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At least 1,315 records · Page 73

Characterization of Al-Cu-Mg-Ag Alloy RX226-T8 Plate

Aluminum-copper-magnesium-silver (Al-Cu-Mg-Ag) alloys that were developed for thermal stability also offer attractive ambient temperature strength-toughness combinations, and therefore, can be considered for a broad range of airframe structural applications. The current study evaluated Al-Cu-Mg-Ag alloy RX226-T8 in plate gages and compared performance with sheet gage alloys of similar composition. Uniaxial tensile properties, plane strain initiation fracture toughness, and plane stress tearing resistance of RX226-T8 were examined at ambient temperature as a function of orientation and thickness location in the plate. Properties were measured near the surface and at the mid-plane of the plate. Tensile strengths were essentially isotropic, with variations in yield and ultimate tensile strengths of less than 2% as a function of orientation and through-thickness location. However, ductility varied by more than 15% with orientation. Fracture toughness was generally higher at the mid-plane and greater for the L-T orientation, although the differences were small near the surface of the plate. Metallurgical analysis indicated that the microstructure was primarily recrystallized with weak texture and was uniform through the plate with the exception of a fine-grained layer near the surface of the plate. Scanning electron microscope analysis revealed Al-Cu-Mg second phase particles which varied in composition and were primarily located on grain boundaries parallel to the rolling direction. Fractography of toughness specimens for both plate locations and orientations revealed that fracture occurred predominantly by transgranular microvoid coalescence. Introduction High-strength, low-density Al-Cu-Mg-Ag alloys were initially developed to replace conventional 2000 (Al-Cu-Mg) and 7000 (Al-Zn-Cu-Mg) series aluminum alloys for aircraft structural applications [1]. During the High Speed Civil Transport (HSCT) program, improvements in thermal stability were demonstrated for candidate aircraft wing and fuselage skin materials through the addition of silver to Al-Cu-Mg alloys based on Al 2519 chemistry [2]. Thermal stability of the resulting Al-Cu-Mg-Ag alloys, C415-T8 and C416-T8, was due to co-precipitation of the thermally stable . (AlCu) and ' (Al2Cu) strengthening phases [1-4]. The strength and toughness behavior was investigated for these alloys produced as 0.090-inch thick rolled sheet in the T8 condition and after various thermal exposures. The mechanical properties were shown to be competitive with conventional aircraft alloys, 2519-T8 and 2618-T8 [2]. During the Integral Airframe Structure (IAS) program, advanced aluminum alloys were examined for use in an integrally stiffened airframe structure where the skin and stiffeners would be machined from plate and extruded frames would be mechanically attached (see Figure 1) [5]. Advantages of integrally stiffened structure include reduced part count, and reduced assembly times compared to conventional built-up airframe structure. The near-surface properties of a thick plate are of significance for a machined integrally stiffened airframe structure since this represents the skin location. Properties measured at the mid-plane of the plate are more representative of the stiffener web. RX226 was developed to exploit strength-toughness improvements and thermal stability benefits of Al-Cu-Mg-Ag alloys in plate gages. This study evaluated the microstructure and properties of three gages of plate produced in the T8 condition.

Lach, Cynthia L.↗

Preliminary design of composite wings for buckling, strength and displacement constraints

An unstiffened panel buckling constraint for balanced, symmetric laminated composites is included on the global design level in a mathematical programming structural optimization procedure for designing wing structures. Constraints are introduced by penalty functions, and Newton's method based on approximate second derivatives of the penalty terms is used as the search algorithm to obtain minimum-mass designs. Constraint approximations used during the optimization process contribute to the computational efficiency of the procedure. A criterion is developed that identifies the appropriate conservative form of the constraint approximations that are used with the optimization procedure. Minimum-mass design results are obtained for a multispar high-aspect-ratio wing subjected to material strength, minimum-gage, displacement, panel buckling and twist constraints. The material systems considered for the examples are all graphite-epoxy, graphite-epoxy with boron-epoxy spar caps, and all aluminum. The composite material designs are shown to have an advantage over the aluminum designs since they can often satisfy additional constraints with only small mass increases.

Starnes, J. H., Jr.↗

The growth of metastable peritectic compounds

The effects of directional solidification processing on the microstructural, compositional, and magnetic properties of high-melting-temperature, commercially important alloys which form from the liquid state via peritectic or eutectic type reactions were determined. Emphasis was placed on ferromagnetic compounds of the commercially important Co-Sm and Al-Mn systems. The primary dendrite spacing for eutectic Sm2Co17/Co scaled with negative square root of V and varied from approximately 50 microns for V 20 cm/h to hundreds of microns for V 10 cm/h. Since the crystal growth mechanism was dendritic rather than cooperative, the assoicated permanent magnet properties were rather poor. Magnetization as a function of sample orientation indicates that the easy axis of magnetization was primarily along the direction of solidification for the eutectic Sm2Co17/Co and peritectic SmCo5/Sm2Co17 compositions. For the Al-Mn case, magnetization and microstructural characterization suggest isotropic, polycrystalling growth for all solidification velocities studied.

Pirich, R. G.↗

Early detection of fatigue damage in composite materials

Early detection of fatigue damage in composite materials by nondestructive inspection (NDI) techniques has been demonstrated for glass/epoxy, graphite/glass/epoxy, and graphite/epoxy composites. Modulus and temperature were monitored and a correlation between them observed. Axial modulus and torsional modulus changes were a function of the laminate orientation. Torsional modulus measurements and coin tap tests were performed at 0, 1 million, 5 million, and 10 million cycles, on axial fatigue specimens. Three distinct regions were noted. In the primary region a small but rapid change in stiffness was noted in the first few thousand cycles. This was followed by a secondary region of little or no stiffness change. The tertiary region was characterized by an increasing rate of stiffness change leading to fracture. NDI procedures including holographic interferometry, ultrasonics, penetrant, and X-ray radiography were evaluated for fatigue damage detection.

Salkind, M. J.↗

Proton-tissue dose buildup factors

When an object is exposed to external radiation, the dose field within the object is a complicated function of the character of the external radiation, the shape of the object (including orientation), and the object's material composition. In this note, the dose conversion factors for protons in tissue are represented using buildup factors. A parametric form for the buildup factors is obtained. The values of the parameters are derived from Monte Carlo calculations of various authors. All the necessary information to estimate nuclear reaction effects in proton irration of convex objects of arbitrary shape is included.

Wilson, J. W.↗

Temperature, density, and composition in the disturbed thermosphere from Esro 4 gas analyzer measurements - A global model

An analysis of density measurements of Ar, N2, O, and He made at 280 km with the gas analyzer aboard the polar-orbiting satellite Esro 4 has yielded a global model of the variations in temperature, density, and composition that occur in the disturbed thermosphere. In the model the increase of temperature over quiet conditions is a nonlinear function of the planetary geomagnetic index, its latitude profile being approximated by a fourth-power sin phi law, where phi is the 'invariant' magnetic latitude. A density wave proceeding from high latitudes is approximated by a fourth power cos phi law. A strong nonlinearity in the relation between the temperature variations and the variations in the height of the homopause explains a previously found behavioral difference in the variation of atomic oxygen during magnetic storms and during periods of sustained geomagnetic activity.

Jacchia, L. G.↗

Measurement of the time-temperature dependent dynamic mechanical properties of boron/aluminum composites

A flexural vibration test and associated equipment were developed to accurately measure the low strain dynamic modulus and damping of composite materials from -200 C to over 500 C. The basic test method involves the forced vibration of composite bars at their resonant free-free flexural modes in a high vacuum cryostat furnace. The accuracy of these expressions and the flexural test was verified by dynamic moduli and damping capacity measurements on 50 fiber volume percent boron/aluminum (B/Al) composites vibrating near 2000 Hz. The phase results were summarized to permit predictions of the B/Al dynamic behavior as a function of frequency, temperature, and fiber volume fraction.

Dicarlo, J. A.↗

The N-BOD2 user's and programmer's manual

A general purpose digital computer program was developed and designed to aid in the analysis of spacecraft attitude dynamics. The program provides the analyst with the capability of automatically deriving and numerically solving the equations of motion of any system that can be modeled as a topological tree of coupled rigid bodies, flexible bodies, point masses, and symmetrical momentum wheels. Two modes of output are available. The composite system equations of motion may be outputted on a line printer in a symbolic form that may be easily translated into common vector-dyadic notation, or the composite system equations of motion may be solved numerically and any desirable set of system state variables outputted as a function of time.

Frisch, H. P.↗

An interactive modular design for computerized photometry in spectrochemical analysis

A general functional description of totally automatic photometry of emission spectra is not available for an operating environment in which the sample compositions and analysis procedures are low-volume and non-routine. The advantages of using an interactive approach to computer control in such an operating environment are demonstrated. This approach includes modular subroutines selected at multiple-option, menu-style decision points. This style of programming is used to trace elemental determinations, including the automated reading of spectrographic plates produced by a 3.4 m Ebert mount spectrograph using a dc-arc in an argon atmosphere. The simplified control logic and modular subroutine approach facilitates innovative research and program development, yet is easily adapted to routine tasks. Operator confidence and control are increased by the built-in options including degree of automation, amount of intermediate data printed out, amount of user prompting, and multidirectional decision points.

Bair, V. L.↗

Fatigue delamination behavior of PEEK thermoplastic composite laminates

The delamination resistance of graphite-reinforced PEEK composites was quantified by conducting static and cyclic edge delamination tests on (35n/-35n/0n/90n)s AS4/PEEK laminates, where n = 1, 2. The experimentally determined mechanical delamination onset strains were used to calculate the critical strain-energy release rate for delamination onset as a function of fatigue cycle. The delamination onset strains decreased dramatically with fatigue cycles and then began to level off to an endurance limit at 1 million cycles. Although the static interlaminar fracture toughness of the AS4/PEEK composite is much greater than the toughness of graphite epoxy composites, the delamination fatigue threshold, calculated from the cyclic strain endurance limit at 1 million cycles, was only slightly greater than the threshold for graphite epoxy composites. The contribution of residual thermal stresses to delamination in the AS4/PEEK is substantial due to the large temperature range between the manufacture and the room temperatures.

O'Brien, T. K.↗

Coherent structures in a baroclinic atmosphere. IV - A comparison between theory and data

This paper presents the results of a data analysis, on an extensive series of Atlantic blocks, for the composites of both the positive and the negative anomaly cases and for the winter climatology, using the composite approach of Dole (1982, 1986). The results are compared with predictions of the theory formulated by Malguzzi and Malanotte-Rizzoli (1984, 1985) and Malanotte-Rizzoli and Malguzzi (1987) to model the blocking events. The results of the analyses indicate that the composite of the positive anomaly cases shows a strong northern barrier centered in the latitude band 62-72 deg N, in agreement with the northern confinement of the block. The northern, positive wall is not present in the climatology; its presence and significance are doubtful and debatable for the negative anomaly composite. For the individual positive cases for which a smooth and zonal upstream wind could be defined, the V-function shows the appearance of both a northern and southern wall below the tropopause.

Malanotte-Rizzoli, Paola↗

Modeling of carbon monoxide oxidation kinetics over NASA carbon dioxide laser catalysts

The recombination of CO and O2 formed by the dissociation of CO2 in a sealed CO2 laser discharge zone is examined. Conventional base-metal-oxide catalysts and conventional noble-metal catalysts are not effective in recombining the low O2/CO ratio at the low temperatures used by the lasers. The use of Pt/SnO2 as the noble-metal reducible-oxide (NMRO), or other related materials from Group VIIIA and IB and SnO2 interact synergistically to produce a catalytic activity that is substantially higher than either componet separately. The Pt/SnO2 and Pd/SnO2 were reported to have significant reaction rates at temperatures as low as -27 C, conditions under which conventional catalysts are inactive. The gas temperature range of lasers is 0 + or - 40 C. There are three general ways in which the NMRO composite materials can interact synergistically: one component altering the properties of another component; the two components each providing independent catalytic functions in a complex reaction mechanism; and the formation of catalytic sites through the combination of two components at the atomic level. All three of these interactions may be important in low temperature CO oxidation over NMRO catalysts. The effect of the noble metal on the oxide is discussed first, followed by the effect of the oxide on the noble metal, the interaction of the noble metal and oxide to form catalytic sites, and the possible ways in which the CO oxidation reaction is catalyzed by the NMRO materials.

Herz, Richard K.↗

Recent advances in carbon-carbon substrate technology at NASA. Langley Research Center

A comparison of specific strengths of candidate high-temperature materials as a function of temperature is shown. From this comparison, it is apparent why there is an interest in carbon-carbon composites for applications as a strong, light-weight thermal protection system (TPS), or as hot structure, for applications above 2500 F. The lower bound of the carbon-carbon band is representative of the tensile strength of cross-ply Advanced Carbon-Carbon (ACC). The upper bound represents capabilities of various experimental carbon-carbon composites. Thin carbon-carbon composites, such as would be used as TPS panels or hot aero-structure, are usually constructed of layups of 2-D fabrics of carbon-fiber yarns (tows). Although the in-plane strengths of these composites can be very attractive, a major problem area is low interlaminar strength. The low interlaminar strength is the result of a relatively weak carbon matrix and poor interaction between the fibers and matrix. The purpose of this paper is to discuss strategies being employed to improve the interlaminar strengths of the materials at the upper bound of the carbon-carbon band, and to present some recent encouraging results. The emphasis of these strategies is to improve interlaminar shear and tensile strengths while maintaining, or even improving, the inplane properties.

Ransone, Philip O.↗

A normal stress subgrid-scale eddy viscosity model in large eddy simulation

The Smagorinsky subgrid-scale eddy viscosity model (SGS-EVM) is commonly used in large eddy simulations (LES) to represent the effects of the unresolved scales on the resolved scales. This model is known to be limited because its constant must be optimized in different flows, and it must be modified with a damping function to account for near-wall effects. The recent dynamic model is designed to overcome these limitations but is compositionally intensive as compared to the traditional SGS-EVM. In a recent study using direct numerical simulation data, Horiuti has shown that these drawbacks are due mainly to the use of an improper velocity scale in the SGS-EVM. He also proposed the use of the subgrid-scale normal stress as a new velocity scale that was inspired by a high-order anisotropic representation model. The testing of Horiuti, however, was conducted using DNS data from a low Reynolds number channel flow simulation. It was felt that further testing at higher Reynolds numbers and also using different flows (other than wall-bounded shear flows) were necessary steps needed to establish the validity of the new model. This is the primary motivation of the present study. The objective is to test the new model using DNS databases of high Reynolds number channel and fully developed turbulent mixing layer flows. The use of both channel (wall-bounded) and mixing layer flows is important for the development of accurate LES models because these two flows encompass many characteristic features of complex turbulent flows.

Horiuti, K.↗

A study of metal-ceramic wettability in SiC-Al using dynamic melt infiltration of SiC

Pressure-assisted infiltration with a 2014 Al alloy of plain and Cu-coated single crystal platelets of alpha silicon carbide was used to study particulate wettability under dynamic conditions relevant to pressure casting of metal-matrix composites. The total penetration length of infiltrant metal in porous compacts was measured at the conclusion of solidification as a function of pressure, infiltration time, and SiC size for both plain and Cu-coated SiC. The experimental data were analyzed to obtain a threshold pressure for the effect of melt intrusion through SiC compacts. The threshold pressure was taken either directly as a measure of wettability or converted to an effective wetting angle using the Young-Laplace capillary equation. Cu coating resulted in partial but beneficial improvements in wettability as a result of its dissolution in the melt, compared to uncoated SiC.

Asthana, R.↗

Towards and FVE-FAC Method for Determining Thermocapillary Effects on Weld Pool Shape

Several practical materials processes, e.g., welding, float-zone purification, and Czochralski crystal growth, involve a pool of molten metal with a free surface, with strong temperature gradients along the surface. In some cases, the resulting thermocapillary flow is vigorous enough to convect heat toward the edges of the pool, increasing the driving force in a sort of positive feedback. In this work we examine this mechanism and its effect on the solid-liquid interface through a model problem: a half space of pure substance with concentrated axisymmetric surface heating, where surface tension is strong enough to keep the liquid free surface flat. The numerical method proposed for this problem utilizes a finite volume element (FVE) discretization in cylindrical coordinates. Because of the axisymmetric nature of the model problem, the control volumes used are torroidal prisms, formed by taking a polygonal cross-section in the (r, z) plane and sweeping it completely around the z-axis. Conservation of energy (in the solid), and conservation of energy, momentum, and mass (in the liquid) are enforced globally by integrating these quantities and enforcing conservation over each control volume. Judicious application of the Divergence Theorem and Stokes' Theorem, combined with a Crank-Nicolson time-stepping scheme leads to an implicit algebraic system to be solved at each time step. It is known that near the boundary of the pool, that is, near the solid-liquid interface, the full conduction-convection solution will require extremely fine length scales to resolve the physical behavior of the system. Furthermore, this boundary moves as a function of time. Accordingly, we develop the foundation of an adaptive refinement scheme based on the principles of Fast Adaptive Composite Grid methods (FAC). Implementation of the method and numerical results will appear in a later report.

Canright, David↗

X-ray Photoelectron Spectroscopy Study of Argon-Plasma-Treated Fluoropolymers

Films of poly(tetrafluoroethylene) (PTFE) and of a tetrafluoroethylene-perfluoroalkyl vinyl ether (approximately 49:1) copolymer (PFA) were exposed to a radio-frequency argon plasma and then examined by X-ray photoelectron spectroscopy (XPS). The use of fluoropolymer films nearly free of surface hydrocarbon contamination as well as the use of a monochromatized X-ray source for XPS removed two factors contributing to conflicting reports on the effect of exposure time on the fluorine-to-carbon (F/C) and oxygen-to-carbon (O/C) ratios for several Ar-plasma-treated fluoropolymers. Contrary to literature indications, a common pattern was found for PTFE and PFA: a moderate decrease in F/C ratio (from 1.99 to 1.40, and from 1.97 to 1.57, respectively), together with a moderate increase in O/C ratio (from negligible to about 0.10, and from 0.012 to about O.10, respectively) at very short exposures, after which the F/C ratios remained essentially constant on prolonged exposures, while the O/C ratios for PTFE and PFA leveled off at 0.11 and 0.15, respectively. The XPS C(sub 1s), spectra for these polymers exposed to the Ar plasma for 20 min were similar and presented, besides a prominent peak at 292.0 eV (CF2,) and a minor peak at 294.0 or 294.1 eV (CF3), a composite band of four curve-resolved peaks (approximately 285-290 eV) representing various CH, CC, CO, CN, and CF functionalities.

Golub, Morton A.↗

Thermal Infrared Spectroscopy from Mars Landers and Rovers: A New Angle on Remote Sensing

The MINUTES instrument of the Athena Precursor Experiment (APEX) on the Mars Surveyor 2001 lander mission will perform the first thermal infrared remote sensing observations from the surface of another planet. Experience gained from this experiment will be used to guide observations from identical instruments mounted on the Athena rovers, to be launched in 2003 and 2005. The utility of infrared spectrometers in determining the mineralogic composition of geologic surfaces from airborne and spaceborne platforms has been amply demonstrated. However, relatively little experience exists in using functionally similar instruments on the ground in the context of planetary science. What work has been done on this problem has mostly utilized field spectrometers that are designed to look down on nearby target rocks. While many Mini-TES observations will be made with this type of geometry, it is likely that other observations will be made looking horizontally at the more vertically-oriented facets of rock targets, to avoid spectral contamination from dust mantles. On rover missions, the Mini-TES may also be pointed horizontally at rocks several meters away, to determine if they are worthy of approaching for in situ observations and possible sample cacheing. While these observations will undoubtedly prove useful, there are important, and perhaps unappreciated, differences between horizontal-viewing, surface-based spectroscopy and the more traditional nadir-viewing, orbit or aircraft-based observations. Plans also exist to step the Mini-TES in a rastering motion to build hyperspectral scenes. Horizontal viewing hyperspectral cubes also possess unique qualities that call for innovative analysis techniques. The effect of viewing geometry: In thermal emission spectroscopy, regardless of whether an instrument is looking down on or horizontally at a target, the same basic equation governs the radiance reaching the sensor .

Moersch, J.↗