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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,297 records · Page 72
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Photovoltaics Research and Development: Device Architecture for Next-Generation CdTe PV. Cooperative Research and Development Final Report, CRADA Number CRD-17-00662

Despite remarkable efficiency improvements at the cell and module level, thin-film CdTe PV suffers from a significant voltage deficit compared with the ideal. The proposed solution is to build cells with fully depleted absorbers and with energy barriers front and back to direct electrons and holes in appropriate directions. Combined with minimal interfacial recombination, this approach, which is similar to the successful silicon HIT cells, circumvents the need for higher lifetimes and carrier concentration to achieve higher voltage, Colorado State is particularly well-positioned to the address the depleted absorbed architecture. It has robust single-vacuum closed-spaced-sublimation deposition chamber, currently being enhanced with new sources for CdTe alloys and grading. It has made reasonable-efficiency cells with absorbers as thin as 0.3 um, it has demonstrated electron reflection at the rear of the absorber with a continuous CdMgTe layer, it has replaced CdS with MgZnO, which has several advantages including tunable band offsets, and it has achieved 16.8% efficiency. It also has a mature suite of measurement equipment for cell evaluation and the experience to effectively analyze its results for refinement in cell fabrication. Several healthy collaborations will continue within the CdTe community.

14 SOLAR ENERGY↗
NASA NTRS1983

Modelling of photodegradation in solar cell modules of substrate and superstrate design made with ethylene-vinyl acetate as pottant material

A computer model was developed which can generate realistic concentration versus time profiles of the chemical species formed during photooxidation of hydrocarbon polymers using as input data a set of elementary reactions with corresponding rate constants and initial conditions. The results of computer simulation have been shown to be consistent with the general experimental observations of the photooxidation of polyethylene exposed to sunlight at ambient temperatures. The useful lifetime (5% oxidation) of the unstabilized polyethylene is predicted to vary from a few months in hot weather (100 F) to almost two years in cool weather (45 F) with an apparent net activation energy of 10 kcal/mol. Modelling studies of alternate mechanisms for stabilization of clear, amorphous, linear polyethylene suggest that the optimum stabilizer would be a molecularly dispensed additive in very low concentration which can trap peroxy radicals and also decompose hydroperoxides.

Somersall, A. C.↗
NASA NTRS1984

Extended parametric representation of compressor fans and turbines. Volume 3: MODFAN user's manual (parametric modulating flow fan)

A modeling technique for single stage flow modulating fans or centrifugal compressors has been developed which will enable the user to obtain consistent and rapid off-design performnce from design point input. The fan flow modulation may be obtained by either a VIGV (variable inlet guide vane) or a VPF (variable pitch rotor) option. Only the VIGV option is available for the centrifugal compressor. The modeling technique has been incorporated into a time-sharing program to facilitate its use. Because this report contains a description of the input output data, values of typical inputs, and examples cases, it is suitable as a user's manual. This report is the last of a three volume set describing the parametric representation of compressor fans, and turbines. The titles of the three volumes are as follows: (1) Volume 1 CMGEN USER's Manual (Parametric Compressor Generator); (2) Volume 2 PART USER's Manual (Parametric Turbine); (3) Volume 3 MODFAN USER's Manual (Parametric Modulating Flow Fan).

Converse, G. L.↗
NASA NTRS2005

The QBO as Potential Amplifier and Conduit to Lower Altitudes of Solar Cycle Influence?

The solar cycle (SC) effect in the lower atmosphere has been linked observationally to the Quasi-biennial Oscillation (QBO), which is generated primarily by small-scale gravity waves (GW). Following up on a 2D study with our Numerical Spectral Model (NSM), we discuss here a 3D study in which we simulated the QBO under the influence of the SC. For a SC period of 10 years, the relative amplitude of radiative forcing is taken to vary exponentially with height, i.e., 0.2% at the surface, 2% at 50 km, 20% at 100 km and above. Applying spectral analysis to filter out and identify the SC signature, this model produces a relatively large modulation in the QBO of the lower stratospheric circulation, which is in qualitative agreement with the results obtained by Salby and Callaghan (2000) who analyzed zonal wind observations covering more than 40 years. The modeled SC modulation of the QBO extends to high latitudes where it produces temperature variations of about 1 K in the troposphere below 10 km. We report that the SC also generates in the model a hemispherically symmetric Equatorial Annual Oscillation (EAO, with 12-month period) that is largely confined to low latitudes. Under the influence of the GWs, the SC modulated EA0 propagates down into the lower stratosphere like the QBO. As is the case for the QBO, the energy of this EA0 is partially redistributed by the meridional circulation and planetary waves, presumably, to generate measurable SC signatures in the tropospheric temperature of the polar regions, which may be related to the so called Arctic Oscillation (Thompson and Wallace, 1998). The larger SC influence at higher altitudes is apparently transferred to the lower and denser regions of the atmosphere by tapping the momentum from the upward propagating GWs that drive the oscillations. The SC modulation of the QBO period could prove to be very effective in this process, as our earlier 2D study indicated. Further studies are needed, (1) to make sure that the SC effects are real and the numerical results are robust, and (2) to explore more fully the mechanism(s) that may conspire to amplify the SC effect. Quasi-decadal oscillations, generated internally by the QBO interacting with the seasonal cycles, may interfere with, or aid, the SC influence.

Mayr, Hans G.↗
NASA NTRS1989

Digitally modulated bit error rate measurement system for microwave component evaluation

The NASA Lewis Research Center has developed a unique capability for evaluation of the microwave components of a digital communication system. This digitally modulated bit-error-rate (BER) measurement system (DMBERMS) features a continuous data digital BER test set, a data processor, a serial minimum shift keying (SMSK) modem, noise generation, and computer automation. Application of the DMBERMS has provided useful information for the evaluation of existing microwave components and of design goals for future components. The design and applications of this system for digitally modulated BER measurements are discussed.

Shalkhauser, Mary Jo W.↗
NASA NTRS2021

NASA Leveraging Commercial Communication Ground Stations for Small Satellites

The Space Communications and Navigation (SCaN) program at NASA has reorganized its operations portfolio into two networks: the Deep Space Network and the new Near Space Network (NSN). With this reorganization, NASA can begin transforming to 100% direct-to-Earth commercial communications services for missions in the near-Earth region. NASA’s leveraging of commercial direct-to-Earth ground stations offers several benefits for the small satellite community, including lower cost, greater coverage, and increased technology infusion. In the fall of 2020, SCaN announced their intention to rely primarily on industry-provided communications services for missions close to Earth by 2030. Commercial services are one way to infuse new technology into the ground station network without requiring an investment from NASA. Digital Video Broadcast, Satellite Second Generation (DVB-S2) is one example of a current technology. When combined with variable coding and modulation (VCM), the system automatically optimizes the data rate based on signal performance, significantly increasing total downlink data volume without an increase in the spacecraft effective isotropic radiated power (EIRP). There are several commercial service providers, including Amazon Web Service (AWS) Ground Station (AGS) and the KSATLITE ground stations that support SmallSat missions using DVB-S2 waveforms for downlinks. This paper identifies some commercial off-the-shelf (COTS) CubeSat/SmallSat DVB-S2 X-band and Ka-band radios. Overall, NASA’s increased dependence on commercial direct-to-Earth ground stations is a significant benefit for the small satellite community.

Space Communications↗
DOE OSTI2023

Neural network model of neutral beam injection in the EAST tokamak to enable fast transport simulations

The neutral beam injection (NBI) system in EAST produces energetic neutral particles, which collide with electrons and ions in tokamak plasmas and heat the plasmas through Coulomb collisions. Moreover, it drives a non-inductive source of current, due to the charge-exchange collision between neutral particles and ions, and injects toroidal torque, which generates a toroidal rotation of the plasma. The effect caused by the NBI system, such as plasma heating, current drive, total neutron rate, momentum transfer, and shine-through, are modeled by a comprehensive module called NUBEAM. However, NUBEAM is computationally intensive since it relies on Monte Carlo methods. In this work, a neural network model has been developed as a surrogate model for NUBEAM in EAST. The database for neural-network model training, validation and testing is generated by running TRANSP for experimental discharges from recent EAST campaigns (after the latest NBI upgrade) while using the NUBEAM module. Simulation results illustrate that the trained neural network has the capability of replicating the predictions made by NUBEAM while demanding a significantly shorter execution time. Finally, these results indicate that surrogate models like the one proposed in this work could enable fast transport simulations for EAST after integrating them into a control-oriented predictive code such as COTSIM.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1992

Tetravalent chromium (Cr(4+)) as laser-active ion for tunable solid-state lasers

Generation of femtosecond pulses from a continuous-wave mode-locked chromium-doped forsterite (Cr(4+):Mg2SiO4) laser has been accomplished. The forsterite laser was actively mode-locked using an acousto-optic modulator operating at 78 MHz with two Brewster high-dispersion glass prisms for intra-cavity chirp compensation. Transform-limited sub-100-fs pulses were routinely generated in the TEM(sub 00) mode with 85 mW of continuous power (with 1 percent output coupler), tunable over 1230-1280 nm. The shortest pulses of 60-fs pulsewidth were measured.

Seas, A.↗
NASA NTRS2004

Development of a Multi-bus, Multi-source Reconfigurable Stirling Radioisotope Power System Test Bed

The National Aeronautics and Space Administration (NASA) has typically used Radioisotope Thermoelectric Generators (RTG) as their source of electric power for deep space missions. A more efficient and potentially more cost effective alternative to the RTG, the high efficiency 110 watt Stirling Radioisotope Generator 110 (SRG110) is being developed by the Department of Energy (DOE), Lockheed Martin (LM), Stirling Technology Company (STC) and NASA Glenn Research Center (GRC). The SRG110 consists of two Stirling convertors (Stirling Engine and Linear Alternator) in a dual-opposed configuration, and two General Purpose Heat Source (GPHS) modules. Although Stirling convertors have been successfully operated as a power source for the utility grid and as a stand-alone portable generator, demonstration of the technology required to interconnect two Stirling convertors for a spacecraft power system has not been attempted. NASA GRC is developing a Power System Test Bed (PSTB) to evaluate the performance of a Stirling convertor in an integrated electrical power system application. This paper will describe the status of the PSTB and on-going activities pertaining to the PSTB in the NASA Thermal-Energy Conversion Branch of the Power and On-Board Propulsion Technology Division.

Coleman, Anthony S.↗
NASA NTRS2004

T/R module development for large aperture L-band phased array

This paper describes a transmit / receive (T/R) module for a large L-band space based radar active phased array being developed at JPL. Electrical performance and construction techniques are described, with emphasis on the former. The T/R modules have a bandwidth of more than 80 MHz centered at 1260MHz and support dual, switched polarizations. Phase and amplitude are controlled by a 6-bit phase shifter and a 6-bit attenuator, respectively. The transmitter power amplifier generates 2.4 W into a nominal 50 ohm load with 36% overall efficiency. The receiver noise figure is 4.4 dB including all front-end losses. The module weighs 32 g and has a footprint of 8 cm x 4.5 cm. Fourteen of these T/R modules were fabricated at the JPL Pick-and-Place Facility and were tested using a computer-controlled measurement facility developed at JPL. Calibrated performance of this set of T/R modules is presented and shows good agreement with design predictions.

transmit / receive (T/R) module↗
NASA NTRS2017

Characterization of Pilot Technique

Skilled pilots often use pulse control when controlling higher order (i.e. acceleration-command) vehicle dynamics. Pulsing does not produce a stick response that resembles what the human Crossover Model predicts. The Crossover Model (CM) assumes the pilot provides compensation necessary (lead or lag) such that the suite of display-human-vehicle approximates an integrator in the region of crossover frequency. However, it is shown that the CM does appear to drive the pilots pulsing behavior in a very predictable manner. Roughly speaking, the pilot generates pulses such that the area under the pulse (pulse amplitude multiplied by pulse width) is approximately equal to area under the hypothetical CM output. This can allow a pilot to employ constant amplitude pulsing so that only the pulse duration (width) is modulated a drastic simplification over the demands of continuous tracking. A pilot pulse model is developed, with which the parameters of the pilots internally-generated CM can be computed in real time for pilot monitoring and display compensation. It is also demonstrated that pursuit tracking may be activated when pulse control is employed.

rotorcraft↗
DOE OSTI2025

Bi-stability and period-doubling cascade of frequency combs in exceptional-point lasers

Abstract Recent studies have demonstrated that a laser can self-generate frequency combs when tuned near an exceptional point (EP), where two cavity modes coalesce. These EP combs induce periodic modulation of the population inversion in the gain medium, and their repetition rate is independent of the laser cavity’s free spectral range. In this work, we perform a stability analysis that reveals two notable properties of EP combs, bi-stability and a period-doubling cascade. The period-doubling cascade enables halving of the repetition rate while maintaining the comb’s total bandwidth, presenting opportunities for the design of highly compact frequency comb generators.

exceptional points↗
NASA NTRS2016

Conventional and Bimodal Nuclear Thermal Rocket (NTR) Artificial Gravity Mars Transfer Vehicle Concepts

A variety of countermeasures have been developed to address the debilitating physiological effects of zero-gravity (0-g) experienced by cosmonauts and astronauts during their approximately 0.5 to 1.2 year long stays in low Earth orbit (LEO). Longer interplanetary flights, combined with possible prolonged stays in Mars orbit, could subject crewmembers to up to approximately 2.5 years of weightlessness. In view of known and recently diagnosed problems associated with 0-g, an artificial gravity (AG) spacecraft offers many advantages and may indeed be an enabling technology for human flights to Mars. A number of important human factors must be taken into account in selecting the rotation radius, rotation rate, and orientation of the habitation module or modules. These factors include the gravity gradient effect, radial and tangential Coriolis forces, along with cross-coupled acceleration effects. Artificial gravity Mars transfer vehicle (MTV) concepts are presented that utilize both conventional NTR, as well as, enhanced bimodal nuclear thermal rocket (BNTR) propulsion. The NTR is a proven technology that generates high thrust and has a specific impulse (Isp) capability of approximately 900 s-twice that of today's best chemical rockets. The AG/MTV concepts using conventional Nuclear Thermal Propulsion (NTP) carry twin cylindrical International Space Station (ISS)- type habitation modules with their long axes oriented either perpendicular or parallel to the longitudinal spin axis of the MTV and utilize photovoltaic arrays (PVAs) for spacecraft power. The twin habitat modules are connected to a central operations hub located at the front of the MTV via two pressurized tunnels that provide the rotation radius for the habitat modules. For the BNTR AG/MTV option, each engine has its own closed secondary helium(He)-xenon (Xe) gas loop and Brayton Rotating Unit (BRU) that can generate 10s of kilowatts (kWe) of spacecraft electrical power during the mission coast phase eliminating the need for large PVAs. A single inflatable TransHab-type habitation module is also used with multiple vertical floors oriented radial to the MTV spin axis. The BNTR MTV's geometry-long and linear-is naturally compatible with AG operation. By rotating the vehicle about its center-of-mass (CM) and perpendicular to its flight vector at approximately 3.0 to 5.2 rpm, a centrifugal force and AG environment corresponding to approximately 0.38 to 1.0 g can be established to help maintain crew fitness out to Mars and back. Vehicles using NTP/ Bimodal Nuclear Thermal Propulsion (BNTP) can more readily accommodate the heavier payload mass and increased RCS propellant loading associated with AG operation, and can travel faster to and from Mars thereby reducing the crew's exposure to galactic cosmic radiation and solar flares. Mission scenario descriptions, key vehicle features and operational characteristics for each propulsion option are presented using the lift capability and payload volumes estimated for the Space Launch System (SLS)-1B and followon Heavy Lift Vehicle (HLV).

Nuclear Propulsion↗
DOE OSTI2021

Suppressing the enhancement of stimulated Raman scattering in inhomogeneous plasmas by tuning the modulation frequency of a broadband laser

The stimulated Raman scattering (SRS) instability can inhibit the performance of laser driven inertial confinement fusion (ICF) implosions by scattering light into unwanted directions or by generating hot electrons that preheat the target fuel. In principle, ICF target designs can avoid parameter regimes conducive to large, linear SRS gains. In practice, kinetic inflation—the nonlinear enhancement of SRS due to electron trapping in the excited plasma wave—makes this difficult. Here we show that laser bandwidth in the form of frequency modulation can either decrease or increase the inflationary SRS (iSRS) threshold in inhomogeneous plasmas depending on the maximum chirp of the laser pulse. The threshold, mapped out by a series of particle-in-cell simulations, exhibits a minimum when the frequency change within the pulse cancels the spatial detuning due to density inhomogeneities along the trajectory of the scattered light. In conclusion, by tuning the pump laser parameters away from this minimum, the iSRS threshold can be larger than at zero bandwidth, providing a path to mitigating kinetic inflation in ignition relevant plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Radio frequency mixing modules for superconducting qubit room temperature control systems

As the number of qubits in nascent quantum processing units increases, the connectorized RF (radio frequency) analog circuits used in first generation experiments become exceedingly complex. The physical size, cost, and electrical failure rate all become limiting factors in the extensibility of control systems. We have developed a series of compact RF mixing boards to address this challenge by integrating I/Q quadrature mixing, intermediate frequency/LO (local oscillator)/RF power level adjustments, and direct current bias fine tuning on a 40 × 80 mm 2 four-layer printed circuit board with electromagnetic interference shielding. The RF mixing module is designed to work with RF and LO frequencies between 2.5 and 8.5 GHz. The typical image rejection and adjacent channel isolation are measured to be ~27 dBc and ~50 dB. By scanning the drive phase in a loopback test, the module short-term amplitude and phase linearity are typically measured to be 5 ×10 -4 (V pp /V mean ) and 1 ×10 -3 radian (pk-pk). The operation of the RF mixing board was validated by integrating it into the room temperature control system of a superconducting quantum processor and executing randomized benchmarking characterization of single and two qubit gates. We measured a single-qubit process infidelity of 9.3(3) × 10 -4 and a two-qubit process infidelity of 2.7(1) × 10 -2 .

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Tailoring Electrochemical CO 2 Reduction on Copper by Reactive Ionic Liquid and Native Hydrogen Bond Donors

Abstract Electrochemical CO 2 reduction (CO 2 RR) on copper (Cu) shows promise for higher‐value products beyond CO. However, challenges such as the limited CO 2 solubility, high overpotentials, and the competing hydrogen evolution reaction (HER) in aqueous electrolytes hinder the practical realization. We propose a functionalized ionic liquid (IL) which generates ion‐CO 2 adducts and a hydrogen bond donor (HBD) upon CO 2 absorption to modulate CO 2 RR on Cu in a non‐aqueous electrolyte. As revealed by transient voltammetry, electrochemical impedance spectroscopy (EIS), and in situ surface‐enhanced Raman spectroscopy (SERS) complemented with image charge augmented quantum‐mechanical/molecular mechanics (IC‐QM/MM) computations, a unique microenvironment is constructed. In this microenvironment, the catalytic activity is primarily governed by the IL and HBD concentrations; former controlling the double layer thickness and the latter modulating the local proton availability. This translates to ample CO 2 availability, reduced overpotential, and suppressed HER where C 4 products are obtained. This study deepens the understanding of electrolyte effects in CO 2 RR and the role of IL ions towards electrocatalytic microenvironment design.

Coskun, Oguz Kagan↗
DOE OSTI2025

Impact of Pendant Amine Basicity on Electrochemically-Promoted Cobalt Hydride Formation: Kinetic and Mechanistic Analysis

Here, we report the role of pendant amine basicity on the proton-coupled electron transfer (PCET) reactivity for the conversion of [Co III Cp(P Ph 2 N R 2 )(CH 3 CN)] 2+ complexes to [HCo III Cp(P Ph 2 N R 2 )] + , which is a key transformation involved in catalytic CO 2 conversion to formate and in H 2 evolution. Three complexes were studied, where the amine substituent (R) varies from benzyl, methoxyphenyl, or phenyl. In previous work on the benzyl system, we showed that the amine on the P Ph 2 N Bn 2 ligand serves as a kinetically accessible protonation site and enables three participating hydride formation mechanisms. In this work, a combination of electrochemical measurements and theoretical calculations were used to show that the electronic donation at the pendant amine influences the accessible PCET mechanism and proton transfer kinetics related to cobalt hydride formation under analogous reaction conditions. Notably, the amine with the most electron-donating substituent correlates to the lowest barrier for amine protonation, and specific cobalt hydride formation mechanisms can be shut off for the amine with the least electron-donating substituent. The mechanistic and kinetic changes upon modulation of the amine substituent have great implications for overall catalytic efficiency and selectivity, especially to generate the cobalt hydride intermediate involved in selective CO 2 reduction to formate. This work shows how to exploit kinetic basicity using ligand-cooperative design to facilitate PCET reactions involved in energy related transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Continuum Model to Define the Chemistry and Mass Transfer in a Bicarbonate Electrolyzer

Bicarbonate electrolyzers are devices designed to convert CO 2 captured from point sources or the atmosphere into chemicals and fuels without needing to first isolate pure CO 2 gas. In this work, we report here an experimentally validated model that quantifies the reaction chemistry and mass transfer processes within the catalyst layer and cation exchange membrane layer of a bicarbonate electrolyzer. Our results demonstrate that two distinct chemical microenvironments are key to forming CO at high rates: an acidic membrane layer that promotes in situ CO 2 formation and a basic catalyst layer that suppresses the hydrogen evolution reaction. We show that the rate of CO product formation can be increased by modulating the catalyst and membrane layer properties to increase the rate of in situ CO 2 generation and transport to the cathode. These insights serve to inform the design of bicarbonate and BPM-based CO 2 electrolyzers while demonstrating the value of modeling for resolving rate-determining processes in electrochemical systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗