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At least 1,297 records · Page 72
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS 4 3– -Bridged Dilanthanide Complexes

We report the synthesis and characterization of the trinuclear 4d-4f compounds [Co(C 5 Me 5 ) 2 ][(C 5 Me 5 ) 2 Ln(μ-S) 2 Mo(μ-S) 2 Ln(C 5 Me 5 ) 2 ], 1-Ln (Ln = Y, Gd, Tb, Dy), containing the highly polarizable MoS 4 3 - bridging unit. UV-Vis-NIR diffuse reflectance spectra and DFT calculations of 1-Ln reveal a low-energy metal-to-metal charge transfer transition assigned to charge transfer from the singly occupied 4d z 2 orbital of Mo V to the empty 5d orbitals of the lanthanides (4d in the case of 1-Y ), mediated by sulfur-based 3p orbitals. Electron paramagnetic resonance spectra collected for 1-Y in a tetrahydrofuran solution show large 89 Y hyperfine coupling constants of A ⊥ = 23 MHz and A || = 26 MHz, indicating the presence of significant yttrium-localized unpaired electron density. Magnetic susceptibility data support similar electron delocalization and ferromagnetic Ln-Mo exchange for 1-Gd , 1-Tb , and 1-Dy . This ferromagnetic exchange gives rise to an S = 15/2 ground state for 1-Gd and one of the largest magnetic exchange constants involving Gd III observed to date, with J Gd-Mo = +16.1(2) cm -1 . Additional characterization of 1-Tb and 1-Dy by ac magnetic susceptibility measurements reveals that both compounds exhibit slow magnetic relaxation. Although a Raman magnetic relaxation process is dominant for both 1-Tb and 1-Dy , an extracted thermal relaxation barrier of U eff = 68 cm -1 for 1-Dy is the largest yet reported for a complex containing a paramagnetic 4d metal center. Furthermore, these results provide a potentially generalizable route to enhanced n d-4f magnetic exchange, revealing opportunities for the design of new n d-4f single-molecule magnets and bulk magnetic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Oxygen vacancies in niobium pentoxide as a source of two-level system losses in superconducting niobium

We identify a major source of quantum decoherence in three-dimensional superconducting radio-frequency (SRF) resonators and two-dimensional transmon qubits composed of oxidized niobium: oxygen vacancies in the niobium pentoxide, which drive two-level system (TLS) losses. By probing the effect of sequential in situ vacuum-baking treatments on the rf performance of bulk Nb SRF resonators and on the oxide structure of a representative Nb sample using TOF SIMS, we find a nonmonotonic evolution of cavity quality factor Q 0 , which correlates with the interplay of Nb 2 O 5 vacancy generation and oxide-thickness reduction. We localize this effect to the oxide itself and present the insignificant role of diffused interstitial oxygen in the underlying Nb by regrowing the oxide via wet oxidation, which reveals a mitigation of aggravated TLS losses. We hypothesize that such vacancies in the pentoxide serve as magnetic impurities and are a source of TLS-driven rf loss.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Oxygen Vacancies in Niobium Pentoxide as a Source of Two-Level System Losses in Superconducting Niobium

We identify a major source of quantum decoherence in three-dimensional superconducting radio-frequency (SRF) resonators and two-dimensional transmon qubits composed of oxidized niobium: oxygen vacancies in the niobium pentoxide, which drive two-level system (TLS) losses. By probing the effect of sequential in situ vacuum-baking treatments on the rf performance of bulk Nb SRF resonators and on the oxide structure of a representative Nb sample using TOF SIMS, we find a nonmonotonic evolution of cavity quality factor Q0, which correlates with the interplay of Nb2O5 vacancy generation and oxide-thickness reduction. We localize this effect to the oxide itself and present the insignificant role of diffused interstitial oxygen in the underlying Nb by regrowing the oxide via wet oxidation, which reveals a mitigation of aggravated TLS losses. We hypothesize that such vacancies in the pentoxide serve as magnetic impurities and are a source of TLS-driven rf loss.

Bafia, Daniel P. [Fermilab]↗
NASA NTRS1978

Propagation of cosmic rays in extragalactic radio sources

A model of extragalactic radio sources is considered which assumes that relativistic electrons carry energy from the central galaxy to the radio lobes and also emit the radio waves. It is suggested that the radio emission is confined to an axis because electrons propagate parallel to the magnetic field more readily than perpendicular to it and that symmetric radio lobes appear on this axis because electrons are deposited at supercoherent transitions far from the central galaxy, where they propagate diffusively. The slow drift velocities that characterize this propagation are shown to explain the secondary structure between the main lobes and to establish a relationship between double sources and galactic radio trails.

Earl, J. A.↗
NASA NTRS1983

Synchrotron radiation as a probe of the inner magnetosphere of Jupiter

A short review is given on the characteristics of Jupiter's inner magnetosphere derived from radio observations in the decimetric wavelength range. A comparison of the data with sophisticated model calculations yields information on the magnetic field configuration and the electron distribution, its density, energy spectrum, and pitch angle dependence as a function of spatial coordinates. The latter information can be used to derive, e.g., the radial diffusion parameters plus the effects of the satellites, Jupiter's ring, and wave-particle interactions upon the electron distribution.

De Pater, I.↗
NASA NTRS1988

Employing analogies for ducted MHD waves in dense coronal structures

Analogies of fast MHD waves propagating along a dense coronal structure are exploited to examine how the size and shape of the inhomogeneity affect the properties of the Love- and Pekeris-type waves. The profile's shape determines the dispersive nature of the waves. Excited impulsively, magnetic Love and Pekeris waves give rise to quasi-periodic oscillations with a duration and time scale that depend on the cross-sectional area and strength of the inhomogeneity. More diffuse coronal inhomogeneities support impulsively generated periodic oscillations, with the quasi-periodic signature being absent.

Edwin, P. M.↗
NASA NTRS1990

Cosmic-ray pitch angle scattering in isotropic turbulence. II - Sensitive dependence on the dissipation range spectrum

The leading-order quasi-linear expressions for cosmic-ray pitch-angle scattering in isotropic magnetic turbulence were analyzed using three separate spectral forms: the Gaussian, the exponential, and the power-law. It is shown that the low-energy limit for the pitch-angle diffusion coefficient did not universally yield the 'slab' results obtained with a Gaussian dissipation range by Bieber et al. (1988). Instead, it was found that the low-energy limit depends on the steepness of the dissipation range spectrum, and the asymptotic functional forms can range between the slab results and the Fisk et al. (1974) results. It is also shown that the 90-deg pitch-angle limit displays a sensitive dependence on the form of the dissipation range spectrum and can depart dramatically from either the slab result or the result of Fisk.

Smith, Charles W.↗
NASA NTRS1998

Polar Plasma Wave Observations in the Auroral Region and Polar Cap

Auroral kilometric radiation (AKR), sometimes associated with auroral myriametric radiation (AMR), has been observed by the plasma wave instrument on board Polar on almost every northern hemisphere pass. High spectral resolution plots of the AKR obtained by the wide-band receiver of the plasma wave instrument on board the spacecraft often show discrete, negative-slope striations each extending over a period of several seconds. A preliminary survey of over 4000 spectrograms (each for 48 seconds of data) indicates that the striations are seen in the northern hemisphere near apogee about 5% of the time. The frequency range is 40 kHz less than f less than 100 kHz, but a few observations of signatures have been made at higher frequency (f less than 225 khz. The frequency drift rates R, are similar ranging from -9.0 kHz/sec less than R less than -1.0 kHz/sec. No data is currently available for perigee (southern hemisphere) passes. The paucity of positive-slope features may be due to the location of the satellite at altitudes well above the AKR source region. Past studies have suggested these features are due to AKR wave growth stimulated by the propagation of electromagnetic ion cyclotron waves travelling up (-R) or down (+R) the field line, through the source region. High-resolution waveform data from both Polar and FAST show the presence of solitary waves in the auroral region which may also be a source of these striations. AMR is seen as diffuse emission associated with, but at lower frequency than the lower AKR. Direction finding of these emissions is not conclusive, but for one case, they have a source region distinct from the magnetic field line containing the AKR source, but possibly associated with the auroral cavity density gradient.

Menietti, J. D.↗
DOE OSTI2026

Insights into Rotational and Translational Dynamics in Mixtures of Ethylene Glycol and Choline Chloride Using Nuclear Magnetic Resonance Techniques

This work examines molecular dynamics and interactions in ethylene glycol–choline chloride (EG–ChCl) mixtures across 0–33 mol % ChCl, spanning the true eutectic region near 17–20 mol % and the commonly used 1:2 formulation. We combine pulsed-field-gradient (PFG) diffusion, fast-field-cycling (FFC) relaxometry, temperature-dependent 13 C T 1 , and nuclear Overhauser effect spectroscopy (NOESY) to disentangle local from macroscopic dynamics. PFG and FFC show that both translational and average rotational motions largely track the strong increase in viscosity with ChCl content, with ethylene glycol consistently diffusing faster than the choline cation and no global dynamical anomaly at the eutectic composition. More subtle, site-specific composition effects nevertheless emerge. The ratio of the diffusion coefficient of the hydroxyl group of choline to the diffusion coefficient of the methyl group of choline displays a shallow minimum in the 17–25 mol % region, indicating a modest change in how the hydroxyl-bearing end of choline samples the underlying translational motion relative to the methyl groups. 13 C T 1 analysis shows that rotational correlation times at 25 °C generally increase with ChCl, reflecting viscosity-coupled slowing, while the CH 2 –N α site exhibits a small but reproducible deviation from this monotonic trend near the eutectic. NOESY spectra at similar compositions reveal enhanced cross-relaxation between EG and choline protons, consistent with increased headgroup–solvent contact density rather than a wholesale structural rearrangement. Overall, our multitechnique study demonstrates that EG–ChCl dynamics are predominantly viscosity-dominated, with the eutectic region acting as a subtle dynamical crossover where specific choline segments become maximally coupled to the hydrogen-bond network. These insights refine the structure–dynamics picture of choline-chloride DESs and provide practical guidance for tuning composition in electrochemical, separation, and catalytic applications.

diffusion↗
NASA NTRS1994

On the cross-field diffusion of ions in one- and two-dimensional hybrid simulations of collisionless shocks

It can be demonstrated analytically that under certain geometries used in numerical simulations of collisionless shocks in which there is at least one ignorable spatial coordinate, the transport of particles across the magnetic field is essentially zero. This notion is tested using one- and two-dimensional hybrid simulations (kinetic ions/fluid electrons). We find, as the theorem predicts, the particles treated kinetically are tied to the same field line on which they start.

Giacalone, Joe↗
DOE OSTI2022

Electron energization dynamics in interaction of self-generated magnetic vortices in upstream of collisionless electron/ion shocks

Abstract Relativistic collisionless shocks are considered responsible for particle energization mechanisms leading to particle acceleration. While electron energization in shock front region of electron/ion collisionless shocks are the most studied, the mechanism of electron energization in interaction with self-generated magnetic vortices (MVs) in the upstream region is still unclear. We investigate electron energization mechanism in the upstream region of electron/ion relativistic collisionless shocks, using two dimensional particle-in-cell (PIC) simulations. We discuss mechanism of electron energization which takes place in the upstream region of the shock, where the counter stream particles interact with incoming flow. The energy gain of electrons happens during their interaction with evolving fields of self-generated magnetic vortices in this region. Three Fermi-like electron energization scenarios are discussed. Stochastic acceleration of electrons in interaction with fields of MV leads to anisotropic heating of fast electrons due to diffusion in the momentum space of electrons and, finally, synergetic effect of evolving fields of MVs leads to the formation of a power-law tail of supra-thermal particles.

Naseri, N.↗
DOE OSTI2025

Deuterium and tritium anomalous transport in the generalized Hasegawa–Wakatani resistive drift wave turbulence model with finite ion Larmor radius

Anomalous transport of mixed deuterium–tritium plasma in the edge of magnetic fusion reactors is investigated using numerical solutions of resistive drift wave turbulence model equations, including finite Larmor radius effects, that are derived within the generalized Hasegawa–Wakatani framework. The anomalous cross field diffusivities of deuterium and tritium are compared in turbulence regimes with different values of the electron adiabaticity parameter controlling the existence of zonal flow. The dependence of the tritium-to-deuterium diffusivity ratio on the deuterium and tritium densities and the logarithmic density gradients is analyzed, and a scaling relation is obtained.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Impurity transport in the pedestal of H-mode plasmas with resonant magnetic perturbations

Experiments on DIII-D show that resonant magnetic perturbations (RMPs) reduce the impurity confinement time in the H-mode pedestal below that of naturally ELMy plasmas. STRAHL modeling of discharges with aluminum laser blow off (LBO) injection show increased diffusion in the pedestal of H-mode discharges with RMPs. The increased diffusion from the RMPs provides improved impurity control compared to the naturally ELMy discharges and prevents the buildup of impurities near the edge of the plasma. Tungsten LBO injection into discharges with and without RMPs led to striking differences in the evolution of the discharge. The naturally ELMy discharge became ELM free and showed an increase in edge radiation, leading to the eventual radiative collapse of the plasma. Injecting a similar number ofWparticles into discharges with RMPs, either with or without ELMs, led to a measurable accumulation of core W but did not significantly impact the evolution of the discharge. Furthermore, these results indicate that RMPs are beneficial for controlling the buildup of impurities in the pedestal region of the plasma.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1985

The local characteristic function of interplanetary particle propagation

An easily measurable intensity function which characterizes the interplanetary propagation of charged solar flare particles is presented. This function is nearly time invariant during a solar event despite the large variations of intensity and anisotropy, but varies from event to event. It characterizes the systematic and stochastic forces of the interplanetary magnetic field which focus and scatter the particles in pitch angle. The model of focused transport shows that this function is essentially determined by the local shape and amplitude of the pitch angle diffusion coefficient kappa (mu) and by the local value of the focusing length. The time profile of the solar particle injection is typically of negligible influence. The local characteristic function may be used as a powerful new tool for a systematic analysis of flare particle angular distributions, Examples are given.

Green, G.↗
NASA NTRS1990

Thermal structure of neutral winds from young stellar objects

The physical processes that control the thermal structure of lightly ionized winds from cool protostars are discussed. Attention is concentrated on the hydrogen gas, and the heating, cooling, and chemical processes that affect the neutral and ionic species of atomic and molecular hydrogen are examined. Warm silicate dust may condense out of the cooling wind and may heat the gas through collisions. Singly ionized sodium atoms, which do not recombine for the mass-loss rates considered, set a lower limit to the ionization fraction in the wind. Magnetic fields, which are presumed to accelerate the wind, couple directly to the ionic component of the gas and transfer momentum and energy to the neutral component through collisions. This process of ambipolar diffusion is found to be the dominant source of heat input to the gas.

Ruden, Steven P.↗
NASA NTRS1991

Field-aligned dynamics of chemically induced perturbations to the ionosphere

Ionospheric modification using photochemically reactive vapors is studied with a one-dimensional, multiion, fluid model of plasma flow along magnetic field lines. The magnitudes of ion and electron density changes are determined by considering both chemical processes (i.e., photoionization, ion-molecule reactions, dissociative recombination, electron attachment) and transport processes (i.e., multispecies diffusion, electric currents, ambipolar electric fields). The numerical treatment in the model is not specific to any type of release or any interaction chemistry. It has been used to simulate releases of Ba, CO2, and CF3Br in the ionosphere, but generalization to other species may be easily accomplished. The results of the calculations are found to be in good agreement with experimental observations. The feasibility of modifying the parallel current paths in the auroral F region is examined.

Bernhardt, P. A.↗
NASA NTRS1993

Kinetic simulations of the Kelvin-Helmholtz instability at the magnetopause

Two-dimensional hybrid simulations with particle ions and fluid electrons are used to calculate the kinetic evolution of the Kelvin-Helmholtz instability for a magnetopauselike configuration. The unidirectional magnetic field is essentially transverse to the plasma flow velocity, which is the most unstable case according to linear theory and models the flow dynamics in the subsolar region of the magnetopause for northward interplanetary magnetic field. We recover effects analogous to those found in MHD simulations, including a mode cascade to longer wavelengths. The boundary layer consists of coherent structure and is not well described by a diffusive process. Isolated structures on the order of the ion gyroradius are formed which can cross the boundary in either direction. We describe how the time evolution of these structures represents transport across boundary layers, and we consider the possible connection of these entities to flux transfer events and other structure seen in the low-latitude boundary layer at the Earth's magnetopause as well as to flux ropes commonly observed near the ionopause of Venus. We also discuss the relation of the hybrid calculations to previous MHD simulations and to observations.

Thomas, V. A.↗