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At least 1,297 records · Page 72

Investigations on the Origin of Topotactic Phase Transition of LaCoO 3 Thin Films with In Situ XRD and Ambient Pressure Hard X-ray Photoelectron Spectroscopy

With the applications of in situ X-ray diffraction (XRD), electrical I–V measurement, and ambient pressure hard X-ray photoelectron spectroscopy (AP-HAXPES), the characteristics of the topotactic phase transition of LaCoO 3 (LCO) thin films are examined. XRD measurements show clear evidence of structural phase transition (SPT) of the LCO thin films from the perovskite (PV) LaCoO 3 to the brownmillerite (BM) La 2 Co 2 O 5 phases through the intermediate La 3 Co 3 O 8 phase at a temperature of 350 °C under high-vacuum conditions, ~10 –5 mbar. The reverse SPT from BM to PV phases is also found under ambient pressure (>100 mbar) of air near 100 °C. Both observed SPTs in XRD are also identified in the electrical I–V measurements, i.e., the metallic PV phase to the insulating BM phase and vice versa. During the onset of SPTs, the bulk chemical and electronic states of LCO thin films are monitored with AP-HAXPES. The oxidation states in Co 2p spectra indicate that the oxygen vacancies are closely related to the SPT of LCO thin films. Also, the presence of enlarged band gap is observed as the SPT from PV to BM phases takes place, revealing the modified electronic properties of LCO due to the creation of oxygen vacancies. In conclusion, the analysis of valence band structures is further compared to the I–V measurements.

36 MATERIALS SCIENCE↗

Magnetotail electric fields observed from lunar orbit

Direct observations of convection electric fields in the earth's magnetotail are reported. The electric fields have been measured from lunar orbit by detection of the E x B/B-squared drift displacement of low-energy electrons at the limb of the moon. It is found that electric fields range in magnitude from a value less than or equal to 0.02 mV/m, the limit of sensitivity of the method, to 2 mV/M. The typical value is 0.15 mV/M, and the corresponding convection velocity is 15 km/s. The sense of the electric field is almost always dawn to dusk. The electric field is often variable on a time scale of hours and sometimes minutes. The observations indicate that the electric field is not uniform across the magnetotail. If it is assumed that the typical measured electric-field value represents an average over the inhomogeneities, the potential drop across the entire tail is of the order of 40 kV.

Mccoy, J. E.↗

Electric Field Conjugation in the Presence of Model Uncertainty

The Wide-Field Infrared Survey Telescope (WFIRST) is a 2.4-meter-diameter space telescope NASA program. The payload will include a coronagraph instrument (CGI). The CGI designs under development use deformable mirrors (DM) to create a point spread function (PSF) with a dark region around the obscured star object. Electric field conjugation (EFC) is an iterative nonlinear optimization procedure that uses measurements of the electric field at the image to determine the DM displacements to modify the PSF to create the region of high contrast in the image. EFC requires a numerical model of the coronagraph to calculate the Jacobian of the system, which is used, along with regularization, to solve for the DM displacements for each iteration of the nonlinear optimization. Ideally, the coronagraph is aligned and calibrated, and the calibration data are used in the numerical model for calculating the Jacobian. However, calibration and alignment measurements always contain uncertainty resulting in calibration error. Therefore, the Jacobian calculated from the numerical model is not an exact representation of the physical coronagraph, and the resulting DM solution for an EFC iteration does not have the exact impact on the electric field of the coronagraph as predicted by the EFC. The result is slow convergence, and, as will be shown, drives the use of more restrictive regularization. Using Monte Carlo trials, we investigate the effect of calibration error on EFC convergence and regulatization. Comparison to results from the High Contrast Imaging Testbed Hybrid Lyot Coronagraph are also presented.

Marx, David↗

Analysis of Electric and Magnetic Lightning-Generated Wave Amplitudes Measured by the Van Allen Probes

Herein we provide a statistical analysis of both electric and magnetic field wave amplitudes of very low frequency lightning-generated waves (LGWs) based on the equivalent of 11.5 years of observations made by the Van Allen Probes encompassing ~24.6 × 10 6 survey mode measurements. We complement this analysis with data from the ground-based World Wide Lightning Location Network to explore differences between satellite and ground-based measurements. LGW mean amplitudes are found to be low compared with other whistler mode waves (1 ± 1.6 pT and 19 ± 59 μV/m). Extreme events (1/5,000) can reach 100 pT and contributes strongly to the mean power below $L$ = 2. We find excellent correlations between World Wide Lightning Location Network-based power and wave amplitudes in space at various longitudes. We reveal strong dayside ionospheric damping of the LGW electric field. LGW amplitudes drop for $L$ < 2, contrary to the Earth's intense equatorial lightning activity. We conclude that it is difficult for equatorial LGW to propagate and remain at $L$ < 2.

Electric wave power↗

Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure

We present a comprehensive study of the inhomogeneous mixed-valence compound, EuPd 3 S 4 , by electrical transport, X-ray diffraction, time-domain 151 Eu synchrotron Mössbauer spectroscopy, and X-ray absorption spectroscopy measurements under high pressure. Electrical transport measurements show that the antiferromagnetic ordering temperature, T N , increases rapidly from 2.8 K at ambient pressure to 23.5 K at ~19 GPa and plateaus between ~19 and ~29 GPa after which no anomaly associated with T N is detected. A pressure-induced first-order structural transition from cubic to tetragonal is observed, with a rather broad coexistence region (~20 GPa to ~30 GPa) that corresponds to the T N plateau. Mössbauer spectroscopy measurements show a clear valence transition from approximately 50:50 Eu 2+ :Eu 3+ to fully Eu 3+ at ~28 GPa, consistent with the vanishing of the magnetic order at the same pressure. X-ray absorption data show a transition to a fully trivalent state at a similar pressure. Our results show that pressure first greatly enhances T N , most likely via enhanced hybridization between the Eu 4 f states and the conduction band, and then, second, causes a structural phase transition that coincides with the conversion of the europium to a fully trivalent state.

36 MATERIALS SCIENCE↗

Magnetospheric electric fields and currents

The progress made in the years 1983-1986 in understanding the character and operation of magnetospheric electric fields and electric currents is discussed, with emphasis placed on the connection with the interior regions. Special attention is given to determinations of global electric-field configurations, measurements of the response of magnetospheric particle populations to the electric-field configurations, and observations of the magnetospheric currents at high altitude and during northward IMF. Global simulations of current distributions are discussed, and the sources of global electric fields and currents are examined. The topics discussed in the area of impulsive and small-scale phenomena include substorm current systems, impulsive electric fields and associated currents, and field-aligned electrodynamics. A key finding of these studies is that the electric fields and currents are interrelated and cannot be viewed as separate entities.

Mauk, B. H.↗

Co-Investigator Proposal for Enstrophy - - Filamentation of Auroral Currents

Cornell University provided three instruments for the Enstrophy experiment: an electric field meter, a plasma wave receiver, and a magnetometer for measuring FAC. The electric field meter consisted of a 6 m Weitzmann boom system with analog signal processing and 12 bit ADC, which yielded one electric field component instantaneously and a two dimensional electric field every half spin. The plasma wave receiver used the same sensing system with the addition of pre-amplifiers in the spheres to sense plasma waves up to and including the electron Langmuir frequency. Signal processing employed a variety of continuous and snap shot techniques depending on the frequency range and band width. The science magnetometer provided by Cornell University was a Billingsly design fluxgate previously used on spacecraft missions but without radiation hardening. The magnetometer was mounted on a one meter, stiff aluminum "flop-down" boom. The Enstrophy payload was launched on february 11, 1999. Because of a design flaw in the event timers, the magnetometer boom was deployed before the payload despun. As a result the magnetometer separated mechanically from the boom but maintained electrical connection. This was confirmed by the calculation of the scalar magnetic field from all three vector components of the magnetic field. However, the individual vector values had no scientific value. The electric field and plasma wave instrumentation worked as designed. The data from these instruments was provided to the University of New Hampshire and to the Principal Investigator, as proposed.

Kintner, Paul M.↗

Microwave Processing of Planetary Surfaces for Volatile Extraction

In-Situ Resource Utilization will be necessary for sustained exploration of space. Volatiles are present in planetary soils, but water by far has the strongest potential for effective utilization. The presence of water at the lunar poles, Mars, and possibly on Phobos opens the possibility of producing LOX for propellant. Water is also a useful radiation shielding material and water (and oxygen) are expendables that are also required for habitation in space. Because of the strong function of water vapor pressure with temperature, heating soil effectively liberates water vapor by sublimation. Microwave energy will penetrate soil and heat from within much more efficiently than heating from the surface with radiant heat. This is especially true under vacuum conditions since the heat transfer rate is very low. The depth of microwave penetration is a strong function of the microwave frequency and to a lesser extent on soil dielectric properties. Methods for measuring the complex electric permittivity and magnetic permeability are being developed and have been measured for some lunar soil simulants at 0.5, 2.45, and 10 GHz from room temperature down to liquid nitrogen temperature. A new method for delivery of microwaves deep into a planetary surface is being prototyped with laboratory experiments and modeled with COMSOL MultiPhysics. We have plans to set up a planetary testbed in a large vacuum chamber in the coming year. Recent results will be presented.

Ethridge, Edwin C.↗

Making Antarctic Atmospheric Electricity Data Available to Living with a Star and Climate Change Investigators

This proposal requests support for making the nearly three decades of Antarctic atmospheric electricity data available to more workers. Measurements of the vertical electric field and air-earth current density made at the Earth's surface in Antarctica have recently been shown to be of considerable interest to scientists interested in monitoring short-term Sun-Earth connections and long term climate change. Such measurements have been made off and on for more than three decades, primarily at Vostok and South Pole stations. There is no single place where all of these data can be obtained via the Internet in a contemporary format. The work proposed here will attempt to remedy this deficiency as much as possible. Data we know to be presently available include data from South Pole, 1982-86 and 1991-1993, and Vostok station, 1997-present. Data were taken at South Pole and Vostok in the 60's and ~O'S, but these may prove difficult to obtain in digital form. At present, only the University of Houston's 1991-1993 data are available on the Web. Unfortunately, they are stored on a server slated for retirement. Also, they are written VAX binary floating point, using the UCLA/Stanford/Michigan flatfile format (FLATDBMS), which is obscure to some users. We propose to combine and reformat the three available data sets plus any others we can obtain onto a newer server. We will use a more common and comprehensible format. Archival copies will be burned onto CD and/or DVD-ROM media. Finally we will register these data with the appropriate NASA data systems.

Bering, Edgar↗

Modeling of the Coupled Magnetospheric and Neutral Wind Dynamos

Over the past four years of funding, SRI, in collaboration with the University of Texas at Dallas, has been involved in assessing the influence of thermospheric neutral winds on the electric field and current systems at high latitudes. The initial direction of the project was to perform a set of numerical experiments concerning the contribution of the magnetospheric and neutral wind dynamo processes, under specific boundary conditions, to the polarization electric field and/or the field-aligned current distribution at high latitudes. To facilitate these numerical experiments we developed a numerical scheme that relied on using output from the NCAR Thermosphere-Ionosphere General Circulation Model (NCAR-TIGCM), expanding them in the form of spherical harmonics and solving the dynamo equations spectrally. Once initial calculations were completed, it was recognized that the neutral wind contribution could be significant but its actual contribution to the electric field or currents depended strongly on the generator properties of the magnetosphere. Solutions to this problem are not unique because of the unknown characteristics of the magnetospheric generator, therefore the focus was on two limiting cases. One limiting case was to consider the magnetosphere as a voltage generator delivering a fixed voltage to the high-latitude ionosphere and allowing for the neutral wind dynamo to contribute only to the current system. The second limiting case was to consider the magnetosphere as a current generator and allowing for the neutral wind dynamo to contribute only to the generation of polarization electric fields. This work was completed and presented at the l994 Fall AGU meeting. The direction of the project then shifted to applying the Poynting flux concept to the high-latitude ionosphere. This concept was more attractive as it evaluated the influence of neutral winds on the high-latitude electrodynamics without actually having to determine the generator characteristics of the magnetosphere. The influence of the neutral wind was then determined not by estimating how much electric potential or current density it provides, but by determining the contribution of the neutral wind to the net electromagnetic energy transferred between the ionosphere and magnetosphere. The estimate of the net electromagnetic energy transfer and the role of the neutral winds proves to be a more fundamental quantity in studies of magnetosphere- ionosphere coupling also showed that by using electric and magnetic field measurements from the HILAT satellite, the Poynting flux could be a measurable quantity from polar-orbiting, low- altitude spacecraft. Through collaboration with Dr. Heelis and others at UTD and their expertise of the electric field measurements on the DE-B satellite, an extensive analysis was planned to determine the Poynting flux from the DE-B measurements in combination with a modeling effort to help interpret the observations taking into account the coupled magnetosphere-ionosphere.

Thayer, Jeffrey P.↗

Variational electric fields at low latitudes and their relation to spread-F and plasma irregularities

In situ measurements of variational electric fields at low latitudes, taken by OGO 6 satellite instruments, are analyzed. The observations are compared with other data on F region and spread-F structures. Conformity of the electric field fluctuations with the overall picture of low-latitude irregularities is examined empirically and theoretically, and candidate processes for generation of the observed irregularities are considered. Three distinct types of irregularities are delineated and compared.

Holtet, J. A.↗

Low cost switching circuit for van der Pauw resistivity and Hall measurements at various temperatures

The electrical characterization of materials, particularly superconductors, semiconductors, and those undergoing metal-insulator transitions (MITs), relies significantly on resistivity and Hall measurements as a function of temperature. The van der Pauw four-point probe method is commonly used for such measurements, which involves resistance measurements for different circuit configurations connected to sample contacts. However, repeating these measurements at different temperatures is challenging and time consuming. Here, this study introduces a novel approach utilizing a switching circuit controlled by an Arduino device and a LabVIEW program to automate resistance measurements for different electrical configurations. The effectiveness of this setup was demonstrated by testing V 2 O 3 thin film samples deposited on Al 2 O 3 (001) substrates using DC magnetron sputtering. The MIT temperature of the sample was 115 K during heating and 100 K during cooling. The sample exhibited p-type charge carriers with a Hall coefficient of 1.3 ± 0.1 x 10 -4 cm 3 /C and Hall mobility of 1.7 x 10 -1 cm 2 /V∙s, which is consistent with findings from other studies employing commercial equipment.

36 MATERIALS SCIENCE↗

A simple tachometer circuit

Electric circuit to measure frequency of repetitive sinusoidal or rectangular wave is presented. Components of electric circuit and method of operation are explained. Application of circuit as tachometer for automobile is discussed.

Dimeff, J.↗

Line of sight microwave propagation

A review of the uses of microwave line-of-sight propagation in remote atmospheric probing is given. The review concentrates on use of the following types of measurements: (1) the use of total electrical path length for measuring average density and water vapor content; (2) the use of amplitude and phase fluctuations over a single path for determining the form of the turbulence spectrum; (3) the use of angle-of-arrival data for measuring the decrease in refractivity; and (4) the use of multiple-element receiving antennas in determining wind speed, atmospheric parameters, and atmospheric models. A review is given of the connection between microwave measurements and meteorological parameters, and the basic electromagnetic theory on which the analyses are made. A few suggestions for future work in these areas is given.

Strohbehn, J. W.↗

The effect of wind on the microwave emission from the ocean's surface at 37 GHz

The microwave brightness temperature measurements from the Electrically Scanned Microwave Radiometer (frequency = 37 GHz) are compared with oceanic wind measurements from data buoys. It is shown that the brightness temperature can be manipulated to yield a measure of the surface roughening which can be very well accounted for by a simple geometric optics model. The data of 1.4, 8.36 and 19.34 GHz were similarly manipulated and shown to require a surface with less slope variance than predicted by optical measurements. It is also shown that the surface may be treated as isotropic to an accuracy equivalent to the roughening produced by a 2 m/s wind speed increment.

Wilheit, T. T.↗

The effect of wind on the microwave emission from the ocean's surface at 37 GHz

The microwave brightness temperature measurements from the electrically scanned microwave radiometer (frequency = 37 GHz) are compared with oceanic wind measurements from data buoys. It is shown that the brightness temperature can be manipulated to yield a measure of the surface roughening, which can be very well accounted for by a simple geometric optics model. The data of Hollinger (1971) at 1.4, 8, 36, and 19.34 GHz were similarly manipulated and shown to require a surface with less slope variance than that predicted by the Cox and Munk (1955) optical measurements. It is also shown that the surface may be treated as isotropic to an accuracy equivalent to the roughening produced by a 2-m/s wind speed increment.

Wilheit, T. T.↗