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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,315 records · Page 73

Optimization of Conductive Fins to Minimize UO2 Fuel Temperature and Radial Temperature Gradient

To further the development of low-enriched uranium fuels, precedence has been placed on delivering the same amount of power while lowering the fuel temperature and radial temperature gradient. To address this, modeling efforts have resulted in a novel design featuring conductive fins of varying thermal conductivities and geometries inserted into the fuel matrix. These conductive inserts were not allowed to exceed 6% of the original fuel volume. This constraint was imposed due to other designs displacing 10% of fuel volume. A parametric study was performed that consisted of 2.56 million BISON simulations involving varying fin characteristics (i.e., fin thermal conductivity, number, and geometry) to determine the optimal geometric configuration for a desired amount of fuel volume displaced. The results from this study show that the thickness and length of each fin affect the fuel temperature and temperature gradient more than varying the number and thermal conductivity of the fins. The parametric study resulted in the development of an optimized combination to produce the lowest peak fuel temperature, lowest radial temperature gradient, and highest temperature reduction for the amount of original fuel volume displaced. The simulations presented in this work will eventually be compared with irradiation experiments of similar fuel designs at Idaho National Laboratory’s Advanced Test Reactor.

Paaren, Kyle M.↗

Compositional Design of Soft Magnetic High Entropy Alloys by Minimizing Magnetostriction Coefficient in (Fe 0.3 Co 0.5 Ni 0.2 ) 100-x (Al 1/3 Si 2/3 ) x System

Developing cost-effective soft magnetic alloys with excellent mechanical properties is very important to energy-saving industries. This study investigated the magnetic and mechanical properties of a series of (Fe 0.3 Co 0.5 Ni 0.2 ) 100–x (Al 1/3 Si 2/3 ) x high-entropy alloys (HEAs) (x = 0, 5, 10, 15, and 25) at room temperature. The Fe 0.3 Co 0.5 Ni 0.2 base alloy composition was chosen since it has very the smallest saturation magnetostriction coefficient. It was found that the (Fe 0.3 Co 0.5 Ni 0.2 ) 95 (Al 1/3 Si 2/3 ) 5 alloy maintains a simple face-centered cubic (FCC) solid solution structure in the states of as-cast, cold-rolled, and after annealing at 1000 °C. The alloy after annealing exhibits a tensile yield strength of 235 MPa, ultimate tensile strength of 572 MPa, an elongation of 38%, a saturation magnetization (Ms) of 1.49 T, and a coercivity of 96 A/m. The alloy not only demonstrates an optimal combination of soft magnetic and mechanical properties, it also shows advantages of easy fabrication and processing and high thermal stability over silicon steel and amorphous soft magnetic materials. Therefore, the alloy of (Fe 0.3 Co 0.5 Ni 0.2 ) 95 (Al 1/3 Si 2/3 ) 5 holds good potential as next-generation soft magnets for wide-range industrial applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Noncured Graphene Thermal Interface Materials for High-Power Electronics: Minimizing the Thermal Contact Resistance

We report on experimental investigation of thermal contact resistance, RC, of the noncuring graphene thermal interface materials with the surfaces characterized by different degree of roughness, Sq. It is found that the thermal contact resistance depends on the graphene loading, ξ, non-monotonically, achieving its minimum at the loading fraction of ξ ~15 wt%. Decreasing the surface roughness by Sq~1 μm results in approximately the factor of ×2 decrease in the thermal contact resistance for this graphene loading. The obtained dependences of the thermal conductivity, KTIM, thermal contact resistance, RC, and the total thermal resistance of the thermal interface material layer on ξ and Sq can be utilized for optimization of the loading fraction of graphene for specific materials and roughness of the connecting surfaces. Our results are important for the thermal management of high-power-density electronics implemented with diamond and other wide-band-gap semiconductors.

36 MATERIALS SCIENCE↗

Novel Application of Hybrid Anion Exchange Resin for Phosphate Desorption Kinetics in Soils: Minimizing Re-Adsorption of Desorbed Ions

The process of phosphate desorption from soils is difficult to measure using stirred batch techniques because of the accumulation of desorbed ions in a bathing solution. To accurately measure the apparent rate coefficient of phosphate desorption from soils, it is necessary to remove the desorbed ions. In this study, a novel hybrid (i.e., iron oxide coated) anion exchange resin was used as a sink to study long-term (seven days) P desorption kinetics in intensively managed agricultural soils in the Midwestern U.S. (total phosphorus (TP): 196–419 mg/kg). The phosphate desorption kinetics in the hybrid anion exchange resin method were compared with those in the other conventional batch desorption method with pure anion exchange resins or without any sink. The extent of P desorption in the hybrid resin methods was >50% of total desorbed phosphate in the other methods. The initial kinetic rate estimated in the pseudo-second-order kinetic model was also highest (3.03–31.35 mg/(g·hr)) in the hybrid resin method when the same soil system was compared. This is because adsorbed P in the hybrid resins was nearly irreversible. The hybrid anion exchange resin might be a new and ideal sink in measuring the P desorption process in soils and sediments

54 ENVIRONMENTAL SCIENCES↗

A Scalable Approach to Minimize Charging Costs for Electric Bus Fleets

Incorporating battery electric buses into bus fleets faces three primary challenges: a BEB’s extended refuel time, the cost of charging, both by the consumer and the power provider, and large compute demands for planning methods. When BEBs charge, the additional demands on the grid may exceed hardware limitations, so power providers divide a consumer’s energy needs into separate meters even though doing so is expensive for both power providers and consumers. Prior work has developed a number of strategies for computing charge schedules for bus fleets; however, prior work has not worked to reduce costs by aggregating meters. Additionally, because many works use mixed integer linear programs, their compute needs make planning for commercial-sized bus fleets intractable. This work presents a multi-program approach to computing charge plans for electric bus fleets. The proposed method solves a series of subproblems where the solution to the charge problem becomes more refined with each problem, moving closer to the optimal schedule. The results demonstrate how runtimes are reduced by using intermediate subproblems to refine the bus charge solution so that the proposed method can be applied to large bus fleets of 100+ buses. Not only will we demonstrate that runtimes scale linearly with the number of buses but we will also show how the proposed method scales to large bus fleets of over 100 buses while managing the monthly cost of energy.

Mortensen, Daniel (ORCID:0000000276494452)↗

Procedure for the Transfer of Polymer Films Onto Porous Substrates with Minimized Defects

The fabrication of devices containing thin film structures necessitate the transfer of these films onto the surfaces of arbitrary support substrates. Accomplishing this transfer in a highly controlled, mechanized, and reproducible manner would eliminate the creation of macroscale defect structures (e.g. tears, cracks, and wrinkles) within the thin film that would otherwise have a negative impact on ultimate device performance. In this work, we describe a general protocol for the highly controlled and mechanized transfer of a polymeric thin film onto an arbitrary porous support substrate for eventual use as a water filtration membrane device. Specifically, we fabricate a block copolymer (BCP) thin film on top of a sacrificial, water-soluble poly(acrylic acid) (PAA) layer and silicon wafer substrate. We then utilize a custom-designed, 3D-printed transfer tool and drain chamber system to deposit, lift-off, and transfer the BCP thin film onto the center of a porous anodized aluminum oxide (AAO) support disc. The transferred BCP thin film is shown to be consistently placed onto the center of the support surface due to the guidance of the meniscus. Additionally, we compare our mechanized transfer-processed thin films to those that have been transferred by other commonly used techniques, such as by hand with the use of tweezers. Optical inspection and image analysis of the transferred thin films from the mechanized process confirm that little-to-no macroscale inhomogeneities or plastic deformations are produced, as compared to the multitude of tears and wrinkles produced from manual transfer by hand. Our findings indicate that the proposed strategy for thin film transfer can reduce defects when compared to other methods across many systems and applications.

36 MATERIALS SCIENCE↗

MINIMAL PROSPECTS FOR RADIO DETECTION OF EXTENSIVE AIR SHOWERS IN THE ATMOSPHERE OF JUPITER

One possible approach for detecting ultra-high-energy cosmic rays and neutrinos is to search for radio emission from extensive air showers created when they interact in the atmosphere of Jupiter, effectively utilizing Jupiter as a particle detector. We investigate the potential of this approach. For searches with current or planned radio telescopes we find that the effective area for detection of cosmic rays is substantial (∼3 × 10{sup 7} km{sup 2}), but the acceptance angle is so small that the typical geometric aperture (∼10{sup 3} km{sup 2} sr) is less than that of existing terrestrial detectors, and cosmic rays also cannot be detected below an extremely high threshold energy (∼10{sup 23} eV). The geometric aperture for neutrinos is slightly larger, and greater sensitivity can be achieved with a radio detector on a Jupiter-orbiting satellite, but in neither case is this sufficient to constitute a practical detection technique. Exploitation of the large surface area of Jupiter for detecting ultra-high-energy particles remains a long-term prospect that will require a different technique, such as orbital fluorescence detection.

79 ASTRONOMY AND ASTROPHYSICS↗

Project AMIGA: A Minimal Covering Factor for Optically Thick Circumgalactic Gas around the Andromeda Galaxy

We present a deep search for H I 21 cm emission from the gaseous halo of Messier 31 as part of Project AMIGA, a large Hubble Space Telescope program to study the circumgalactic medium of the Andromeda galaxy. Our observations with the Robert C. Byrd Green Bank Telescope target sight lines to 48 background AGNs, more than half of which have been observed in the ultraviolet with the Cosmic Origins Spectrograph, with impact parameters 25≲ρ≲340 kpc (0.1≲ρ/R{sub vir}≲1.1). We do not detect any 21 cm emission toward these AGNs to limits of N(H I)≈4×10{sup 17} cm{sup −2} (5σ; per 2 kpc-diameter beam). This column density corresponds to an optical depth of ∼2.5 at the Lyman limit; thus, our observations overlap with absorption line studies of Lyman limit systems at higher redshift. Our non-detections place a limit on the covering factor of such optically thick gas around M31 to f{sub c}<0.051 (at 90% confidence) for ρ⩽R{sub vir}. Although individual clouds have previously been found in the region between M31 and M33, the covering factor of strongly optically thick gas is quite small. Our upper limits on the covering factor are consistent with expectations from recent cosmological “zoom” simulations. Recent COS-Halos ultraviolet measurements of H I absorption about an ensemble of galaxies at z≈0.2 show significantly higher covering factors within ρ≲0.5R{sub vir} at the same N(H I), although the metal ion-to-H I ratios appear to be consistent with those seen in M31.

79 ASTRONOMY AND ASTROPHYSICS↗

In-Cylinder Oxygen Mass Fraction Estimation Method for Minimizing Cylinder-to-Cylinder Variations

Recent developments in advanced combustion engines have demonstrated the potential increases in efficiency and reductions in emissions through low temperature combustion (LTC). These combustion modes often rely on high exhaust gas recirculation (EGR), early fuel injection systems, and in some cases a combination of fuels with different reactivities. Despite the advantages of LTC, such operations are highly sensitive to the in-cylinder pre-combustion conditions and face significant challenges in multi-cylinder operation due to cylinder-to-cylinder variations of the combustion process. The cause of cylinder-to-cylinder variations is strongly tied to non-uniform trapped mass. In particular, in-cylinder oxygen concentration plays a critical role in the combustion process of each cylinder and can be leveraged to predict combustion characteristics and to develop control algorithms that mitigate cylinder-to-cylinder variation. This paper discusses a control-oriented model for estimating the in-cylinder oxygen mass fraction of each individual cylinder. The method relies on an Arrhenius correlation that establishes a relation between oxygen mass fraction, ignition delay, fuel activation energy, and in-cylinder average temperature and pressure during the ignition delay period. The scope of this study is the investigation of this relation on a single injection diesel fuel combustion in a multi-cylinder engine where the main characteristics of LTC operation, early fuel injection and high EGR, are realized. The model developed in this work accurately estimates the oxygen mass fraction of an individual cylinder in the 20 operating conditions studied with a standard deviation of 0.47% O2.

Kassa, Mateos↗