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At least 1,315 records · Page 73

Studies of basic mechanisms occurring in high pressure gases: Applications to high efficiency high power lasers

The atomic fluorine laser was investigated. In the hollow cathode, lasing on Fluorine transitions in the doublet system lasted for up to 80 microns with no signs of self-termination. The excitation process of the laser appears to depend heavily upon the fluorine donor utilized. For instance, a single step process is involved when NF3 is used whereas a two step process is evident for SF6. The details are discussed.

Crane, J. K., III↗

Optical surface damage from reentrant gases on STS

The effect of an ammonia environment on the spectral reflectance of certain optical surfaces in the vacuum ultraviolet region was studied. In particular, the optical surfaces in the space shuttle were considered. Scans made of sample beams showed no change in the relative intensities before or after exposure to ammonia. Ammonia showed no effect on the Al/MgF2 mirror reflectance in the vacuum ultraviolet.

Mcdonald, J. K.↗

Experimental studies of the formation/deposition of sodium sulfate in/from combustion gases

Interference in a reflected beam of monochromatic light from a linearly polarized helium-neon laser was used to determine the dew point and deposition rate of B2O3 on a heated platinum target. Preliminary results at different BCl3 seed levels, except for one flow velocity and equivalence ratio (.813) are presented and discussed. Alkali chloride reactions with atomic oxygen were also investigated. Readily detectable Na*(g) and K*(g) - atoms were observed in emission at 589 nm, 766nm, 796nm, respectively.

Rosner, D. E.↗

Investigation of infrared spectra of atmospheric gases to support stratospheric spectroscopic investigations

Four papers are presented which discuss the following: information measures in nonlinear experimental design; information in spectra of collision broadened absorption lines; band analysis by spectral curve fitting; and least squares analysis of Voight shaped lines. Abstracts of five research papers on which the author collaborated and which were delivered at the 34th Symposium of Molecular Spectroscopy (Ohio State University, June 1979) are included along with a subroutine for use with BMDP3R to retrieve the parameters of 10 Voight shaped lines.

Shaw, J. H.↗

Determination of trace gases in learjet and U-2 whole air samples collected during the intertropical convergence zone experiment

The contribution of Washington State University (WSU) to the Intertropical Convergence Zone (ITCZ) study, conducted in the Panama Canal Zone in July 1977 is reported. The ITCZ program had the objective to study the meteorology and air chemistry to determine, if possible, the magnitude of injection of tropospheric air into the stratosphere in the ITCZ. WSU was responsible for two phases of the air chemistry program for the ITCZ study: (1) the collection of whole-air samples from ground level to 13.7 km using a Learjet as a sampling platform, and the analysis of the samples for selected halocarbons, C2 hydrocarbons, N2O, and SF6; and (2) the analysis for selected halocarbon species and N2O of low pressure whole-air samples, collected between 13.7 km and 21.3 km by a U-2 aircraft. The report is divided into separate sections describing the Learjet and the U-2 sampling methods, analytical methods, and results. Complete data tables for all samples analyzed are given.

Cronn, D. R.↗

Pressure sensing of the atmosphere by solar occultation - An application to remote sensing of atmospheric minor gases

The simultaneous inference of pressure and gas concentration in a remote-sensing experiment will increase the accuracy of inverted gas concentrations and minimize the dependence of the experiment on pressure or mass-path error resulting from use of climatological pressure data, satellite ephemeris, and instrument pointing accuracy. A technique for obtaining tangent-point pressure information needed for inversion of gas concentration in an IR solar occultation experiment is described. By measuring IR absorption in bands of atmospheric CO2 (e.g., 2.0, 2.7, or 4.3 microns) pressure values for each layer (2 km or less in the vertical) of the atmosphere can be obtained with rms errors of less than 3%.

Park, J. H.↗

Monte Carlo solution of Boltzmann equation for a simple model of highly nonequilibrium diatomic gases - Translational rotational energy relaxation

Theoretical results pertaining to internally excited translational-rotational energy relaxation in a spatially uniform diatomic gas far removed from solid boundaries are obtained by solving the Boltzmann equation by means of the Monte Carlo direct simulation method. The analysis is based on calculations involving three different types of initial conditions: equilibrium, nonequilibrium-equipartition (i.e., equipartition is satisfied, but the distributions are perturbed), and nonequilibrium-nonequipartition (i.e., both equipartition and the distributions are perturbed). Results of monatomic-gas simulations are also included to facilitate comparisons with the coupled translational-rotational relaxation simulations, and some simulations for a normal shock-wave structure are briefly examined. The results show that: (1) single-step transitions are the significant mechanisms of intermodal energy transfer; (2) translational-rotational transitions are coupled most efficiently for low-lying states of rotationally excited molecules and least efficiently for highly rotationally excited molecules; and (3) relaxation occurs via a successive set of distributions that are not Maxwell-Boltzmann (nonlocal Maxwellian).

Yoshikawa, K. K.↗

Solar gases in meteorites - The origin of chondrites and C1 carbonaceous chondrites

Evidence suggesting that chondritic meteorites broke off from parent bodies in earth-crossing orbits is considered. It is suggested that ordinary chondrites have an asteroidal origin, and the possibility that C1 chondrites have a cometary origin is examined. Indications of heavy shock and reheating among L and H chondrites provides support for an asteroidal origin, while the Apollo and Amor objects are too small to be unfragmented asteroids, as proposed in the Anders theory of the origin of gas-rich meteorites. Events associated with the megaregolith are discussed in the framework of the proposed cometary origin of C1 chondrites.

Heymann, D.↗

Comparisons between observed and predicted cosmogenic noble gases in lunar samples

Comparisons are made between cosmogenic production rates and isotopic ratios predicted on the basis of nuclear systematics with those observed in well-documented lunar samples. Although some significant differences are found, the agreement in general is surprisingly good. The predicted production rates for Ar-38 and Xe-126 agree reasonably well with observation but the predicted rate for Ne-21 appears to be too high; in most cases the predicted rate for Kr-83 agrees to within 50%, although some larger differences are apparent. There are some prominent cases in which predicted isotopic compositons differ from observation: Kr-78/Kr-83 trends in the wrong sense with the Zr/Sr ratio; Xe-124/Xe-126 is too large by about 13%; Xe-128/Xe-126 is too small by about 6%; Xe-130/Xe-126 is too low by 30-40%.

Hohenberg, C. M.↗

Electron impact on atmospheric gases. III - Spatial yield spectra for N2

Spatial yield spectra have been calculated for electron energy degradation into molecular nitrogen gas using a Monte Carlo method for 0.1- to 5.0-keV incident electrons. The spectra contain the spatial yield information about the electron degradation process and can be employed to calculate a 'yield' for any inelastic state at any position in the medium. Because of the spectrum's useful nature and simple characteristics, the three-variable spatial yield spectrum U(E, z, E sub zero) is analytically represented as well. This analytic form can then be easily applied to atmospheric and laboratory problems dealing with energetic electron degradation.

Jackman, C. H.↗

Isotopic anomalies of noble gases in meteorites and their origins. III - LL-chondrites

Nine LL-chondrites were studied by selective etching to characterize the noble gas components in three mineral fractions: HF-HCl-solubles, chromite and carbon. The Ne-20/Ar-36 ratio is considered, noting that chondrites of different petrologic types cannot all be derived from the same volatile rich ancestor, but must have formed over a range of temperatures, with correspondingly different volatile contents. Variations in the carbonaceous chondrite fission (CCFXe) component in LL3, LL5, and LL6 chondrites are discussed, noting that if CCFXe comes from a supernova, then its distribution in LL-chondrites requires three presolar carrier minerals of the right solubility properties, containing three different xenon components. However, if CCFXe comes from fission of a volatile superheavy element, then its decrease from LL3 to LL6 can be attributed to less complete condensation from the solar nebula. Finally, the three types of primordial xenon components which occur in different minerals of the same meteorite are described.

Alaerts, L.↗