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At least 1,297 records · Page 72

Chemical Characterization and Reactivity Testing of Fuel-Oxidizer Reaction Product (Test Report)

The product of incomplete reaction of monomethylhydrazine (MMH) and nitrogen tetroxide (NTO) propellants, or fuel-oxidizer reaction product (FORP), has been hypothesized as a contributory cause of an anomaly which occurred in the chamber pressure (PC) transducer tube on the Reaction Control Subsystem (RCS) aft thruster 467 on flight STS-51. A small hole was found in the titanium-alloy PC tube at the first bend below the pressure transducer. It was surmised that the hole may have been caused by heat and pressure resulting from ignition of FORP. The NASA Johnson Space Center (JSC) White Sands Test Facility (WSTF) was requested to define the chemical characteristics of FORP, characterize its reactivity, and simulate the events in a controlled environment which may have lead to the Pc-tube failure. Samples of FORP were obtained from the gas-phase reaction of MMH with NTO under laboratory conditions, the pulsed firings of RCS thrusters with modified PC tubes using varied oxidizer or fuel lead times, and the nominal RCS thruster firings at WSTF and Kaiser-Marquardt. Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), ion chromatography (IC), inductively coupled plasma (ICP) spectrometry, thermogravimetric analysis (TGA) coupled to FTIR (TGA/FTIR), and mechanical impact testing were used to qualitatively and quantitatively characterize the chemical, thermal, and ignition properties of FORP. These studies showed that the composition of FORP is variable but falls within a limited range of compositions that depends on the fuel loxidizer ratio at the time of formation, composition of the post-formation atmosphere (reducing or oxidizing), and reaction or postreaction temperature. A typical composition contains methylhydrazinium nitrate (MMHN), ammonium nitrate (AN), methylammonium nitrate (MAN), and trace amounts of hydrazinium nitrate and 1,1-dimethylhydrazinium nitrate. The thermal decomposition reactions of FORP compositions used in this study were unremarkable, Neither the various compositions of FORP, the pure major components of FORP, nor mixtures of FORP with propellant-system corrosion products showed any unusual thermal activity when decomposed under laboratory conditions. Off-limit thruster operations were simulated by rapid mixing of liquid MMH and liquid NTO in a confined space. The test hardware was constructed with pressure- and temperature-measurement devices to determine if the expected fuel oxidizer reaction would result in increased energy release when FORP, FORP constituents, or propellant-system corrosion products were present. These tests demonstrated that FORP, MMHN, AN, or Inconel corrosion products can induce a mixture of MMH and NTO to produce component-damaging energies. The simulation-test program was not extensive enough to provide statistical probabilities for these events but did show that such events can occur. Damaging events required FORP or metal salts to be present at the initial mixing of MMH and NTO. Based on the results of these studies, it is suggested that removal or mitigation of a buildup of these materials may decrease the incidence of these high-energy, potentially damaging events.

Source record↗

Tidal Disruptions of Main Sequence Stars - I. Observable Quantities and their Dependence on Stellar and Black Hole Mass

This paper introduces a series of papers presenting a quantitative theory for the tidal disruption of main-sequence stars by supermassive black holes. Using fully general relativistic hydrodynamics simulations and MESA-model initial conditions, we explore the pericenter-dependence of tidal disruption properties for eight stellar masses(MM0.1510)and six black hole masses( MM105 105BH7). We present here the results most relevant to observations. The effects of internal stellar structure and relativity decouple for both the disruption cross section and the characteristic energy width of the debris. Moreover, the full disruption cross section is almost independent of Må for Må/Me3. Independent of Må, relativistic effects increase the critical pericenter distance for full disruption events by up to a factor of∼3 relative to the Newtonian prediction. The probability of a direct capture is also independent of Må; at MBH/Me;5×106 this probability is equal to the probability of a complete disruption. The breadth of the debris energy distribution ΔE can differ from the standard estimate by factors of0.35−2, depending on Må and MBH, implying a corresponding change(∝(ΔE)−3/2)in the characteristic mass-return timescale. We provide analytic forms, suitable for use in both event rate estimates and parameter inference, to describe all these trends. For partial disruptions, we find a nearly universal relation between the star’s angular momentum and the fraction of Må remaining. Within the “empty loss-cone” regime, partial disruptions must precede full disruptions. These partial disruptions can drastically affect the rate and appearance of subsequent total disruptions.

Taeho Ryu↗

The violet absorber on Io: Disulfur monoxide derivatives

Following the Voyager flybys of Jupiter it was generally accepted that the surface of Io is covered with SO2 frost and elemental sulfur. However, several difficulties have recently become apparent with this hypothesis. The S2O, which is readily formed under a variety of conditions from the dissociation of SO2, may be an important compound on Io, but at that time no reflectance data on the frost was available. The reflectance spectra of S2O/SO2 mixtures as low temperature frosts and their derivatives, polysulfur oxides, were measured at a variety of temperatures. Specific features possessed by these frosts and identified on Io are bands at 340 nm and 440 nm and a maximum at 800 nm, with decreasing IR reflectance. Thus, this material can account for many of the features in the spectrum of Io. So S2O rather than elemental S is probably the reddening agent on Io, and there is presently no good evidence for S on the surface.

Hapke, B.↗

Presumed PDF Modeling of Early Flame Propagation in Moderate to Intense Turbulence Environments

The present paper describes the results obtained from a one-dimensional time dependent numerical technique that simulates early flame propagation in a moderate to intense turbulent environment. Attention is focused on the development of a spark-ignited, premixed, lean methane/air mixture with the unsteady spherical flame propagating in homogeneous and isotropic turbulence. A Monte-Carlo particle tracking method, based upon the method of fractional steps, is utilized to simulate the phenomena represented by a probability density function (PDF) transport equation. Gaussian distributions of fluctuating velocity and fuel concentration are prescribed. Attention is focused on three primary parameters that influence the initial flame kernel growth: the detailed ignition system characteristics, the mixture composition, and the nature of the flow field. The computational results of moderate and intense isotropic turbulence suggests that flames within the distributed reaction zone are not as vulnerable, as traditionally believed, to the adverse effects of increased turbulence intensity. It is also shown that the magnitude of the flame front thickness significantly impacts the turbulent consumption flame speed. Flame conditions studied have fuel equivalence ratio s in the range phi = 0.6 to 0.9 at standard temperature and pressure.

Carmen, Christina↗

BAOBAB (Big And Outrageously Bold Asteroid Belt) Project

One of the intriguing results of NASA's Dawn mission is the composition and structure of the Main Asteroid Belt's only known dwarf planet, Ceres [1]. It has a top layer of dehydrated clays and salts [2] and an icy-rocky mantle [3,4]. It is widely known that the asteroid belt failed to accrete as a planet by resonances between the Sun and Jupiter. About 20-30 asteroids >100 km diameter are probably differentiated protoplanets [5]. 1) how many more and which ones are fragments of protoplanets? 2) How many and which ones are primordial rubble piles left over from condensation of the solar nebula? 3) How would we go about gaining better and more complete characterization of the mass, interior structure and composition of the Main Belt asteroid population? 4) What is the relationship between asteroids and ocean worlds? Bulk parameters such as the mass, density, and porosity, are important to characterize the structure of any celestial body, and for asteroids in particular, they can shed light on the conditions in the early solar system. Asteroid density estimates exist but currently they are often based on assumed properties of taxonomic classes, or through astronomical survey data where interactions with asteroids are weak at best resulting in large measurement uncertainty. We only have direct density estimates from spacecraft encounters for a few asteroids at this time. Knowledge of the asteroids is significant not only to understand their role in solar system workings, but also to assess their potential as space resources, as impact hazards on Earth, or even as harboring life forms. And for the distant future, we want to know if the idea put forth in a contest sponsored by Physics Today, to surface the asteroids into highly reflecting, polished surfaces and use them as a massively segmented mirror for astrophysical exploration [6], is feasible.

Asteroid Belt↗

Soil developments in polar deserts: Implications for exobiology and future Mars missions

Chemical alterations, weathering, and diagenesis of soil profiles from the dry valleys of Antarctica were studied as analogs of regolith development for the Martian regolith. Chemical weathering processes play an important part in soil development within the dry valleys of Antarctica. A suite of core samples were studied which were taken within the valley floors in addition to samples taken in the vicinity of evaporite and brine ponds. Analysis of water soluable cations and anions from core samples were performed along with petrographic analysis of selected samples. It was shown that ionic transport processes operate primarily above the permafrost zone. Abundances of the water soluable ions reflect the nature of secondary minerals produced by evaporation and weathering. Chloride, calcium, and sodium abundances for soils from the cores within the North and South Forks of Wright Valley, reflect the secondary mineralogy of the soil columns. Calculations for Na, Ca, and Cl abundances reflect the appearance of halite and antarcticite. In areas where excess Ca is present, X-ray diffraction studies show the presence of gypsum. It is well known that the Martian surface conditions may be favorable for chemical weathering. Primary silicates would be expected to be reactive with any ground water. It seems likely that Martian subsurface water is available to assist in the weathering of the primary minerals. Such weathering could result in the formation of clays, sulfates, carbonates, hydrates, halides, and zeolites. The dry valley cores have shown that they maybe excellent analogs to weathering processes on the near-surface of Mars. Since movement of water within the near-surface region clearly results in chemical weathering, leaching, and salt formation in the dry valleys, similar processes are probably operating within the Martian regolith.

Gibson, Everett K., Jr.↗

Heterogeneous Chemistry of HONO on Liquid Sulfuric Acid: A New Mechanism of Chlorine Activation on Stratospheric Sulfate Aerosols

Heterogeneous chemistry of nitrous acid (HONO) on liquid sulfuric acid (H2SO4) Was investigated at conditions that prevail in the stratosphere. The measured uptake coefficient (gamma) of HONO on H2SO4 increased with increasing acid content, ranging from 0.03 for 65 wt % to about 0.1 for 74 wt %. In the aqueous phase, HONO underwent irreversible reaction with H2SO4 to form nitrosylsulfuric acid (NO(+)HSO4(-). At temperatures below 230 K, NO(+)HSO4(-) was observed to be stable and accumulated in concentrated solutions (less than 70 wt % H2SO4) but was unstable and quickly regenerated HONO in dilute solutions (less than 70 wt %). HCl reacted with HONO dissolved in sulfuric acid, releasing gaseous nitrosyl chloride (ClNO). The reaction probability between HCl and HONO varied from 0.01 to 0.02 for 60-72 wt % H2SO4. In the stratosphere, ClNO photodissociates rapidly to yield atomic chlorine, which catalytically destroys ozone. Analysis of the laboratory data reveals that the reaction of HCl with HONO on sulfate aerosols can affect stratospheric ozone balance during elevated sulfuric acid loadings after volcanic eruptions or due to emissions from the projected high-speed civil transport (HSCT). The present results may have important implications on the assessment of environmental acceptability of HSCT.

Zhang, Renyi↗

Impact conditions required for formation of melt by jetting in silicates

It is demonstrated that the process of jetting which occurs when particles collide at oblique angles may produce melt at much lower velocities than are required for melt production in head-on collisions. The minimum velocities of impact required for jetting in aluminum, bronzitite, dunite, and quartz are calculated by the method of shock polars. The analysis, which depends on stated assumptions about attained pressures and the occurrence of jetting, uses shock-velocity particle-velocity equations of state with three shock regimes. The treatment indicates that jetting should arise in bronzitite, dunite, and quartz at relative velocities as low as 1-2 km/sec. At such velocities material which passes near the stagnation point in the jet-forming region is subjected to sufficiently high pressures so that it is probably melted.

Kieffer, S. W.↗

Remote Sensing of Liquid Water and Ice Cloud Optical Thickness and Effective Radius in the Arctic: Application of Airborne Multispectral MAS Data

A multispectral scanning spectrometer was used to obtain measurements of the reflection function and brightness temperature of clouds, sea ice, snow, and tundra surfaces at 50 discrete wavelengths between 0.47 and 14.0 microns. These observations were obtained from the NASA ER-2 aircraft as part of the FIRE Arctic Clouds Experiment, conducted over a 1600 x 500 km region of the north slope of Alaska and surrounding Beaufort and Chukchi Seas between 18 May and 6 June 1998. Multispectral images of the reflection function and brightness temperature in 11 distinct bands of the MODIS Airborne Simulator (MAS) were used to derive a confidence in clear sky (or alternatively the probability of cloud), shadow, and heavy aerosol over five different ecosystems. Based on the results of individual tests run as part of the cloud mask, an algorithm was developed to estimate the phase of the clouds (water, ice, or undetermined phase). Finally, the cloud optical thickness and effective radius were derived for both water and ice clouds that were detected during one flight line on 4 June. This analysis shows that the cloud mask developed for operational use on MODIS, and tested using MAS data in Alaska, is quite capable of distinguishing clouds from bright sea ice surfaces during daytime conditions in the high Arctic. Results of individual tests, however, make it difficult to distinguish ice clouds over snow and sea ice surfaces, so additional tests were added to enhance the confidence in the thermodynamic phase of clouds over the Beaufort Sea. The cloud optical thickness and effective radius retrievals used 3 distinct bands of the MAS, with the newly developed 1.62 and 2.13 micron bands being used quite successfully over snow and sea ice surfaces. These results are contrasted with a MODIS-based algorithm that relies on spectral reflectance at 0.87 and 2.13 micron.

King, Michael D.↗

Probabilistic Structural Evaluation of Uncertainties in Radiator Sandwich Panel Design

The Jupiter Icy Moons Orbiter (JIMO) Space System is part of the NASA's Prometheus Program. As part of the JIMO engineering team at NASA Glenn Research Center, the structural design of the JIMO Heat Rejection Subsystem (HRS) is evaluated. An initial goal of this study was to perform sensitivity analyses to determine the relative importance of the input variables on the structural responses of the radiator panel. The desire was to let the sensitivity analysis information identify the important parameters. The probabilistic analysis methods illustrated here support this objective. The probabilistic structural performance evaluation of a HRS radiator sandwich panel was performed. The radiator panel structural performance was assessed in the presence of uncertainties in the loading, fabrication process variables, and material properties. The stress and displacement contours of the deterministic structural analysis at mean probability was performed and results presented. It is followed by a probabilistic evaluation to determine the effect of the primitive variables on the radiator panel structural performance. Based on uncertainties in material properties, structural geometry and loading, the results of the displacement and stress analysis are used as an input file for the probabilistic analysis of the panel. The sensitivity of the structural responses, such as maximum displacement and maximum tensile and compressive stresses of the facesheet in x and y directions and maximum VonMises stresses of the tube, to the loading and design variables is determined under the boundary condition where all edges of the radiator panel are pinned. Based on this study, design critical material and geometric parameters of the considered sandwich panel are identified.

Kuguoglu, Latife↗

Tidal Disruptions of Main Sequence Stars - II. Simulation Methodology and Stellar Mass Dependence of the Character of Full Tidal Disruptions

This paper introduces a series of papers presenting a quantitative theory for the tidal disruption of main-sequence stars by supermassive black holes. Using fully general relativistic hydrodynamics simulations and MESA-model initial conditions, we explore the pericenter-dependence of tidal disruption properties for eight stellar masses (0.15 < M_/M<10)and six black hole masses( ́10<MM105 105BH7). We present here the results most relevant to observations. The effects of internal stellar structure and relativity decouple for both the disruption cross section and the characteristic energy width of the debris. Moreover, the full disruption cross section is almost independent of Må for Må/Me3. Independent of Må, relativistic effects increase the critical pericenter distance for full disruption events by up to a factor of ∼3 relative to the Newtonian prediction. The probability of a direct capture is also independent of Må; at MBH/Me5×106this probability is equal to the probability of a complete disruption. The breadth of the debris energy distribution ΔE can differ from the standard estimate by factors of 0.35−2, depending on Må and MBH, implying a corresponding change(∝(ΔE)−3/2)in the characteristic mass-return timescale. We provide analytic forms, suitable for use in both event rate estimates and parameter inference, to describe all these trends. For partial disruptions, we find a nearly universal relation between the star’s angular momentum and the fraction of Må remaining. Within the “empty loss-cone” regime, partial disruptions must precede full disruptions. These partial disruptions can drastically affect the rate and appearance of subsequent total disruptions

Taeho Ryu↗

Primary display latency criteria based on flying qualities and performance data

With a pilots' increasing use of visual cue augmentation, much requiring extensive pre-processing, there is a need to establish criteria for new avionics/display design. The timeliness and synchronization of the augmented cues is vital to ensure the performance quality required for precision mission task elements (MTEs) where augmented cues are the primary source of information to the pilot. Processing delays incurred while transforming sensor-supplied flight information into visual cues are unavoidable. Relationships between maximum control system delays and associated flying qualities levels are documented in MIL-F-83300 and MIL-F-8785. While cues representing aircraft status may be just as vital to the pilot as prompt control response for operations in instrument meteorological conditions, presently, there are no specification requirements on avionics system latency. To produce data relating avionics system latency to degradations in flying qualities, the Navy conducted two simulation investigations. During the investigations, flying qualities and performance data were recorded as simulated avionics system latency was varied. Correlated results of the investigation indicates that there is a detrimental impact of latency on flying qualities. Analysis of these results and consideration of key factors influencing their application indicate that: (1) Task performance degrades and pilot workload increases as latency is increased. Inconsistency in task performance increases as latency increases. (2) Latency reduces the probability of achieving Level 1 handling qualities with avionics system latency as low as 70 ms. (3) The data suggest that the achievement of desired performance will be ensured only at display latency values below 120 ms. (4) These data also suggest that avoidance of inadequate performance will be ensured only at display latency values below 150 ms.

Funk, John D., Jr.↗

Characterization of Operational Performance of Ka-Band Links in Deep Space Network

This paper presents a characterization of performance of 32-GHz Ka-band link in an operational environment. The data come from tracking of Kepler spacecraft by the NASA Deep Space Network (DSN) in the past few years. Ka-band link offers a significant signal-to-noise advantage compared to the more common X- or S-band; however, it is subject to more signal fluctuation caused by the weather. Kepler is the first mission supported by the DSN that solely rely on the higher deep space Ka-band communications link to return its high-rate science data. A well characterization of the operational performance of Kepler would benefit future Ka-band missions, especially for those operating with smaller link margin. The study examines how weather conditions at the DSN facilities (e.g., winds, clouds, rains) affect the received signal, particularly on telemetry data. It addresses questions such as how often the weather affects the link and how much degradation the link could suffer. Among the 22 Ka-band passes in 2012, heavy clouds affected one pass and two passes were impacted by high winds. The adverse weather caused at time as much as 3-dB instantaneous change in the signal to noise ratio (SNR). Estimates of degradation to the SNR as a function of wind speeds are captured based on observations. This study also quantifies the probability distribution of the variation of received signal power. With such information, future missions can better plan their link design. An optimal link design aims for just having enough margin to realize the data return with a targeted probability, with neither having too much margin that it reduces the downlink data rate nor insufficient reserve that causes frequent data outages. The study tries to provide some answers to the questions such as how much does SNR vary from one tracking pass to the next, and what is the cumulative distribution of signal fluctuation. Regarding the signal variation over many tracking passes, we found that the averaged symbol SNR (SSNR) for each pass changed by as much as 4 dB. Some variations were due to geometry such as the changing distance between spacecraft and Earth and different antenna pointing elevations. Other variations seem to be random in nature, reflecting the randomness of operational environments. Some passes were found to be quite stable, with a standard deviation of symbol SNR around 0.25 dB while others had greater variation, up to 1.4 dB. Overall, the cumulative distribution of the symbol SNR reflects that 50% of the fluctuations was less than 0.6 dB, 90% of fluctuation was within 1.6 dB and 95% within 2.2 dB. Some of the challenges in data processing, validation and modeling were captured in this paper. We observed some inconsistent measurements where operational data significantly deviate from a normal expectation. These inconsistent measurements made it hard to develop an accurate and consistent performance model, such as the degradation of signal SNR as a function of high wind. The difficulty was compounded by the fact that there were only a few Ka-band passes observed in high winds.

Pham, Timothy↗

Bias and spread in EVT performance tests.

Performance tests (error probability measurements) of communications systems characterized by low bit rates and high reliability requirements frequently utilize classical extreme value theory (EVT) to avoid the excessive test times encountered with bit error rate (BER) tests. If the underlying noise is Gaussian or perturbed Gaussian, the EVT error estimates have either excessive bias or excessive variance if an insufficient number of test samples is used. EVT is examined to explain the cause of this bias and spread. Experimental verification is made by testing a known Gaussian source, and procedures that minimize these effects are described. It seems apparent that even under the best of conditions the EVT test results are not particularly better than those of BER tests.

Smith, J. G.↗

Kinetics of Open Circuit Processes in Undischarged Li/SOC12 Cells

The kinetics of the heat producing processes in undischarged Li/SOCl2 cells under open circuit conditions were measured by heat-conduction microcalorimetry. The cells studied, Honeywell type G2666 reserve cells, were activated as needed and the rate of open circuit heat output determined as a function of time since activation and temperature. The results at each temperature can be described by an equation of the form q = Bktx where q is the rate of heat output, B is the heat produced per unit of reaction, k and x are empirical constants, and t is the time since activation. Both x and k are found to be functions of temperature; therefore, accelerated testing at elevated temperatures is probably not valid for these cells until the processes involved are better understood.

Hansen, L. D.↗

Strong metal-support interactions

It has been demonstrated that synergistic metal-support effects can occur which markedly enhance specific activity and alter selectivity in certain reactions. Because of the presence of such effects in certain reactions conducted under reducing conditions (that is, under H2 pressure), but not others, the creation of unique sites at the metal-support interface seems to be the best model at the present time to explain this behavior. The postulation of these sites, which are specific for a certain reactant such as CO, provides an effective explanation for the higher methanation rates that have been reported over some catalysts. The creation of these sites in the adlineation zone is facilitated by hydrogen spillover from the metal surface, and this same process can also enhance the reduction of many oxide supports. Although oxygen spillover is much less probable due to its higher heat of adsorption, it is much less well understood and the possibility of rate enhancements in CO oxidation caused by special interface sites cannot be discounted at the present time. Consequently, this seems to be an important area of future research.

Vannice, M. Albert↗

Shock effects and argon loss in samples of the Leedey L6 chondrite experimentally shocked to 29-70 GPa pressures

The recovery of polished 600-micron-thick 7-mm-diameter disk samples and powder samples of the Leedey L6 chondrite from 29-70-GPa experimental shocks is investigated experimentally under vacuum conditions, with a focus on the possible direct shock loss of radiogenic Ar. The results of petrographic examination of the shocked samples and Ar isotope measurements are presented in tables, graphs, and micrographs and characterized in detail. The principal damage mechanisms are identified as mechanical disaggregation and increasing cataclasis, with little melting. The degassing of radiogenic Ar is found to be relatively modest and to increase with shock pressure and sample porosity; it is attributed to a combination of mechanical grain disruption and feldspar melting. It is inferred that Ar loss in naturally shocked materials (especially those showing few signs of melting) probably occurs during extended exposure to high temperatures during impact formation.

Bogard, Donald↗

Disruption of the Globular Cluster Pal 5

Orbit calculations suggest that the sparse globular cluster, Pal 5, will pass within 7 kpc of the Galactic center the next time it crosses the plane, where it might be destroyed by tidal stresses. We study this problem, treating Pal 5 as a self-consistent dynamical system orbiting through an external potential that represents the Galaxy. The first part of the problem is to find suitable analytic approximations to the Galactic potential. They must be valid in all regions the cluster is likely to explore. Observed velocity and positional data for Pal 5 are used as initial conditions to determine the orbit. Methods we used for a different problem some 12 years ago have been adapted to this problem. Three experiments have been run, with M/L= 1, 3, and 10, for the cluster model. The cluster blew up shortly after passing through the Galactic plane (about 130 Myrs after the beginning of the run) with M/L=1. At M/L = 3 and 10 the cluster survived, although it got quite a kick in the fundamental mode on passing through the plane. But the fundamental mode oscillation died out in a couple of oscillation cycles at M/L=10. Pal 5 will probably be destroyed on its next crossing of the Galactic plane if M/L=1, but it can survive (albeit with fairly heavy damage) if NI/L=3. We haven't tried to trap the mass limits more closely than that. Pal 5 comes through pretty well unscathed at M/L=10. An interesting follow-up experiment would be to back the cluster up along its orbit to look at its previous passage through the Galactic plane, to see what kind of object it might have been at earlier times.

Miller, R. H.↗