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At least 1,315 records · Page 73

Mercury Speciation via Diffusive Gradients Thin-Films Technology

Objectives: Develop and test various diffusive gradient in thin films (DGT) samplers for mercury - SRNL is developing reactive DGTS (rDGTs). Test chemistry to differentiate methylmercury from total and/or inorganic mercury in environmental samples. Fabricate and test rDGT samplers for deployment. Deploy the rDGTs in variable settings. Mercury is a persistent-bioaccumulative-toxic environmental pollutant. Mercury exists in different species such as elemental, inorganic, and methyl. Mercury speciation determine mercury behavior and toxicity. For example, methylmercury strongly accumulates in biota such as fish resulting in potential human health impacts. DGTs are innovative samplers to measure water concentration by diffusion and capture. Types of Hg DGTs used: Total Hg, Inorganic Hg, and Methyl Hg. Deployment Sites: Upper Three Runs, Lower Three Runs, Steele Creek, East Fork Poplar Creek (SRNL Sites), Horizons Creek, NOA Creek, Bruners Creek (ORNL Sites). DGT concentration estimates closely matched alternative measurements for soluble mercury at each Oak Ridge site - DGTs did not respond to particulate mercury. DGTs provide a representative measure for biota uptake since they are left out longer which allows for an average exposure concentration. DMA-80 provided an efficient and quick analysis. Variability in site location made a difference in Hg species. DGT preparations and sampling wasn't as quick and simple as microcolumn technology. Copper reagent degraded agarose gel - more work and cleaner data are needed to assess speciation in rDGTs. Future Work: Use cross-linked polyacrylamide for the collection layer for a stronger plastic. Make a copper diffusion layer without agarose. Test copper separation in lab using realistic stream conditions such as high organic carbon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

2D Dam-Break Analysis of L Lake and PAR Pond Dams Using HEC-RAS

In 1991 a dam-break study was conducted for the high hazard dams located at L Lake and PAR Pond on the Savannah River Site. Two scenarios were considered, over topping from a Probable Maximum Flood (PMF), and a fair weather dam-break for either or both dams. Unfortunately, no inundation map was developed from the study. The purpose of this project was to redo the original dam-break study with improved data and methodology to generate Inundation maps to assist with emergency response and evacuation plans. The Hydrologic Engineering Center's River Analysis System (HEC-RAS) is a free to download river analysis modeling program developed by the US Army Corps of Engineers capable of 1D and 2D hydraulic calculations. Version 5.0.7 (released March 2019) was used for this project. Digital elevation models for the area were retrieved from the US Geological Survey database and converted to a .hdf file within the program. Then the 2D flood area was identified from the contours. Both L Lake and PAR Pond were inputted as 1D storage areas because DEM data does not contain elevation values under water bodies. An elevation vs volume curve was available for both storage areas. Initial elevations were set for both scenarios. Both dams are earthen dams. The Steel Creek dam at L Lake has 6 ft diameter conduit with an upper and lower sluice gate. PAR pond dam consist of a weir and sluice gate connected to an 8 x 8 ft channel. Both outlets were modeled with a pool elevation vs discharge curve. The steel creek dam sluice gates were assumed to be fully open in all cases. As in the previous study, the dams were set to breach when they were overtopped by 1.5 ft during PMF conditions (Figure 1). A fair weather breach was set to be due to a piping failure (Figure 1). In the dual dam break during fair weather conditions the PAR pond dam fails 3 hours after Steel Creek to achieve maximum flooding in the down stream reaches. Simulation was run 3 days for each case and with a 1 minute computational interval. Maximum flooding occurs under PMF conditions with the failure of both dams. PAR pond dam fails first 16 hours and 32 minutes after the start of the simulation with the Steel creek dam failing 6 minutes later. In all cases, the bridges and roads spanning Steel Creek and Lower Three Runs will be inundated and potentially washed away. The Burtons Ferry Highway south of the storage areas will be partially flooded during PMF failure, dual fair weather failure, and PAR pond failure under fair weather conditions.

54 ENVIRONMENTAL SCIENCES↗

Filter 'Cook-Off': Filter Selection via Side-by-Side Testing at Actual Process Conditions - 20040

In 2005, the THOR steam reforming fluidized-bed reactor technology was selected by the U.S. Department of Energy for treatment of sodium-bearing waste at the INL. During the final phase of commissioning prior to radiological operations, regeneration of the high temperature filters in the process gas filter (PGF) vessel became ineffective. After approximately 50 days of testing, the differential pressure across the filters began increasing exponentially and the plant had to be shutdown. Subsequent investigation revealed that the Inconel 625 (I625) sintered metal filter media was corroding in the 550 deg. C reducing environment. A pilot plant run tested four candidate replacement filter media. The top candidate was further tested during a long-term pilot plant run to validate the selection. Data from the testing indicate the selected filters will provide reliable service throughout the life of the project, including after in-situ radiological decontamination. This paper presents the data from this effort and reinforces the value of pilot plant testing. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Utilizing Commercial Submersible Mixer Pumps for Sludge Removal in Savannah River Site's Tank 26 - 20289

The Savannah River Site (SRS) Liquid Waste System (LWS) safely manages, stores, treats, and dispositions liquid radioactive waste. The LWS consists of 51 underground waste storage tanks (eight of which are operationally closed and filled with grout), waste evaporators, treatment facilities, and solidification facilities, known as the Defense Waste Processing Facility (DWPF) and Saltstone Production Facility (SPF). One of the waste storage tanks, Tank 26, was placed into service in 1980 as an F Tank Farm (FTF) Evaporator Feed Tank. From 1980 to 2013, Tank 26 received F Canyon receipts and dilute supernate that was then transferred to the 242-16F FTF Evaporator for volume reduction. In 2013, the steam tube bundle failed in the FTF Evaporator, and the decision was made not to repair/resume evaporator operation. During operation of Tank 26, solids built up to a level of 2.03 m in the tank with a volume of 1062.9 kL. Due to the evaporator failure and subsequent shutdown, the solids in Tank 26 were selected to feed Sludge Batch 10, which is collected and prepped prior to being sent to DWPF for final disposition. To accomplish solids removal, Commercial Submersible Mixer Pumps (CSMPs) were selected to slurry the solids in preparation to be sent to Tank 51. Four CSMPs were installed in Tank 26 with each one installed in a separate quadrant of Tank 26. This work would mark the first deployment of CSMPs in an SRS waste tank. The CSMPs were developed in response to operational issues from previous mixing pumps and budgetary constraints. The CSMPs use the concept of modifying commercially available equipment for nuclear waste applications. The CSMPs consist of a 230-horsepower submersible mixing pump (manufactured by GPM, Inc.) joined to a mast fabricated at SRS. For this application, Savannah River Remediation (SRR) design services was challenged to provide a mast design that required no steel superstructure support system on top of Tank 26. Also, SRR design services provided a simplified Tank 26 riser interface that did not require extensive machine parts to adjust height of the suction screen of the CSMP within the tank. Other design improvements include no requirements for tank top radiation monitors and no requirements for flushing of the CSMPs during startup/shutdown operations. The CSMPs were operated at an initial height of 2.29 m above the Tank 26 bottom for 10 days. After sludge sounding, the CSMPs were lowered to a height of 1.52 m with no issues due to proper work planning and the simplified riser interface. With the CSMPs lowered to a level of 1.52 meters above the tank bottom, the CSMPs were operated for 12 days and another sounding was performed. The sounding level came back matching the disturbance depth results of the first pump run. Chemistry samples were analyzed while the tank was left to settle. The analysis revealed enough weight percent solids to provide good feed to Sludge Batch 10. Also, the results revealed the supernate within the mixture would provide good salt solution feed to Salt Waste Processing Facility (SWPF) Salt Batch 3. So, the plan was modified to let the disturbed solids settle and decant the salt solution for addition to SWPF Salt Batch 3. Then water will be added back to Tank 26, and the CSMPs run in order to wash the solids to decrease settling time prior to being sent to Tank 51 for Sludge Batch 10. Utilizing CSMPs for waste removal in an SRS Tank has provided a cost-effective means for further waste removal efforts. In addition, the CSMPs are easier to operate by utilizing a robust and simplified design. The CSMPs performed quite well with no process shutdown or delays during operation. As a result, CSMPs are integral to the future of removing radioactive waste from storage tanks at SRS. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Probabilistic Groundwater Modeling of the RDX Plume at Los Alamos National Laboratory to Support Risk Assessment - 20359

A plume of the contaminant hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) with concentrations greater than the New Mexico tap water drinking standard (9.66 ppb) is present in the regional aquifer near the southwestern boundary of Los Alamos National Laboratory (LANL). A risk assessment is performed for exposure to regional aquifer groundwater, with long-term predictions of RDX concentrations provided by a calibrated, probabilistic, numerical fate and transport model. The structure of the model is hierarchical, with the RDX Regional Aquifer (RA) groundwater model acting as the primary tool for analysis of downgradient RDX concentrations. The RA model is deeply informed by the conceptual site model (CSM) and is calibrated using site RDX concentration data and hydraulic head measurements, along with other analyses. The model is calibrated using data through December 2019. Where data are scarce other lines of evidence are used to inform inputs, including the multiphase RDX Vadose Zone (VZ) model and Pipe and Disk analytical screening tool. Model inputs are described with informative prior distributions using a robust approach to development that incorporates all available lines of evidence for every parameter used as an input to the RA model. Calibration is performed using a classical nonlinear optimization routine, which is then used to initialize a Bayesian calibration. The Bayesian calibration constrains the uncertainty in the classical calibration, ultimately providing posterior distributions for all model parameters. The challenges of the calibration include high-dimensional parameter space, including spatially heterogeneous hydraulic conductivities, comparatively sparse data, and low RDX concentrations. Posterior parameter distributions developed in the calibration process are then used for stochastic predictive model runs into the future. The result of the forward runs is spatially and temporally explicit estimates of head and concentration with uncertainty at all points in space and time. The probabilistic modeling approach presented here includes innovative computational and statistical methods that leverage high-performance computing (HPC) resources. It makes use of prior modeling work performed at the chromium plume site in the central LANL area, with extensive updates. The risk assessment will ultimately be used to support decision-making at the site, using multiple appropriately weighted sources of information, as well as uncertainty, sensitivity, and value-of-information analyses. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Native Natural circulation in VERA

This work seeks to introduce a native natural circulation solver to VERA's thermohydraulics capabilities. This work begins with initial investigations into the viability of such a solver by determining the fundamental equations as well as necessary inputs. The method was then implemented in the form of a Python script coupled to CTF which was compared to TRACE. Once viability of the natural circulation solver was established, it was then implemented natively in MPACT for use with previously created simplified thermohydraulics solvers. This new implementation of the native natural circulation solver in MPACT is then tested for single physics problems for both a BWR and PWR single channel model and compared to TRACE where it shows an error of about 30% for BWRs and about 15% for PWRs. The solver is additionally tested for NuScale based models where it demonstrates an error to the reported flow rate of about 10%, resulting in an eigenvalue error of only 138 pcm when comparing fixed flow rate multiphysics runs. Finally, the solver is tested in multiphysics systems for a small PWR assembly, a small BWR assembly, and a full core approximate model of the NuScale design. In these multiphysics runs, it demonstrates no impact on multiphysics convergence stability, as well as negligible impact on runtimes. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Microwave-Assisted Co-Gasification of Mixed Plastics and Corn Stover to Produce Clean Hydrogen Using Fe-Based Catalyst

Microwave-assisted gasification is an energy-efficient alternative to conventional gasification in which known feedstocks can be converted into syngas, char, and other byproducts to produce clean hydrogen at lower temperatures (~550 °C) through selective heating. Fe oxides are well-known gasification catalysts that can reduce in-situ to activate the methyl radicals by supplying surface oxygen and promoting H2 formation. This study introduces Fe2O3 as a microwave-active catalyst to enhance H2 production and tar reduction for plastic-corn stover co-gasification. The results found that the microwave reaction at 800 °C produced 24 times more mmol of hydrogen per kWh energy as compared to the conventional run at 900 °C. The X-ray diffraction results show the presence of Fe3O4 and FeO peaks indicating reduction of Fe2O3 to help devolatize reaction intermediates; while the appearance of metallic Fe in the microwave run at 800 °C indicates that Fe2O3 achieves full reduction at the microwave gasification temperature yielding maximum hydrogen production.

Abedin, Ashraf↗

The precision measurement of the muon $g-2$ at Fermilab

The Muon $g-2$ Experiment at Fermilab aims to measure the magnetic anomaly of the muon with the unprecedented precision of 140 parts per billion. In April 2021, the collaboration published the first measurement based on the first year of data collection, which was found to be consistent with the previous experiment at Brookhaven. The new global average of the experimental measurements strengthens the long-standing tension with the data-driven Standard Model prediction to a combined discrepancy of 4.2$\sigma$. On the theory side, however, recent improvements in the theoretical calculation of the hadronic contribution based on Lattice-QCD techniques are introducing new tensions on the value predicted by the theory. The Muon $g-2$ Experiment at Fermilab has now concluded its sixth and final year of data taking and a new result based on the Run-2 and Run-3 data was published in August 2023. This paper briefly describes the precision measurement conducted by the Muon $g-2$ Experiment at Fermilab and its current status.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The Construction of the sPHENIX Detector and Status of Its Commissioning

sPHENIX is the first new major detector at RHIC in over twenty years. It is designed for pioneering studies of the Quark Gluon Plasma and Cold QCD phenomena using high-pT jet and heavy flavor probes with a broad kinematic reach and a capability to take large statistics sets of A+A, p+p and p+A data. sPHENIX construction was completed in April 2023. It was commissioned and took first Au+Au data in the RHIC 2023 Run. This paper describes the details of the detector design, challenges of sPHENIX construction, progress on the commissioning and first data from the RHIC 2023 run.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Performance Versus Maintainability: A Case Study of Scream on Frontier

The Simple Cloud-Resolving E3SM Atmosphere Model (Scream) won the inaugural ACM Gordon Bell Prize for Climate Modeling. While most of Scream is portable Kokkos code, the Gordon-Bell runs did include tuning specifically for Frontier, the exascale computer at Oak Ridge National Laboratory. Production science runs use the same high-level configuration of Scream, but the tuned kernels do not meet the software standards necessary to merge into the production code base. This work describes experiments to refactor these kernels to meet the maintainability requirements of the production Scream code base while preserving high performance.

White, Trey↗

Characterization of Non-Science Grade DESI CCDs and Creating Additional ICARUS Monitoring Metrics for Data Quality

DESI, otherwise known as the Dark Energy Spectroscopic Instrument, is an astronomical project measuring millions of optical spectra to characterize Dark Energy. The survey has been running for 3 years. My work delves into the data taking/analysis side of the DESI CCDs (Charge-Coupled Devices) which will help in swapping out broken CCDs on the instrument. Additionally, I worked on making new metrics for ICARUS, Imaging Cosmic and Rare Underground Signals for their monitoring of run data. This paper will talk about the types of characterizations done for DESI and additional metrics for data quality and tools used for ICARUS monitoring.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

An Accelerated Clip Algorithm for Unstructured Meshes: A Batch-Driven Approach

The clip technique is a popular method for visualizing complex structures and phenomena within 3D unstructured meshes. Meshes can be clipped by specifying a scalar isovalue to produce an output unstructured mesh with its external surface as the isovalue. Similar to isocontouring, the clipping process relies on scalar data associated with the mesh points, including scalar data generated by implicit functions such as planes, boxes, and spheres, which facilitates the visualization of results interior to the grid. In this paper, we introduce a novel batch-driven parallel algorithm based on a sequential clip algorithm designed for high-quality results in partial volume extraction. Our algorithm comprises five passes, each progressively processing data to generate the resulting clipped unstructured mesh. The novelty lies in the use of fixed-size batches of points and cells, which enable rapid workload trimming and parallel processing, leading to a significantly improved memory footprint and run-time performance compared to the original version. On a 32-core CPU, the proposed batch-driven parallel algorithm demonstrates a run-time speed-up of up to 32.6x and a memory footprint reduction of up to 4.37x compared to the existing sequential algorithm. The software is currently available under an open-source license in the VTK visualization system.

Tsalikis, Spiros↗

Identification of Climatological Representative Days in the Mid-Atlantic for High-Fidelity Offshore Wind Energy Modeling

The goal of reaching 30 GW of offshore wind energy by 2030 becomes more realistic with the continued approval of offshore wind energy areas by the Biden Administration. In the Mid-Atlantic, where wind energy projects are in the most advanced stages of development, there is increased research focus on the eventual interaction of these wind farms. These interactions, in the form of wakes and cluster wakes, or wakes from multiple wind farms, could have detrimental effects on power production and forecastability for downwind wind farms (Pryor et al. 2022, Golbazi et al. 2022, Rosencrans et al. 2023). To help alleviate these issues, numerical simulations in the form of numerical weather prediction (NWP) and large eddy simulations (LES) can provide insight into when cluster wake situations may occur, but running such simulations can be expensive and difficult to run for multiple years. In this study, we leverage and build upon existing techniques in the literature (Fischereit et al. 2022) to identify climatologically representative days for wind energy areas in the Mid-Atlantic where conditions would promote cluster wake situations. We select meteorological variables (wind speed, wind direction, atmospheric stability, boundary-layer height, TKE) critical to understanding wind energy production and wake propagation. We then consider two different NWP datasets of varying spatial and temporal resolution: ERA5 provides data at hourly intervals from 1940 to present at 0.25 deg (31 km) spatial resolution (Hersbach et al. 2020), and the NOW-23 dataset provides data at 5-minute resolution for 21 years at 2-km spatial resolution (Bodini et al. 2020). Our first step is to compare these two datasets for an overlapping 21-year time period. Initial results show that the required number of days to represent the long-term climate increases with each additional variable considered. In their study of the German Bight, Fischereit et al. (2022) found that they could represent the long-term wind and wave climate in a "near-perfect" way with -180 days, by reaching a Perkins Skill Score (PSS) of 0.9; our investigation of the mid-Atlantic wind resource region with ERA5 and NOW-23 data suggests that we will need -100 days to reach a PSS of 0.9. As we expand our parameter space to include multiple variables, the number of required days will likely grow. These results will ultimately be used to select case studies to best represent cluster wake conditions that apply to this region for the lifetime of likely wind farms in this mid-Atlantic region.

clusterwakes↗

Search For Low-Mass Quark-Antiquark Resonances Produced With an Initial State Photon at 13 TeV Using the CMS Detector

We present a search for low-mass narrow qq̅ resonances. This search uses data from LHC pp collisions at a center of mass of 13 TeV in Run 2, and corresponds to an integrated luminosity of 137 fb^{-1}, currently using 10\% of data. Utilizing full Run 2 data allows the use of a lower photon pT threshold trigger than a previous analysis performed with only 2016 data, allowing this analysis to be more sensitive to resonances in the low mass region. We require an initial state photon recoiling against the narrow resonance, leading to the resonance having a high transverse momentum. The high pT decay products of the resonance collimate and are reconstructed as a single large jet with an internal two-pronged substructure. A two-pronged dijet score based on the ParticleNet tagger is used to select jets with two-pronged substructure. The background is estimated via a data-driven method using a transfer factor between the distributions which fail and pass the two-pronged substructure requirement. The new physics signal is searched for as a narrow peak excess above the Standard Model backgrounds in the jet mass spectrum.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Architectural Implications of Neural Network Inference for High Data-Rate, Low-Latency Scientific Applications

With more scientific fields relying on neural networks (NNs) to process data incoming at extreme throughputs and latencies, it is crucial to develop NNs with all their parameters stored on-chip. In many of these applications, there is not enough time to go off-chip and retrieve weights. Even more so, off-chip memory such as DRAM does not have the bandwidth required to process these NNs as fast as the data is being produced (e.g., every 25 ns). As such, these extreme latency and bandwidth requirements have architectural implications for the hardware intended to run these NNs: 1) all NN parameters must fit on-chip, and 2) codesigning custom/reconfigurable logic is often required to meet these latency and bandwidth constraints. In our work, we show that many scientific NN applications must run fully on chip, in the extreme case requiring a custom chip to meet such stringent constraints.

Weng, Olivia↗

Warrick Conductivity Level Controllers Series 3H

This is my internship poster. In the poster I talk about the level controllers that I wired together and installed to support electrolysis testing systems in efforts to make the systems more efficient and run based on the communication between devices to ensure a closed loop system that can run on its own in a safe and controlled manner. I included pictures of some of the wiring as well as the level sensor devices and relays. I also included pictures of the tanks that will be filled at different heights with deionized water based on where the level sensors are.

08 HYDROGEN↗

A Graph Neural Network Surrogate Model for hls4ml

Recent advancements in use of machine learning (ML) techniques on field-programmable gate arrays (FPGAs) have allowed for the implementation of embedded neural networks with extremely low latency. This is invaluable for particle detectors at the Large Hadron Collider, where latency and used area are strictly bounded. The hls4ml framework is a procedure that converts trained ML model software to a synthesis result to can be used on an FPGA. However, running the pipeline is a time-consuming procedure, and there is a strong risk of failure. In particular, it may not be possible to successfully convert a model into a synthesis result, or the resource consumption of the model may exceed the resources of the target FPGA. To aid with this development, we introduce wa-hls4ml, a surrogate model using a graph neural network to emulate the structure of the source models. The goal is to estimate the chance of success and resource consumption of a given model when passed through the hls4ml pipeline, without needing to run the pipeline.

Plotnikov, Dennis↗

Measurement of the Pion Exclusive Electro-Production Cross-Section in the E12-19-006 Experiment in Hall-C at Jefferson Lab

One of the most effective methods for exploring the transition from hadronic degrees of freedom to quark-gluon degrees of freedom in Quantum Chromodynamics (QCD) is through the investigation of \exclusive" pion and kaon electro-production reactions at various Q2 and ?t values. The E12-19-006 experiment is conducted within the confi?nes of experimental Hall C at the Thomas Jefferson National Accelerator Facility, USA, for such studies. The primary aim of the experiment is to ?first enhance our comprehension of the pion electro-production cross-section and its form factor at Q2 = 0.38 and 0.42 GeV2. This is the fi?rst run period of the E12-19-006 experiment which ran in summer 2019. A more profound understanding of the pion electro-production reaction, 1H(e,e'?+)n, at low Q2 is deemed essential to employ this electro-production reaction (an indirect technique) for the high Q2 studies, thereby delving deeper into the realm of QCD. Consequently, this dissertation presents a thorough analysis of the experimental data acquired in the ?first run period of the E12-19-006 experiment. In pursuit of precision, a series of systematic studies (target boiling correction study, the elastic reaction cross-section measurements, study for determining vari- ous kinematics o?sets, etc.) are conducted to discern the accuracy of the analyzed data, a prerequisite for the use of Rosenbluth separation technique to separate the pion electro-production cross-section terms in t bins. The separated pion electro-production cross-section through the Rosenbluth separation technique is then used to extract the pion electromagnetic form factor. In this dissertation, the pion electro-production cross-section is carefully dissected into its four constituent components: longitudinal (?L), transverse (?T ), longitudinal-transverse (?LT ), and transverse-transverse (?TT ), using the full version of Rosenbluth separation technique for the Q2 = 0.38 GeV2. The technique is simultaneously fi?tted to the unseparated pion electro-production cross-sections at the three values of polarization of the virtual photon (?), i.e., ? = 0.286, 0.629 and 0.781. An iterative process is applied to re?ne the parameters of the model cross-sections until the yield ratio of experimental and Monte Carlo simulation converges. In this study, 21 iterations are conducted to re?ne the model cross-section parameters. The fi?nal pion electro-production cross-section terms are then determined for 7 t bins using the optimized parameters of the model cross-sections.

Kumar, Vijay↗