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At least 1,297 records · Page 72

Modeling Two-Phase Flow and Vapor Cycles Using the Generalized Fluid System Simulation Program

This work presents three new applications for the general purpose fluid network solver code GFSSP developed at NASA's Marshall Space Flight Center: (1) cooling tower, (2) vapor-compression refrigeration system, and (3) vapor-expansion power generation system. These systems are widely used across engineering disciplines in a variety of energy systems, and these models expand the capabilities and the use of GFSSP to include fluids and features that are not part of its present set of provided examples. GFSSP provides pressure, temperature, and species concentrations at designated locations, or nodes, within a fluid network based on a finite volume formulation of thermodynamics and conservation laws. This paper describes the theoretical basis for the construction of the models, their implementation in the current GFSSP modeling system, and a brief evaluation of the usefulness of the model results, as well as their applicability toward a broader spectrum of analytical problems in both university teaching and engineering research.

Smith, Amanda D.↗

Characterization of a Carbon Nanotube Field Emission Electron Gun for the VAPoR Miniaturized Pyrolysis-Time-of-Flight Mass Spectrometer

We are developing the VAPoR (Volatile Analysis by Pyrolysis of Regolith) instrument towards studying soil composition, volatiles, and trapped noble gases in the polar regions of the Moon. VAPOR will ingest a soil sample and conduct analysis by pyrolysis and time-of-flight mass spectrometry (ToF-MS). Here, we describe miniaturization efforts within this development, including a carbon nanotube (CNT) field emission electron gun that is under consideration for use as the electron impact ionization source for the ToF-MS.

Getty, Stephanie↗

The Climatology of Carbon Monoxide and Water Vapor on Mars as Observed by CRISM and Modeled by the GEM-Mars General Circulation Model

Radiative transfer modeling of near-infrared spectra taken by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument onboard Mars Reconnaissance Orbiter (MRO) enables the column-integrated abundance of carbon monoxide (CO) and water vapor (H 2 O) to be retrieved. These results provide a detailed global description of the seasonal and spatial distribution of CO in the Mars atmosphere and new information about the interannual variability of H2O. The CRISM retrievals show the seasonally and globally averaged carbon monoxide mixing ratio to be near 800 parts per million, but with strong seasonal variations, especially at high latitudes. At low latitudes, the carbon monoxide mixing ratio varies in response to the mean seasonal cycle of surface pressure and shows little variation with topography. At high latitudes, carbon monoxide is depleted in the summer hemisphere by a factor of two or more, while in the winter hemisphere there is relatively higher mixing ratio in regions with low-lying topography. Water vapor shows only modest interannual variations, with the largest observed difference being unusually dry conditions in the wake of the Mars Year 28 global dust storm. Modeling results from the GEM (Global Environmental Multiscale) - Mars general circulation model generally reproduce the observed seasonal and spatial trends and provide insight into the underlying physical processes.

Smith, Michael D.↗

Analysis and Applications of Water Vapor-Derived Multispectral Composites for Geostationary Satellites

Analysis of multispectral (red-green-blue, RGB) satellite image composites can be used to improve understanding of thermodynamic and / or dynamic features associated with the development of significant weather events (cyclones, hurricanes, intense convection, turbulence, etc.). These composites minimize the need for a more time consuming analysis of multiple images and can provide additional insight not available from a single channel. The enhanced water vapor imaging capabilities of the Advanced Baseline Imager on GOES-16,-17 satellites provide a unique opportunity to demonstrate this capability through a comparison of the Air Mass and Differential Water Vapor RGB image products for several case studies.

Jedlovec, Gary J.↗

Analysis and Applications of Water Vapor-Derived Multispectral Composites for Geostationary Satellites

Analysis of multispectral (red-green-blue, RGB) satellite image composites can be used to improve understanding of thermodynamic and / or dynamic features associated with the development of significant weather events (cyclones, hurricanes, intense convection, turbulence, etc.) The enhanced water vapor imaging capabilities of the Advanced Baseline Imager on GOES-16 and GOES-17 satellites provide a unique opportunity to demonstrate this capability through a comparison of the Air Mass (AM) and Differential Water Vapor (DWV) RGB image products for several case studies.

Berndt, Emily↗

Compositional and Microstructural Effects in the Protection of SiC Components in Water Vapor

Greater gas turbine engine efficiency is a major goal in aeronautics research often pursued through increased engine operating temperatures. However, it is necessary to replace the current hot-stage alloy components with more thermally robust parts, such as promising Silicon-based ceramics and composites. Unfortunately, these materials are still susceptible to the effects of oxidation, water vapor, and (Calcium-Magnesium-Alumino-Silicate) CMAS interaction, among other issues at high temperature. To mitigate these effects, environmental barrier coating (EBC) materials are employed to help control the rate of degradation to the underlying composite. Often, a thermally grown oxide (TGO) layer forms between the EBC and the composite which can act as a point of failure. The current study focuses on the combined effects of water vapor, composite composition, and microstructure in TGO formation on protected and unprotected SiC samples which have been produced under different processing conditions.

Kowalski, Benjamin↗

Satellite Mapping of PM2.5 Episodes in the Wintertime San Joaquin Valley: A "Static" Model Using Column Water Vapor

The use of satellite Aerosol Optical Thickness (AOT) from imaging spectrometers has been successful in quantifying and mapping high PM2.5 (particulate matter mass <2.5µm diameter) episodes for pollution abatement and health studies. However, some regions have high PM2.5 but poor estimation success. The challenges in using Aerosol Optical Thickness (AOT) from imaging spectrometers to characterize PM2.5 worldwide was especially evident in the wintertime San Joaquin Valley (SJV). The SJV's attendant difficulties of high-albedo surfaces and very shallow, variable vertical mixing also occur in other significantly polluted regions around the world. We report on more accurate PM2.5 maps for the whole-winter period in the SJV, Nov 14, 2012?Dec 11, 2013. Intensive measurements by including NASA aircraft were made for several weeks in that winter, the DISCOVER-AQ California mission.We found success with a relatively simple method based on calibration and checking with surface monitors and a characterization of vertical mixing, and incorporating specific understandings of the region's climatology. We estimate PM2.5 to within ~7µgm?3 RMSE and with R values of ~0.9, based on remotely sensed MAIAC (Multi-Angle Implementation of Atmospheric Correction) observations, and that certain further work will improve that accuracy. Mapping is at 1km resolution. This allows a time sequence of mapped aerosols at 1km for cloud-free days. We describe our technique as a "static estimation". Estimation procedures like this one, not dependent on well-mapped source strengths or on transport error, should help full source-driven simulations by deconstructing processes. They also provide a rapid method to create a long-term climatology.Essential features of the technique are (a) daily calibration of the AOT to PM2.5 using available surface monitors, and (b) characterization of mixed-layer dilution using column water vapor (CWV, otherwise "precipitable water"). We noted that on multi-day timescales both water vapor and particles share near-surface sources and both fall to very low values with altitude; indeed, both are largely removed by precipitation. The existence of layers of H2O or aerosol not within the mixed layer adds complexity, but mixed-effects statistical regression captures essential proportionality of PM2.5 and the ratio variable (AOT/CWV). Accuracy is much higher than previous statistical models, and can be extended to the whole Aqua-satellite data record. The maps and time-series we show suggest a repeated pattern for large valleys like the SJV ? progressive stabilization of the mixing height after frontal passages: PM2.5 is somewhat more determined by day-by-day changes in mixing than it is by the progressive accumulation of pollutants (revealed as increasing AOT).

Chatfield, Robert B.↗

Airborne, Direct-Detection, 2-μm Triple-Pulse IPDA Lidar for Simultaneous and Independent Atmospheric Water Vapor and Carbon Dioxide Active Remote Sensing

Atmospheric water vapor and carbon dioxide are important greenhouse gases that significantly contribute to the global radiation budget on Earth. A 2-micron triple-pulse, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric carbon dioxide and water vapor concentration measurements using direct detection was developed at NASA Langley Research Center. This active remote sensing instrument provides an alternate approach with significant advantages for measuring atmospheric concentrations of the gases. A high energy pulsed laser transmitter approach coupled with sensitive receiver detection provides a high-precision measurement capability by having a high signal-to-noise ratio. This paper presents the concept, development, integration and testing of the 2-micron triple-pulse IPDA. The integration includes the various IPDA transmitter, receiver and data acquisition subsystems and components. Ground and airborne testing indicated successful operation of the IPDA lidar.

Refaat, Tamer F.↗

Ground Testing of 2-µm Triple-Pulse IPDA Lidar for Carbon Dioxide and Water Vapor Measuremets

A triple-pulse, 2-µm, Integrated Path Differential Absorption (IPDA) lidar was developed at NASA Langley Research Center. This active remote sensing instrument provides a technique for measuring atmospheric carbon dioxide and water vapor simultaneously and independently. A 2-µm high-energy pulsed laser is incorporated for the IPDA transmitter, which provides high signal-to-noise ratio measurements using a commercial direct detection system. This results in a high-precision measurement capability for the low troposphere weighted-average column dry-air volume mixing ratio of the gases. Recent IPDA ground testing indicated carbon dioxide and water vapor measurements sensitivities of 8% and 14%, respectively and biases of 0.1%. However, using the R30 centerline position for the on-line enhances the CO2 measurement sensitivity to 0.6%.

Refaat, Tamer F.↗

Corrosion Behavior of Stainless Steel 304 and Nickel 625 Under Iodine Vapor at 300 °C

The chemical, structural, and microstructural behavior of stainless steel 304 (SS 304) and nickel 625 (Ni 625) were probed after exposure to iodine vapor laminar flow at 300 °C. This work was conducted in support of the development of in-space propulsion utilizing iodine as a propellant. The kinetics of corrosion was measured in a custom-built iodine-compatible thermogravimetric analyzer rig at 300 °C in which samples were exposed to an iodine laminar vapor flow of 1 mg/min (carried by 20 mL/min argon gas) for up to 31 days. Samples were characterized after the experiment by X-ray diffraction, electron microscopy, energy dispersive X-ray spectroscopy, and dynamic secondary ion mass spectrometry. All samples formed scales consisting mainly of metal oxyiodides showing different chemistry, microstructure, and crystalline phases. The paralinear rate law best describes the kinetics of oxidation of the samples. SS 304 exhibited slightly slower kinetics of oxidation (106±3·10(exp –5) mg/sq.cm/day) than Ni 625 (122±3·10(exp –5) mg/sq.cm/day) in the low-oxygen and low-water environment.

Chemistry and Materials↗

Remote Sensing of Clouds, Water Vapor, and Near-Surface Winds Under Various Aerosol Conditions During CAMP2Ex

The Cloud, Aerosol and Monsoon Processes Philippines Experiment (CAMP2Ex) field campaign took place from August – October 2019. CAMP2Ex science objectives include understanding aerosol-cloud interaction under various Meteorological conditions, and how these Meteorological phenomena affect aerosol distribution in the atmosphere. Numerous instruments were flown on the National Aeronautics and Space Administration (NASA) P-3 aircraft during 19 CAMP2Ex science flights, including the Advanced Microwave Precipitation Radiometer (AMPR) the Airborne Third Generation Precipitation Radar (APR-3), and the High Spectral Resolution Lidar 2 (HSRL2). Geophysical retrieval equations for cloud liquid water, columnar water vapor, and near-surface wind speed using AMPR brightness temperatures have been derived and tested using CAMP2Ex data. Water vapor and wind speed retrievals have been validated using in situ observations, such as dropsondes and shipborne instruments. This presentation will demonstrate these AMPR-based retrievals during CAMP2Ex, including discussions of retrieval uncertainties. Specific CAMP2Ex flights will be presented in greater detail, including inferences of other Meteorological phenomena in clear air and around precipitating and non-precipitating clouds, such as background wind speeds and potential identification of gust fronts. These analyses will be supplemented with APR-3 reflectivity and Doppler velocity data to infer microphysical processes occurring within and around selected clouds of interest. In cases where multiple remote-sensing measurements were obtained for the same cloud, a time-evolution analysis of these features may be performed. Throughout these analyses, HSRL2 data will be used to quantify aerosol properties beneath the P-3, and variations in the AMPR/APR-3 observations with respect to various aerosol conditions will be discussed.

Corey Amiot↗

A comparison of water vapor derived from GPS occultations and global weather analyses

Occultation measurements from the Global Positioning System (GPS) should improve upon this situation. Individual occultations yield profiles of specific humidity accurate to 0.2 to 0.5 g/kg providing sensitive measurements of lower and middle tropospheric water vapor with global coverage in a unique, all-weather, limb-viewing geometry with several hundred metres to a kilometre vertical resolution. The authors have derived water vapor profiles from June 21 to July 4, 1995

global↗

Precipitable water vapor over oceans from the Maritime Aerosol Network: Evaluation of global models and satellite products under clear sky conditions

We present results from an evaluation of precipitable water vapor (W) over remote oceanic areas as derived from global reanalysis models and from satellites against observations from the Maritime Aerosol Network (MAN) for cloudless skies during the period of 2004–2017. They cover polar, mid latitude and tropical oceanic regions and represent a first effort to use MAN observations for such evaluation. The global reanalysis model products evaluated in this study are from the Modern-Era Retrospective analysis for Research and Applications Version 2 (MERRA-2), the European Centre for Medium-Range Weather Forecasts (ECMWF) Interim Reanalysis (ERA I), and the Climate Forecast System Reanalysis (CFSR) model. The satellite products evaluated are from the Moderate Resolution Imaging Spectroradiometer (MODIS), the Polarization and Directionality of the Earth's Reflectances (POLDER), the Global Ozone Monitoring Experiment (GOME-2), the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY), and the Atmospheric Infra-red Sounder (AIRS). Satellite retrievals of W are based on the attenuation of solar reflected light by water vapor absorption bands, except those from AIRS that rely on brightness temperature measurements. A very good agreement is observed between the model estimates and MAN, with mean differences of ~5% and standard deviations of ~15%. These results are within the uncertainties associated with the models and the measurements, indicating the skill of the reanalysis models to estimate W over oceans under clear sky conditions. Mean differences of W between the satellite and MAN products are ~11, 6.7, 12, −7, and 3% for MODIS, POLDER, GOME-2, SCIAMACHY and AIRS respectively, while their standard deviations are 31, 29, 28, 20 and 17%. These differences reveal the need to address inconsistencies among different satellite sensors and ground-based measurements to reduce the uncertainties associated with the retrievals.

Daniel Pérez-Ramírez↗

SAGE III/ISS Validation of Ozone and Water Vapor V5.2 Data Using Collocated Balloon-Borne Measurements

The Stratospheric Aerosol and Gas Experiment III (SAGE III) instrument installed on the International Space Station (ISS) has completed nearly four years of data collection and production of science data products. The SAGE III/ISS is a solar and lunar occultation instrument that scans the light from the Sun and Moon through the limb of the Earth’s atmosphere to produce vertical profiles of aerosol, ozone, water vapor, and other trace gases. It continues the legacy of previous SAGE instruments dating back to the 1970s to provide data continuity of stratospheric constituents critical for assessing trends in the ozone layer. This presentation shows the validation results of comparing SAGE III/ISS ozone and water vapor vertical profiles from the newly released v5.2 science product with those of balloon launched ozonesonde and frost point hygrometer measurements and satellite data from the Microwave Limb Sounder.

S Kizer↗

Precipitable Water Vapor Variation in the Clear-Cloud Transition Zone From the ARM Shortwave Spectrometer

A new technique to retrieve precipitable water vapor (PWV)amount in the clear-cloud transition zone using ground-based zenith spectral radiance is developed. The method uses zenith radiances at the water vapor band at 720 nm and adjacent non-absorbing band at 750 nm.Radiative transfer calculations show that the relative difference in zenith radiance between the two bands depends on PWV and the variations in cloud optical depth introduce a small change in the relative difference which is independent of PWV amount. This allows us to retrieve PWV variations in the cloud-clear transition zone for clouds over dark ocean surface. We applied this method to a Cu cloud case with zenith radiance observations by the Shortwave Array Spectroradiometer-Zenith (SASZe) during the Marine ARM GPCI Investigation of Clouds (MAGIC) field campaign. We found that there is about 10% change in PWV amount from known-cloudy region to known-clear sky in cloud edges.

Atmosphere↗

Solid Particle Erosion of a Plasma Spray – Physical Vapor Deposition Environmental Barrier Coating in a Combustion Environment

Environmental barrier coatings (EBCs) were developed to reduce the susceptibility of SiC-based composites to the rapid volatilization and surface recession that occurs in the presence of water vapor. Extensive research and development has been performed on EBCs, and their corresponding failure mechanisms under different environmental conditions. However, one key failure mechanism, solid particle erosion (SPE), has not been thoroughly investigated. As a result, the present work investigates the SPE behavior of a ytterbium disilicate (Yb2Si2O7) environmental barrier coating (EBC) deposited via plasma spray-physical vapor deposition (PS-PVD). Erosion testing was performed at elevated temperature (1,200 °C) in a simulated combustion environment at the NASA Glenn Research Center Erosion Burner Rig Facility. Alumina (Al2O3) particles were used as the eroding media. A range of particle kinetic energies and impingement angles were investigated along with the effect of coating surface roughness. The post-erosion damage morphology was characterized using scanning electron microscopy (SEM). The SPE behavior of the PS-PVD EBC was shown to be comparable to other EBC systems reported in the literature.

Solid particle erosion; environmental barrier coat↗

An Assessment of Stratospheric Water Vapor Trends and Variations Above the Boulder Region

This study analyzes time series of stratospheric water vapor (SWV) data at 30 hPa, based on frost-point hygrometer (FPH) measurements at Boulder, CO (40°N, 255°E), and on sets of HALOE scans above that region for 1993 through 2005; their differing trends agree with previously published findings. Yet, there is an apparent switch over in 2002 from positive to negative trends in the HALOE time series, and that change follows the episodic decrease of tropical, lower stratospheric SWV in early 2001. The HALOE data points only resolve medium to large scale spatial variations, as they are based on an average of four or more limb scans within a latitude/longitude sector near Boulder. The FPH time series do not indicate a similar change of trend in 2002, although its time series points have variations about the mean that are twice as large as those from HALOE. The FPH soundings are sensitive to variations from all spatial scales, however, including the effects of a local vertical mixing of the air due to gravity waves. The vertical gradient SWV mixing ratio with altitude is positive at 30 hPa. There is also a positive trend in methane and its conversion to water vapor during this time that may explain a slightly larger SWV trend from the local FPH data than from the HALOE data. The Nimbus 7 LIMS experiment provides daily SWV plots at medium to large scales during the dynamically active, winter and springtime periods, for assessing the effects of meridional transport of SWV from its source regions. There is transport of high SWV from polar regions and of lower SWV from the subtropics at those times. SWV variations and trends from both the FPH and HALOE time series are reasonable and in accord with the spatial scales that they observed.

Ellis Remsberg↗

Differences in Water Vapor Radiative Transfer Among 1D Models Can Significantly Affect the Inner Edge of the Habitable Zone

An accurate estimate of the inner edge of the habitable zone is critical for determining which exoplanets are potentially habitable and for designing future telescopes to observe them. Here, we explore differences in estimating the inner edge among seven one-dimensional radiative transfer models: two line-by-line codes (SMART and LBLRTM) as well as five band codes (CAM3, CAM4_Wolf, LMDG, SBDART, and AM2) that are currently being used in global climate models. We compare radiative fluxes and spectra in clear-sky conditions around G and M stars, with fixed moist adiabatic profiles for surface temperatures from 250 to 360 K. We find that divergences among the models arise mainly from large uncertainties in water vapor absorption in the window region (10 μm) and in the region between 0.2 and 1.5 μm. Differences in outgoing longwave radiation increase with surface temperature and reach 10–20Wm(exp −2); differences in shortwave reach up to 60 Wm(exp −2), especially at the surface and in the troposphere, and are larger for an M-dwarf spectrum than a solar spectrum. Differences between the two line-by-line models are significant, although smaller than among the band models. Our results imply that the uncertainty in estimating the insolation threshold of the inner edge (the runaway greenhouse limit) due only to clear-sky radiative transfer is ≈10% of modern Earth’s solar constant (i.e., ≈34 Wm(exp −2) in global mean) among band models and ≈3% between the two line-by-line models. These comparisons show that future work is needed that focuses on improving water vapor absorption coefficients in both shortwave and longwave, as well as on increasing the resolution of stellar spectra in broadband models.

Numerical methods↗