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At least 1,297 records · Page 72

Improving Time Step Convergence in an Atmosphere Model With Simplified Physics: The Impacts of Closure Assumption and Process Coupling

Convergence testing is a common practice in the development of dynamical cores of atmospheric models but is not as often exercised for the parameterization of sub-grid physics. An earlier study revealed that the stratiform cloud parameterizations in several predecessors of the Energy Exascale Earth System Model (E3SM) showed strong time-step sensitivity and slower-than-expected convergence when the model's time step was systematically refined. In this work, a simplified atmosphere model is configured that consists of the spectral-element dynamical core of the E3SM atmosphere model coupled with a large-scale condensation parameterization based on commonly used assumptions. This simplified model also resembles E3SM and its predecessors in the numerical implementation of process coupling and shows poor time-step convergence in short ensemble tests. We present a formal error analysis to reveal the expected time-step convergence rate and the conditions for obtaining such convergence. Numerical experiments are conducted to investigate the root causes of convergence problems. We show that revisions in the process coupling and closure assumption help to improve convergence in short simulations using the simplified model; the same revisions applied to a full atmosphere model lead to significant changes in the simulated long-term climate. This work demonstrates that causes of convergence issues in atmospheric simulations can be understood by combining analyses from physical and mathematical perspectives. Addressing convergence issues can help to obtain a discrete model that is more consistent with the intended representation of the physical phenomena.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric pressure plasma chemical vapor deposition reactor for 100 mm wafers, optimized for minimum contamination at low gas flow rates

Gas discharge plasmas used for thinfilm deposition by plasma-enhanced chemical vapor deposition (PECVD) must be devoid of contaminants, like dust or active species which disturb the intended chemical reaction. In atmospheric pressure plasma systems employing an inert gas, the main source of such contamination is the residual air inside the system. To enable the construction of an atmospheric pressure plasma (APP) system with minimal contamination, we have carried out fluid dynamic simulation of the APP chamber into which an inert gas is injected at different mass flow rates. On the basis of the simulation results, we have designed and built a simple, scaled APP system, which is capable of holding a 100 mm substrate wafer, so that the presence of air (contamination) in the APP chamber is minimized with as low a flow rate of argon as possible. This is examined systematically by examining optical emission from the plasma as a function of inert gas flow rate. It is found that optical emission from the plasma shows the presence of atmospheric air, if the inlet argon flow rate is lowered below 300 sccm. That there is minimal contamination of the APP reactor built here, was verified by conducting an atmospheric pressure PECVD process under acetylene flow, combined with argon flow at 100 sccm and 500 sccm. The deposition of a polymer coating is confirmed by infrared spectroscopy. X-ray photoelectron spectroscopy shows that the polymer coating contains only 5% of oxygen, which is comparable to the oxygen content in polymer deposits obtained in low-pressure PECVD systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Influence of Lower Tropospheric Moisture on Local Soil Moisture-Precipitation Feedback Over the U.S. Southern Great Plains

Land-atmosphere coupling (LAC) has long been studied focusing on land surface and atmospheric boundary layer processes. However, the influence of lower tropospheric (LT) humidity on LAC remains largely unexplored. In this study, we use radiosonde observations from the U.S. Southern Great Plains (SGP) site and an entrained parcel buoyancy model to investigate the impact of LT humidity on LAC there during the warm season (May–September). We quantify the effect of LT humidity on convective buoyancy by measuring the difference between the 2–4 km vertically integrated buoyancy with and without the influence of background LT humidity. Our results show that, under dry soil conditions, anomalously high LT humidity is necessary to produce the buoyancy profiles required for afternoon precipitation events (APEs). These APEs under dry soil moisture cannot be explained by commonly used local land-atmosphere coupling indices such as the convective triggering potential/low-level humidity index (CTP/HI Low ), which do not account for the influence of the LT humidity. On the other hand, consideration of LT humidity is unnecessary to explain APEs under wet soil moisture conditions, suggesting the boundary layer moisture alone could be sufficient to generate the required buoyancy profiles. These findings highlight the need to consider the impact of LT humidity, which is often decoupled from the humidity near the surface and largely controlled by moisture transport, in understanding land-atmospheric feedbacks over dry soil conditions, especially during droughts or dry spells over the SGP.

Gaoyun Wang↗

Science Goals and Mission Concept for the Future Exploration of Titan and Enceladus

Saturn׳s moons, Titan and Enceladus, are two of the Solar System׳s most enigmatic bodies and are prime targets for future space exploration. Titan provides an analogue for many processes relevant to the Earth, more generally to outer Solar System bodies, and a growing host of newly discovered icy exoplanets. Processes represented include atmospheric dynamics, complex organic chemistry, meteorological cycles (with methane as a working fluid), astrobiology, surface liquids and lakes, geology, fluvial and aeolian erosion, and interactions with an external plasma environment. In addition, exploring Enceladus over multiple targeted flybys will give us a unique opportunity to further study the most active icy moon in our Solar System as revealed by Cassini and to analyse in situ its active plume with highly capable instrumentation addressing its complex chemistry and dynamics. Enceladus׳ plume likely represents the most accessible samples from an extra-terrestrial liquid water environment in the Solar system, which has far reaching implications for many areas of planetary and biological science. Titan with its massive atmosphere and Enceladus with its active plume are prime planetary objects in the Outer Solar System to perform in situ investigations. In the present paper, we describe the science goals and key measurements to be performed by a future exploration mission involving a Saturn-Titan orbiter and a Titan balloon, which was proposed to ESA in response to the call for definition of the science themes of the next Large-class mission in 2013. The mission scenario is built around three complementary science goals: (A) Titan as an Earth-like system; (B) Enceladus as an active cryovolcanic moon; and (C) Chemistry of Titan and Enceladus - clues for the origin of life. The proposed measurements would provide a step change in our understanding of planetary processes and evolution, with many orders of magnitude improvement in temporal, spatial, and chemical resolution over that which is possible with Cassini-Huygens. This mission concept builds upon the successes of Cassini-Huygens and takes advantage of previous mission heritage in both remote sensing and in situ measurement technologies.

future missions↗

The influence of orography on the transport of atmospheric constituents

Given the fact that martian orography varies over a range of two scale heights (cf., about one scale height on Earth), it is thought that on Mars some aspects of the circulation should be affected to a large degree by the presence of orography. Initial results from two numerical models are presented that illustrate the effect of orography on cross-equatorial transport on Mars. On Earth, western boundary currents are found not only in the oceans as one would expect, but also in the troposphere, the most notable example being the East African Jet, which has an important effect on the monsoon circulation of the Eastern Indian Ocean. Two models were used for this investigation: a simple GCM (hereafter referred to as the SGCM); and a simple one-level barotropic model (BM). The SGCM solves the hydrostatic primitive equations on a sphere by representing model variables by spherical harmonics in the horizontal, with nonlinear terms being calculated in grid-point space. In the vertical, the model uses the sigma coordinate system in finite-difference form. The model represents the radiative processes in the atmosphere by a Newtonian relaxation to a specified zonal mean temperature state and surface drag by Rayleigh friction in the lowest model level.

Joshi, Manoj M.↗

It's a Sooty Problem: Black Carbon and Aerosols from Space

Our knowledge of atmospheric aerosols (smoke, pollution, dust or sea salt particles, small enough to be suspended in the air), their evolution, composition, variability in space and time and interaction with solar radiation, clouds and precipitation is lacking despite decades of research. Just recently we recognized that understanding the global aerosol system is fundamental for progress in climate change and hydrological cycle research. While a single instrument was used to demonstrate 50 yrs ago that the global CO2 levels are rising, posing thread to our climate, we need an may of satellites, surface networks of radiometers, elaborated laboratory and field experiments coupled with chemical transport models to understand the global aerosol system. This complexity of the aerosol problem results from their short lifetime (1 week), variability of the chemical composition and complex chemical and physical processes in the atmosphere. The result is a heterogeneous distribution of aerosol and their properties. The new generation of satellites and surface networks of radiometers provides exciting opportunities to measure the aerosol properties and their interaction with clouds and climate. However farther development in the satellite capability, aerosol chemical models and climate models is needed to fully decipher the aerosol secrets with accuracy required to predict future climates.

Kaufman, Yoram J.↗

Quality Control Algorithms for the Kennedy Space Center 50-Megahertz Doppler Radar Wind Profiler Winds Database

This paper presents the process used by the Marshall Space Flight Center Natural Environments Branch (EV44) to quality control (QC) data from the Kennedy Space Center's 50-MHz Doppler Radar Wind Profiler for use in vehicle wind loads and steering commands. The database has been built to mitigate limitations of using the currently archived databases from weather balloons. The DRWP database contains wind measurements from approximately 2.7-18.6 km altitude at roughly five minute intervals for the August 1997 to December 2009 period of record, and the extensive QC process was designed to remove spurious data from various forms of atmospheric and non-atmospheric artifacts. The QC process is largely based on DRWP literature, but two new algorithms have been developed to remove data contaminated by convection and excessive first guess propagations from the Median Filter First Guess Algorithm. In addition to describing the automated and manual QC process in detail, this paper describes the extent of the data retained. Roughly 58% of all possible wind observations exist in the database, with approximately 100 times as many complete profile sets existing relative to the EV44 balloon databases. This increased sample of near-continuous wind profile measurements may help increase launch availability by reducing the uncertainty of wind changes during launch countdown

Barbre, Robert E., Jr.↗

An extensible perturbed parameter ensemble for the Community Atmosphere Model version 6

This paper documents the methodology and preliminary results from a perturbed parameter ensemble (PPE) technique, where multiple parameters are varied simultaneously and the parameter values are determined with Latin hypercube sampling. This is done with the Community Atmosphere Model version 6 (CAM6), the atmospheric component of the Community Earth System Model version 2 (CESM2). We apply the PPE method to CESM2–CAM6 to understand climate sensitivity to atmospheric physics parameters. The initial simulations vary 45 parameters in the microphysics, convection, turbulence and aerosol schemes with 263 ensemble members. These atmospheric parameters are typically the most uncertain in many climate models. Control simulations and targeted simulations to understand climate forcing due to aerosols and fast climate feedbacks are analyzed. The use of various emulators is explored in the multi-dimensional space mapping input parameters to output metrics. Parameter impacts on various model outputs, such as radiation, cloud and aerosol properties, are evaluated. Machine learning is also used to probe optimal parameter values against observations. Our findings show that PPE is a valuable tool for climate uncertainty analysis. Furthermore, by varying many parameters simultaneously, we find that many different combinations of parameter values can produce results consistent with observations, and thus careful analysis of tuning is important. The CESM2–CAM6 PPE is publicly available and extensible to other configurations to address questions of other model processes in the atmosphere and other model components (e.g., coupling to the land surface).

54 ENVIRONMENTAL SCIENCES↗

An Extensible Perturbed Parameter Ensemble for the Community Atmosphere Model Version 6

This paper documents the methodology and preliminary results from a Perturbed Parameter Ensemble (PPE) technique, where multiple parameters are varied simultaneously and the parameter values are determined with Latin hypercube sampling. This is done with the Community Atmosphere Model version 6 (CAM6), the atmospheric component of the Community Earth System Model version 2 (CESM2). We apply the PPE method to CESM2-CAM6 to understand climate sensitivity to atmospheric physics parameters. The initial simulations vary 45 parameters in the microphysics, convection, turbulence and aerosol schemes with 263 ensemble members. These atmospheric parameters are typically the most uncertain in many climate models. Control simulations are analyzed and targeted simulations to understand climate forcing due to aerosols and fast climate feedbacks. The use of various emulators is explored in the multi- dimensional space mapping input parameters to output metrics. Parameter impacts on various model outputs, such as radiation, cloud and aerosol properties are evaluated. Machine learning is also used to probe optimal parameter values against observations. Our findings show that using PPE is a valuable tool for climate uncertainty analysis. Furthermore, by varying many parameters simultaneously, we find that many different combinations of parameter values can produce results consistent with observations, and thus careful analysis of tuning is important. The CESM2-CAM6 PPE is publicly available, and extensible to other configurations to address questions of other model processes in the atmosphere and other model components (e.g. coupling to the land surface).

Machine learning↗

NOAA satellite-derived operational sea surface temperature products

The National Oceanic and Atmospheric Administration (NOAA) began processing global measurements of emitted radiation in the 10.5 to 12.5 micron atmospheric window for purposes of deriving weekly composite and mean monthly sea surface temperature fields in the early 1970s. Atmospheric attenuation corrections, begun with empirical means, were accomplished chiefly with the aid of coarser resolution measurements from atmospheric sounders aboard the same polar orbiting spacecraft. Cloud filtering depended heavily upon the use of histogram techniques applied to 11 x 11 arrays of 8 km resolution Scanning Radiometer Infrared (SRIR) data. Details of the SRIR processing for SST are found in a NOAA Technical Memorandum.

Mcclain, E. P.↗

Environmental Persistence of Biological Aerosols in Outdoor and Simulated Environments

The fate of biological aerosols in the atmosphere depends on the unique and dynamic environmental conditions it is exposed to during transport. There exist many processes that can impact the effectiveness of an aerosol release, and its fate in the environment. Aerosol properties may be modified if biological particles that are released into the atmosphere interact with free radicals, volatile organic compounds(VOC), semi-volatile organic compounds, and inorganic gasphase compounds, such as NOx and SOx. Meteorological conditions such as ultraviolet(UV)- light, relative humidity(RH), and temperature have also been shown to affect biological aerosols, with interactions dependent on both the organism and aerosol's chemical make-up. Oxidation or secondary-organic aerosol (SOA) formations on the particle can also lead to changes in surface proteins and extra-cellular nucleic acids that may agent detection technologies, at a different rate than the infectivity of the agents. Once modified, agents may then be transported via many atmospheric processes such as deposition or incorporation into cloud condensation nuclei(CCN). Although these processes are known, it is unclear what the resulting form and potency ofthe bioaerosol may be after alteration by these processes.

54 ENVIRONMENTAL SCIENCES↗

Quantifying the Impact of Electric Fields on the Local Structure and Migration of Potassium Ions at the Orthoclase (001) Surface

Developing an understanding of the response of mineral/water interfaces to applied electric fields is central to detecting and interpreting signatures of interfacial processes in the subsurface. Here we focus density functional theory calculations on understanding K + cation binding and diffusion across the (001) surface of orthoclase feldspar under various applied electric fields with and without surface hydration. The calculations reveal how water ligands labilize surface K + cations for diffusion while also increasing their sensitivity to electric field effects on the binding energy at different surface sites. The calculations also show how the direction and strength of the electric field systematically affect surface cation mobility, sorption, and hydration behavior. Specifically, electric fields directed toward the surface increase the potassium binding energies, facilitate K + diffusion across multiple binding sites, and increase the propensity of surface K + ions to lose their hydration shells. Furthermore, the findings help fill a major knowledge gap into the impact of electric fields on mineral/water interface structure and dynamics more generally, featuring in this case a commonly found type of feldspar involved in a multitude of atmospheric and geochemical processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effects of Southeastern Pacific Sea Surface Temperature on the Double-ITCZ Bias in NCAR CESM1

The double intertropical convergence zone (ITCZ) is a long-standing bias in the climatology of coupled general circulation models (CGCMs). The warm biases in southeastern Pacific (SEP) sea surface temperature (SST) are also evident in many CGCMs. In this study, the role of SEP SST in the double ITCZ is investigated by prescribing the observed SEP SST in the Community Earth System Model, version 1 (CESM1). Both the double ITCZ and dry equator problems are significantly improved with SEP SST prescribed. Both atmospheric and oceanic processes are involved in the improvements. The colder SST over the SEP decreases the precipitation, which enhances the southeasterly winds outside the prescribed SST region, cooling the ocean via increased evaporation. The enhanced descending motion over the SEP strengthens the Walker circulation. The easterly winds over the equatorial Pacific enhance upwelling and shoal the thermocline over the eastern Pacific. The changes of surface wind and wind curl lead to a weaker South Equatorial Countercurrent and stronger South Equatorial Current, preventing the warm water from expanding eastward, thereby improving both the double ITCZ and dry equator. The enhanced Walker circulation also increases the low-level wind convergence and reduces the wind speed in the tropical western Pacific, leading to warmer SST and stronger convection there. The stronger convection in turn leads to more cloud and reduces the incoming solar radiation, cooling the SST. These competing effects between radiative heat flux and latent heat flux make the atmospheric heat flux secondary to the ocean dynamics in the western Pacific warming.

54 ENVIRONMENTAL SCIENCES↗

Comparative Analysis of Empirical and Machine Learning Models for Chla Extraction Using Sentinel-2 and Landsat OLI Data: Opportunities, Limitations, and Challenges

Remote retrieval of near-surface chlorophyll-a (Chla) concentration in small inland waters is challenging due to substantial optical interferences of various water constituents and uncertainties in the atmospheric correction (AC) process. Although various algorithms have been developed to estimate Chla from moderate-resolution terrestrial missions (∼10–60 m), the production of both accurate distribution maps and time series of Chla has proven challenging, limiting the use of remote analyses for lake monitoring. Here, we develop a support vector regression (SVR) model, which uses satellite-derived remote-sensing reflectance spectra () from Sentinel-2 and Landsat-8 images as input for Chla retrieval in a representative eutrophic prairie lake, Buffalo Pound Lake (BPL), Saskatchewan, Canada. Validated against in situ Chla from seven ice-free seasons (N ∼ 200; 2014–2020), the SVR model outperformed both locally tuned, -fed empirical models (Normalized Difference Chlorophyll Index, 2- and 3-band, and OC3) and Mixture Density Networks (MDNs) by 15–65%, while exhibiting comparable performance to a locally trained MDN, with an error of ∼35%. Comparison of Chla retrieval models, AC processors (iCOR, ACOLITE), and radiometric products (Rayleigh-corrected, surface, and top-of-atmosphere reflectance) showed that the best Chla maps and optimal time series (up to 100 mg m−3) were produced using a coupled SVR-iCOR system.

algal blooms↗

Cross-Scale Land-Atmosphere Experiment (CSLAEX) (Final Report)

It is now well recognized that land-atmosphere interactions play an important role in both weather and climate. These interactions take place over a wide range of spatial and temporal scales. Most of the current formulations of the momentum, heat and moisture transport laws are informed by observations with a limited temporal or spatial scale, and hence may have limited applicability. The objective of this work is to improve the multi-scale representation of the near-surface heat transfer in the ground and in the atmosphere using a combination of modeling and field observations. Our knowledge and predictive capacity in land-atmosphere coupling is limited by our capacity to observe the full-scale spectrum at play. In order to bridge this fundamental gap in our observation capacity I will work to: create the first long-term Integrated Cross-Scale land-Atmosphere Experiment (CSLAEX) since I will work to: measure the components of the surface energy balance at a spatial scale relevant to remote sensing and meteorological applications (5km), along with observations of the nested subscale processes with Distributed Temperature Sensors (DTS). This proposal aims to fill the gaps in modeling and observing land-atmosphere interactions across scales via a novel Cross-Scale Land-Atmosphere Experiment (CSLAEX) to be implemented as part of the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site near Lamont, Oklahoma. The proposed research effort aims at exploring land-atmosphere processes across multiple spatial scales and to investigate the effect of landscape heterogeneity using Distributed Temperature Sensor measurements. The novel instrumentation of the Surface Energy Balance and simultaneous observations of the atmospheric state (boundary layer, cloud, convection) available at the DOE ARM SGP site will be used to create CSLAEX. This dataset will be used to frame and evaluate new transport laws and parameterizations for the boundary layer and the land surface, which can be implemented into the Weather and Research Forecasting (WRF) model and Community Atmospheric Model (CAM). The result of this study should impact multiple fields: meteorology, climate, and hydrology.

54 ENVIRONMENTAL SCIENCES↗

A New Framework for the Attribution of Air‐Sea CO 2 Exchange

Abstract The air‐sea transfer of carbon dioxide can be viewed as a dynamic system through which atmospheric and oceanic processes push surface waters away from thermodynamic equilibrium, while diffusive gas transfer pulls them back toward local equilibrium. These push/pull processes drive significant sub‐seasonal, seasonal, and interannual variability in air‐sea carbon fluxes, the quantification of which is critical both for diagnosing the ocean response to fossil fuel emissions and for attempts to mitigate anthropogenic climate disruption through intentional modification of surface ocean biogeochemistry. In this study, we present a new approach for attributing air‐sea carbon fluxes to specific mechanisms. The new framework is first applied to a two‐box ocean nutrient and carbon cycle model as an illustrative example. Next, outputs from a regional eddy‐resolving model of the Southern Ocean are analyzed. The roles of multiple physical and biogeochemical processes are identified. The decomposition of the seasonal air‐sea carbon flux shows the dominant role of biological carbon pumps that are partially compensated by the transport convergence. Finally, the framework is used to diagnose the response to mesoscale iron and alkalinity release, explicitly quantifying transport feedback and eventual impacts on net air‐sea carbon flux. Ocean carbon transport has divergent influences between iron and alkalinity release, due to opposing near‐surface gradients of dissolved inorganic carbon. We suggest that our attribution framework may be a useful analytical technique for monitoring natural ocean carbon fluxes and quantifying the impacts of human intervention on the ocean carbon cycle.

Ito, Takamitsu [School of Earth and Atmospheric Sc↗

Global Autocorrelation Scales of the Partial Pressure of Oceanic CO2

A global database of approximately 1.7 million observations of the partial pressure of carbon dioxide in surface ocean waters (pCO2) collected between 1970 and 2003 is used to estimate its spatial autocorrelation structure. The patterns of the lag distance where the autocorrelation exceeds 0.8 is similar to patterns in the spatial distribution of the first baroclinic Rossby radius of deformation indicating that ocean circulation processes play a significant role in determining the spatial variability of pCO2. For example, the global maximum of the distance at which autocorrelations exceed 0.8 averages about 140 km in the equatorial Pacific. Also, the lag distance at which the autocorrelation exceed 0.8 is greater in the vicinity of the Gulf Stream than it is near the Kuroshio, approximately 50 km near the Gulf Stream as opposed to 20 km near the Kuroshio. Separate calculations for times when the sun is north and south of the equator revealed no obvious seasonal dependence of the spatial autocorrelation scales. The pCO2 measurements at Ocean Weather Station (OWS) 'P', in the eastern subarctic Pacific (50 N, 145 W) is the only fixed location where an uninterrupted time series of sufficient length exists to calculate a meaningful temporal autocorrelation function for lags greater than a few days. The estimated temporal autocorrelation function at OWS 'P', is highly variable. A spectral analysis of the longest four pCO2 time series indicates a high level of variability occurring over periods from the atmospheric synoptic to the maximum length of the time series, in this case 42 days. It is likely that a relative peak in variability with a period of 3-6 days is related to atmospheric synoptic period variability and ocean mixing events due to wind stirring. However, the short length of available time series makes identifying temporal relationships between pCO2 and atmospheric or ocean processes problematic.

Li, Zhen↗

Spatial and Temporal Scaling of Thermal Infrared Remote Sensing Data

Although remote sensing has a central role to play in the acquisition of synoptic data obtained at multiple spatial and temporal scales to facilitate our understanding of local and regional processes as they influence the global climate, the use of thermal infrared (TIR) remote sensing data in this capacity has received only minimal attention. This results from some fundamental challenges that are associated with employing TIR data collected at different space and time scales, either with the same or different sensing systems, and also from other problems that arise in applying a multiple scaled approach to the measurement of surface temperatures. In this paper, we describe some of the more important problems associated with using TIR remote sensing data obtained at different spatial and temporal scales, examine why these problems appear as impediments to using multiple scaled TIR data, and provide some suggestions for future research activities that may address these problems. We elucidate the fundamental concept of scale as it relates to remote sensing and explore how space and time relationships affect TIR data from a problem-dependency perspective. We also describe how linearity and non-linearity observation versus parameter relationships affect the quantitative analysis of TIR data. Some insight is given on how the atmosphere between target and sensor influences the accurate measurement of surface temperatures and how these effects will be compounded in analyzing multiple scaled TIR data. Last, we describe some of the challenges in modeling TIR data obtained at different space and time scales and discuss how multiple scaled TIR data can be used to provide new and important information for measuring and modeling land-atmosphere energy balance processes.

Quattrochi, Dale A.↗