level of dependence on Safety Class and Safety Significant fire alarm and fire suppression systems could allow significant cost savings. At present we are continuing research and development efforts towards the goal of a ceramic filter design, including improved ceramic filter media, that could reduce total operation cost for facilities utilizing HEPA filters.

42 ENGINEERING↗

Passively-Powered Adaptively-Located Flexible Hybrid Sensors Final Report

PARC, a Xerox Company, is developing a low-cost system of peel-and-stick wireless sensors that will enable widespread building environment sensor deployment with the potential to deliver up to 30% energy savings. The system is embodied by a set of RF hubs that provide power to the automatically located sensor nodes, and relays data wirelessly to the building management system (BMS). The sensor nodes are flexible electronic labels powered by rectified RF energy transmitted by a RF hub and can contain multiple printed and conventional sensors. The system design overcomes limitations in wireless sensors related to power delivery, lifetime, and cost by eliminating batteries and photovoltaic devices. The sensor label can be equipped with a variety of printed and conventional sensors for building energy optimization, including lighting, occupancy, temperature, humidity, motion, and air quality. A key advantage of this system is its ability to automatically locate multiple sensor nodes to within 0.5 m (at a 5-m read distance) for simplified commissioning, as well as its interoperability with a wide range of existing BMS hardware and software. This enables automatic sensor reconfiguration and recommissioning, which is an important cost reduction driver. Moreover, the sensors are compatible with low-cost-, high-throughput roll-to-roll manufacturing, further reducing system costs. Upon successfully developing, manufacturing and deploying the system with optimized control, it can lead to annual primary energy savings >280 TBtu in offices, and up to ~1850 TBtu in combined offices and residences. The technology is based on PARC innovations in small antenna design, efficient RF energy capture, and flexible electronics. PARC is a leader in flexible hybrid integration similar to what is used in current RFID tags, which will provide a low-cost system in a flexible form factor. Our team member, Energy ETC, is a leader in supplier-agnostic BMS deployments, and will design the commissioning and deployment procedures to maximize system interoperability. The project will result in a demonstrator that will provide temperature and humidity data and will be wirelessly integrated into PARC’s BMS.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Large scale, Low Temperature, Microplasma UV Lighting Tiles for Water Purification and Sterilization

Eden Park Illumination, Inc. is pursuing the development and commercialization of microcavity plasma lamps capable of generating light in the vacuum ultraviolet and deep ultraviolet wavelength ranges (VUV and UVC respectively), but in a slim and flat form factor. Ultraviolet light is well known to be efficient in enabling a number of chemical processes,and is particularly effective for disinfection.The ability of deep UV and VUV radiation to neutralize pathogens, drugs (hormone regulators), and organic chemicals is of increasing concern in drinking water and water re-use and is well-documented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Corrections to the elastic p ↑ p ↑ analyzing power parameterization at high energies

The HJET polarimeter was designed to measure the absolute polarization of the proton beams at RHIC. It can also be used for the precise measurement of the elastic pp single and double spin analyzing powers. Recently Boris Kopeliovich pointed out that analyzing power parametrization,which is conventionally used for these measurements, was derived with specific simplifications and for the experimental accuracy achieved at HJET, the corrections should be applied. In this not ewe evaluate the corrections to analyzing powers due to (i) the differences between electromagnetic and hadronic form factors, and (ii) the ~$m$ $^{2}_{p}$/s term in elastic pp electromagnetic amplitude. The corresponding variations of the measured hadronic spin-flip amplitudes are about experimental uncertainties of the HJET measurements. It should also be noted that the evaluated corrections might be essential for the elastic pp forward real-to-imaginary amplitude ratios ρ listed in PDG.

43 PARTICLE ACCELERATORS↗

Prototype Ceramic HEPA Filter Testing and Filter Media Research and Development for Nuclear Facility Ventilation

This is a brief summary of recent and past Ceramic HEPA Filter research and development activities under an NNSA NSR&D funded project and describes on-going plans for FY19 work as presently planned. Prior work has evaluated concepts for a ceramic HEPA filter including ceramic support materials, filter media including electrospun filter media, and metal housing designs to accommodate the conservative temperature performance target of up to 500°C. This has been supported by modelling efforts discussed with nuclear facility system engineers and their management. The temperature and time-attemperature are based on conservative, bounding temperatures from fire analysis presented as an EFCOG best practice paper for nuclear facility safety analysis. The overall goal is to improve safety of DOE nuclear facilities during fire scenarios by developing improved filtration technology including increasing temperature performance while maintaining acceptable filter pressure drop. Ceramic filtration technology can provide robust, passive mitigation against radiological releases. The goal of the ceramic HEPA filter is to provide a HEPA filter that provides increased temperature performance in an equivalent form factor (size and shape) that is similar to existing conventional HEPA filters used in facilities. Once development is complete and qualified for use in facilities, ceramic HEPA filters could simplify and reduce safety and support system costs, as well as lower life-cycle costs. Installation, monitoring, and maintenance of active fire suppression systems, as well as other related systems, are a considerable on-going cost to nuclear facilities. Reducing the level of dependence on Safety Class and Safety Significant fire alarm and fire suppression systems could allow significant cost savings. At present we are continuing research and development efforts towards the goal of a ceramic filter design, including improved ceramic filter media, that could reduce total operation cost for facilities utilizing HEPA filters.

36 MATERIALS SCIENCE↗

Assembly and characterization of fast neutron detectors for TREAT fuel motion monitoring system

The TREAT fuel motion monitoring system (FMMS) currently uses a fast neutron hodoscope which allows for fast neutron imaging produced by fission in the reactor core. These neutrons are then passed unmoderated through a core slot and collimated to the 360 detector array, or hodoscope. The purpose of this project was to assemble, characterize, and qualify another 96 PMT’s to add to the current batch of 96. The assembly consists of four main components starting with a PMT, a voltage divider, a PRS button that will scintillate when struck by neutrons, and a Phenolic shroud which will house all the components to create a standard form factor. The characterization will be completed in the lab to reach the goal of having all PMT’s characterized with a determination of operability before finalized and placed inside the TREAT hodoscope.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Next Generation Photovoltaic Technologies For High-Performance Remote Power Generation (Final Report)

A unique, micro-scale architecture is proposed to create a novel hybrid concentrated photovoltaic system. Micro-scale (sub-millimeter wide), multi-junction cells are attached to a large-area silicon cell backplane (several inches wide) that can optimally collect both direct and diffuse light. By using multi- junction III-V cells, we can get the highest possible efficiency of the direct light input. In addition, by collecting the diffuse light in the large-area silicon cell, we can produce power on cloudy days when the concentrating cells would have minimal output. Through the use of micro-scale cells and lenses, the overall assembly will provide higher efficiency than conventional concentrators and flat plates, while keeping the form factor of a flat plate module. This report describes the hybrid concept, the design of a prototype, including the PV cells and optics, and the experimental results.

14 SOLAR ENERGY↗

Prototype Ceramic HEPA Filter Testing and Filter Media Research and Development for Nuclear Facility Ventilation

This is a brief summary of recent and past Ceramic HEPA Filter research and development activities under an NNSA NSR&D funded project and describes on-going plans for FY19 work as presently planned. Prior work has evaluated concepts for a ceramic HEPA filter including ceramic support materials, filter media including electrospun filter media, and metal housing designs to accommodate the conservative temperature performance target of up to 500°C. This has been supported by modelling efforts discussed with nuclear facility system engineers and their management. The temperature and time-at-temperature are based on conservative, bounding temperatures from fire analysis presented as an EFCOG best practice paper for nuclear facility safety analysis. The overall goal is to improve safety of DOE nuclear facilities during fire scenarios by developing improved filtration technology including increasing temperature performance while maintaining acceptable filter pressure drop. Ceramic filtration technology can provide robust, passive mitigation against radiological releases. The goal of the ceramic HEPA filter is to provide a HEPA filter that provides increased temperature performance in an equivalent form factor (size and shape) that is similar to existing conventional HEPA filters used in facilities. Once development is complete and qualified for use in facilities, ceramic HEPA filters could simplify and reduce safety and support system costs, as well as lower life-cycle costs. Installation, monitoring, and maintenance of active fire suppression systems, as well as other related systems, are a considerable on-going cost to nuclear facilities. Reducing the level of dependence on Safety Class and Safety Significant fire alarm and fire suppression systems could allow significant cost savings, while maintaining safety. At present we are continuing research and development efforts towards the goal of a ceramic filter design, including improved ceramic filter media, that could reduce total operation cost for facilities utilizing HEPA filters.

36 MATERIALS SCIENCE↗

Annual BTMS Testing Section (SNL)

One of the first milestones of the Behind the Meter Storage (BTMS) program was to develop testing protocols so that the state-of-the-art cell chemistries and form factors could be evaluated against BTMS aggressive performance and lifetime metrics. To help guide this conversation, a pack estimation calculation was run. At the time the team was assuming a worst-case scenario in which the battery alone would need to charge an electric vehicle in 15 minutes with no support from the grid. This calculation varied the amount of current applied by each string or module in the storage system and estimated how many cells (and estimated cost) would be needed to charge an electric vehicle in 15 minutes under the current applied.

25 ENERGY STORAGE↗

Proton Track Identication in MicroBooNE Simulation for Neutral Current Elastic Events

The net contribution of the strange quark spins to the proton spin, Δs, can be determined from neutral current elastic neutrino-proton interactions at low momentum transfer combined with data from electron-proton scattering. The probability of neutrino-proton interactions depends in part on the axial form factor, which represents the spin structure of the proton and can be separated into its quark flavor contributions. Low momentum transfer neutrino neutral current interactions can be measured in MicroBooNE, a high-resolution liquid argon time projection chamber (LArTPC) in its first year of running in the Booster Neutrino Beamline at Fermilab. The signal for these interactions in MicroBooNE is a single short proton track. We present our work on the automated reconstruction and classification of proton tracks in LArTPCs, an important step in the determination of neutrinonucleon cross sections and the measurement of Δs.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Tandem particle-slurry batch reactors for solar water splitting (Final Scientific/Technical Report)

Economically, particle slurry reactors are projected to be one of the most promising technologies for solar photoelectrochemical hydrogen production, according to a 2009 techno-economic analysis commissioned by the US DOE and performed by Directed Technologies, Inc. The Fuel Cell Technologies Office’s Multi-Year Research, Development and Demonstration (MYRD&D) goals and targets are to reduce the cost of H 2 produced from renewable sources at the plant gate (i.e. not including delivery, dispensing, or storage) to < $2.00/gge, equivalent to ~$2.00/kg H 2 . Research results from our techno-economic modeling research suggest that this target could be met using particle slurry reactors assuming STH efficiencies in the range of 5 – 10%, materials lifetimes of < 1 year, and nanoparticles that cost up to 20 times more than projected costs of TiO 2 -coated Fe 2 O 3 nanoparticles. Although most large worldwide research efforts directed at solar photoelectrochemical hydrogen production focus on wafer-based designs, the projected lower cost for a particle slurry reactor at these disparate projected STH efficiencies clearly suggests that particle slurry reactors could be a scalable and deployable technology, assuming several challenges are overcome. These major technological challenges include the demonstration of a vertically-stacked-vessel architecture that is capable of operating sustainably while mostly relying on diffusion and natural convection to mix the redox shuttles between the vessels, and the demonstration that photocatalyst particles can operate at an overall 1% STH efficiency or larger when incorporated into this two-vessel design. Our research adds to the understanding of photocatalytic reactors for solar water splitting through numerical modeling results and experimental results. Numerical models were developed to simulate relevant device physics including particle and reactor dimensions which affect optical, transport, and rheological properties, electrocatalytic and photovoltaic properties of particles at various temperatures, and properties of redox shuttles and separators. Moreover, theoretical maximum solar-to-hydrogen efficiencies for ensembles of particles like in photocatalyst reactors were modeled and simulated and shown to equal or exceed those of photoelectrochemical designs under most scenarios. These results help determine constraints on the reactor that will enable more optimal designs for future prototypes. In parallel, experiments were performed to identify the most effective redox shuttles and to empirically validate the numerical models and simulations. Toward the latter, state-of-the-art light-absorbing particles and electrocatalysts were synthesized and characterized physically and photoelectrochemically for water electrolysis and redox chemistry with redox shuttles in the form factor of mesoporous electrodes and free-floating particles. The most promising materials candidates were used in a suspension reactor to evaluate performance toward photocatalytic H 2 production and results from the two measurements were compared. Predominantly, state-of-the-art cocatalyst-modified Rh-doped SrTiO 3 and BiVO 4 particles were further characterized to assess for their ability to perform visible-light-driven H 2 and O 2 evolution, respectively, and results were similar to those reported for the state-of-the-art in the peer-reviewed literature. Outcomes from this work inform the public of the effectiveness and promise of solar photocatalytic water splitting for clean and renewable hydrogen production. This work may also help increase research interest and funding for photocatalysis projects, which will accelerate development of a technology that will benefit the public by generating fuel while emitting few greenhouse gases and pollutants.

08 HYDROGEN↗

JEDEC Tray Flexures for High-Consequence Electronics

JEDEC matrix trays are an industry standard for the safe handling, transport, and storage of electronics. Manufacturing tolerances of the trays (typical for injection-molded components) forces the creation of an envelope around components rather than a secure interface to prevent the trays themselves from damaging the electronics during use. However, this allows relative motion between the components, another potential damage source. This paper covers the design of tray features (flexures) than enable intentional, tuned contact preload to prevent relative motion, maximizing component safety while keeping the JEDEC tray form-factor. The target preload is balanced between gravity and shipment forces that could be experience during adverse handling or transport to prevent loss of contact or slip and keeping the load itself low enough to prevent component damage. Typical features/dimensions for JECEC trays were employed to maximize utility and minimize tray fabrication difficulty. The design also increases usability and component safety by making the chips visible while still sandwiched between trays. The point design described here exemplifies a simple, easy-to-manufacture tray-matrix flexure that significantly improves the security of supported components

42 ENGINEERING↗

Measuring Atmospheric Gas Using Small Satellites (Final Report)

The research focused on demonstrating that a small satellite (< 10 kg) is able to provide useable data in support of stratospheric circulation and broader atmospheric measurement generally thought to required large, lengthy and high cost space programs. The research goals targeting enabling CubeSats to serve as science platforms including low-cost communication infrastructure, science enabling solar panels and a ruggedized small form factor science instrument were highly successful with demonstrated on-orbit results. The collection of science data on-orbit was not successful due to a high tumbling rate impacted to the spacecraft at time of release on orbit, preventing reliable solar charging and leading to premature ending of the mission. The successes acquired on orbit will act as a springboard for further research and space projects at LLNL. Several research groups (both private and government) have expressed interest in the area of this research that proved successful such as the solar panels and iridium crosslink as well as the LLNL developed CubeSat standard.

42 ENGINEERING↗

Manufacturing of low-background copper electrical components for rare-event detection. Final report

This SBIR Phase I project developed the manufacturing capability for the production of ultra-low-background copper and lead for use in electronic interconnects and support architecture. Copper is an attractive electronic and support material because of its favorable conductivity and mechanical properties. Fortuitously, the material can also be electroplated with high radiopurity, particularly if the electroforming is performed in shielded, buried facilities within which the cosmogenic background is minimized. The machining of the electroformed copper into wires, feedthroughs, and support hardware can potentially introduce impurities through the shop environment or through the dies used in wire-drawing and part formation. During Phase I, we demonstrated an alternative low-cost solution-based approach in which copper nanoparticles are colloidally-grown and self-assembled into solids that can serve as thermal structures- such as cold-fingers, mechanical structures- such as the inner shielding lining, and electronic devices. We demonstrated ultrastrong, high-conductivity free-standing copper conductors during Phase I suitable for battery electrodes, interconnects, and cabling, all components that enable next-generation flexible electronics. In nanoparticle form, copper forms in a crystalline lattice with very low impurity content, but its self-assembly is facilitated by organic capping ligands that can serve as impurity sources. Upon the formation of a colloidal solid, the copper particles can be fused and the organic components evaporated through vacuum annealing. The study of ultra-pure copper was expanded during Phase I to include nanostructured lead, which is an important radiation-shielding material. By growing lead particles in a water-based solution the resulting solution can be poured into the desired form-factor mold, within which it will self-assemble and harden upon evaporation of the water and any organics. The effort during Phase II is designed to complete the development of the manufacturing process and to use that process to deliver high radio-purity copper and lead components to the rare-event detection community so that the noise-floor contribution from the surrounding materials is substantially eliminated.

36 MATERIALS SCIENCE↗

Round 3 Update of Stress Testing Results for Organic Light-Emitting Diode Panels and Luminaires

Organic light-emitting diode (OLED) sources are a potential solid-state lighting technology for use in indoor lighting applications. Some of the advantages offered by OLEDs include thin profiles, low glare, diffuse lighting, and unique form factors. The U.S. Department of Energy (DOE) has released six technical reports focused on OLED technologies to provide information and analysis to the lighting industry. These reports include the evaluation of two different field deployment sites, a market analysis, a tear-down analysis, and two independent assessments of the performance of select commercially available OLED products. This report builds on earlier DOE efforts with OLED technology by updating information about previously benchmarked commercial OLED products. Specifically, this report provides updated findings about the robustness and reliability of commercial OLED products.

42 ENGINEERING↗