Preliminary investigation of effects of combustion in ram jet performance of supersonic diffusers II : perforated supersonic inlet
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Schroeder, Albert H↗
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Results for “effective diffusivity”
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Spatially-correlated Site Occupancy in the Nonstoichiometric Meta-stable ε -Al 60 Sm 11 Phase during Devitrification of Al-10.2 at.% Sm Glasses
A metastable ε-Al 60 Sm 11 phase appears during the initial devitrification of as-quenched Al-10.2 at.% Sm glasses. The ε phase is nonstoichiometric in nature since Al occupation is observed on the 16 f Sm lattice sites. Scanning transmission electron microscopic images reveal profound spatial correlation of Sm content on these sites, which cannot be explained by the “average crystal” description from Rietveld analysis of diffraction data. Thermodynamically favorable configurations, established by Monte Carlo (MC) simulations based on a cluster-expansion model, also give qualitatively different correlation functions from experimental observations. On the other hand, molecular dynamics simulations of the growth of ε-Al 60 Sm 11 in undercooled liquid show that when the diffusion range of Sm is limited to ~4 Å, the correlation function of the as-grown crystal structure agrees well with that of the scanning transmission electronic microscopy (STEM) images. Furthermore, our results show that kinetic effects, especially the limited diffusivity of Sm atoms plays the fundamental role in determining the nonstoichiometric site occupancies of the ε-Al 60 Sm 11 phase during the crystallization process.
36 MATERIALS SCIENCE↗
High-resolution planar electron beam induced current in bulk diodes using high-energy electrons
Understanding the impact of high-energy electron radiation on device characteristics remains critical for the expanding use of semiconductor electronics in space-borne applications and other radiation harsh environments. Here in this paper, we report on in situ measurements of high-energy electron radiation effects on the hole diffusion length in low threading dislocation density homoepitaxial bulk n-GaN Schottky diodes using electron beam induced current (EBIC) in high-voltage scanning electron microscopy mode. Despite the large interaction volume in this system, quantitative EBIC imaging is possible due to the sustained collimation of the incident electron beam. This approach enables direct measurement of electron radiation effects without having to thin the specimen. Using a combination of experimental EBIC measurements and Monte Carlo simulations of electron trajectories, we determine a hole diffusion length of 264 ± 11 nm for n-GaN. Irradiation with 200 kV electron beam with an accumulated dose of 24 × 10 16 electrons cm -2 led to an approximate 35% decrease in the minority carrier diffusion length.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Understanding the interacted mechanism between carbonation and chloride aerosol attack in ordinary Portland cement concrete
An experimental study is carried out with the aim to understand the interacted mechanism between carbonation and chloride aerosol attack in ordinary Portland cement (OPC) concrete. Effects of carbonation on the chloride profile, the chloride binding capacity and the chloride diffusion coefficient are evaluated. Besides, effect of chloride aerosol attack on the carbonation rate is investigated. Concrete specimens with three water-to-cement ratios (0.38, 0.47 and 0.53) are fabricated in this work. Tested results demonstrate that carbonation remarkably affects the chloride profile, reduces the chloride binding capacity, and also accelerates the rate of chloride ion diffusion of concrete. Besides, the presence of chloride aerosol can lead to lower the carbonation depth and increase the pH value of carbonated concrete. Microscopic properties such as morphology, porosity, and pore size distribution for the contaminated concretes are explored by scanning electron microscope and mercury intrusion porosimetry, which provide strong evidence to these research findings.
36 MATERIALS SCIENCE↗
Thermophoretically augmented mass transfer rates to solid walls across laminar boundary layers
Predictions of mass transfer (heavy vapor and small particle deposition) rates to solid walls, including the effects of thermal (Soret) diffusion ('thermophoresis' for small particles), are made by numerically solving the two-dimensional self-similar forced convection laminar boundary-layer equations with variable properties, covering the particle size range from vapor molecules up to the size threshold for inertial (dynamical nonequilibrium) effects. The effect of thermophoresis is predicted to be particularly important for submicron particle deposition on highly cooled solid surfaces, with corresponding enhancement factors at atmospheric conditions being over a thousand-fold at T(w)/T(e) equal to about 0.6. As a consequence of this mass transfer mechanism, the particle size dependence of the mass transfer coefficient to a cooled wall will be much weaker than for the corresponding case of isothermal capture by Brownian-convective diffusion.
Gokoglu, S. A.↗
Reduced Artifact Approach for Determining Diffusion Coefficients in Time-Resolved Microscopy
Ultrafast microscopy methods traditionally assume a Gaussian profile to extract excited state diffusivities from transport measurements. Although this fitting method recovers accurate diffusion coefficients when the point spread function is well-represented by a Gaussian, even minor spatial aberrations introduced by the imaging system cause significant errors in the determined value. To provide a more accurate measure of excited state transport in nano- and microscale materials systems, in this work an alternative analysis protocol is proposed that numerically convolves the Green’s function solution to the diffusion equation with the experimentally measured point spread function. In contrast to the Gaussian fitting approach, the numerical convolution is shown to be robust against artifacts caused by nonideal point spread functions. Furthermore, the numerical convolution approach is highly effective at resolving anisotropic diffusion in modeled data.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Mass Dependency of Isotope Fractionation of Gases Under Thermal Gradient and Its Possible Implications for Planetary Atmosphere Escaping Process
Physical processes that unmix elements/isotopes of gas molecules involve phase changes, diffusion (chemical or thermal), effusion and gravitational settling. Some of those play significant roles for the evolution of chemical and isotopic compositions of gases in planetary bodies which lead to better understanding of surface paleoclimatic conditions, e.g. gas bubbles in Antarctic ice, and planetary evolution, e.g. the solar-wind erosion induced gas escaping from exosphere on terrestrial planets.. A mass dependent relationship is always expected for the kinetic isotope fractionations during these simple physical processes, according to the kinetic theory of gases by Chapman, Enskog and others [3-5]. For O-bearing (O16, -O17, -O18) molecules the alpha O-17/ alpha O-18 is expected at 0.5 to 0.515, and for S-bearing (S32,-S33. -S34, -S36) molecules, the alpha S-33/ αlpha S-34 is expected at 0.5 to 0.508, where alpha is the isotope fractionation factor associated with unmixing processes. Thus, one isotope pair is generally proxied to yield all the information for the physical history of the gases. However, we recently] reported the violation of mass law for isotope fractionation among isotope pairs of multiple isotope system during gas diffusion or convection under thermal gradient (Thermal Gradient Induced Non-Mass Dependent effect, TGI-NMD). The mechanism(s) that is responsible to such striking observation remains unanswered. In our past studies, we investigated polyatomic molecules, O2 and SF6, and we suggested that nuclear spin effect could be responsible to the observed NMD effect in a way of changing diffusion coefficients of certain molecules, owing to the fact of negligible delta S-36 anomaly for SF6.. On the other hand, our results also showed that for both diffusion and convection under thermal gradient, this NMD effect is increased by lower gas pressure, bigger temperature gradient and lower average temperature, which indicate that the nuclear spin effect may not be the significant contributor as the energies involved in the hyperfine effect are much smaller than those with molecular collisions, especially under convective conditions.
Sun, Tao↗
Hydrogen Diffusion in Slit Pores: Role of Temperature, Pressure, Confinement, and Roughness
Diffusion of hydrogen (H 2 ) is important to understand the leakage risk and transport behavior for H 2 geologic storage. We applied molecular dynamics simulations to investigate the influencing factors of H2 diffusion in the slit pores of calcite, hematite, and quartz, owing to their abundance. It is revealed that the H2 self-diffusion coefficient increases with the temperature, regardless of the type of pore minerals. The diffusion of H 2 in the 20 nm slit pores falls into the bulk diffusion regime when the pressure is 10 MPa. The self-diffusion of H 2 decreases with pressure in all three types of slit pores, following a power law model with the exponents ranging from -0.825 to -0.964. Furthermore, the impact of confinement on H 2 diffusion is more pronounced for the slit pores with stronger interactions with H 2 -like calcite. The role of surface roughness in H 2 diffusion depends on the slit aperture. The rough surface enhances H 2 diffusion in the larger slit pores due to the enlarged effective pore space, whereas it weakens H 2 diffusion in the small slit pores due to stronger adsorption. These findings will fill the knowledge gap on the coupling effect of different factors influencing H 2 diffusion.
08 HYDROGEN↗
A transport model of the turbulent scalar-velocity
Performance tests of the third-order turbulence closure for predictions of separating and recirculating flows in backward-facing steps were studied. Computations of the momentum and temperature fields in the flow domain being considered entail the solution of time-averaged transport equations containing the second-order turbulent fluctuating products. The triple products, which are responsible for the diffusive transport of the second-order products, attain greater significance in separating and reattaching flows. The computations are compared with several algebraic models and with the experimental data. The prediction was improved considerably, particularly in the separated shear layer. Computations are further made for the temperature-velocity double products and triple products. Finally, several advantages were observed in the usage of the transport equations for the evaluation of the turbulence triple products; one of the most important features is that the transport model can always take the effects of convection and diffusion into account in strong convective shear flows such as reattaching separated layers while conventional algebraic models cannot account for these effects in the evaluation of turbulence variables.
Amano, R. S.↗
Transport models of the turbulent velocity-temperature products for computations of recirculating flows
Performance tests of the third-order turbulence closure for predictions of separating and recirculating flows in backward-facing steps were studied. Computations of the momentum and temperature fields in the flow domain being considered entail the solution of time-averaged transport equations containing the second-order turbulent fluctuating products. The triple products, which are responsible for the diffusive transport of the second-order products, attain greater significance in separating and reattaching flows. The computations are compared with several algebraic models and with the experimental data. The prediction was improved considerably, particularly in the separated shear layer. Computations are further made for the temperature-velocity double products and triple products. Finally, several advantages were observed in the usage of the transport equations for the evaluation of the turbulence triple products; one of the most important features is that the transport model can always take the effects of convection and diffusion into account in strong convective shear flows such as reattaching separated layers while conventional algebraic models cannot account for these effects in the evaluation of turbulence variables.
Amano, R. S.↗
Automated Symbolic Upscaling: 1. Model Generation for Extended Applicability Regimes
Abstract In porous media theory, upscaling techniques are fundamental to deriving rigorous Darcy‐scale models for flow and reactive transport in subsurface systems. Due to limitations in classical techniques, a number of ad hoc approaches have been proposed to address physical regimes in which reactive time scales are similar to, or faster than, diffusive time scales. In Part 1 of this two part series, we present a strategy for expanding the applicability of classical homogenization theory by generalizing the assumed closure form. We detail the implementation of this strategy on two reactive mass transport problems with moderately reactive physics. The strategy produces nontrivial homogenized models with emergent terms and effective parameters that couple reactive, diffusive, and advective transport. The differences in equation forms between the macroscopic and pore‐scale descriptions advise caution to further studies where the forms of macroscopic equations are assumed, as opposed to rigorously derived. Numerical validation is provided for each problem to show that the error estimates of homogenization theory are satisfied, and to justify the implemented strategy. In Part 2, the presented strategy is automated using symbolic computing to expedite its implementation.
Pietrzyk, Kyle↗
Rate of energy gain and maximum energy in diffusive shock acceleration
The problem of diffusive shock acceleration of fast charged particles is reexamined with emphasis on the rate of energy gain, and the maximum energy which can be attained in a given circumstance. The direction of the average magnetic field at the shock is shown to have a large effect. If the perpendicular diffusion coefficient is much smaller than the parallel coefficient, particles can gain much more energy if the shock is quasi-perpendicular than if it is quasi-parallel. The maximum energy attainable can be substantially higher (by a factor of 100 or more) than previous discussions would predict, in cases where the shock is quasi-perpendicular. The energy gain increases as kappa-perpendicular decreases. The principal limitation comes from the requirement that diffusion be a valid approximation to the particle motion, and that the particle be able to diffuse fast enough to encounter the shock many times.
Jokipii, J. R.↗
Coupled low-energy - ring current plasma diffusion in the Jovian magnetosphere
The outwardly diffusing Iogenic plasma and the simultaneously inwardly diffusing ring current plasma in the Jovian magnetosphere are described using a coupled diffusion model which incorporates the effects of the pressure gradient of the ring current into the cross-L diffusion coefficient. The coupled diffusion coefficient is derived by calculating the total energy available to drive the diffusion process. The condition is imposed that the diffusion coefficient takes on a local minimum value at some point in the region L = 7-8, at which point the gradient of the Io plasma density is specified as ramp value given by Siscoe et al. (1981). The hypothesis that the pressure gradient of the ring current causes the diminution of radial plasma transport is tested, and solution profiles for the Iogenic and ring current plasma densities are obtained which imply that the Io plasma ramp is caused by a high-density, low-energy component of the ring current hitherto unobserved directly.
Summers, D.↗
Changes in "thermal lens" measure diffusivity
In an extension of "thermal lens" effect to new applications and better resolution, two laser beams combine to rapidly measure thermal diffusivity and other molecular dynamic properties. New double-beam technique handles very small samples unlike classical techniques for measuring diffusivity. It can be used for measurements on samples undergoing stress, making it applicable to data collection for structural engineering.
Gupta, A.↗
Screen printable copper pastes for silicon solar cells
The current work demonstrates the successful metallization of a PERC silicon solar cell with screen-printable copper (Cu) paste that is sintered at elevated temperature in air atmosphere. The existing state of the art in Silicon (Si) solar cell metallization is silver (Ag) paste; Cu cost is 1/100th the cost of Ag and has a comparable conductivity. However, Cu undergoes rapid oxidation at elevated temperatures and the high diffusion of Cu into Si restricts its usage in the metallization of silicon solar cells. In this paper, a Cu paste containing a proprietary mixture of antioxidant additives and diffusion inhibitors was used to make front gridlines on PERC cells. The Cu-printed cells were fired in an IR belt furnace with a peak temperature of 576°C in air atmosphere. The solar cells discussed here reached an efficiency of 19%, which is 88% of the efficiency measured for a commercial Ag-printed cell. The working devices were further characterized using STEM, EDX, ToF-SIMS and long-term suns-V oc studies demonstrating an absence of Cu diffusion. Furthermore, thermally stressing the Cu-printed solar cells yielded a reduction of less than 1.9% of the initial pseudo fill factor (pFF) after 1000 hours at 200°C. Here, the shunt resistance of cells monitored over 3 years remained within 2.5% of its initial value, which demonstrates the effectiveness of the Cu diffusion barrier.
14 SOLAR ENERGY↗
Resonant diffusion in strongly turbulent plasmas.
The effect of turbulent fluctuations on plasma particles is considered, and equations are derived which describe the evolution of macroscopic properties such as temperature and flow speed of the turbulent plasma. Initially, a diffusion equation for a single-particle distribution function averaged over an ensemble of plasmas is derived for an unmagnetized plasma. For the resonant diffusion in strongly turbulent plasmas, an ensemble of three-dimensional plasmas is considered with an approximately homogeneous and stationary distribution of random electromagnetic fluctuations. For each realization, the single-particle distribution function satisfies the Vlasov equation.
Birmingham, T. J.↗
Diffusion at the magnetopause: Hybrid simulations
Electromagnetic wave generation and resulting cross-field diffusion of plasma are considered at a tangential discontinuity, which characterizes the magnetopause for northward interplanetary magnetic field. Two-dimensional hybrid (particle ions, massless fluid electrons) simulations, in which the tangential discontinuity is generated self-consistently via a stream-stream interaction, are used to show that wave growth occurs when the ambient magnetic field is predominantly perpendicular to the direction of the density gradient. Low-frequency (much less than ion gyrofrequency) waves, with amplitudes delta B/B less than or equal to 0.2 and anticorrelated density fluctuations delta n/n less than or equal to 0.6, are generated at the discontinuity, resulting in cross-field diffusion that is comparable to the Bohm rate. Both the fluctuation level and the lack of ion heating in the calculations are consistent with observations at the magnetopause. The magnitude of the diffusion is considered in the presence of numerical effects and in the context of the inferred diffusion rate at the magnetopause. The relation of the low-frequency waves and their consequences to faster growing, short-wavelength waves due to the lower hybrid drift instability is also addressed. The overall conclusion of this initial study is that diffusion due to low frequency waves is not likely to be a major effect at the magnetopause.
Winske, D.↗
Gravity wave-driven fluctuations in OH nightglow from an extended, dissipative emission region
The paper theoretically examines the modification of the characteristics of OH nightglow from an extended emission region by eddy momentum and eddy thermal diffusivities. The reactions that account for OH decay are presented with the additional modifications demonstrating the importance of the upper limit of vertical integration of the extended source. When the vertical wavelengths are smaller than the thickness of the main OH emission region, oscillations cause the effects, particularly at long wavelengths. Eddy diffusion increases the vertical wavelength, and therefore the interference effects related to a finite range of vertical integration can be reduced by accounting for eddy diffusion. It is determined that the effects of eddy momentum and thermal diffusivities are important elements of gravity wave dynamics and should be considered when calculating OH emission perturbations and related variables.
Schubert, G.↗