Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Environmental”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,315 records · Page 73
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Environmentally Friendly Foundry Molding and Core Sands

The paper describes the current state of knowledge in a field where change has been driven in foundry molding sand practice due to the increasing requirements regarding environmental protection. These trends must take into account not only the technological quality and economics of their production process, but also the increasingly stringent requirements related to environmental protection. As part of this study, tests were performed in relation to reducing the toxicity of current molding sands with organic binders, so as to develop new organic binders for foundry practice. Molding sands with binders having various contents of furfuryl alcohol were tested. It was shown that reducing the total furfuryl alcohol content in the binder results in lower strength properties of the molding sands in practice. It was also suggested to replace the use of a furfuryl binder with one based on alkyd resin. The final stage of the study was to demonstrate the desirability of using biomaterials as a component of organic binders for foundry molding sands. Compositions: typical synthetic resins and biodegradable materials were designed as binders to improve the quality of the organic binders used with molding sands.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Reducing the environmental impact of road and rail vehicles

Methods have been developed to measure in situ the dynamic impact of both road and rail vehicles on the infrastructure and the environment. The resulting data sets have been analysed to quantify the environmental impacts in a transparent manner across both modes. A primary concern is that a small number of vehicles are being operated outside safe or regulatory limits which can have a disproportionate large impact. The analysis enables the various impacts to be ranked across both modes so enabling one to discern the benefits of intermodal transport. The impact of various policy options is considered and how to identify vehicles which can be classified as environmentally friendly. This would require European agreement as many heavy goods vehicle operate across country borders.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Strategic environmental assessment of energy planning tools. A study of Italian regions and provinces

SEA has been applied in different ways in EU energy and environmental planning instruments, because different member states have interpreted European Directive 2001/42/CE in a variety of ways. Italy, for example, has only recently completed the integration of the directive into its legislation, through a number of decrees which were approved between 2006 and 2010. As a result SEA practice in Italy is very fragmented, particularly with respect to energy planning, and needs to be steered towards homogeneous quality objectives. The aim of this paper is to study the quality of the SEA reports on the energy and environmental planning tools used by Italian regions and provinces. We study nine cases and use the methodology suggested by Fisher (2010) in his review of the quality of SEA. To be more precise, we integrate the views of external evaluators with those of a selection of the personnel directly involved in preparing the plans. Our results show that there are some differences in the quality scores given by the outsiders and insiders, although the two groups identified similar strengths and weaknesses in implementing SEA. - Highlights: • This is a comparative study on SEA report quality within Italian energy planning tools. • In Italy, the level of SEA implementation on energy planning is still poor. • External academic experts and internal officers assessed SEA reports' quality. • Outsiders and insiders unveil a similar judgement. • Most critical remarks concern consultation, monitoring measures, and follow-up.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Compensatory mitigation and screening rules in environmental impact assessment

Concerns about the effectiveness of environmental impact assessment (EIA) have prompted proposals to improve its performance by limiting the discretion of decision-makers in screening. To investigate whether such proposals are likely to generate the desired results, we conducted an evaluation of the screening process under the Australian government's EIA regime from its introduction on 16 July 2000 to 30 June 2013 (study period). Almost 1 in 5 ‘particular manner’ decisions—a type of screening decision under the regime—were found to be unlawful. The extent of non-compliance is explained on the basis of convenience. The department was required to assess a large number of projects under tight timeframes and with limited resources, while being pressured by proponents to allow their projects to bypass EIA. These pressures resulted in the development of an informal custom whereby the formal compensatory mitigation restrictions were frequently ignored. The results highlight the relative significance of formal and informal institutions in EIA. Formal EIA rules typically provide a mere outline of the process. The informal institutions adopted by administrators often have a greater influence on how the process operates and what it achieves. - Highlights: • Concerns about the effectiveness of environmental impact assessment (EIA) have prompted proposals to improve its performance by limiting the discretion of decision-makers in screening. • To investigate whether such proposals are likely to generate the desired results, we conducted an evaluation of the Australian government's screening process, looking at the extent of compliance with a formal prohibition on the consideration of compensatory mitigation. • Almost 1 in 5 ‘particular manner’ decisions – a type of screening decision under the regime – were found to be unlawful (with a 95% confidence interval of between 1:4 and 1:7) because of a failure to abide by the compensatory mitigation restrictions. For urban development actions, the ratio between lawful and unlawful particular manner decisions was worse than 1:1. • The extent of non-compliance is explained on the basis of convenience. Budget and interest group pressures resulted in the development of an informal custom whereby the formal compensatory mitigation restrictions were ignored. • The results highlight the relative significance of formal and informal institutions in EIA. Formal EIA rules typically provide a mere outline of the process. The informal institutions adopted by administrators often have a greater influence on how the process operates and what it achieves.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2016

Strategic Environmental Assessment practices in European small islands: Insights from Azores and Orkney islands

The literature concerning Strategic Environmental Assessment (SEA) often refers to the importance of context-specific approaches. However, there is a lack of systematised and consistent studies that enhance tailor-made SEA practices and procedures. Small islands are bounded units of study which may help explore SEA theory and practice in special territories. Small islands present particular features and unique values, such as, small size and population, geographic isolation, limited resources and vulnerable ecosystems. Hence, the main goal of this research was to profile SEA practices and procedures in European small islands and provide a background for future research aiming to improve context-specific SEA applications. To achieve this goal, an exploratory case study was developed using Azores (Portugal) and Orkney (Scotland) archipelagos. An analysis of the corresponding mainland was also carried out to contextualise both case studies. The data collection was achieved through a qualitative content analysis of 43 Environmental Reports. The research found that there is not an SEA context-specific approach used within these European small islands, including guidelines, assessment topics, assessment techniques, follow-up and stakeholders engagement. The debate concerning specific approaches to small islands must be re-focused on the enhancement of SEA capacity-building amongst different stakeholders (including decision-makers), on the development and implementation of collaborative approaches, and on the exchange of knowledge and experiences between small islands networks. - Highlights: • Reviewed the differences between the Portuguese and Scottish SEA system • Showed a low integration of SEA specific features in reports of European small islands • Provides background for future SEA research for small islands approaches.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Selection of suitable alternatives to reduce the environmental impact of road traffic noise using a fuzzy multi-criteria decision model

Road traffic noise is one of the most significant environmental impacts generated by transport systems. To this regard, the recent implementation of the European Environmental Noise Directive by Public Administrations of the European Union member countries has led to various noise action plans (NAPs) for reducing the noise exposure of EU inhabitants. Every country or administration is responsible for applying criteria based on their own experience or expert knowledge, but there is no regulated process for the prioritization of technical measures within these plans. This paper proposes a multi-criteria decision methodology for the selection of suitable alternatives against traffic noise in each of the road stretches included in the NAPs. The methodology first defines the main criteria and alternatives to be considered. Secondly, it determines the relative weights for the criteria and sub-criteria using the fuzzy extended analytical hierarchy process as applied to the results from an expert panel, thereby allowing expert knowledge to be captured in an automated way. A final step comprises the use of discrete multi-criteria analysis methods such as weighted sum, ELECTRE and TOPSIS, to rank the alternatives by suitability. To illustrate an application of the proposed methodology, this paper describes its implementation in a complex real case study: the selection of optimal technical solutions against traffic noise in the top priority road stretch included in the revision of the NAP of the regional road network in the province of Almeria (Spain).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Progressing quality control in environmental impact assessment beyond legislative compliance: An evaluation of the IEMA EIA Quality Mark certification scheme

The effectiveness of Environmental Impact Assessment (EIA) systems is contingent on a number of control mechanisms: procedural; judicial; evaluative; public and government agency; professional; and development aid agency. If we assume that procedural and judicial controls are guaranteed in developed EIA systems, then progressing effectiveness towards an acceptable level depends on improving the performance of other control mechanisms over time. These other control mechanisms are either absent, or are typically centrally controlled, requiring public finances; this we argue is an unpopular model in times of greater Government austerity. Here we evaluate a market-based mechanism for improving the performance of evaluative and professional control mechanisms, the UK Institute of Environmental Management and Assessments' EIA Quality Mark. We do this by defining dimensions of effectiveness for the purposes of our evaluation, and by identifying international examples of the approaches taken to delivering the other control measures to validate the approach taken in the EIA Quality Mark. We then evaluate the EIA Quality Mark, when used in combination with legal procedures and an active judiciary, against the effectiveness dimensions and use time-series analysis of registrant data to examine its ability to progress practice. We conclude that the EIA Quality Mark has merit as a model for a market-based mechanism, and may prove a more financially palatable approach for delivering effective EIA in mature systems in countries that lack centralised agency oversight. It may, therefore, be of particular interest to some Member States of the European Union for ensuring forthcoming certification requirements stemming from recent amendments to the EIA Directive. - Highlights: • Quality control mechanisms in EIA are identified. • Effectiveness of EIA is conceptualised for evaluation purposes. • The UK IEMA EIA Quality Mark is introduced as a market-based mechanism. • The EIA Quality Mark is found to progress quality in many, but not all, areas.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2017

Governance in Strategic Environmental Assessment: Lessons from the Portuguese practice

The analysis of governance in Strategic Environmental Assessment (SEA) can help understand why, whether and how strategic decision-making happens. Understanding the governance context is strategic to improve the role and capacity of SEA to stimulate, and legitimate decisions that integrate environmental issues and are sustainability driven. The objective of this paper is to discuss why governance is important in SEA. In the SEA literature governance is mostly addressed in silos (i.e. public participation or decisions transparency or accountability) rather than in an integrated way. In addition few authors adopt a strategic view to address the governance context within which SEA is used. In this paper we address the heuristics of governance in SEA based on theoretical and empirical evidence, suggesting how SEA may incorporate the governance dimension. First a review of the SEA literature in relation to governance sets the context to the analysis on how governance is approached in practice, based on 60 Portuguese SEA cases. This is followed by the presentation of an empirical SEA case conducted in Portugal to illustrate what, in our understanding, can be an example of good practice in considering governance in SEA. Final discussion reflects on the role of governance in SEA in promoting engagement, enabling collaborative action, learning processes and dialogues, concluding on the relevance of governance in creating development contexts that can deal with change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Streamlining or sidestepping? Political pressure to revise environmental licensing and EIA in Brazil

In the Anthropocene, governments are increasingly being forced to take action to minimize or reverse human impacts on the environment. One of the most widespread legal instruments to prevent negative impacts on the environment is Environmental Impact Assessment (EIA). Almost all countries have an EIA system in place aimed at mitigating the diverse impacts causing by development projects. A common drawback of such systems is that they are often ineffective and time-consuming, and are therefore frequently viewed by politicians as “in the way” of development. This is the case in Brazil, where EIA has had a very limited influence on decision-making and where environment reforms (e.g. the new Forest Code) have often been strongly influenced by powerful lobbies (e.g. agribusiness groups, industry actors, etc.) and conservative legislators. Continuing this trend, the most recent political developments have seen the proposal of a series of amendments aimed at “streamlining” the Brazilian EIA system. In this viewpoint, we provide an in depth analysis of the proposed changes, highlighting the serious consequences that would accompany the weakening of environmental licensing and EIA legislation in Brazil.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2017

Health impact assessment in environmental impact assessment in China: Status, practice and problems

In China, the environmental impact assessment (EIA) system has gradually developed into an integrated evaluation system, owing to continuous improvement on institutional framework, system infrastructure, technical methods and professionals training, since EIA was first introduced in 1979. Though health impact assessment (HIA) is a part of the EIA system, the development of HIA is so slow as to remain at the early developing stage. This research aims to understand the extent and main issues concerning “health considerations” under the context of EIA, in China. Through case study on 42 environmental impact statements, the results demonstrate that HIA was not implemented in most of the cases, and health issues were not even mentioned in more than half of these cases. Where HIA was implemented, various problems were revealed through this study, including lacks of systematic approaching tools, insufficient supporting data on health effects, ineffective public participation, limited health considerations on biophysics, and so forth. Nevertheless, these problems can be attributed to lacks of legal supports, systematic evaluation methods, knowledge on evaluation technologies, and professional training institutions for HIA in China. In order to improve HIA methodologies, technologies, and management, to perfect HIA evaluation system, and to enhance public participation system within HIA, some recommendations from institutional, technical, administrative, and managerial aspects were then proposed in this study. - Highlights: •The status and deficiencies of HIA in EIA in China were identified and evaluated. •There were great industrial differences for the implementation of HIA in EIA. •Public participation was not well executed within HIA in EIA.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Building rehabilitation versus demolition and new construction: Economic and environmental assessment

Since the end of the twentieth century, discussion on dwelling rehabilitation versus its demolition and new construction has been steadily increasing in intensity, which is especially due to the necessity for the regeneration of urban centres. However, rehabilitation is not always considered the most economical solution, and demolition and new construction may constitute a better option. In the present work, a multi-family building in Seville, Spain, is used as a case study. After having suffered damage from a construction failure, it is assessed for its complete rehabilitation. Defective maintenance has worsened the bad condition of the building. A model is proposed, from the project budget perspective, that allows the environmental (Ecological Footprint indicator) and the economic (project's bill of quantities) assessment of the recovery of the dwelling. In the case study, the rehabilitation Ecological Footprint and the project cost are 0.06 gha/m{sup 2} of floor area (457.22 EUR/m{sup 2}) and 0.14 gha/m{sup 2} (576.33 EUR/m{sup 2}) for a new building on the same plot, respectively. It can be deduced that, even with a severely damaged building, the repair and retrofit work incurs a lower economic and environmental impact than that of the total replacement with a new construction.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Land take and the effectiveness of project screening in Environmental Impact Assessment: Findings from an empirical study

Land take is emerging as a global environmental concern, and is particularly critical in intensively developed and land-scarce regions. This paper seeks to understand the effectiveness of the screening stage of Environmental Impact Assessment (EIA) in addressing land take. Screening is the stage where a decision is made as to whether an EIA is required for a project. In many jurisdictions, screening results in three pathways: full EIA directly, preliminary EIA only, or preliminary EIA followed by full EIA. We compared the land take of 217 projects triggering the different pathways in a study region in Italy over a 15-year time interval. Land take was quantified by overlaying the footprint of the projects with a land cover map. The results show that while more attention was given to projects with larger land take impacts overall, the cumulative land take from smaller projects not triggering full EIA was considerable (40% of overall land take). The case-by-case examination conducted through the preliminary EIA was found to work better for some project types (ski areas and small urban development), than for others (quarries). Our findings lead us to advocate improvements in current screening procedures to ensure that the land take impacts are quantified and made explicit in preliminary EIA reports. Our evidence-based approach to determining land take in EIA provides a compelling basis for understanding ways to improve EIA policies, guidance and practice. - Highlights: •We quantified the land take of 217 projects triggering different EIA screening pathways. •Projects that “fly under the radar” of full EIA caused 40% of the overall land take. •The case-by-case examination works better for some project types than others. •We recommend improvements in screening procedures to ensure that land take impacts are quantified.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Including health in environmental impact assessments of three mega transport projects in Sydney, Australia: A critical, institutional, analysis

This article details how health impacts came to be assessed in three mega, billion dollar, transport infrastructure projects, two road tunnels and one light rail, in Sydney Australia. The known health impacts of transport decisions include environmental, behavioural and social factors. EIA practice prioritises environmental risks, and there has been scant attention to understanding why this is persistently the case. Here we provide a critical theory lens, using critical realist methodology, to analyse empirical data collected through interviews and documents for the three cases. Our analysis focusses on EIA practice within its institutional context, building on ‘new institutional’ approaches to policy analysis that emphasise actors (the stakeholders involved in the EIA), structures (the ‘rules of the game’ that influence practice in systems), and power. We find that the various actors engaged in the EIAs principally to address particular goals that were pre-determined by the system in which they worked or belonged. Structurally, each EIA was undertaken as a compliance process relatively late in the planning process. Considering project options was not part of the EIA's purpose. Resources to undertake the EIAs were provided by those funding the projects (“the proponents”) and determined the types of issues to be considered. The full range of links between transport and health were not identified. Concerning power, health impacts were considered through inter-professional technical negotiation. The inability to engage in the fundamental options driving projects meant impacted communities questioned the validity of the EIA, and the health assessment within this. Our institutional analysis provides important knowledge about how the EIAs preferenced a focus on specific health risks to the detriment of the known broader determinants that shape the health impacts of transport.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Mining project's economic impact on local communities, as a social determinant of health: A documentary analysis of environmental impact statements

Australian mining developments cause indirect economic impacts on nearby communities leading to poor health and wellbeing of local residents. Economic instability is a recognised social determinant of health (SDoH); however, SDoHs are rarely considered adequately in Environmental Impact Assessments (EIAs). This research aimed to determine the extent economic impacts as a SDoH are considered in three Environmental Impact Statements (EISs) of mining projects in the New South Wales, Australia. We adopted an exploratory case study design following Yin (2012). Three cases in New South Wales, Australia, were purposively sampled as being of concern to the local community who had sought legal advice about the content of the EIS (although not necessarily for health reasons). Two were open cut mines: Watermark located in the Liverpool Plains and Warkworth Continuation in the Hunter Valley Region. The third is a comparative case – the underground Mandalong Southern Extension located in Lake Macquarie. We adapted a health-focused EIA coding framework to investigate how economic indicators as SDoH were explicitly mentioned in EISs and applied this to the three cases. Economic indicators as SDoH were rarely considered. There was a greater focus on population characteristics rather than the potential economic impacts of the mining projects on the communities. Causal association of economic determinants and health outcomes were insufficiently reported compared to best practice, and health data were not used to inform assessments. Despite two EISs – Warkworth Continuation and Watermark – associating some economic indicators to health outcomes, impacts were not adequately discussed when compared to the known literature on economic impacts of mines. Our findings show that the three EISs were inadequately utilised to determine economic impacts of mining projects on the health and wellbeing of local communities. The evidence base linking economic impacts of mines to health is underdeveloped, which compromises assessing the quality of economic coverage in EISs. EIA scoping should enable sufficient inclusion of broader determinants of health using appropriate methodology, and the economic-focused content of EISs should be subject to rigorous peer-review process to fully inform government approvals for projects. Our methods lend themselves to research in other contexts to investigate the quality of EIAs.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Sheep lymph-nodes as a biological indicator of environmental exposure to fluoro-edenite

A significantly increased incidence of pleural mesothelioma in Biancavilla (Sicily, Italy) has been attributed to exposure to fluoro-edenite (FE), a fibrous amphibole extracted from a local stone quarry. The lymph-nodes draining the pulmonary lobes of sheep grazing around the town were examined, to gain insights into fibre diffusion. The pasture areas of six sheep flocks lying about 3 km from Biancavilla were located using the global positioning system. The cranial tracheobronchial and one middle mediastinal lymph-node as well as four lung tissue samples were collected from 10 animals from each flock and from 10 control sheep for light and scanning electron microscopy (SEM) examination. The lymph-nodes from exposed sheep were enlarged and exhibited signs of anthracosis. Histologically, especially at the paracortical level, they showed lymph-follicle hyperplasia with large reactive cores and several macrophages (coniophages) containing grey-brownish particulate interspersed with elements with a fibril structure, forming aggregates of varying dimensions (coniophage nodules). Similar findings were detected in some peribronchiolar areas of the lung parenchyma. SEM examination showed that FE fibres measured 8–41 µm in length and 0.4–1.39 µm in diameter in both lymph-nodes and lung tissue. Monitoring of FE fibres in sheep lymph-nodes using appropriate techniques can help set up environmental pollution surveillance. - Highlights: • Lymph-nodes draining sheep lung were used to assess environmental fluoro-edenite exposure. • Monitoring fluoro-edenite fibres in sheep lung nodes can provide pollution surveillance. • Our findings document a risk of fluoro-edenite fibre inhalation a few kilometres from the source. • Sheep appear to be a valuable bioindicator species.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Low doses and non-targeted effects in environmental radiation protection; where are we now and where should we go?

The field of low dose radiobiology has advanced considerably in the last 30 years from small indications in the 1980's that all was not simple, to a paradigm shift which occurred during the 1990's, which severely dented the dose-driven models and DNA centric theories which had dominated until then. However while the science has evolved, the application of that science in environmental health protection has not. A reason for this appears to be the uncertainties regarding the shape of the low dose response curve, which lead regulators to adopt a precautionary approach to radiation protection. Radiation protection models assume a linear relationship between dose (i.e. energy deposition) and effect (in this case probability of an adverse DNA interaction leading to a mutation). This model does not consider non-targeted effects (NTE) such as bystander effects or delayed effects, which occur in progeny cells or offspring not directly receiving energy deposition from the dose. There is huge controversy concerning the role of NTE with some saying they reflect “biology” and that repair and homeostatic mechanisms sort out the apparent damage while others consider them to be a class of damage which increases the size of the target. One thing which has recently become apparent is that NTE may be very critical for modelling long-term effects at the level of the population rather than the individual. The issue is that NTE resulting from an acute high dose such as occurred after the A-bomb or Chernobyl occur in parallel with chronic effects induced by the continuing residual effects due to radiation dose decay. This means that if ambient radiation doses are measured for example 25 years after the Chernobyl accident, they only represent a portion of the dose effect because the contribution of NTE is not included. - Highlights: • This paper presents a new concept in Environmental Radiobiology, which could explain why effects are detected in Chernobyl and Fukushima wildlife at ambient doses which are very low. • We suggest that non-targeted effects such as genomic instability, lethal mutations and bystander signalling, contribute a persistent legacy dimension to the total measured effect. • This “historic dose” component needs to be incorporated into dose effect models in order to predict true levels of risk.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

5 G wireless telecommunications expansion: Public health and environmental implications

The popularity, widespread use and increasing dependency on wireless technologies has spawned a telecommunications industrial revolution with increasing public exposure to broader and higher frequencies of the electromagnetic spectrum to transmit data through a variety of devices and infrastructure. On the horizon, a new generation of even shorter high frequency 5G wavelengths is being proposed to power the Internet of Things (IoT). The IoT promises us convenient and easy lifestyles with a massive 5G interconnected telecommunications network, however, the expansion of broadband with shorter wavelength radiofrequency radiation highlights the concern that health and safety issues remain unknown. Controversy continues with regards to harm from current 2G, 3G and 4G wireless technologies. 5G technologies are far less studied for human or environmental effects. }It is argued that the addition of this added high frequency 5G radiation to an already complex mix of lower frequencies, will contribute to a negative public health outcome both from both physical and mental health perspectives. }Radiofrequency radiation (RF) is increasingly being recognized as a new form of environmental pollution. Like other common toxic exposures, the effects of radiofrequency electromagnetic radiation (RF EMR) will be problematic if not impossible to sort out epidemiologically as there no longer remains an unexposed control group. This is especially important considering these effects are likely magnified by synergistic toxic exposures and other common health risk behaviors. Effects can also be non-linear. Because this is the first generation to have cradle-to-grave lifespan exposure to this level of man-made microwave (RF EMR) radiofrequencies, it will be years or decades before the true health consequences are known. Precaution in the roll out of this new technology is strongly indicated. }This article will review relevant electromagnetic frequencies, exposure standards and current scientific literature on the health implications of 2G, 3G, 4G exposure, including some of the available literature on 5G frequencies. The question of what constitutes a public health issue will be raised, as well as the need for a precautionary approach in advancing new wireless technologies.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Concentrations of organophosphate flame retardants and plasticizers in urine from young children in Queensland, Australia and associations with environmental and behavioural factors

Highlights: • Eight OPFRs and eleven metabolites were measured in the urine of Australian kids. • Age was positively associated with BBOEP and negatively associated with BCIPP. • Mouthing activities were associated with higher concentrations of TBOEP, and TPHP. • Children living with window AC units had higher concentrations of BCIPHIPP and DBP. In recent years, the production and usage volumes of organophosphate flame retardants (OPFRs) has increased substantially. Certain OPFRs are suspected reproductive toxins, carcinogenic, and neurotoxic. Insufficient information is available on human exposure pathways to these chemicals, particularly in Australia. We aim to assess the association between OPFR concentrations in the urine of children to environmental and behavioural risk factors. Concentrations of eight OPFRs and eleven metabolites were measured in the urine of 51 children, aged 3–29 months, in Southeast Queensland, Australia and compared to their behavioural and environmental risk factor data obtained by an online questionnaire. Of the 11 OPFR metabolites analysed, 55% were frequently detected in the majority (> 80%) of samples. The most frequently detected metabolite was bis(1,3-dichloroisopropyl) phosphate (BDCIPP) (detected in 100% of samples), followed by 1-hydroxy-2-propyl bis(1-chloro-2-propyl) phosphate (BCIPHIPP) (96%), diphenyl phosphate (DPHP) (94%) and bis(1-chloroisopropyl) phosphate (BCIPP) (86%). In multivariable modelling, age was positively associated with concentrations of bis(2-butoxyethyl) phosphate (BBOEP) and negatively associated with concentrations of BCIPP and BCIPHIPP. Other non-age related factors, including vacuuming frequency, hand-washing frequency and presence and number of some electrical appliances in the home were also associated with concentrations of OPFR metabolites.

54 ENVIRONMENTAL SCIENCES↗