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At least 1,297 records · Page 72

Dendritic microstructures observed in electron-beam deposited hafnia films

Dendritic microstructures inside hafnia dielectric coatings fabricated via electron-beam deposition are investigated. These structures are observable with different optical characterization tools, including atomic force microscopy, fluorescence microscopy, Raman microscopy, and differential interference contrast microscopy. Long-term monitoring of individual samples over a seven-year time span revealed that the dendrite-like structures evolve over time, while the hafnia material in the dendrite structure—as compared to the rest of the coating—shows a decrease in crystallinity and an increase in defect density.

Hoffman, B. N. [Univ. of Rochester, NY (United Sta↗

Large optical nonlinearities in a GaAs/AlGaAs hetero n-i-p-i structure

Light-induced changes in the absorption of a multiple quantum well hetero n-i-p-i structure at room temperature have been measured using a pump-probe method. Changes in the absorption coefficient in the quantum wells of more than 2000/cm have been observed with pump intensities as small as 375 mW/sq cm. Corresponding changes in the index of refraction of about 0.02 have been calculated.

Kost, A.↗

A Miniaturized, High-Bandwidth Optical Fiber Fabry–Perot Cavity Vibration Sensor Demonstrated up to 800 °C

A typical structural health monitoring technique involves measuring the vibrational characteristics of components or systems to detect signs of degradation or damage. Many industrial applications require engineered systems to safely operate under extreme, high-temperature environments that pose challenges not only to materials but also to sensors that would be used for structural health monitoring. Here, in this study, miniaturized optical Fabry-Perot cavities (FPCs) were developed and tested as a means of measuring the resonant frequencies of metal components that are most relevant to extreme-environment applications. Two of the three candidate FPC designs tested up to 800 ° C provided accurate measurements (validated by theoretical models and laser Doppler vibrometry) of the fundamental vibrational mode of the specimen to which each was bonded, although both sensors failed during thermal cycling. An analysis of the reflected optical spectrum from the FPC and X-ray computed tomography revealed two opportunities to improve the sensor reliability. First, the Cu optical fiber coating that was used could either be replaced with a more oxidation-resistant material or protected with commercially available films. Second, the adhesives used to bond the fibers to metal capillaries and establish the FPC could be replaced with a more robust solution, although the Resbond 907TS adhesive appeared to outperform Resbond 907.

Birri, Anthony [Oak Ridge National Laboratory (ORN↗

X-ray transfer in binary systems - A Monte Carlo study

Results are presented for Monte Carlo calculations of X-ray light curves for binary systems surrounded by clouds with simple density distributions, chemical compositions, and ionization structures. Occultation of the X radiation by the companion star is taken into account along with Compton scattering and photoionization within the clouds. The models are used to examine the effect of various cloud geometries and ionization structures on the emergent X-ray flux as a function of orbital phase and X-ray energy. The results demonstrate the sensitivity of observed light curves and phase-dependent spectra with respect to the optical depth, geometry, and ionization structure of a surrounding cloud for the cases of a uniform-density cloud with a radius four times the binary orbital separation, a steady-state constant-velocity stellar wind emanating from the companion star, and a spherically symmetric shell or 'cocoon' of the type proposed for Cyg X-3. It is concluded that X-ray binary systems are unlikely to be surrounded by obscuring clouds.

Hertz, P.↗

Novel photovoltaic delta-doped GaAs superlattice structure

An asymmetric delta-doped GaAs structure is described which exhibits novel photovoltaic effects and low-intensity nonlinear optics. Of particular interest in this kind of structure is the ability to design the electrooptical and nonlinear optical properties and the material response time over a wide range by appropriate design of the doping profile.

Glass, A. M.↗

Quantum electronics and optics at the interface of solid neon and superfluid helium

Here, we predict a new quantum electronic structure at the interface between two condensed phases of noble-gas elements: solid neon and superfluid helium. An excess electron injected onto this interface self-confines its wavefunction into a nanometric dome structure. Its size varies with pressure and optical transitions cover a broad mid-infrared spectrum. A collection of such electrons can form a classical Wigner crystal resembling a quantum-dot array on a triangular lattice. Under ultrafast laser illumination, this Wigner crystal can exhibit the quantum optical phenomenon of superradiance in the picosecond time scale. The ultralong spin-coherence time and micron-scale deterministic configurability allow the electrons in this system to serve as quantum information carriers. Their spin states can be controlled and readout by on-chip single-electron devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Structural Phase Transitions between Layered Indium Selenide for Integrated Photonic Memory

The primary mechanism of optical memoristive devices relies on phase transitions between amorphous and crystalline states. The slow or energy-hungry amorphous–crystalline transitions in optical phase-change materials are detrimental to the scalability and performance of devices. Leveraging an integrated photonic platform, nonvolatile and reversible switching between two layered structures of indium selenide (In 2 Se 3 ) triggered by a single nanosecond pulse is demonstrated. The high-resolution pair distribution function reveals the detailed atomistic transition pathways between the layered structures. With interlayer “shear glide” and isosymmetric phase transition, switching between the α- and β-structural states contains low re-configurational entropy, allowing reversible switching between layered structures. Broadband refractive index contrast, optical transparency, and volumetric effect in the crystalline–crystalline phase transition are experimentally characterized in molecular-beam-epitaxy-grown thin films and compared to ab initio calculations. Finally, the nonlinear resonator transmission spectra measure of incremental linear loss rate of 3.3 GHz, introduced by a 1.5 µm-long In 2 Se 3 -covered layer, resulted from the combinations of material absorption and scattering.

36 MATERIALS SCIENCE↗

An integral sunshade for optical reception antennas

Optical reception antennas (telescopes) must be capable of receiving communications even when the deep-space laser source is located within a small angle of the Sun. Direst sunlight must not be allowed to shine on the primary reflector of an optical reception antenna, because too much light would be scattered into the signal detectors. A conventional sunshade that does not obstruct the antenna aperture would have to be about five times longer than its diameter in order to receive optical communications at a solar elongation of 12 degrees without interference. Such a long sunshade could not be accommodated within the dome of any existing large-aperture astronomical facility, and providing a new dome large enough would be prohibitively expensive. It is also desirable to reduce the amount of energy a space-based large-aperture optical reception facility would expend orienting a structure with such a sizable moment of inertia. Since a large aperture optical reception antenna will probably have a hexagonally segmented primary reflector, a sunshade consisting of hexagonal tubes can be mounted in alignment with the segmentation without producing any additional geometric obstruction. An analysis of the duration and recurrence of solar-conjunction communications outages (caused when a deep-space probe near an outer planet appears to be closer to the Sun than a given minimum solar elongation), and the design equations for the integral sunshade are appended.

Kerr, E. L.↗

Galaxy evolution and large-scale structure in the far-infrared. II - The IRAS faint source survey

The new IRAS Faint Source Survey data base is used to confirm the conclusion of Hacking et al. (1987) that the 60 micron source counts fainter than about 0.5 Jy lie in excess of predictions based on nonevolving model populations. The existence of an anisotropy between the northern and southern Galactic caps discovered by Rowan-Robinson et al. (1986) and Needham and Rowan-Robinson (1988) is confirmed, and it is found to extend below their sensitivity limit to about 0.3 Jy in 60 micron flux density. The count anisotropy at f(60) greater than 0.3 can be interpreted reasonably as due to the Local Supercluster; however, no one structure accounting for the fainter anisotropy can be easily identified in either optical or far-IR two-dimensional sky distributions. The far-IR galaxy sky distributions are considerably smoother than distributions from the published optical galaxy catalogs. It is likely that structure of the large size discussed here have been discriminated against in earlier studies due to insufficient volume sampling.

Lonsdale, Carol J.↗

Integral sunshade for an optical reception antenna

Optical reception antennas (telescopes) must be capable of receiving communications even when the deep-space laser source is located within a small angle of the sun. Direct sunlight must not be allowed to shine on the primary reflector of an optical reception antenna, because too much light would be scattered into the signal detectors. A conventional sunshade that does not obstruct the antenna aperture would have to be about five times longer than its diameter in order to receive optical communications at a solar elongation of 12 degrees without interference. Such a long sunshade could not be accommodated within the dome of any existing large-aperture astronomical facility, and providing a new dome large enough would be prohibitively expensive. It is also desirable to reduce the amount of energy a space-based large-aperture optical reception facility would expend orienting a structure with such a sizable moment of inertia. Since a large aperture optical reception antenna will probably have a hexagonally segmented primary reflector, a sunshade consisting of hexagonal tubes can be mounted in alignment with the segmentation without producing any additional geometric obstruction. An analysis of the duration and recurrence of solar-conjunction communications outages (caused when a deep-space probe near an outer planet appears to be closer to the sun than a given minimum solar elongation), and the design equations for the integral sunshade are appended.

Kerr, Edwin L.↗

When can we detect lianas from space? Toward a mechanistic understanding of liana‐infested forest optics

Abstract Lianas, woody vines acting as structural parasites of trees, have profound effects on the composition and structure of tropical forests, impacting tree growth, mortality, and forest succession. Remote sensing could offer a powerful tool for quantifying the scale of liana infestation, provided the availability of robust detection methods. We analyze the consistency and global geographic specificity of spectral signals—reflectance across wavelengths—from liana‐infested tree crowns and forest stands, examining the underlying mechanisms of these signals. We compiled a uniquely comprehensive database, including leaf reflectance spectra from 5424 leaves, fine‐scale airborne reflectance data from 999 liana‐infested canopies, and coarse‐scale satellite reflectance data covering 775 ha of liana‐infested forest stands. To unravel the mechanisms of the liana spectral signal, we applied mechanistic radiative transfer models across scales, establishing a synthesis of the relative importance of different mechanisms, which we corroborate with field data on liana leaf chemistry and canopy structure. We find a consistent liana spectral signal at canopy and stand scales across globally distributed sites. This signature mainly arises at the canopy level due to direct effects of more horizontal leaf angles, resulting in a larger projected leaf area, and indirect effects from increased light scattering in the near and short‐wave infrared regions, linked to lianas' less costly leaf construction compared with trees on average. The existence of a consistent global spectral signal for lianas suggests that large‐scale quantification of liana infestation is feasible. However, because the traits responsible for the liana canopy‐reflectance signal are not exclusive to lianas, accurate large‐scale detection requires rigorously validated remote sensing methods. Our models highlight challenges in automated detection, such as potential misidentification due to leaf phenology, tree life history, topography, and climate, especially where the scale of liana infestation is less than a single remote sensing pixel. The observed cross‐site patterns also prompt ecological questions about lianas' adaptive similarities in optical traits across environments, indicating possible convergent evolution due to shared constraints on leaf biochemical and structural traits.

Environmental Sciences & Ecology↗

Understanding Heterogeneities in Quantum Materials

Quantum materials are usually heterogeneous, with structural defects, impurities, surfaces, edges, interfaces, and disorder. These heterogeneities are sometimes viewed as liabilities within conventional systems; however, their electronic and magnetic structures often define and affect the quantum phenomena such as coherence, interaction, entanglement, and topological effects in the host system. Therefore, a critical need is to understand the roles of heterogeneities in order to endow materials with new quantum functions for energy and quantum information science applications. In this article, several representative examples are reviewed on the recent progress in connecting the heterogeneities to the quantum behaviors of real materials. Specifically, three intertwined topic areas are assessed: i) Reveal the structural, electronic, magnetic, vibrational, and optical degrees of freedom of heterogeneities. ii) Understand the effect of heterogeneities on the behaviors of quantum states in host material systems. iii) Control heterogeneities for new quantum functions. This progress is achieved by establishing the atomistic-level structure-property relationships associated with heterogeneities in quantum materials. Finally, the understanding of the interactions between electronic, magnetic, photonic, and vibrational states of heterogeneities enables the design of new quantum materials, including topological matter and quantum light emitters based on heterogenous 2D materials.

36 MATERIALS SCIENCE↗

In-Situ X-Ray Imaging High Strain Rate Compression of Laminate Al-Graphene Composite and Mechanical Property Characterization

Owing to the opaque nature of the laminated structures, traditional high-speed optical camera cannot be used to detect the dynamic process of sub-surface deformation. In this article, we report a study of using high speed X-ray imaging to study the high strain rate deformation in laminated Al structures. We used a Kolsky bar apparatus to apply dynamic compression and a high-speed synchrotron X-ray phase contrast imaging (PCI) setup to conduct the in situ X-ray imaging study. The in situ X-ray imaging captures the shock wave propagation in the laminated structures. After shock compression, we characterized the microstructures by using transmission electron microscopy (TEM), which demonstrates an increase of dislocation density. In conclusion, the micro-pillar compression tests show that the yield strength at 0.2% offset of laminated Al-graphene composite has a significant increase of 67%, from 30 to 50 MPa, compared to laminate Al after shock loading.

36 MATERIALS SCIENCE↗

Optical vibrational spectra of β -U 3 O 8

Technogenic uranium oxides are ubiquitous in the nuclear fuel cycle. Identifying the chemical composition of these oxides is frequently done with optical vibrational spectroscopy (infrared and Raman spectroscopy). The α phase of U 3 O 8 is the most stable and common uranium oxide, but a β phase of U 3 O 8 can be produced via very slow cooling of the α phase from elevated temperatures or the application of small shear forces. However, optical spectra of this compound have not been reported. In this work, we use high-resolution attenuated total reflection infrared spectroscopy and Raman spectroscopy to collect the optical vibrational spectra. Despite similarities in the crystal structure of α and β – U 3 O 8 , the optical spectra of these compounds differ substantially, with additional Raman active modes in β – U 3 O 8 that are likely originating from differences in the U–O coordination units. Measurements presented here provide spectral characterization that can be used for chemical identification in future studies of uranium oxides.

36 MATERIALS SCIENCE↗

An analysis of doping modulated superlattice structures

A new method of growing doping modulated superlattice structures is discussed. This method uses organo-metallic chemical vapor deposition (MO-CVD) with the added feature of controlled plasma in the growth regions. The main objective was to study how the growth environment affected the electronic and optical properties of the superlattice structures. Because a serious safety hazard was discovered in the growth process, no superlattice structures were fabricated and the research on this material had to be terminated. The hazard had to do with the lack of adequate means for the disposal of toxic elemental beryllium.

Buoncristiani, A. M.↗

A millimeter-wave tunneLadder TWT

A millimeter wave traveling wave tube was developed using a dispersive, high impedance forward interaction structure based on a ladder, with non-space harmonic interaction, for a tube with high gain per unit length and high efficiency. The TunneLadder interaction structure combines ladder properties modified to accommodate Pierce gun beam optics in a radially magnetized permanent magnet focusing structure. The development involved the fabrication of chemically milled, shaped ladders diffusion brazed to diamond cubes which are in turn active-diffusion brazed to each ridge of a doubly ridged waveguide. Cold test data are presented, representing the omega-beta and impedance characteristics of the modified ladder circuit. These results were used in small and large signal computer programs to predict TWT gain and efficiency. Actual data from tested tubes verify the predicted performance while providing broader bandwidth than expected.

Jacquez, A.↗

Characterization of GaAlAs optical waveguide heterostructures grown by molecular beam epitaxy

Multiple-layer GaAlAs optical waveguide heterostructures have been grown by MBE. These samples were designed to operate at 840 nm with negligible coupling of guided light to the absorbing GaAs substrate. The Al concentration was 13 percent for the guiding layer and was 16 percent for the cladding layers. The process for growing waveguide layers was calibrated primarily by high-energy electron diffraction, with the optical quality confirmed by photoluminescence measurements. Channel waveguide structures having widths of 5 microns were etched in a low-pressure magnetically confined multipolar plasma reactor. The resulting waveguide structures were characterized by Raman spectroscopy, ellipsometry, AES, and optical-waveguide loss measurements.

Radens, C. J.↗