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At least 1,315 records · Page 73

FY16 Safeguards Technology Cart-Portable Mass Spectrometer Project Final Report

The Oak Ridge National Laboratory project for the Next Generation Safeguards Initiative Safeguards Technology Development Subprogram has been involved in the development of a cart portable mass spectrometer based on a Thermo ITQ ion trap mass spectrometer (referred to simply as the ITQ) for the field analysis of 235U/238U ratios in UF6. A recent discovery of the project was that combining CO2 with UF6 and introducing the mixture to the mass spectrometer (MS) appeared to increase the ionization efficiency and, thus, reduce the amount of UF6 needed for an analysis while also reducing the corrosive effects of the sample. However, initial experimentation indicated that mixing parameters should be closely controlled to ensure reproducible results. To this end, a sample manifold (SM) that would ensure the precise mixing of UF6 and CO2 was designed and constructed. A number of experiments were outlined and conducted to determine optimum MS and SM conditions which would provide the most stable isotope ratio analysis. The principal objective of the project was to provide a retrofit ITQ mass spectrometer operating with a SM capable of achieving a variation in precision of less than 1% over 1 hour of sampling. This goal was achieved by project end with a variation in precision of 0.5 to 0.8% over 1 hour of sampling.

47 OTHER INSTRUMENTATION↗

Technology Enabling Ultra High Concentration Multi-Junction Cells. Final report

The project goal is to enable multijunction cells to operate at greater than 2000× suns intensity with efficiency above forty percent. To achieve this goal the recipients have developed a robust high-bandgap tunnel junction, reduce series resistance, and integrated a practical heat dissipation scheme.

14 SOLAR ENERGY↗

Final Report for the Restart of the Waste Characterization, Reduction and Repackaging Facility (WCRRF) Contractor Readiness Assessment (CRA)

The Los Alamos National Laboratory (LANL or Laboratory) Contractor Readiness Assessment (CRA) required for restart of the Technical Area (TA) 50 Waste Characterization, Reduction, and Repackaging Facility (WCRRF) for remediated nitrate salt (RNS) waste operations was performed in compliance with the requirements of Department of Energy (DOE) Order (O) 425.1D, Verification of Readiness to Start Up or Restart Nuclear Facilities, and LANL procedure FSD-115-001, Verification of Readiness to Start Up or Restart LANL Nuclear Facilities, Activities, and Operations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Renewable Firming EnergyFarm Final Report

The American Recovery and Reinvestment Act (ARRA) of 2009 (Recovery Act) provided the U.S. Department of Energy (DOE) with funds to modernize the electric power grid. One program under this initiative is the Smart Grid Demonstration program (SGDP). The SGDP mandate is to demonstrate how a suite of existing and emerging smart grid technologies can be innovatively applied and integrated to prove technical, operational, and business-model feasibility. Primus Power is a provider of low cost, long life and long duration energy storage systems. The Company’s flow batteries are shipping to US and international microgrid, utility, military, commercial and industrial customers. Primus Power’s EnergyPod® is a modular battery system for grid scale applications available in configurations ranging from 25 kW to more than 25 MW. The EnergyPod provides nameplate power for 5 hours. This long duration unlocks economic benefits on both sides of the electric meter. It allows commercial and industrial customers to shift low cost electricity purchased at night to offset afternoon electrical peaks to reduce utility demand charges. It also allows utilities to economically reduce power peaks and defer costly upgrades to distribution infrastructure. An EnergyPod contains one or more EnergyCells-a highly engineered flow battery core made from low cost, readily available materials. An EnergyCell includes a membrane-free stack of titanium electrodes located above a novel liquid electrolyte management system. This patented design enables reliable, low maintenance operation for decades. It is safe and robust, featuring non-flammable aqueous electrolyte, sophisticated fault detection and built-in secondary containment. Unlike Li Ion batteries, the EnergyCell is not susceptible to thermal runaway. This cooperative agreement project was started in Feb 2010. The objectives of the project are: 1. Trigger rapid adoption of grid storage systems in the US by demonstrating a low cost, robust and flexible EnergyFarm®. 2. Accelerate adoption of renewable energy and enhance grid stability by firming the output of wind & solar farms. 3. Demonstrate improved grid asset utilization by storing energy during off-peak periods for dispatch during local load peaks. 4. Establish an advanced battery manufacturing industry in the U.S. 5. Reduce CO2 emissions from utilities. This report summarizes the key milestones, data, results and lessons learned from the project. The desired goals and benefits of the cooperative agreement with the DOE have all been achieved. The project has contributed to reducing power costs, accelerating adoption of renewable energy resources, reducing greenhouse gas emissions and establishing advanced battery manufacturing in the U.S. The Recovery Act funds provided thru the DOE have been leveraged multiple times by additional private equity investment. Primus Power continues to ship low cost, long life and long duration EnergyPod® flow battery systems to utilities, commercial/industrial, microgrid and data center customers. After the conclusion of this project, Primus Power has modified the EnergyPod® design to optimize around energy performance. Primus Power has moved to a prefabricated enclosure instead of multiple EnergyCells in a container. This lowers capital and maintenance costs and can optimize site design. Utilities are starting to adopt energy storage for a variety of functions. The market will grow as the technology is proven and profitable applications expand.

25 ENERGY STORAGE↗

Final Report: Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation Applications (2012-2016)

This report summarizes project activities for Strategic Analysis, Inc. (SA) Contract Number DE-EE0005236 to the U.S. Department of Energy titled “Transportation Fuel Cell System Cost Assessment”. The project defined and projected the mass production costs of direct hydrogen Proton Exchange Membrane fuel cell power systems for light-duty vehicles (automobiles) and 40-foot transit buses. In each year of the five-year contract, the fuel cell power system designs and cost projections were updated to reflect technology advances. System schematics, design assumptions, manufacturing assumptions, and cost results are presented.

08 HYDROGEN↗

Final Report: Hydrogen Production Pathways Cost Analysis (2013 – 2016)

This report summarizes work conducted under a three year Department of Energy (DOE) funded project to Strategic Analysis, Inc. (SA) to analyze multiple hydrogen (H 2 ) production technologies and project their corresponding levelized production cost of H 2 . The analysis was conducted using the H2A Hydrogen Analysis Tool developed by the DOE and National Renewable Energy Laboratory (NREL). The project was led by SA but conducted in close collaboration with the NREL and Argonne National Laboratory (ANL). In-depth techno-economic analysis (TEA) of five different H 2 production methods was conducted. These TEAs developed projections for capital costs, fuel/feedstock usage, energy usage, indirect capital costs, land usage, labor requirements, and other parameters, for each H 2 production pathway, and use the resulting cost and system parameters as inputs into the H2A discounted cash flow model to project the production cost of H 2 ($/kgH 2 ). Five technologies were analyzed as part of the project and are summarized in this report: Proton Exchange Membrane technology (PEM), High temperature solid oxide electrolysis cell technology (SOEC), Dark fermentation of biomass for H 2 production, H 2 production via Monolithic Piston-Type Reactors with rapid swing reforming and regeneration reactions, and Reformer-Electrolyzer-Purifier (REP) technology developed by Fuel Cell Energy, Inc. (FCE).

08 HYDROGEN↗

MPT_DOE Final Report 12-15-16 rev1

The goal of this project was to achieve breakthrough thermal efficiency on a light duty passenger car engine, with minimal impact to emissions. The enabling technology or technologies were to be relatively low cost and integrateable into existing production processes. Through the use of Turbulent Jet Ignition (TJI), an enabling technology for ultra-lean engine operation, the project team was able to meet or exceed all technical goals of this program.

33 ADVANCED PROPULSION SYSTEMS↗

Final Report - Advanced High Energy Li-Ion Cell for PHEV and EV Applications

Lithium Ion Battery (LIB) technology’s potential to enable a commercially viable high energy density is the key to a lower $/Wh, thereby a low cost battery. The design of a LIB with high energy, high power, safety and long life is a challenge that requires cell design from the ground up and synergy between all components. 3M Company (3M), the Recipient, led by its Principal Investigator, Jagat Singh, pursued this challenging task of a LIB by ‘teaming’ key commercial businesses [General Motors (GM), Umicore and Iontensity] and labs [Army Research Laboratory (ARL) and Lawrence Berkley National Laboratory (LBNL)]. The technology from each team member was complimentary and a close working relationship spanning the value chain drove productivity.The completion of this project is a significant step towards more energy efficient and environmentally friendly vehicles, making America less dependent on imported oil.

25 ENERGY STORAGE↗

STI/DOE Solar decathlon- Final Report

Team Orange successfully designed and constructed a house driven by new design concepts and technical innovations that harmonize with Southern California’s lifestyle and respect its cultural heritage. The basic elements of our 2015 proposal can be summarized as follows: Increased emphasis on the passive solar design concept, with a visually stimulating design that enhances the Southern California lifestyle; Use of design and construction techniques to create a market-ready home for an efficient and affordable lifestyle; Integrated use of new technology to create a behavior-adaptive smart home; A zero net energy house complying with the Living Building philosophy; and compliance with all DOE Solar Decathlon requirements.

14 SOLAR ENERGY↗

Sacramento State Solar Decathlon 2015: Research Performance Final Report

Our primary objective is to design and build a 600-1000sf home that produces more energy than it consumes and to showcase this home at the 2015 Solar Decathlon in Irvine, CA. Further objectives are to educate consumers and home builders, alike (including K-12 students – the industry’s future consumers), inspire a shift towards the adoption of net-zero energy solutions in residential building, and to be a leader in the transformation of the California residential marketplace to a net-zero standard. Our specific mission statement for this project is as follows: Solar NEST strives to discover the future of sustainable, energy-efficient housing and deliver these innovations to home buyers at an affordable price. To make substantial improvements to conventional building methods with regard to aesthetics, performance, and affordability. Through our efforts, we aspire to bridge the gap between ‘what is’ and ‘what is possible’ by providing unique, elegant simplicity.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Behavioral Responses Of Fish To A Current-Based Hydrokinetic Turbine Under Mutlipe Operational Conditions: Final Report

There is significant interest in the interaction of aquatic organisms with current-based marine and hydrokinetic (MHK) technologies. Determining the potential impacts of MHK devices on fish behavior is critical to addressing the environmental concerns that could act as barriers to the permitting and deployment of MHK devices. To address these concerns, we use field monitoring and fish behavior models to characterize the behavioral responses of fish to MHK turbines and infer potential stimuli that may have elicited the observed behavioral changes.

60 APPLIED LIFE SCIENCES↗

Shock-Driven Hydrodynamic Instability Growth Near Phase Boundaries and Material Property Transitions: Final Report

Activities for this grant included: 1) Development of dynamic impact experiments to probe strength and phase transition influence on dynamic deformation, 2) development of modern strength and phase aware simulation capabilities, 3) and post-processing of experimental data with simulation and closed form analytical techniques. Two different dynamic experiments were developed to probe material strengths in solid metals (largely copper and iron in this effort). In the first experiment a flyer plate impacts a flat target with an opposite rippled surface that is partially supported by a weaker window material. Post mortem analysis of the target sample showed a strong and repeatable residual plastic deformation dependence on grain orientation. Yield strengths for strain rates near 10 5 s -1 and plastic strains near ~50% were estimated to be around 180 to 240 MPa, varying in this range with grain orientation. Unfortunately dynamic real-time measurements were difficult with this setup due to diagnostic laser scattering; hence, an additional experimental setup was developed to complement these results. In the second set of experiments a rippled surface was ablated by a controlled laser pulsed, which launched a rippled shock front to an opposite initially flat diagnostic surface that was monitored in real-time with spatially resolved velocimetry techniques, e.g., line VISAR in addition to Transient Imaging Displacement Interferometry (TIDI) displacement measurements. This setup limited the displacements at the diagnostic surface to a reasonable level for TIDI measurements (~ less than one micrometer). These experiments coupled with analytical and numerical solutions provided evidence that viscous and elastic deviatoric strength affect shock front perturbation evolution in clearly different ways. Particularly, normalized shock front perturbation amplitudes evolve with viscosity (η) and perturbation wavelength (λ) as η/λ, such that increasing viscosity (or decreasing the initial wavelength) delays the perturbation decay. Conversely our experimental data, analysis and simulations show that for materials with elastic yield strength Y the normalized shock perturbation amplitude evolves with Yλ/A 0 , which shows wavelength increases have the opposite effect as in viscous materials and perturbation decay is also dependent on initial amplitude A 0 (viscous materials are independent of this parameter). Materials where strength had clear strain rate dependence, e.g., such as a PTW material law, behaved similarly to materials with only an effective yield stress (elastic-perfectly plastic) in the shock front perturbation studies obeying a Y eff λA 0 relationship where Y eff was a constant (near ~400 MPa for Cu for strain rates around 10 6 s -1 ). Magnitude changes in strain rate would increase Y eff as would be expected from the PTW behavior, but small perturbations (typical of regions behind the shock front) near a mean had little effect. Additional work based on simulations showed that phase transformation kinetics can affect the behavior of the perturbed shock front as well as the evolution of the RM-like instability that develops due to the imprint of the perturbed shock front on the initially flat surface as the shock breaks out.

36 MATERIALS SCIENCE↗

Final Report on Developing Microstructure-Property Correlation in Reactor Materials using in situ High-Energy X-rays

This report provides a summary of research activities on understanding microstructure – property correlation in reactor materials using in situ high-energy X-rays. The report is a Level 2 deliverable in FY16 (M2CA-13-IL-AN_-0403-0111), under the Work Package CA-13-IL-AN_- 0403-01, “Microstructure-Property Correlation in Reactor Materials using in situ High Energy Xrays”, as part of the DOE-NE NEET Program. The objective of this project is to demonstrate the application of in situ high energy X-ray measurements of nuclear reactor materials under thermal-mechanical loading, to understand their microstructure-property relationships. The gained knowledge is expected to enable accurate predictions of mechanical performance of these materials subjected to extreme environments, and to further facilitate development of advanced reactor materials. The report provides detailed description of the in situ X-ray Radiated Materials (iRadMat) apparatus designed to interface with a servo-hydraulic load frame at beamline 1-ID at the Advanced Photon Source. This new capability allows in situ studies of radioactive specimens subject to thermal-mechanical loading using a suite of high-energy X-ray scattering and imaging techniques. We conducted several case studies using the iRadMat to obtain a better understanding of deformation and fracture mechanisms of irradiated materials. In situ X-ray measurements on neutron-irradiated pure metal and model alloy and several representative reactor materials, e.g. pure Fe, Fe-9Cr model alloy, 316 SS, HT-UPS, and duplex cast austenitic stainless steels (CASS) CF-8 were performed under tensile loading at temperatures of 20-400°C in vacuum. A combination of wide-angle X-ray scattering (WAXS), small-angle X-ray scattering (SAXS), and imaging techniques were utilized to interrogate microstructure at different length scales in real time while the specimen was subject to thermal-mechanical loading. In addition, in situ X-ray studies were complemented and benchmarked by ex situ characterization using advanced electron microscopy, atom probe tomography (APT) and micro/nano-indentation. The report presented in situ tensile test results on neutron-irradiated pure Fe, Fe-9Cr model alloy, 316 SS and CASS CF-8. These in situ experiments demonstrate the broad applications of the new capability in understanding several outstanding issues related to irradiated materials.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Open-Source Integrated Design-Analysis Environment for Nuclear Energy Advanced Modeling & Simulation Phase I Final Report

Our proposal described an approach for addressing the barriers of advanced modeling and simulation (M&S) adoption by the nuclear energy industry. This will be achieved by developing a state-of-the-art, open-source integrated design-analysis environment (IDAE) to work on a range of nuclear energy applications, while leveraging best-in-class software created through millions of investment dollars from the Department of Energy (DOE) Office for Nuclear Energy (NE) and from several other funding agencies.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A detailed study of CO 2 -brine capillary trapping mechanisms as applied to geologic carbon storage. Final Report

The proposed research focuses on improved fundamental understanding of the efficiency of physical trapping mechanisms, and as such will provide the basis for subsequent upscaling efforts. The overarching hypothesis of the proposed research is that capillary pressure plays a significant role in capillary trapping of CO 2 , especially during the water imbibition stage of the sequestration process. We posit that the relevant physics of the sequestration process is more complex than is currently captured in relative permeability models, which are often based on so-called trapping models to represent relative permeability hysteresis. Our 4 main questions, guiding the 4 main tasks of the proposed research, are as follows: (1) What is the morphology of capillary trapped CO 2 at the pore scale as a function of temperature, pressure, brine concentration, interfacial tension, and pore-space morphology under injection and subsequent imbibition? (2) Is it possible to describe the capillary trapping process using formation-dependent, but otherwise unique continuum-scale functions in permeability-capillary pressure, interfacial area and saturation space, rather than hysteretic functions in permeability-saturation or capillary pressure-saturation space? (3) How do continuum-scale relationships between kr-Pc-S-Anw developed based on pore-scale observations compare with traditional models incorporating relative permeability hysteresis (such as Land’s and other models,) and with observations at the core (5-10cm) scale? (4) How can trapped CO 2 volume be optimized via engineered injection and sweep strategies, and as a function of formation type (incl. heterogeneity)?

54 ENVIRONMENTAL SCIENCES↗

Catalytic Depolymerization and Upgrading of Lignin for Vanillin Production: Cooperative Research and Development Final Report, CRADA Number CRD-14-545

Examine catalytic conversion of lignin using multifunctional catalysts that are able to depolymerize and oxidize lignin to a vanillin-rich stream. Examine separation processes for isolation of vanillin from product mixtures. Conduct preliminary experiments to determine if deconstructed lignin streams can be metabolized by Pseudomonas putida.

09 BIOMASS FUELS↗

North American Board of Certified Energy Practitioners Final Report

The U.S. DOE’s Office of EERE National Solar Energy Technology Program (SETP) calls for a “National Accreditation and Certification Program for Installation and Acceptance of Photovoltaic Systems.” A near-term goal listed in the U.S. Photovoltaic Industry’s Roadmap, 2000 - 2020 is to work to establish standards, codes, and certifications which are essential for consumer protection and acceptance as part of the goal of building toward a viable future PV industry. This program paves the way for a voluntary national certification program for PV system practitioners and installers, initiation of the first steps toward certification of hardware, and reinforcement of all five of the technical objectives in the Systems category of SETPs Multi-Year technical Plan. Through this project, NABCEP will direct the continued initiation of and sustained implementation and administration of the NABCEP Solar PV Installer Certification Program (hereafter the “Program”). The NABCEP Program is a national, voluntary program designed to provide certification for those PV installers who demonstrate the requisite skills, abilities and knowledge typically required to install and maintain PV systems. The core document upon which the Program was developed and upon which the national exam is based, is referred to as the (Program) Task Analysis. It is a thorough descriptive document containing specific psychomotor and cognitive tasks for the purposes of identifying the types of training/assessment methods that apply. Psychomotor skills require measuring, assembling, fastening and related activities. Cognitive skills require knowledge processing, decision-making and computations. NABCEP effectively evaluates an applicant’s psychomotor skills through review of a candidate’s PV installations and hands-on training received. NABCEP evaluates the candidate’s cognitive skills through administration of its national Program exam. By first qualifying for and then obtaining the required passing score, NABCEP certificants receive an accreditation that upholds NABCEP’s standards of quality, compliance to applicable codes and safety in PV installation. The objectives of DOE’s National Solar Energy Technology Program (SETP) are intrinsic to NABCEP. As detailed in the PV Roadmap, the lifespan of a PV system is a function of reliability and value. PV system reliability is directly dependent upon the quality of components and, design, installation and maintenance of a system. The latter three are all core components of the NABCEP Task Analysis - accordingly NABCEP certified installers will be instrumental in improving reliability of systems through safe, code and manufacturer-compliant installation and necessary post-installation maintenance of PV systems. This will have the effect of ensuring and increasing the performance of installed systems and, as consumers realize the benefits of well-installed and maintained systems, increased demand will follow and manufacturers will respond - supporting further growth in the PV industry. Furthermore, as more NABCEP certified installers perform these installations and maintenance competently, additional installations (whole system re-installations) and unnecessary repairs can be avoided. This will drive down system costs. This combined with creation/enhancement of the DE-FG36-04GO14348/005 NABCEP Central Data Base of Installers – providing consumers with installation/maintenance service options will further reduce system costs and help meet the overall goal of reducing life cycle costs. As consumers receive more value from PV systems which are providing longer, trouble free, renewable energy, they will join the ranks of professionals and enthusiasts calling for reduced technological barriers to installation (particularly for grid-tied systems). States and utilities will react to pressure and begin easing onerous net-metering and other technological restrictions. The benefits of NABCEP’s Program will be evident to consumers, manufacturers, distributors, state energy officials and solar academic institutions. Consumers benefit through increased system performance and reduced costs. Manufacturers of PV and balance of system components as well as distributors support and benefit from NABCEP because of assurances that systems are installed in accordance to code (i.e., NEC) and their specifications, resulting in longer life. Collaborators including state energy officials (i.e., New York State Energy Research and Development Authority) benefit by knowing that rebate funds are spent on systems whose benefits will far exceed system costs. Program Objectives The improvements and advantages offered by a national voluntary certification program can only expand the horizons for photovoltaic applications.

14 SOLAR ENERGY↗

Team West Virginia/Rome Final Report

Overall, the team, West Virginia University (WVU) and University of Rome Tor Vergata (UTV), has a goal of building an attractive, low-cost, energy-efficient solar-powered home that represents both the West Virginian and Italian cultures.

14 SOLAR ENERGY↗