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At least 1,315 records · Page 73

Technologies Enabling Exploration of Skylights, Lava Tubes and Caves

Robotic exploration of skylights and caves can seek out life, investigate geology and origins, and open the subsurface of other worlds to humankind. However, exploration of these features is a daunting venture. Planetary voids present perilous terrain that requires innovative technologies for access, exploration, and modeling. This research developed technologies for venturing underground and conceived mission architectures for robotic expeditions that explore skylights, lava tubes and caves. The investigation identified effective designs for mobile robot architecture to explore sub-planetary features. Results provide insight into mission architectures, skylight reconnaissance and modeling, robot configuration and operations, and subsurface sensing and modeling. These are developed as key enablers for robotic missions to explore planetary caves. These results are compiled to generate "Spelunker", a prototype mission concept to explore a lunar skylight and cave. The Spelunker mission specifies safe landing on the rim of a skylight, tethered descent of a power and communications hub, and autonomous cave exploration by hybrid driving/hopping robots. A technology roadmap was generated identifying the maturation path for enabling technologies for this and similar missions.

Robot↗

The Water Budget of a Simulated Hurricane

The Pennsylvania State University-National Center for Atmospheric Research mesoscale model MM5 is used to simulate Hurricane Bonnie at high resolution (2-km spacing) in order to examine budgets of water vapor, cloud condensate, and precipitation. Virtually all budget terms are derived directly from the model (except for the effects of storm motion). The water vapor budget reveals that a majority of the condensation in the eyewall occurs in convective hot towers, while outside of the eyewall most of the condensation occurs in weaker updrafts, indicative of a larger role of stratiform precipitation processes. The ocean source of water vapor in the eyewall region is only a very small fraction of that transported inward in the boundary layer inflow or that condensed in the updrafts. In contrast, in the outer regions, the ocean vapor source is larger owing to the larger area, counters the drying effect of low-level subsidence, and enhances the moisture transported in toward the eyewall. In this mature storm, cloud condensate is consumed as rapidly as it is produced. Cloud water peaks at the top of the boundary layer and within the melting layer, where cooling from melting enhances condensation. Unlike in squall lines, in the hurricane, very little condensate produced in the eyewall convection is transported outward into the surrounding precipitation area. Most of the mass ejected outward is likely in the form of small snow particles that seed the outer regions and enhance in situ stratiform precipitation development through additional growth by vapor deposition and aggregation. We examine artificial source terms for cloud and precipitation mass associated with setting to zero negative mixing ratios that arise from numerical advection errors. Although small at any given point and time, the cumulative effect of these terms contributes an amount of mass equivalent to 13% of the total condensation and 15-20% of the precipitation. Thus, these terms must be accounted for to balance the model budgets and the results suggest the need for improved model numerics.

Braun, S.↗

Modeling powder spreadability in powder-based processes using the discrete element method

Powder-bed fusion (PBF) processes refer to a subset of Additive Manufacturing (AM) techniques where powder is spread on the build-plate before melting (by a laser or electron beam). While PBF processes are attractive due to their ability for realizing complex structures that are either difficult or impossible to create through conventional means, the parts fabricated with these techniques can exhibit defects such as pores, inclusions, and excessive surface roughness. To minimize these defects, much research has been dedicated towards process maturation by optimizing laser or electron beam parameters. However, these developmental efforts typically do not address the recoating process where achieving dense and uniform layers of powder is a necessity for ensuring process repeatability and part quality. While the recoating process can be studied through experimentation, the dynamics of particle movement are difficult to analyze experimentally. Therefore, here, in this study, powder spreading in PBF was simulated through the Discrete Element Method (DEM) to elucidate the mechanisms that control powder-bed quality. Utilizing the Buckingham Pi theorem, a dimensionless metric referred to as the spreading index is developed that combines powder-bed density, roughness, and particle size to assess the quality of powder layers. The formulated spreading index is then related to several dimensionless quantities that provide insight into the mechanisms dominating powder spreading in PBF. The DEM simulations conducted in this work focused on the scenario where powder is spread onto an existing powder bed and revealed that a reduction in the recoating velocity causes an increase in the spreading index while little to no impact on the spreading index was observed when varying layer thickness from 30 μm to 75 μm.Particle size effects on the powder-bed quality were also investigated.

36 MATERIALS SCIENCE↗

Nuclear localization of CPI-17, a protein phosphatase-1 inhibitor protein, affects histone H3 phosphorylation and corresponds to proliferation of cancer and smooth muscle cells

Highlights: •Non-canonical roles of the myosin phosphatase inhibitor (CPI-17) were studied. •CPI-17 is localized in the nucleus of hyperplastic cancer and smooth muscle cells. •CPI-17 Ser12 phosphorylation may regulate the nuclear import. •CPI-17 regulates histone H3 phosphorylation and cell proliferation. •The nuclear CPI-17-PP1 axis plays a proliferative role in cells. -- Abstract: CPI-17 (C-kinase-activated protein phosphatase-1 (PP1) inhibitor, 17 kDa) is a cytoplasmic protein predominantly expressed in mature smooth muscle (SM) that regulates the myosin-associated PP1 holoenzyme (MLCP). Here, we show CPI-17 expression in proliferating cells, such as pancreatic cancer and hyperplastic SM cells. Immunofluorescence showed that CPI-17 was concentrated in nuclei of human pancreatic cancer (Panc1) cells. Nuclear accumulation of CPI-17 was also detected in the proliferating vascular SM cell culture and cells at neointima of rat vascular injury model. The N-terminal 21-residue tail domain of CPI-17 was necessary for the nuclear localization. Phospho-mimetic Asp-substitution of CPI-17 at Ser12 attenuated the nuclear import. CPI-17 phosphorylated at Ser12 was not localized at nuclei, suggesting a suppressive role of Ser12 phosphorylation in the nuclear import. Activated CPI-17 bound to all three isoforms of PP1 catalytic subunit in Panc1 nuclear extracts. CPI-17 knockdown in Panc1 resulted in dephosphorylation of histone H3 at Thr3, Ser10 and Thr11, whereas it had no effects on the phosphorylation of myosin light chain and merlin, the known targets of MLCP. In parallel, CPI-17 knockdown suppressed Panc1 proliferation. We propose that CPI-17 accumulated in the nucleus through the N-terminal tail targets multiple PP1 signaling pathways regulating cell proliferation.

60 APPLIED LIFE SCIENCES↗

Joint impedance and facies inversion of time-lapse seismic data for improving monitoring of CO 2 incidentally stored from CO 2 EOR

Time-lapse seismic monitoring is an effective and proven technology for mapping the distribution of CO 2 in a subsurface reservoir. When injected CO 2 displaces other reservoir fluids, porous-medium properties are changed and thus the seismic impedance changes, causing time-lapse seismic amplitude differences in the injection zones. The analysis and interpretation of images created from these amplitude differences can provide information about reservoir architecture and the CO 2 migration within the reservoir. Incorporating seismic inversion and rock physics into the interpretation of time-lapse seismic data can considerably improve the modeling and monitoring to detect and assess the location of CO 2 over time. The joint inversion method presented in this paper has an integral representation of the geology in the inversion algorithm using elastic facies, which provides information about the spatial distribution of the geologic heterogeneities controlling the movement of fluids in the reservoir. The method was successfully applied to time-lapse seismic data from a mature oil field undergoing CO 2 enhanced oil recovery. The estimated seismic acoustic impedances and facies reflect the characteristics of individual geologic facies and fluid conditions of the reservoir subject to CO 2 injection. Finally, the probabilities estimated by the joint impedance and facies inversion for the reservoir's litho-fluid facies can be used for forecasting CO 2 saturation and pressure changes within the target reservoir.

4D seismic↗

Bulk and position-specific isotope geochemistry of natural gases from the Late Cretaceous Eagle Ford Shale, south Texas

Here, a dataset of bulk and position-specific isotope compositions of shale gases from the Late Cretaceous Eagle Ford Shale, south Texas is reported. The chemical and bulk isotopic compositions of the seven samples in this study and those available from the literature show that across the play, produced natural gas from the Eagle Ford Shale preserves a wide range of gas compositions (wetness, ~5 to >90%) and δ 13 C values of C 1 –C 3 . The depth profiles of the isotopic compositions suggest that the western region of the Eagle Ford Shale deposit had experienced as much as 700–800 m of uplift-erosion or gas migration. The timing of and lost-gas fractions by gas expulsion events very likely affected their gas compositions and bulk isotope compositions. Some deep (>3000–3500 m), matured (%Ro > 1.5) gases with heavy δ 13 C(C 1 –C 3 ) values indicate significant loss (>50%) of the early-stage gases. For the position-specific isotope deviations of propane, the ΔC 2-1 values of the five samples show small decrease with well depths, while the ΔH 2-1 values have a general increasing trend. Although some samples fall very close to the equilibrium model trajectories with reasonable calculated temperatures (138–148 °C), the position-specific isotope compositions of propane from the Eagle Ford Shale gases are likely results of thermal cracking of various organic molecules within the source rocks, which have different activation energy for cracking and non-statistical distributions of C/H isotope within them.

58 GEOSCIENCES↗

Ensemble Shear Strength, Stability, and Permeability of Mixed Mineralogy Fault Gouge Recovered From 3D Granular Models

We conduct numerical shear experiments on mixtures of quartz and talc gouge using a three-dimensional (3D) distinct element model. A modified slip-weakening constitutive law is applied at contacts. We perform velocity-stepping experiments on both uniform and layered mixtures of quartz and talc analogs. We separately vary the proportion of talc in the uniform mixtures and talc layer thickness in the layered mixtures. Shear displacements are cycled through velocities of 1 and 10 μm/s. We follow the resulting evolution of ensemble shear strength, slip stability, and permeability of the gouge mixture and explore the mesoscopic mechanisms. Simulation results show that talc has a strong weakening effect on shear strength—a thin shear-parallel layer of talc (three particles wide) can induce significant weakening. However, the model offsets laboratory-derived strong weakening effects of talc observed in uniform mixtures, implying the governing mechanisms may be the shear localization effect of talc, which is enhanced by its natural platy shape or preimposed layered structure. Ensemble stability (a – b ) can be enhanced by increasing talc content in uniform talc-quartz mixtures. Reactivation-induced permeability increase is amplified with increased quartz content before the maturation of shear localization. Postmaturation permeability enhances on velocity upsteps and diminishes on velocity downsteps. Talc enhances compaction at velocity downsteps, potentially reducing fault permeability. Evolution trends of stability relating to the composition and structure of the fault gouge are straightforwardly obtained from the 3D simulation. Local friction evolution indicates that talc preferentially organizes and localizes in the shear zone, dominating the shear strength and frictional stability of faults

58 GEOSCIENCES↗

Role of Caulobacter Cell Surface Structures in Colonization of the Air-Liquid Interface

In aquatic environments, Caulobacter spp. can be found at the boundary between liquid and air known as the neuston. I report an approach to study temporal features of Caulobacter crescentus colonization and pellicle biofilm development at the air-liquid interface and have defined the role of cell surface structures in this process. At this interface, C. crescentus initially forms a monolayer of cells bearing a surface adhesin known as the holdfast. When excised from the liquid surface, this monolayer strongly adheres to glass. The monolayer subsequently develops into a three-dimensional structure that is highly enriched in clusters of stalked cells known as rosettes. As this pellicle film matures, it becomes more cohesive and less adherent to a glass surface. A mutant strain lacking a flagellum does not efficiently reach the surface, and strains lacking type IV pili exhibit defects in organization of the three-dimensional pellicle. Strains unable to synthesize the holdfast fail to accumulate at the boundary between air and liquid and do not form a pellicle. Phase-contrast images support a model whereby the holdfast functions to trap C. crescentus cells at the air-liquid boundary. Unlike the holdfast, neither the flagellum nor type IV pili are required for C. crescentus to partition to the air-liquid interface. While it is well established that the holdfast enables adherence to solid surfaces, this study provides evidence that the holdfast has physicochemical properties that allow partitioning of nonmotile mother cells to the air-liquid interface and facilitate colonization of this microenvironment. In aquatic environments, the boundary at the air interface is often highly enriched with nutrients and oxygen. Colonization of this niche likely confers a significant fitness advantage in many cases. This study provides evidence that the cell surface adhesin known as a holdfast enables Caulobacter crescentus to partition to and colonize the air-liquid interface. Additional surface structures, including the flagellum and type IV pili, are important determinants of colonization and biofilm formation at this boundary. Considering that holdfast-like adhesins are broadly conserved in Caulobacter spp. and other members of the diverse class Alphaproteobacteria , these surface structures may function broadly to facilitate colonization of air-liquid boundaries in a range of ecological contexts, including freshwater, marine, and soil ecosystems

54 ENVIRONMENTAL SCIENCES↗

Gasification Studies: Task 4 Topical Report, Utah Clean Coal Program

A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical processes (Subtask 4.4) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation. Highlights of this work include: (1) Verification and validation activities performed with the Arches coal gasification simulation tool on experimental data from the CANMET gasifier (Subtask 4.1). (2) The simulation of multiphase reacting flows with coal particles including detailed gas-phase chemistry calculations using an extension of the one-dimensional turbulence model’s capability (Subtask 4.2). (3) The demonstration and implementation of the Reverse Monte Carlo ray tracing (RMCRT) radiation algorithm in the ARCHES code (Subtask 4.3). (4) Determination of steam and CO 2 gasification kinetics of bituminous coal chars at high temperature and elevated pressure under entrained-flow conditions (Subtask 4.4). In addition, attempts were made to gain insight into the chemical structure differences between young and mature coal soot, but both NMR and TEM characterization efforts were hampered by the highly reacted nature of the soot. (5) The development, operation, and demonstration of in-situ gas phase measurements from the University of Utah’s pilot-scale entrained-flow coal gasifier (EFG) (Subtask 4.6). This subtask aimed at acquiring predictable, consistent performance and characterizing the environment within the gasifier.

01 COAL, LIGNITE, AND PEAT↗

First Results from the Search for Muon-Neutrino Disappearance with the ICARUS Detector

After successful operation at LNGS and a major upgrade at CERN, the 760-ton ICARUS T600 detector has been running at Fermilab since 2020, collecting neutrino interactions from the BNB and NuMI beams. In late 2025, ICARUS reached five years of continuous data taking, demonstrating the maturity of large-scale LAr-TPC technology and its relevance for future experiments such as DUNE. This contribution presents the first ICARUS search for muon-neutrino disappearance in the BNB. Charged-current 1$\mu$Np events selected from 2022–2023 data are compared to simulations and interpreted, for the first time, within a two-neutrino approximation of the 3+1 sterile-neutrino model, including systematic uncertainties from flux, interaction, and detector effects. Although currently limited by systematic uncertainties, this first oscillation analysis probes the parameter space suggested by existing $\nu_\mu$ disappearance results and lays the groundwork for future SBN combined analyses with SBND, which will significantly improve sensitivity to sterile-neutrino scenarios.

Steklain, Andre [Parana Tech. Fed. U., Toledo] (OR↗

Thermodynamics of Bimetallic Joints between Titanium and Tantalum Produced by Laser Powder Bed Fusion

Laser powder bed fusion (LBPF) is currently the most mature metal additive manufacturing (AM) technology. While it does not have the same flexibility as directed energy deposition techniques to produce compositional gradients, LPBF can still be used to generate bimetallic parts by depositing one metal on a build plate made of another. Here, in this study, we print combinations of Ti-6Al-4V with Ta and characterize defects that occur at the interface. We use thermodynamic modeling to explain the formation of keyhole porosity and solidification cracks when Ta is built on a Ti baseplate, and the lack of defects when the materials are reversed. By understanding the mechanisms that lead to defect formation, the methodology demonstrated here can be applied to other material systems to efficiently design bimetallic LPBF processes.

36 MATERIALS SCIENCE↗

Light element geochemistry of the Apollo 12 site

Analytical techniques of improved sensitivity have revealed details of the concentrations and isotopic compositions of light elements for a comprehensive suite of samples from the Apollo 12 regolith. These samples show a wide spread in maturity, although maximum contents observed for solar wind elements are less than observed at other sites, possibly reflecting relative recency of craters at the Apollo 12 site. Isotopic composition of nitrogen is consistent with the idea that N-15/N-14 in the solar wind has increased with time, at least a major part of this increase having occurred in the past 3.1 Gyr. Sulfur isotope systematics support a model in which sulfur is both added to the regolith, by meteoritic influx, and lost, by an isotopically selective process. Most soils from this site are heavily contaminated with terrestrial carbon.

Kerridge, J. F.↗

Roughness Based Crossflow Transition Control for a Swept Airfoil Design Relevant to Subsonic Transports

A high fidelity transition prediction methodology has been applied to a swept airfoil design at a Mach number of 0.75 and chord Reynolds number of approximately 17 million, with the dual goal of an assessment of the design for the implementation and testing of roughness based crossflow transition control and continued maturation of such methodology in the context of realistic aerodynamic configurations. Roughness based transition control involves controlled seeding of suitable, subdominant crossflow modes in order to weaken the growth of naturally occurring, linearly more unstable instability modes via a nonlinear modification of the mean boundary layer profiles. Therefore, a synthesis of receptivity, linear and nonlinear growth of crossflow disturbances, and high-frequency secondary instabilities becomes desirable to model this form of control. Because experimental data is currently unavailable for passive crossflow transition control for such high Reynolds number configurations, a holistic computational approach is used to assess the feasibility of roughness based control methodology. Potential challenges inherent to this control application as well as associated difficulties in modeling this form of control in a computational setting are highlighted. At high Reynolds numbers, a broad spectrum of stationary crossflow disturbances amplify and, while it may be possible to control a specific target mode using Discrete Roughness Elements (DREs), nonlinear interaction between the control and target modes may yield strong amplification of the difference mode that could have an adverse impact on the transition delay using spanwise periodic roughness elements.

Li, Fei↗

Overview and Accomplishments of Advanced Mirror Technology Development Phase 2 (AMTD-2) Project

The Advance Mirror Technology Development (AMTD) project is in Phase 2 of a multiyear effort, initiated in FY12, to mature by at least a half TRL step critical technologies required to enable 4 meter or larger UVOIR space telescope primary mirror assemblies for both general astrophysics and ultra-high contrast observations of exoplanets. AMTD Phase 1 completed all of its goals and accomplished all of its milestones. AMTD Phase 2 started in 2014. Key accomplishments include deriving primary mirror engineering specifications from science requirements; developing integrated modeling tools and using those tools to perform parametric design trades; and demonstrating new mirror technologies via sub-scale fabrication and test. AMTD-1 demonstrated the stacked core technique by making a 43-cm diameter 400 mm thick 'biscuit-cut' of a 4-m class mirror. AMTD-2 is demonstrating lateral scalability of the stacked core method by making a 1.5 meter 1/3rd scale model of a 4-m class mirror.

Space Telescope Mirrors↗

Computational Modeling of Two Mars Powered Descent Vehicle Concepts Tested in the Langley Unitary Plan Wind Tunnel

Future human Mars missions will require powered descent starting at supersonic conditions, something which has never been done before at Mars. Computational powered descent flowfield simulations have been completed at full-scale Mars conditions, but the available ground test data are not suitable for calibrating computational uncertainties for aerodynamic interference on proposed Mars descent vehicles. Testing was conducted in the NASA Langley Unitary Plan Wind Tunnel in order to investigate the aerodynamic interference of sub-scale versions of two Mars powered descent vehicle concepts at supersonic Mach numbers (2.4 and 3.5): a model based on a blunt hypersonic inflatable aerodynamic decelerator (HIAD) and the second representing a more slender rigid vehicle with body flaps (CobraMRV). This paper covers computational flowfield predictions completed at wind tunnel conditions and comparisons to the test data. On the blowing HIAD models, the time-averaged pressure inboard of the nozzles was generally well-predicted, especially if the nozzles are canted outward, when the nozzles are located further from the nose. At intermediate CobraMRV thrust coefficients, CFD pressures are more accurately predicted than they are for the HIAD models, largely due to the nozzle locations and pointing directions. Overall, the CFD pressure coefficients were predicted within 0.2 of the steady pressure measurements for all blowing models, with smaller discrepancies at higher HIAD thrust, and larger discrepancies at lower HIAD CobraMRV thrust. All HIAD models were predicted to have a gradually decreasing axial force coefficient as the total thrust increases, in agreement with available pressure sensitive paint data. On models with canted nozzles or with nozzles further from the nose, the force coefficient was slightly higher for a given thrust. On the CobraMRV model, the CFD also shows consistent results between solvers and follows trends revealed in the data; the aerodynamic force coefficient remains near the non-blowing value at a tunnel Mach number of 2.4 regardless of thrust, and increases above that level at a Mach number of 3.5, consistent with the discrete pressure data. CFD analysis at tunnel and flight conditions will continue as flight system designs concepts mature.

Supersonic Retropropulsion↗

Computational Modeling of Two Mars Powered Descent Vehicle Concepts Tested in the Langley Unitary Plan Wind Tunnel

Future human Mars missions will require powered descent starting at supersonic conditions, something which has never been done before at Mars. Computational powered descent flowfield simulations have been completed at full-scale Mars conditions, but the available ground test data are not suitable for calibrating computational uncertainties for aerodynamic interference on proposed Mars descent vehicles. Testing was conducted in the NASA Langley Unitary Plan Wind Tunnel in order to investigate the aerodynamic interference of sub-scale versions of two Mars powered descent vehicle concepts at supersonic Mach numbers (2.4 and 3.5): a model based on a blunt hypersonic inflatable aerodynamic decelerator (HIAD) and the second representing a more slender rigid vehicle with body flaps (CobraMRV). This paper covers computational flowfield predictions completed at wind tunnel conditions and comparisons to the test data. On the blowing HIAD models, the time-averaged pressure inboard of the nozzles was generally well-predicted, especially if the nozzles are canted outward, when the nozzles are located further from the nose. At intermediate CobraMRV thrust coefficients, CFD pressures are more accurately predicted than they are for the HIAD models, largely due to the nozzle locations and pointing directions. Overall, the CFD pressure coefficients were predicted within 0.2 of the steady pressure measurements for all blowing models, with smaller discrepancies at higher HIAD thrust, and larger discrepancies at lower HIAD CobraMRV thrust. All HIAD models were predicted to have a gradually decreasing axial force coefficient as the total thrust increases, in agreement with available pressure sensitive paint data. On models with canted nozzles or with nozzles further from the nose, the force coefficient was slightly higher for a given thrust. On the CobraMRV model, the CFD also shows consistent results between solvers and follows trends revealed in the data; the aerodynamic force coefficient remains near the non-blowing value at a tunnel Mach number of 2.4 regardless of thrust, and increases above that level at a Mach number of 3.5, consistent with the discrete pressure data. CFD analysis at tunnel and flight conditions will continue as flight system designs concepts mature.

Supersonic Retropropulsion↗

Evaluating Cu/BEA Catalyst Performance with Techno-Economic Analysis to Develop a Market-Responsive Biorefinery Concept Around the Conversion of Methanol to High-Octane Hydrocarbons

A recent advancement in the conversion of methanol to hydrocarbon fuels is the development of a Cu-modified beta zeolite catalyst (Cu/BEA) that exhibits a higher productivity and yield than the parent H-form BEA catalyst in the production of branched C4-C8 hydrocarbons. This Cu/BEA catalyst enables process improvements in the High-Octane Gasoline (HOG) pathway, which operates under lower severity conditions than traditional methanol-to-fuels processes, offering a lower coke formation rate, higher selectivity to C5+gasoline-range hydrocarbons, and subsequently, improved process economics based on a recent process model and techno-economic analysis (TEA). Here, a market-responsive biorefinery concept around methanol and the HOG pathway is presented, where the major C4 products, isobutane and isobutene, serve as versatile intermediates that can either be recycled to increase the yield of the HOG product or directed to jet-fuel range hydrocarbons. Based on simulated recycle experiments with 13C-labeled isobutane, the Cu/BEA catalyst achieved increased yield to the HOG products during DME homologation by activating the co-fed isobutane and incorporating it into the chain growth pathway, as evidenced by the presence of isotopically-labeled 13C in C5+ products. Olefin coupling of an isobutene-rich mixture was also investigated, and the fuel properties of the resulting synthetic kerosene product were within the specifications for a typical jet-fuel. These experimental results were incorporated into an updated Aspen-based process model and TEA to quantify their impact on a market-responsive biorefinery concept. The improvements offered by C4 recycling with the Cu/BEA catalyst result in a decrease in the methanol-to-fuel synthesis cost from 101 cents per gallon of gasoline equivalent (GGE) with the baseline BEA catalyst to 72 cents/GGE, due in part to a significantly increased HOG yield from 40 to 55 GGE/dry-ton biomass. Expanding the process model to direct C4 products to a jet-range hydrocarbon product demonstrated a yield of 42 GGE/dry-ton HOG with 12 GGE/dry-ton distillate, resulting in a minor increase in the fuel synthesis cost to 77 cents/GGE versus the HOG-only case. With continued development, these advancements in fuel yield and reductions in cost position a market-responsive biorefinery around the HOG pathway to be competitive against mature fuel-synthesis technologies from a variety of carbon sources through methanol.

09 BIOMASS FUELS↗

Wheat signature modeling and analysis for improved training statistics

The author has identified the following significant results. The spectral, spatial, and temporal characteristics of wheat and other signatures in LANDSAT multispectral scanner data were examined through empirical analysis and simulation. Irrigation patterns varied widely within Kansas; 88 percent of wheat acreage in Finney was irrigated and 24 percent in Morton, as opposed to less than 3 percent for western 2/3's of the State. The irrigation practice was definitely correlated with the observed spectral response; wheat variety differences produced observable spectral differences due to leaf coloration and different dates of maturation. Between-field differences were generally greater than within-field differences, and boundary pixels produced spectral features distinct from those within field centers. Multiclass boundary pixels contributed much of the observed bias in proportion estimates. The variability between signatures obtained by different draws of training data decreased as the sample size became larger; also, the resulting signatures became more robust and the particular decision threshold value became less important.

Nalepka, R. F.↗