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At least 1,315 records · Page 73
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Morphology-defined interaction of copper phthalocyanine with O 2 /H 2 O

Copper phthalocyanine (CuPc) is an important hole transport layer for organic photovoltaics (OPVs), but its interaction with ambient gas/vapor may lead to changes in electronic properties of the material which subsequently limits the lifetime of OPV devices. CuPc films of thickness 25 nm and 100 nm were grown by thermal sublimation at 25°C, 150°C, and 250°C in order to vary morphology. Using a source-measure unit and a quartz crystal microbalance (QCM), we measured changes in electrical resistance and film mass in situ during exposure to controlled pulses of O 2 and H 2 O vapor. Mass loading by O 2 was enhanced by a factor of 5 in films deposited at 250 C, possibly due to the ~200° C CuPc -> transition which allows higher O 2 mobility between stacked molecules. While gas/vapor sorption occurred over timescales of < 10 minutes, resistance change occurred over timescales > 1 hour, suggesting that mass change occurs by rapid adsorption at active surface sites, whereas resistive response is dominated by slow diffusion of adsorbates into the film bulk. Resistive response generally increases with film deposition temperature due to increased porosity associated with larger crystalline domains. The 25 nm thick films exhibit higher resistive response than 100 nm thick films after an hour of O 2 /H 2 O exposure due to the smaller analyte diffusion length required for reaching the film/electrode interface. We found evidence of decoupling of CuPc from the gold-coated QCM crystal due to preferential adsorption of O 2 /H 2 O molecules on gold, which is consistent with findings of other studies.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine

Copper-catalyzed aerobic oxidative C–H/N–H coupling between simple ketones and diamines was developed toward the synthesis of a variety of pyrazines. Various substituted ketones were compatible for this transformation. Preliminary mechanistic investigations indicated that radical species were involved. X-ray absorption fine structure experiments elucidated that the Cu(II) species 5 coordinated by two N atoms at a distance of 2.04 Å and two O atoms at a shorter distance of 1.98 Å was a reactive one for this aerobic oxidative coupling reaction. Density functional theory calculations suggested that the intramolecular coupling of cationic radicals was favorable in this transformation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Effect of the Surface Modification of Synthetic Diamond with Nickel or Tungsten on the Properties of Copper–Diamond Composites

Tungsten- and nickel-containing coatings have been produced on the surface of synthetic diamond crystals by rotary chemical vapor deposition (RCVD) using tungsten hexacarbonyl, W(CO){sub 6}, and nickelocene, Ni(C{sub 5}H{sub 5}){sub 2}, as gaseous precursors. The thickness, composition, and morphology of the coatings have been shown to depend on the RCVD process duration and reactant concentrations in the vapor phase. The synthetic diamond microcrystals with tungsten- and nickel-containing coatings have been used to produce copper–diamond heat-conducting composites. Powder mixtures containing 50 vol % diamond with a particle size of 50, 100, or 200 μm have been consolidated by spark plasma sintering or hot pressing. It has been shown that the highest relative density (97%) and thermal conductivity (340 W/(m K)) are offered by the composites produced by spark plasma sintering using tungsten carbide-coated 50-μm diamond crystals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Crystal Growth and Structural Characterization of a Thiocyanato-Bridged Copper(I/II) Mixed-Valence Coordination Polymer

A new mixed-valence coordination polymer [Cu{sub 3}(SCN){sub 4}(DMSO){sub 2}]{sub n} (SCN{sup –} = thiocyanato and DMSO = dimethyl sulfoxide) was prepared and characterized by single crystal X-ray diffraction method. The in situ formation of thiocyanate during the synthesis induces reduction of a part of Cu(II) to Cu(I). The three-dimensional structure of the binuclear thiocyanato bridged compound provided an example of pseudohalide materials containing two different environments for both copper centers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

Neutron production in collisions between carbon nuclei of energy 2 GeV per nucleon and carbon, aluminum, copper, cadmium, and lead nuclei

Double-differential cross sections for neutron production were measured by the time-of-flight method for the interactions between carbon nuclei of energy 2 GeV per nucleon and carbon, aluminum, copper, cadmium, and lead nuclei. These measurements were performed for angles of 30 Degree-Sign , 53 Degree-Sign , and 90 Degree-Sign in the neutron-energy range fromseveral hundred keVunits to 300MeV. The phenomenologicalmodel of four moving sources was used as a basis in analyzing experimental results and in estimating the contribution to neutron emission from various reaction stages. The temperature parameters determined from the slope of the neutron energy spectra proved to be 22 {+-} 2 MeV for a hot source (fireball) and 4.5 {+-} 0.3 MeV for the stage of thermal fragmentation of highly excited heavy nuclear residues. The relative contribution of these two sources to the total neutron yield is independent of the type of the target nucleus and is about 42%, on average.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2015

Deposition of copper coatings in a magnetron with liquid target

Copper coatings were deposited on monocrystalline Si substrates using a magnetron discharge with a liquid cathode in the metal vapour plasma. During the deposition, the bias voltage in the range from 0 V to–400 V was applied to the substrate. The prepared films were investigated by a scanning electron microscope, and their adhesive properties were studied using a scratch tester. It was demonstrated that the adhesion of the deposited films strongly depends on the bias voltage and varies in a wide range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

First result of the experimental search for the 2K-capture of {sup 124}Xe with the copper proportional counter

First result of experiment for searching of 2K-capture of {sup 124}Xe with the large-volume copper proportional counter (LPC) is given. The 12 liters sample with 63.3% (44 g) of {sup 124}Xe was used in measurements. The limit on the half-life of {sup 124}Xe with regard to 2K(2ν)-capture for the ground state of {sup 124}Te (0{sup +} → 0{sup +}, g.s.) has been found: T{sub 1/2} ≥ 4.67 × 10{sup 20} yr (90% C.L.). A sample with volume 52 liters comprising of {sup 124}Xe (10.6L - 58.6 g) and {sup 126}Xe (14.1L - 79.3 g) will used at the next step of the experiment to increase a sensitivity of 2K-caption of {sup 124}Xe registration. In this case sensitivity to the investigated process will be at the level of S = 1.46 × 10{sup 21} yr (90% C.L.) for 1 year measurement.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

First result of the experimental search for the 9.4 keV solar axion reactions with {sup 83}Kr in the copper proportional counter

The experimental search for solar hadronic axions is started at the Baksan Neutrino Observatory of the Institute for Nuclear Researches of Russian Academy of Science (BNO INR RAS). It is assumed that axions are created in the Sun during M1 transition between the first thermally excited level at 9.4 keV and the ground state in {sup 83}Kr. The experiment is based on axion detection via resonant absorption process by the same nucleus in the detector. The big copper proportional counter filled with krypton is used to detect signals from axions. The experimental setup is situated in the deep underground low background laboratory. No evidence of axion detection were found after the 26.5 days data collection. Resulting new upper limit on axion mass is m{sub A} ≤ 130 eV at 95% C.L.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2017

Coherent production of the K{sup +}π{sup 0} system by K{sup +} mesons on copper nuclei in the OKA detector

In a sample of ∼5 × 10{sup 9} positive kaon collisions with copper nuclei, the events of coherent production of K{sup +}π{sup 0} pairs are selected, the contributions of the Coulomb and strong production mechanisms are discriminated, and the corresponding cross sections are determined. The phase shift difference between the Coulomb and strong amplitudes is obtained.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2012

Laser-induced desorption of atomic and molecular fragments from a tin dioxide surface modified by a thin organic covering of copper phthalocyanine

The systematic features of laser-induced desorption from an SnO{sub 2} surface exposed to 10-ns pulsed neodymium laser radiation are studied at the photon energy 2.34 eV, in the range of pulse energy densities 1 to 50 mJ/cm{sup 2}. As the threshold pulse energy 28 mJ/cm{sup 2} is achieved, molecular oxygen O{sub 2} is detected in the desorption mass spectra from the SnO{sub 2} surface; as the threshold pulse energy 42 mJ/cm{sup 2} is reached, tin Sn, and SnO and (SnO){sub 2} particle desorption is observed. The laser desorption mass spectra from the SnO{sub 2} surface coated with an organic copper phthalocyanine (CuPc) film 50 nm thick are measured. It is shown that laser irradiation causes the fragmentation of CuPc molecules and the desorption of molecular fragments in the laser pulse energy density range 6 to 10 mJ/cm{sup 2}. Along with the desorption of molecular fragments, a weak desorption signal of the substrate components O{sub 2}, Sn, SnO, and (SnO){sub 2} is observed in the same energy range. Desorption energy thresholds of substrate atomic components from the organic film surface are approximately five times lower than thresholds of their desorption from the atomically clean SnO{sub 2} surface, which indicates the diffusion of atomic components of the SnO{sub 2} substrate to the bulk of the deposited organic film.

36 MATERIALS SCIENCE↗
DOE OSTI2017

n-ZnO/p-CuI barrier heterostructure based on zinc-oxide nanoarrays formed by pulsed electrodeposition and SILAR copper-iodide films

A p-CuI/n-ZnO barrier structure is investigated as a promising base diode structure for a semitransparent near-ultraviolet detector. We analyze the crystal structure and electrical and optical properties of zinc-oxide nanoarrays electrodeposited in the pulsed mode and copper-iodide films formed by the successive ionic layer adsorption and reaction (SILAR) method, which were used as the basis for an n-ZnO/p-CuI barrier heterostructure sensitive to ultraviolet radiation in the spectral range of 365–370 nm. Using the I–V characteristics, a shunting resistance of R{sub sh} · S{sub c} = 879 Ω cm{sup 2}, a series resistance of R{sub s} · S{sub c} = 8.5 Ω cm{sup 2}, a diode rectification factor of K = 17.6, a rectifying p–n-junction barrier height of Φ = 1.1 eV, and a diode ideality factor of η = 2.4 are established. It is demonstrated that at low forward biases (0 V < {sup U} < 0.15 V), the effects of charge-carrier recombination and tunneling are equal. As the bias increases above 0.15 V, the tunneling–recombination transport mechanism starts working. The diode saturation current J{sub 0} is found to be 6.4 × 10{sup –6} mA cm{sup –2} for recombination and tunneling charge-carrier transport and 2.7 × 10{sup –3} mA cm{sup –2} for tunneling–recombination charge-carrier transport.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Temperature dependence of the atomic structure and electrical activity of defects in ZnSb thermoelectric lightly doped with copper

A model for describing the temperature dependence of the defect microstructure in high-efficiency ZnSb thermoelectric with a copper content of 0.1 at % is chosen. The temperature dependences of the chargecarrier density and mobility for thermal cycle I (300–700–300 K) are analyzed taking into account the features of the crystal structure and covalent chemical bond in ZnSb. The basic defect structure (at temperatures of T = 560–605 K) is the state when all Cu atoms are equally distributed between sites of both sublattices and behave as acceptors, and the number of intrinsic donor and acceptor defects is much smaller. The effect of the latter becomes noticeable when the temperature goes beyond the above-mentioned range. At T > 605 K, extra acceptors (antisite Zn{sub Sb}) occur; upon cooling below 560 K, Cu{sub 2} dimers arise and the electrical activity of the impurity lowers. Dimer decay upon heating leads to growth in the concentration with temperature up to saturation in the above-mentioned range. Additional thermal cycles II–VIII are performed; the observed changes in the temperature dependences of the hole concentration and mobility are discussed in the context of the investigated model.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Copper(I) Selenide Thin Films: Composition, Morphology, Structure, and Optical Properties

The systematized results of studies of the composition, morphology, structure, optical properties, and conductivity of hydrochemically deposited copper(I) selenide thin films (Cu{sub 1.8}Se) with the thickness of 390–400 nm are reported. The studies are carried out using scanning electron microscopy, energy-dispersive analysis, X-ray diffraction analysis, and X-ray photoelectron spectroscopy. The hole conductivity of the layers is established by the thermopower technique. The optical band gap determined from the results of studies of optical absorbance and diffuse reflection spectra of the films at 298 K is 2.5 and 1.84 eV for direct and indirect optical transitions, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Narrowband luminescence of copper in the presence of gold nanoparticles

Narrow bands were experimentally revealed in the spectrum of copper under a layer of gold nanoparticles. Luminescence was excited with a He–Ne laser (6328 Å). The spectra of films of individual metals contained no similar bands. Experimental conditions and recorded spectra were presented, and some possible explanations of the observed effect were discussed.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Effect of Carbon on the Electrical Properties of Copper Oxide-Based Bulk Composites

The effect of carbon filler on the electrical resistance and the thermopower of copper oxide-based composites produced by ceramic technology by hot pressing has been studied. It is found that the dependences of the electrical resistivity on the filler concentration are characteristic by S-like curves that are typical of percolation systems; in this case, the resistivity decreases more substantially as the carbon content increases as compared to the decrease in thermopower value, which is accompanied by the existence of the maximum of the factor of thermoelectric power near the percolation threshold. The studies of the temperature dependences of the resistivity and the thermopower at low temperatures show that, in the range 240–300 K, the predominant mechanism of the electrotransfer of all the composites under study is the hopping mechanism. At temperatures lower than 240 K, the composites with a nanocrystalline CuO matrix have a hopping conductivity with a variable hopping distance over localized states of the matrix near the Fermi level, which is related to the conductivity over intergrain CuO boundaries. A schematic model of the band structure of nanocrystalline CuO with carbon filler is proposed on the base of the analysis of the found experimental regularities of the electrotransfer.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Photoluminescence of Copper-Doped Lithium Niobate Crystals

The photoluminescence (PL) of copper-doped lithium niobate single crystals is studied using different UV–Vis light-emitting diodes and a pulse-periodic laser with a wavelength of 266 nm as excitation radiation sources. With the resonance excitation from a 527-nm light-emitting diode, the intensity of PL increases sharply (by two orders of magnitude). When using a 467-nm light-emitting diode for excitation, the PL spectrum is characterized by the presence of multiphonon lines in the range of 520–620 nm.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗