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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,315 records · Page 73
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Exploring the Electrochemical Stability Window of an All-Solid-State Composite Cathode via a Novel Operando Tender XPS Setup

All-solid-state batteries (ASSBs) have the potential to provide greater energy density than conventional batteries based on liquid electrolytes. Here, an operando ASSB cell setup for tender X-ray photoelectron spectroscopy (XPS) was developed, and the interface of a Ni-rich layered transition metal oxide cathode active material (CAM) and an Li 6 PS 5 Cl (LPSCl) solid electrolyte (SE) was evaluated during initial charge/discharge cycles. After validating the cell performance against a conventional pouch cell operated at high compression, intermittent galvanostatic cycling was performed, and XPS data were recorded as a function of state of charge (SOC). Upon the initial charge of the cell to ≈3.3 V Li , the LPSCl appears to decompose into LiCl, Li 3 PS 4 , and polysulfides, whose amount gradually increases with potential. Upon further charge, at a potential higher than ≈3.8 V Li , initially, present sulfate and sulfite impurities decompose, and at ≈74% SOC (corresponding to a cathode potential of ≈4.10 V Li ), surface reconstruction of the CAM particles due to lattice oxygen release is detected. In addition, at potentials beyond ≈4.6 V Li , a decrease of the S 1s counts of the sum of the LPSCl, the thiophosphate, and polysulfide species suggests the formation of elemental sulfur that is lost via sublimation into the vacuum chamber.

25 ENERGY STORAGE↗
DOE OSTI2016

A Practical Look at Assumptions and Constraints for Steady State Modeling of sCO2 Brayton Power Cycles

Modeling supercritical CO2 (sCO2) power cycles requires specification of system constraints and component performance metrics such as pressure losses and temperature limitations.? Differing assumptions made by the model designers may lead to significantly different results which are due to the assumptions and not to the underlying thermodynamics which characterize the cycle performance. As leaders in setting standards for techno-economic analyses, NETL and EPRI have collaborated to propose a set of practical modeling assumptions that can serve as a common baseline for both indirect and direct sCO2 power plant studies, allowing for more meaningful cycle comparisons. These include specifications for turbine inlet temperature (high temperature and pressure limitations), compressor inlet temperature and pressure (cooling limitations), heat exchanger effectiveness/temperature differentials and pressure drop, and full- and part-load turbine and compressor efficiencies.

Weiland, Nathan↗
DOE OSTI2016

A Practical Look at Assumptions and Constraints for Steady State Modeling of sCO2 Brayton Power Cycles

Modeling supercritical CO2 (sCO2) power cycles requires specification of system constraints and component performance metrics such as pressure losses and temperature limitations.? Differing assumptions made by the model designers may lead to significantly different results which are due to the assumptions and not to the underlying thermodynamics which characterize the cycle performance. As leaders in setting standards for techno-economic analyses, NETL and EPRI have collaborated to propose a set of practical modeling assumptions that can serve as a common baseline for both indirect and direct sCO2 power plant studies, allowing for more meaningful cycle comparisons. These include specifications for turbine inlet temperature (high temperature and pressure limitations), compressor inlet temperature and pressure (cooling limitations), heat exchanger effectiveness/temperature differentials and pressure drop, and full- and part-load turbine and compressor efficiencies.

Thimsen, David↗
DOE OSTI2017

Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

One method for the formation of nanofilms of materials, is Electrochemical atomic layer deposition (E-ALD), one atomic layer at a time. It uses the galvanic exchange of a less noble metal, deposited using underpotential deposition (UPD), to produce an atomic layer of a more noble element by reduction of its ions. This process is referred to as surface limited redox replacement and can be repeated in a cycle to grow thicker deposits. Previously, we performed it on nanoparticles and planar substrates. In the present report, E-ALD is applied for coating a submicron-sized powder substrate, making use of a new flow cell design. E-ALD is used to coat a Pd powder substrate with different thicknesses of Rh by exchanging it for Cu UPD. Furthermore, cyclic voltammetry and X-ray photoelectron spectroscopy indicate an increasing Rh coverage with increasing numbers of deposition cycles performed, in a manner consistent with the atomic layer deposition (ALD) mechanism. Cyclic voltammetry also indicated increased kinetics of H sorption and desorption in and out of the Pd powder with Rh present, relative to unmodified Pd.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Nitrogen-doped nanostructured porous carbon derived from monosodium glutamate for high-performance lithium sulfur battery

Highlights: N-doped porous carbon nanosheets were prepared by a low-cost carbonization approach. The product possesses a special micro/mesoporous structure with high surface area. The S/NPCN-800 exhibits excellent electrochemical cycling and rate performance. The enhancement is attributed to synergistic effect of hierarchical porous structure and N-doping. - Abstract: Carbon host materials play an important role in improving the electrochemical performances of lithium-sulfur batteries. In this work, we have successfully prepared nitrogen-doped porous carbon nanosheets (NPCN) by using low-cost raw materials (monosodium glutamate) via a facile carbonization approach without any activation process. The obtained NPCN-800 possesses a special micro/mesoporous structure, with a relatively high BET surface area and appropriate nitrogen doping. By employing the NPCN-800 as a reservoir to impregnate sulfur as the cathode material of lithium-sulfur batteries, the resulting sulfur/carbon composite with 65.5 wt% sulfur exhibits an initial discharge capacity of 1070 mAh g{sup −1} at 0.2 C and enhanced capacity retention of 680 mAh g{sup −1} after 150 cycles. Moreover, a capacity of 452 mAh g{sup −1} at 0.5 C is achieved over 200 cycles with 98.6% Coulombic efficiency. The superior electrochemical performance is attributed to the synergistic effect of the hierarchical porous structure (physisorption) and N-doping (chemisorption).

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS2005

A Streaming Language Implementation of the Discontinuous Galerkin Method

We present a Brook streaming language implementation of the 3-D discontinuous Galerkin method for compressible fluid flow on tetrahedral meshes. Efficient implementation of the discontinuous Galerkin method using the streaming model of computation introduces several algorithmic design challenges. Using a cycle-accurate simulator, performance characteristics have been obtained for the Stanford Merrimac stream processor. The current Merrimac design achieves 128 Gflops per chip and the desktop board is populated with 16 chips yielding a peak performance of 2 Teraflops. Total parts cost for the desktop board is less than $20K. Current cycle-accurate simulations for discretizations of the 3-D compressible flow equations yield approximately 40-50% of the peak performance of the Merrimac streaming processor chip. Ongoing work includes the assessment of the performance of the same algorithm on the 2 Teraflop desktop board with a target goal of achieving 1 Teraflop performance.

Barth, Timothy↗
DOE OSTI2022

Unraveling the Stable Cathode Electrolyte Interface in all Solid‐State Thin‐Film Battery Operating at 5 V

Abstract Spinel‐type LiNi 0.5 Mn 1.5 O 4 (LNMO) is one of the most promising 5 V‐class cathode materials for Li‐ion batteries that can achieve high energy density and low production costs. However, in liquid electrolyte cells, the high voltage causes continuous cell degradation through the oxidative decomposition of carbonate‐based liquid electrolytes. In contrast, some solid‐state electrolytes have a wide electrochemical stability range and can withstand the required oxidative potential. In this work, a thin‐film battery consisting of an LNMO cathode with a solid lithium phosphorus oxynitride (LiPON) electrolyte is tested and their interface before and after cycling is characterized. With Li metal as the anode, this system can deliver stable performance for 600 cycles with an average Coulombic efficiency >99%. Neutron depth profiling indicates a slight overlithiated layer at the interface prior to cycling, a result that is consistent with the excess charge capacity measured during the first cycle. Cryogenic electron microscopy further reveals intimate contact between LNMO and LiPON without noticeable structure and chemical composition evolution after extended cycling, demonstrating the superior stability of LiPON against a high voltage cathode. Consequently, design guidelines are proposed for interface engineering that can accelerate the commercialization of a high voltage cell with solid or liquid electrolytes.

25 ENERGY STORAGE↗
NASA NTRS1992

Validation test of advanced technology for IPV nickel-hydrogen flight cells: Update

Individual pressure vessel (IPV) nickel-hydrogen technology was advanced at NASA Lewis and under Lewis contracts with the intention of improving cycle life and performance. One advancement was to use 26 percent potassium hydroxide (KOH) electrolyte to improve cycle life. Another advancement was to modify the state-of-the-art cell design to eliminate identified failure modes. The modified design is referred to as the advanced design. A breakthrough in the low-earth-orbit (LEO) cycle life of IPV nickel-hydrogen cells has been previously reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3,500 cycles for cells containing 31 percent KOH. The boiler plate test results are in the process of being validated using flight hardware and real time LEO testing at the Naval Weapons Support Center (NWSC), Crane, Indiana under a NASA Lewis Contract. An advanced 125 Ah IPV nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, LEO spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent KOH electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are: extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion. The advanced cell design is in the process of being validated using real time LEO cycle life testing of NWSC, Crane, Indiana. An update of validation test results confirming this technology is presented.

Smithrick, John J.↗
NASA NTRS1992

Validation test of advanced technology for IPV nickel-hydrogen flight cells - Update

Individual pressure vessel (IPV) nickel-hydrogen technology was advanced at NASA Lewis and under Lewis contracts with the intention of improving cycle life and performance. One advancement was to use 26 percent potassium hydroxide (KOH) electrolyte to improve cycle life. Another advancement was to modify the state-of-the-art cell design to eliminate identified failure modes. The modified design is referred to as the advanced design. A breakthrough in the LEO cycle life of IPV nickel-hydrogen cells has been previously reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3,500 cycles for cells containing 31 percent KOH. The boiler plate test results are in the process of being validated using flight hardware and real time LEO testing. The primary function of the advanced cell is to store and deliver energy for long-term, LEO spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent KOH electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are: extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion.

Smithrick, John J.↗
DOE OSTI2015

High rate capacitive performance of single-walled carbon nanotube aerogels

Single-walled carbon nanotube (SWCNT) aerogels produced by critical-point-drying of wet-gel precursors exhibit unique properties, such as high surface-area-to-volume and strength-to-weight ratios. They are free-standing, are binder-free, and can be scaled to thicknesses of more than 1 mm. In this paper, we examine the electric double layer capacitive behavior of these materials using a common room temperature ionic liquid electrolyte, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-TFSI). Electrochemical performance is assessed through galvanostatic cycling, cyclic voltammetry and impedance spectroscopy. Results indicate stable capacitive performance over 10,000 cycles as well as an impressive performance at high charge and discharge rates, due to accessible pore networks and enhanced electronic and ionic conductivities of SWCNT aerogels. Finally, these materials can find applications in mechanically compressible and flexible supercapacitor devices with high power requirements.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Dynamic Model of a supercritical CO2 10MW Recompression Closed Brayton Cycle

This model of the 10MW recompression closed Brayton cycle (RCBC) was developed in conjunction with the DOE’s Supercritical Transformational Electric Power (STEP) project. A high-fidelity dynamic model was used extensively to study the dynamic characteristics of the cycle and develop the process control architecture and strategies for start-up and shutdown procedures. This version of the model has been simplified from the original version to be more accessible for a variety of applications and research. The controllers developed for the original model have been maintained for this version and tuned to give a similar performance to the original model. This model can be used to perform similar studies as those performed in Liese et al (2020). The overall cycle performance will not be identical but will perform similarly.

Controls,Power Cycles,Process Systems Engineering,↗
DOE OSTI2017

Flywheel Energy Storage - Dynamic Modeling

A flywheel energy storage systems (FESS) is suitable for high-power, low-energy content to deliver or absorb power in surges. This type of application is very suitable for frequency regulation in an electric grid. In addition, a modern FESS is built as a high-efficiency, high-speed motor/generator drive system that employs modern power electronics, therefore, the power quality of the grid-connected output is excellent. In addition, a FESS is very valuable to delivering ancillary services to the grid, and it can contribute reactive power compensation. Thus, a FESS can maintain high reliability in power systems by providing ride-through capability to the power system area while the rest of the generating fleet, which has a slower response in the power system, performs primary and secondary frequency response to the grid. A FESS has several advantages compared to a chemical-based energy storage (CBES) system, namely: it has high energy density and durability, and it can be cycled frequently without impacting performance. The response of FESS is faster than that of a CBES. Also, unlike some CBES, FESS has the same performance regardless of the number of cycles of charging/discharging performed throughout its lifetime.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1978

Effect of thermal barrier coatings on the performance of steam and water-cooled gas turbine/steam turbine combined cycle system

An analytical study was made of the performance of air, steam, and water-cooled gas-turbine/steam turbine combined-cycle systems with and without thermal-barrier coatings. For steam cooling, thermal barrier coatings permit an increase in the turbine inlet temperature from 1205 C (2200 F), resulting in an efficiency improvement of 1.9 percentage points. The maximum specific power improvement with thermal barriers is 32.4 percent, when the turbine inlet temperature is increased from 1425 C (2600 F) to 1675 C (3050 F) and the airfoil temperature is kept the same. For water cooling, the maximum efficiency improvement is 2.2 percentage points at a turbine inlet temperature of 1683 C (3062 F) and the maximum specific power improvement is 36.6 percent by increasing the turbine inlet temperature from 1425 C (2600 F) to 1730 C (3150 F) and keeping the airfoil temperatures the same. These improvements are greater than that obtained with combined cycles using air cooling at a turbine inlet temperature of 1205 C (2200 F). The large temperature differences across the thermal barriers at these high temperatures, however, indicate that thermal stresses may present obstacles to the use of coatings at high turbine inlet temperatures.

Nainiger, J. J.↗
DOE OSTI2013

Geothermal life cycle assessment - part 3

A set of key issues pertaining to the environmental performance of geothermal electric power have been addressed. They include: 1) greenhouse gas emissions (GHG) from geothermal facilities, 2) the use of supercritical carbon dioxide (scCO 2 ) as a geofluid for enhanced geothermal systems (EGS), 3) quantifying the impact of well field exploration on the life cycle of geothermal power, and finally 4) criteria pollutant emissions for geothermal and other electric power generation. A GHG emission rate (g/kWh) distribution as function of cumulative running capacity for California has been developed based on California and U. S. government data. The distribution is similar to a global distribution for compared geothermal technologies. A model has been developed to estimate life cycle energy of and CO 2 emissions from a coupled pair of coal and EGS plants, the latter of which is powered by scCO 2 captured from coal plant side. Depending on the CO 2 capture rate on the coal side and the CO 2 consumption rate on the EGS side, significant reductions in GHG emissions were computed when the combined system is compared to its conventional coal counterpart. In effect, EGS CO 2 consumption acts as a sequestration mechanism for the coal plant. The effects CO 2 emissions from the coupled system, prompt on the coal side and reservoir leakage on the EGS side, were considered as well as the subsequent decline of these emissions after entering the atmosphere over a time frame of 100 years. A model was also developed to provide better estimates of the impact of well field exploration on the life cycle performance of geothermal power production. The new estimates increase the overall life cycle metrics for the geothermal systems over those previously estimated. Finally, the GREET model has been updated to include the most recent criteria pollutant emissions for a range of renewable (including geothermal) and other power generating technologies.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1987

Heat pipe radiators for solar dynamic space power system heat rejection

The paper presents the results of a concept development study of heat rejection systems for Space Station solar dynamic power systems. The thermal performance and weights of each of the heat rejection subsystems have been addressed in detail, and critical technologies which require development tests and evaluation for successful demonstration were assessed and identified. Baseline and several alternate heat rejection system configurations and optimum designs were developed for both Brayton and Rankine cycles. The thermal performance, mass properties, assembly requirements, reliability, maintenance requirements, and life cycle costs were determined for each of the system configurations. Trade studies were performed on each configuration with respect to the heat pipe wall thickness and the amount of redundancy to determine the effects on system reliability, maintenance requirements, and life cycle costs. An optimum design was then selected for each configuration.

Gustafson, Eric↗
NASA NTRS1984

Computer simulation of the heavy-duty turbo-compounded diesel cycle for studies of engine efficiency and performance

Reductions in heat loss at appropriate points in the diesel engine which result in substantially increased exhaust enthalpy were shown. The concepts for this increased enthalpy are the turbocharged, turbocompounded diesel engine cycle. A computer simulation of the heavy duty turbocharged turbo-compounded diesel engine system was undertaken. This allows the definition of the tradeoffs which are associated with the introduction of ceramic materials in various parts of the total engine system, and the study of system optimization. The basic assumptions and the mathematical relationships used in the simulation of the model engine are described.

Assanis, D. N.↗
DOE OSTI2024

Heteroatom anchoring to enhance electrochemical reversibility for high-voltage P2-type oxide cathodes of sodium-ion batteries

P2-type cathode has received extensive attention due to its faster Na+ diffusion and a high theoretical capacity in sodium-ion batteries (SIBs). However, undesirable phase transformations have induced dramatic capacity decay of SIBs during the cycling process. In this study, heteroatom anchoring through Cu/Mg dual doping is introduced into P2-type Na 0.67 Ni 0.33 Mn 0.67 O 2 cathode to enhance high-voltage electrochemical reversibility and modulate interfacial Na + kinetics. Further, the as-prepared Na 0.67 Ni 0.23 Mg 0.05 Cu 0.05 Mn 0.67 O 2 exhibits an outstanding capacity retention (83.4% after 2000 cycles at 10C) and rate performance (73 mAh g -1 at 10C, accounting for 58.7% of that at 0.1 C) over the voltage range of 2.5–4.4 V. Intensive explorations further manifest that the modified mechanism of dual-ion doping strategy is attributed to the synergistic coupling effect of a substantial change in Na occupancy distribution and an increase in oxygen vacancy buffer. Thus, the optimized cathode expedites Na + diffusion and reduces detrimental phase transformation, which favors high-rate performance and long-term cycling stability. This study develops a route to rationally design high-voltage cathode materials for SIBs.

25 ENERGY STORAGE↗