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At least 1,297 records · Page 72

Assigning Optical Absorption Transitions with Light-Induced Crystal Structures: Case Study of a Single-Crystal Nanooptomechanical Transducer

UV/vis absorption spectroscopy affords indirect structural information about the photochemistry and photophysics of molecules by inferring types of electronic transitions from spectral features. Direct structural information would become available, though, if light-induced crystal structures could be mapped against changes in optical absorption spectra as a photochemical process evolves. We present a series of light-induced crystal structures that track real-time changes in solid-state optical absorption spectra of a crystalline nanooptomechanical transducer, while the transduction process unfolds within its crystal lattice at 100 K. Results afford a combined structural and spectral mapping of its solid-state optical absorption, from which the operational mechanism of nanooptomechanical transduction is revealed. Metal-to-ligand and metal-centered charge-transfer bands are assigned to optical absorption peaks directly from their 3-D light-induced crystal structures. This approach could be used to characterize many solid-state optoelectronic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Monarch Initiative in 2024: an analytic platform integrating phenotypes, genes and diseases across species

Abstract Bridging the gap between genetic variations, environmental determinants, and phenotypic outcomes is critical for supporting clinical diagnosis and understanding mechanisms of diseases. It requires integrating open data at a global scale. The Monarch Initiative advances these goals by developing open ontologies, semantic data models, and knowledge graphs for translational research. The Monarch App is an integrated platform combining data about genes, phenotypes, and diseases across species. Monarch's APIs enable access to carefully curated datasets and advanced analysis tools that support the understanding and diagnosis of disease for diverse applications such as variant prioritization, deep phenotyping, and patient profile-matching. We have migrated our system into a scalable, cloud-based infrastructure; simplified Monarch's data ingestion and knowledge graph integration systems; enhanced data mapping and integration standards; and developed a new user interface with novel search and graph navigation features. Furthermore, we advanced Monarch's analytic tools by developing a customized plugin for OpenAI’s ChatGPT to increase the reliability of its responses about phenotypic data, allowing us to interrogate the knowledge in the Monarch graph using state-of-the-art Large Language Models. The resources of the Monarch Initiative can be found at monarchinitiative.org and its corresponding code repository at github.com/monarch-initiative/monarch-app.

60 APPLIED LIFE SCIENCES↗

The CMSSM survives Planck , the LHC, LUX-ZEPLIN, Fermi -LAT, H.E.S.S. and IceCube

We revisit the viability of the CMSSM, searching for regions of parameter space that yield a neutralino dark matter density compatible with Planck measurements, as well as LHC constraints including sparticle searches and the mass of the Higgs boson, recent direct limits on spin-independent and -dependent dark matter scattering from the LUX-ZEPLIN (LZ) experiment, the indirect constraints from Fermi-LAT and H.E.S.S. on dark matter annihilations to photons in dwarf spheroidal galaxies and the Galactic Centre, and the IceCube limits on muons from annihilations to neutrinos in the Sun. For representative values of tan β and A 0 we map in detail the Planck-compatible strips in CMSSM parameter planes, which exhibit multiple distinctive features for large tan β, A 0 = 0 and μ > 0, and identify portions of the strips that survive all the phenomenological constraints. We find that the most powerful constraint is that from m h , followed by the LZ limit on spin-independent scattering, whereas sparticle searches at the LHC and indirect dark matter searches are less restrictive. Most of the surviving CMSSM parameter space features a Higgsino-like dark matter particle with a mass ~ 1000–1100 GeV, which could best be probed with future direct searches for dark matter scattering.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Interactive color display for multispectral imagery using correlation clustering

A method for processing multispectral data is provided, which permits an operator to make parameter level changes during the processing of the data. The system is directed to production of a color classification map on a video display in which a given color represents a localized region in multispectral feature space. Interactive controls permit an operator to alter the size and change the location of these regions, permitting the classification of such region to be changed from a broad to a narrow classification.

Haskell, R. E.↗

Evaluation of SIR-A space radar for geologic interpretation: United States, Panama, Colombia, and New Guinea

Comparisons between LANDSAT MSS imagery, and aircraft and space radar imagery from different geologic environments in the United States, Panama, Colombia, and New Guinea demonstrate the interdependence of radar system geometry and terrain configuration for optimum retrieval of geologic information. Illustrations suggest that in the case of space radars (SIR-A in particular), the ability to acquire multiple look-angle/look-direction radar images of a given area is more valuable for landform mapping than further improvements in spatial resolution. Radar look-angle is concluded to be one of the most important system parameters of a space radar designed to be used for geologic reconnaissance mapping. The optimum set of system parameters must be determined for imaging different classes of landform features and tailoring the look-angle to local topography.

Macdonald, H.↗

Correction and geological analysis of lunar 3.8 CM radar data

Several 3.8 cm radar frames were calibrated empirically by histogram fitting, because no instrument background data is available. Then data were corrected for geometric distortion by: (1) redetermining position of individual frames using most accurate recent lunar ephemerides; (2) reprojecting frames into simple cylindrical map projection; (3) using most recent catalog of lunar craters to determine the exact positions of features identifiable on radar frames; and (4) correcting for apparent distortion (misplacement of features in frames) by resampling using a different bilinear interpolation derived for each of the parallelopideds of the set defined for each frame. A hardcopy set of corrected frames was produced. Attempts to produce a mosaic of such corrected frames continue. The resulting mosaic can be used to show the systematic relationship between photographic thermal IR and radar data at different wavelengths in a region dominated by both mare and highland terrain.

Clark, P. E.↗

Patterns of vegetation in the Owens Valley, California

Spectral characteristics of semi-arid shrub communities were examined using Airborne Imaging Spectrometer (AIS) data collected in the tree mode on 23 May 1985. Mesic sites with relatively high vegetation density and distinct zonation patterns exhibited greater spectral signature variations than sites with more xeric shrub communities. Spectral signature patterns were not directly related to vegetation density or physiognomy, although spatial maps derived from an 8-channel maximum likelihood classification were supported by photo-interpreted surface features. In AIS data, the principal detected effect of shrub vegetation on the alluvial fans is to lower reflectance across the spectrum. These results are similar to those reported during a period of minimal physiological activity in autumn, indicating that shadows cast by vegetation canopies are an important element of soil-vegetation interaction under conditions of relatively low canopy cover.

Ustin, S. L.↗

A simulation of the IPS variations from a magnetohydrodynamical simulation

Calculations of the variations of interplanetary scintillation (IPS) from a disturbance simulated by a 3-D magnetohydrodynamical (MHD) model of the solar wind are presented. The simulated maps are compared with observations and it is found that the MHD model reproduces the qualitative features of observed disturbances. The disturbance produced by the MHD simulation is found to correspond in strength with the weakest disturbance which can be reliably detected by existing single station IPS observations.

Tappin, S. J.↗

Radiometer system requirements for microwave remote sensing from satellites

An area of increasing interest is the establishment of a significant research program in microwave remote sensing from satellites, particularly geosynchronous satellites. Due to the relatively small resolution cell sizes, a severe requirement is placed on beam efficiency specifications for the radiometer antenna. Geostationary satellite microwave radiometers could continuously monitor several important geophysical parameters over the world's oceans. These parameters include the columnar content of atmospheric liquid water (both cloud and rain) and water vapor, air temperature profiles, and possibly sea surface temperature. Two principle features of performance are of concern. The first is the ability of the radiometer system to resolve absolute temperatures with a very small absolute error, a capability that depends on radiometer system stability, on frequency bandwidth, and on footprint dwell time. The second is the ability of the radiometer to resolve changes in temperature from one resolution cell to the next when these temperatures are subject to wide variation over the overall field-of-view of the instrument. Both of these features are involved in the use of the radiometer data to construct high-resolution temperature maps with high absolute accuracy.

Juang, Jeng-Nan↗

A Study of the Non-Thermal X-ray Emission of Shell-Type Supernova Remnants

The term of the forth year of the award is the period from March 15, 2003 to March 14, 2004. During this year, Dr. Thomas Pannuti, who had been performing most of the analyses, made a transition to a new position at Caltech. As of September 2003, Dr. Michael Stage began performing most of the analyses. Dr. Stage has begun constructing a detailed catalog of the spatial and spectral properties of young supernova remnants as described in sections 1 and 4 of the proposal. Specifically, he has focused on the analysis of Chandra ACIS data. The exquisite spatial resolution of the Chandra telescope and the modest spectral resolution of the CCDs make these data ideal. Dr. Stage has developed a standard set of procedures to reduce the data, generate telescope and detector response libraries and handle instrumental and celestial background subtraction. He has also adapted some existing code to automate spectral extraction and fitting. This code enables us to analyze the spectra of tens of thousands of small subregions of supernova remnants. Dr. Stage has recently applied this process to ACIS data for the supernova remnants Cas A and Kepler. The results include maps of the fitted parameters, such as individual line intensities and centroids (i.e. Doppler shifts), the electron temperature, and the absorption column density. These maps are more accurate than simple energy-cut images because it is difficult (and sometimes impossible) to cleanly separate the line emission from the underlying continuum (especially at low energies). It is now possible to identify the locations at which emission from each element is produced. Some of the elements are seen to be layered. The electron temperature maps demonstrate that the outer edges of Cas A and Kepler are very hot with weak lines. This emission is almost certainly synchrotron dominated. Therefore, not only are the maps interesting in and of themselves, but they also provide an unbiased means of easily identifying features in the remnants that can be studied in more detail using, for example, synchrotron models. Over the next year, Dr. Stage will refine the analysis procedures, expand the analyses to include several other remnants, present the results at major scientific conferences and publish a catalog of the results. Since this work is producing impressive results, we have applied for very long Chandra observations of Kepler and Tycho to obtain enough counts to take lull advantage of the technique. A i Ms observation of Cas A is already scheduled. Over the past year, I completed a joint, spectra,l analysis of some X-ray, radio, and gamma-ray data for the supernova remnant SN 1006. The results of this analysis show that the synchrotron and, hence, electron spectrum of the remnant is curved. The amount of curvature in the electron spectrum is quantitatively consistent with predictions of the amount of curvature in the proton spectrum of the remnant. A paper describing this work is nearly complete. When Dr. Pannuti left, he was analyzing X-ray data for the young supernova remnant G266.2-1.2. Dr. Pannuti found the first evidence of thermal X-ray emission from this remnant. Furthermore, like SN 1006, the cutoff frequency varies with azimuth along the bright northeastern rim. This work will be published during the coming year.

Allen, Glenn E.↗

Human-Robot Site Survey and Sampling for Space Exploration

NASA is planning to send humans and robots back to the Moon before 2020. In order for extended missions to be productive, high quality maps of lunar terrain and resources are required. Although orbital images can provide much information, many features (local topography, resources, etc) will have to be characterized directly on the surface. To address this need, we are developing a system to perform site survey and sampling. The system includes multiple robots and humans operating in a variety of team configurations, coordinated via peer-to-peer human-robot interaction. In this paper, we present our system design and describe planned field tests.

Fong, Terrence↗

Multi-Decadal Surface Water Dynamics in North American Tundra

Over the last several decades, warming in the Arctic has outpaced the already impressive increases in global mean temperatures. The impact of these increases in temperature has been observed in a multitude of ecological changes in North American tundra including changes in vegetative cover, depth of active layer, and surface water extent. The low topographic relief and continuous permafrost create an ideal environment for the formation of small water bodies - a definitive feature of tundra surface. In this study, water bodies in Nunavut territory in northern Canada were mapped using a long-term record of remotely sensed observations at 30 meters spatial resolution from the Landsat suite of instruments. The temporal trajectories of water extent between 1985 and 2015 were assessed. Over 675,000 water bodies have been identified over the 31-year study period with over 168,000 showing a significant (probability is less than 0.05) trend in surface area. Approximately 55 percent of water bodies with a significant trend were increasing in size while the remaining 45 percent were decreasing in size. The overall net trend for water bodies with a significant trend is 0.009 hectares per year per water body.

Carroll, Mark L.↗

Addressing Usability for Discrete User Goals When Adding New Features to the Worldview Application

The Worldview (https://worldview.earthdata.nasa.gov/) application from NASA's Earth Observing System Data and Information System (EOSDIS) provides a low friction solution for users of different scientific backgrounds to access near real-time satellite imagery and data products. Worldview credits its successful growth by displaying new imagery from the Global Imagery Browse Services (GIBS), which has an increasing archive of 700+ products serving full-resolution satellite imagery from NASA's Earth observing fleet. NASA promotes the open sharing of all data with researchers, private industry, academia, and the general public. Worldview encourages this open data policy. Numerous general news publications feature Worldview for its unique imagery. Worldview also helps scholarly research in identifying field research locations, mapping thermal hotspots of active burning fires, and visualizing theoretical models of weather storm systems.

web application↗

ROSAT observations of the Orion-Eridanus superbubble

The Orion-Eridanus bubble is a superbubble created by the Orion OB1 stellar association. The X-ray emission from the interior of this bubble forms a prominent feature of the soft X-ray diffuse background extending across approximately 20 x 35 deg. The Rosat all sky survey maps of this object show various soft X-ray shadows cast by neutral foreground clouds against the bright emission of the superbubble interior. The velocities of some of these absorbing clouds were identified and distance limits were established, providing a 3D model of the bubble. The data are consistent with a model for the bubble in which the structure is formed by stellar winds and a recent supernova. Absorption features associated with the shell of the local bubble were identified which enable constraints to be placed on the distance and direction and to obtain measurement of the thermal pressure of the hot gas in this direction.

Burrows, David N.↗

Visualizing conical intersection passages via vibronic coherence maps generated by stimulated ultrafast X-ray Raman signals

Significance The capabilities of modern X-ray sources have substantially increased the temporal and spectral resolutions for the observation of elementary molecular events. Theoretically, it has been shown that these unique features can be exploited to probe vibronic coherences that emerge when molecules pass through conical intersections. Here, we demonstrate this technique for the photorelaxation of the RNA-nucleobase uracil after UV excitation. The generated coherence maps reveal the path of the nuclear wavepacket on the excited-state surface in the vicinity of the conical intersection. This information is directly accessible from the spectroscopically recorded signal. Being transferrable to other molecules, these coherence maps will provide detailed visualizations of other nonadiabatic passages in the future.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the Origin of Whistler Mode Radiation in the Plasmasphere

The origin of whistler mode radiation in the plasmasphere is examined from three years of plasma wave observations from the Dynamics Explorer and three years from the Imager for Magnetopause-to-Aurora Global Exploration (IMAGE) spacecraft. These data are used to construct plasma wave intensity maps of whistler mode radiation in the plasmasphere. The highest average intensities of the radiation in the wave maps show source locations and/or sites of wave amplification. Each type of emission is classified based on its magnetic latitude and longitude rather than any spectral feature. Equatorial electromagnetic (EM) emissions (approx. 30-330 Hz), plasmaspheric hiss (approx. 330 Hz - 3.3 kHz), chorus (approx. 2 kHz - 6 kHz), and VLF transmitters (approx. 10-50 kHz) are the main types of waves that are clearly delineated in the plasma wave maps. Observations of the equatorial EM emissions show that the most intense region is on or near the magnetic equator in the afternoon sector and that during times of negative B(sub z) (interplanetary magnetic field),the maximum intensity moves from L values of 3 to less than 2. These observations are consistent with the origin of this emission being particle-wave interactions in or near the magnetic equator. Plasmaspheric hiss shows high intensity at high latitudes and low altitudes (L shells from 2 to 4) and in the magnetic equator over L values from 2 to 3 in the early afternoon sector. The longitudinal distribution of the hiss intensity (excluding the enhancement at the equator) is similar to the distribution of lightning: stronger over continents than over the ocean, stronger in the summer than winter, and stronger on the dayside than nightside. These observations strongly support lightning as the dominant source for plasmaspheric hiss, which through particle-wave interactions, maintains the slot region in the radiation belts. The enhancement of hiss at the magnetic equator is consistent with particle-wave interactions. The chorus emissions are most intense on the morning side as previously reported. At frequencies from approx. 10-50 kHz VLF transmitters dominate the spectrum. The maximum intensity of the VLF transmitters is in the late evening or early morning with enhancements all along L shells from 1.8 to 3.

Green, James L.↗

A Self-Contained Mapping Closure Approximation for Scalar Mixing

Scalar turbulence exhibits interplays of coherent structures and random fluctuations over a broad range of spatial and temporal scales. This feature necessitates a probabilistic description of the scalar dynamics, which can be achieved comprehensively by using probability density functions (PDFs). Therefore, the challenge is to obtain the scalar PDFs (Lundgren 1967; Dopazo 1979). Generally, the evolution of a scalar is governed by three dynamical processes: advection, diffusion and reaction. In a PDF approach (Pope 1985), the advection and reaction can be treated exactly but the effect of molecular diffusion has to be modeled. It has been shown (Pope 1985) that the effect of molecular diffusion can be expressed as conditional dissipation rates or conditional diffusions. The currently used models for the conditional dissipation rates and conditional diffusions (Pope 1991) have resisted deduction from the fundamental equations and are unable to yield satisfactory results for the basic test cases of decaying scalars in isotropic turbulence, although they have achieved some success in a variety of individual cases. The recently developed mapping closure approach (Pope 1991; Chen, Chen & Kraichnan 1989; Kraichnan 1990; Klimenko & Pope 2003) provides a deductive method for conditional dissipation rates and conditional di usions, and the models obtained can successfully describe the shape relaxation of the scalar PDF from an initial double delta distribution to a Gaussian one. However, the mapping closure approach is not able to provide the rate at which the scalar evolves. The evolution rate has to be modeled. Therefore, the mapping closure approach is not closed. In this letter, we will address this problem.

He, Guo-Wei↗