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At least 1,297 records · Page 72

Synthesis and Characterization of Mesoporous Silica Nanoparticles Loaded with Pt Catalysts

Coating the catalyst with a nanoporous layer has been demonstrated to be an effective approach to improve catalyst stability. Herein, we systematically investigate two types of core-shell mesoporous silica nanoparticles with a platinum nanocatalyst using a variety of characterization methods. One of the mesoporous particles has a unique amine ring structure in the middle of a shell (Ring-mSiO 2 /Pt-5.0/SiO 2 ), and the other one has no ring structure (mSiO 2 /Pt-5.0/SiO 2 ). Brunauer–Emmett–Teller/Barrett–Joyner–Halenda (BET/BJH) presented a similar surface area for both particles, and the pore size was 2.4 nm. Ultra-Small-Angle X-ray Scattering (USAXS)/ Small-Angle X-ray Scattering (SAXS) showed the size of mSiO 2 /Pt-5.0/SiO 2 and Ring-mSiO 2 /Pt-5.0/SiO 2 were 420 nm and 272 nm, respectively. It also showed that the ring structure was 30 nm above the silica core. Using high-resolution Transmission Electron Microscopy (TEM), it was found that the platinum nanoparticles are loaded evenly on the surface of the silica. In situ SAXS heating experiments and Thermogravimetric Analysis (TGA) indicated that the mSiO 2 /Pt-5.0/SiO 2 were more stable during the high temperature, while the Ring-mSiO 2 /Pt-5.0/SiO 2 had more change in the particle.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

ImpactX v0.1

ImpactX is the next generation of the IMPACT-Z code. It is a s-based simulation code for modeling intense beams in particle accelerators using symplectic tracking methods and includes collective effects. It is multi-node parallel and supports modern compute hardware such as GPUs, modern algorithms such as mesh-refinement and realistic geometries (embedded boundaries).

Huebl, Axel↗

The effect of surface conditions on the work function of insulators and semiconductors

Ionization energies of organic semiconductors were determined using single crystals of the material. The theory of the method is essentially that of Millikan's oil drop experiment. The technique employed in the experiment is based on the electrostatic method of balancing a charged particle in an electric field against the force of gravity for different excitation energies above the threshold value, and from an estimate of the balancing voltages, read off the ionization energy from the intercept of the energy axis in a plot wavelength corresponding to the balancing potential for the incident radiation of wavelength. In the modified technique which is adopted in the present experimental investigation, a small single crystal is suspended by a fine quartz fiber between two vertical capacitor plates to which a suitable high voltage is applied.

George, A.↗

Ground-state energies of simple metals

A structural expansion for the static ground-state energy of a simple metal is derived. Two methods are presented, one an approach based on single-particle band structure which treats the electron gas as a nonlinear dielectric, the other a more general many-particle analysis using finite-temperature perturbation theory. The two methods are compared, and it is shown in detail how band-structure effects, Fermi-surface distortions, and chemical-potential shifts affect the total energy. These are of special interest in corrections to the total energy beyond third order in the electron-ion interaction and hence to systems where differences in energies for various crystal structures are exceptionally small. Preliminary calculations using these methods for the zero-temperature thermodynamic functions of atomic hydrogen are reported.

Hammerberg, J.↗

Method of preparing zinc orthotitanate pigment

Zinc orthotitanate suitable for use as a pigment for spacecraft thermal control coatings is prepared by heating a slightly zinc deficient reaction mixture of precipitated oxalates of zinc and titanium. The reaction mixture can be formed by coprecipitation of zinc and titanium oxalates from chloride solution or by mixing separately precipitated oxalates. The mixture is first heated to 400 to 600 C to remove volatiles and is then rapidly heated at 900 to 1200 C. Zinc orthotitanate produced by this method exhibits the very fine particle size needed for thermal control coatings as well as stability in a space environment.

Gates, D. W.↗

NASA Agricultural Aircraft Research Program in the Langley Vortex Research Facility and the Langley Full Scale Wind Tunnel

The current status of aerial applications technology research at the Langley's Vortex Research Facility and Full-Scale Wind Tunnel is reviewed. Efforts have been directed mainly toward developing and validating the required experimental and theoretical research tools. A capability to simulate aerial dispersal of materials from agricultural airplanes with small-scale airplane models, numerical methods, and dynamically scaled test particles was demonstrated. Tests on wake modification concepts have proved the feasibility of tailoring wake properties aerodynamically to produce favorable changes in deposition and to provide drift control. An aerodynamic evaluation of the Thrush Commander 800 agricultural airplane with various dispersal systems installed is described. A number of modifications intended to provide system improvement to both airplane and dispersal system are examined, and a technique for documenting near-field spray characteristics is evaluated.

Jordan, F. L., Jr.↗

Diagnostics of wear in aeronautical systems

The use of appropriate diagnostic tools for aircraft oil wetted components is reviewed, noting that it can reduce direct operating costs through reduced unscheduled maintenance, particularly in helicopter engine and transmission systems where bearing failures are a significant cost factor. Engine and transmission wear modes are described, and diagnostic methods for oil and wet particle analysis, the spectrometric oil analysis program, chip detectors, ferrography, in-line oil monitor and radioactive isotope tagging are discussed, noting that they are effective over a limited range of particle sizes but compliment each other if used in parallel. Fine filtration can potentially increase time between overhauls, but reduces the effectiveness of conventional oil monitoring techniques so that alternative diagnostic techniques must be used. It is concluded that the development of a diagnostic system should be parallel and integral with the development of a mechanical system.

Wedeven, L. D.↗

Crystallography of decahedral and icosahedral particles. I - Geometry of twinning

The crystal structure of the tetrahedral twins in multiply-twinned particles with decahedral and icosahedral point group symmetries has been examined and correlated with the face-centered cubic structure. Details on the crystal structure as well as the geometrical relationships among twins in each particle are presented. These crystallographic facts serve as a basis for the interpretation of small particle images obtained with advanced methods of transmission electron microscopy.

Yang, C. Y.↗

Inversion of the anomalous diffraction approximation for variable complex index of refraction near unity

The Fymat analytic inversion method for retrieving a particle-area distribution function from anomalous diffraction multispectral extinction data and total area is generalized to the case of a variable complex refractive index m(lambda) near unity depending on spectral wavelength lambda. Inversion tests are presented for a water-haze aerosol model. An upper-phase shift limit of 5 pi/2 retrieved an accurate peak area distribution profile. Analytical corrections using both the total number and area improved the inversion.

Smith, C. B.↗

A search for mini-clusters in Japan-USSR Joint Experiment at Pamir

A search for mini-clusters, very collimated shower clusters of hadrons and electromagnetic particles, is made for the hadron and gamma families observed by Japan-USSR joint carbon chamber at Pamir. The existence of anomalous correlation between hadrons and electromagnetic particles is found. The decascading method is applied to the families and it is found that 11 clusters which include hadrons as members have smaller spread, Er 3.5 GeV.m and larger lateral spread, E'R' 100 GeV.m, from the family center. In the simulated events, such clusters were found to be very rare.

Source record↗

A combined Eulerian-Lagrangian two-phase flow analysis of SSME HPOTP nozzle plug trajectories. II - Results

An analysis of Space Shuttle Main Engine high-pressure oxygen turbopump nozzle plug trajectories has been performed, using a Lagrangian method to track nozzle plug particles expelled from a turbine through a high Reynolds number flow in a turnaround duct with turning vanes. Axisymmetric and parametric analyses reveal that if nozzle plugs exited the turbine they would probably impact the LOX heat exchanger with impact velocities which are significantly less than the penetration velocity. The finding that only slight to moderate damage will result from nozzle plug failure in flight is supported by the results of a hot-fire engine test with induced nozzle plug failures.

Mcconnaughey, P. K.↗

Techniques for debris control

This paper will summarize a range of techniques which have been proposed for controlling the growth of man-made debris in earth orbit. Several techniques developed in studies at the Johnson Space Center will be described in detail. These techniques include the retrieval of inoperative satellites with an orbital maneuvering vehicle and self-disposal devices for satellites and upper stages. Self-disposal devices include propulsive deorbit motors and passive drag-augmentation devices. Concepts for sweeping small debris from the orbital environment will also be described. An evaluation of the technical feasibility and economic practicality of the various control methods will be summarized. In general, methods which prevent the accumulation of large debris objects were found to provide greater promise for control of the debris problem than methods of removing small debris particles.

Petro, Andrew J.↗

Digital Correlation In Laser-Speckle Velocimetry

Periodic recording helps to eliminate spurious results. Improved digital-correlation process extracts velocity field of two-dimensional flow from laser-speckle images of seed particles distributed sparsely in flow. Method which involves digital correlation of images recorded at unequal intervals, completely automated and has potential to be fastest yet.

Gilbert, John A.↗