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At least 1,297 records · Page 72

Kelvin wave-induced trace constituent oscillations in the equatorial stratosphere

Kelvin wave induced oscillations in ozone (O3), water vapor (H2O), nitric acid (HNO3) and nitrogen dioxide (NO2) in the equatorial stratosphere are analyzed using Limb Infrared Monitor of the Stratosphere (LIMS) data. Power and cross-spectrum analyses reveal coherent eastward propagating zonal wave 1 and 2 constituent fluctuations, due to the influence of Kelvin waves previously documented in the LIMS data. Comparison is made between a preliminary and the archival versions of the LIMS data; significant differences are found, demonstrating the sensitivity of constituent retrievals to derived temperature profiles. Because Kelvin waves have vanishing meridional velocity, analysis of tracer transport in the meridional plane is substantially simplified. Kelvin wave vertical advection is demonstrated by coherent, in-phase temperature-tracer oscillations, co-located near regions of strong background vertical gradients.

Randel, William J.↗

Analysis of 2018 Aerothermal Calibration Test at the NASA Propulsion Systems Laboratory

This report documents some of the key findings from an aerothermal calibration test that was conducted at the NASA Propulsion Systems Laboratory (PSL) as part of a series of fundamental ice-crystal icing tests in 2018. The purpose of the aerothermal calibration test was to characterize the cloud-off temperature and flow of the PSL test facility prior to performing the cloud-on icing experiments. This report presents the temperature measurements and analysis of that test day which examined uniformity and the influence of spray bars and wall temperature effects. Air temperature profiles were measured just upstream of the test section, and at the test section, for several cases across a range of parameters, including, but not limited to, spray-bar air temperature (Tnozz), altitude, air flow velocity, and spray-bar atomizing pressure (Pnozz).

NASA Propulsion Systems Laboratory↗

Experimental and Mathematical Simulation Study on the Granulation of a Modified Basic Oxygen Furnace Steel Slag

Basic oxygen furnace (BOF) steel slag is a major waste of the steelmaking industry. Utilization of BOF slag contributes to the sustainability of the steel industry by alleviating its environmental impact. Vitrification during cooling is an effective method to promote the cementitious activity of slags with the aim to apply slags in high value-added applications. In the present study, an Al{sub 2}O{sub 3}- and SiO{sub 2}-modified BOF slag was water granulated at a pilot scale. The amorphous and mineral fractions were measured quantitatively. The critical cooling rate to vitrify the modified slag was calculated through the Time-Temperature-Transformation diagrams constructed using in situ confocal scanning laser microscopy. To provide an insight into the crystallization behavior during the granulation process, a mathematical model was developed. The model was validated by comparing the amorphous fraction obtained from experiments with that from simulation. Temperature profiles of the slag particles with varied sizes were calculated with the aid of COMSOL Multiphysics software. The effect of particle size on the vitrified fraction was discussed in detail and the temperature gradient from surface to center of the particle was identified. The results provide novel fundamental understanding of the vitrification process regarding to the slag valorization, which will help the industrial implementation of granulation for pollution remediation and other engineered environmental systems such as chemical industry and pharmaceutical industry.

36 MATERIALS SCIENCE↗

ThO 2 and Th 1– x U x O 2 Nanoscale Materials and Thin Films for Nuclear Science Applications

This study investigates the dynamics and mechanisms of solution combustion synthesis (SCS) for the preparation of nanoscale ThO 2 and Th 1–x U x O 2 materials, utilizing metal nitrates (Th(NO 3 ) 4 and UO 2 (NO 3 ) 2 ) and acetylacetone (C 5 H 8 O 2 ) as reactants dissolved in a 2-methoxyethanol (C 3 H 8 O 2 ) solvent. By combining thermodynamic calculations, dynamic time–temperature profile measurements with differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), this research reveals how variations in acetylacetone concentration and uranium content influence the structural parameters of the synthesized oxides. The time–temperature measurements show that the heating rate and maximum combustion temperatures are sensitive to acetylacetone concentration. DSC-TGA results indicate shifts in exothermic peak temperatures as the uranium content changes. The complexation between thorium and acetylacetone emerges as a critical factor, impacting combustion parameters and the structural characteristics of the final products. The uniform distribution of Th and U in the Th 1–x U x O 2 solid solution and the formation of nanoscale particles with strained crystallites are considered essential for the low-temperature densification of these materials for nuclear fuel pellet applications. Additionally, high-quality ThO 2 and Th 1–x U x O 2 thin (100–150 nm) films are successfully synthesized via electrospray deposition of combustible solutions followed by a brief period of heat treatment. Furthermore, these films exhibit excellent structural and morphological uniformity, making them ideal candidates for nuclear measurements, irradiation damage studies, and investigations into the physical properties of both pure and mixed oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spatially and temporally resolved plasma parameter estimations of laser heated MagLIF relevant gas pipes at NIF

The ability to control laser pre-heat is an integral part of the inertial confinement fusion concept known as Magnetized Liner Inertial Fusion. This process is studied at the National Ignition Facility (NIF) where 4 of the 192 laser beams are propagated through a 1-cm long gas cell where they deposit >20 kJ of energy into the gaseous fuel via inverse bremsstrahlung absorption. This process ionizes the gas, producing a plasma that follows behind the laser front and expands over the radius of the cell. Emission from this plasma, as viewed by a gated x-ray detector, can be used to build spatially and temporally resolved estimations of the pre-heat plasma's density and temperature profiles. This can then be used to estimate the plasma pressure, internal energy, and radiation losses. Estimations show the evolution of the plasma in magnetized and unmagnetized gas cells filled with ambient temperature neopentane (C5H12) +1% Ar, as well as unmagnetized cryogenically cooled (32 K) deuterium +1% Ne filled targets. This analysis shows the effects of initial gas-fill density, composition, and axial magnetization on the time-dependent plasma parameters. Previously, these parameters at the NIF had not been experimentally characterized, and these estimations provided a potential new means of testing radiation magneto-hydrodynamic predictive capability models. Results in unmagnetized targets have strong agreement with simulations. However, in targets with a 19 T applied axial magnetic field, this method yields electron temperatures up to 100% hotter than those predicted by HYDRA codes.

Bremsstrahlung↗

Development and application of processing and process control for nano-composite materials for lithium ion batteries (CRADA Final Report)

Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System’s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged ‘pinch point’ test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals.

25 ENERGY STORAGE↗

Experimental Capabilities to Support Design, Development and Demonstration of Microreactors

This work provides a summary of selected experimental capabilities being developed to support non-nuclear demonstration of microreactors under the U.S. Department of Energy’s (DOE’s) Microreactor Program. Major capabilities include the single primary heat extraction and removal emulator (SPHERE) and the microreactor agile non-nuclear experimental test bed (MAGNET). The SPHERE facility allows for controlled testing of the steady-state and transient heat rejection capabilities of a single heat pipe using electrical heaters that simulate nuclear heating. The facility is capable of monitoring axial temperature profiles along the heat pipe and surrounding test articles during startup, steady-state operation, and transients. Instrumentation includes non-contact infrared thermal imaging, surface thermocouples, spatially distributed fiber-optic temperature and strain sensors, electrical power meters, and a water-cooled, gas gap calorimeter for quantifying heat rejection from the heat pipe. The facility can be operated under both vacuum and inert-gas conditions.

42 ENGINEERING↗

Temperature rise of installed FCC

Report discusses temperature profiles of installed FCC for wood and tile surfaces. Three-conductor FCC was tested at twice nominal current-carrying capacity over bare floor and under carpet, with result indicating that temperature rise is not a linear function of current with FCC at this level.

Hankins, J. D.↗

Capabilities of operational infrared sounding systems from satellite altitude

Initial attempts at using satellite radiances resulted in the production of temperature profiles similar to those produced by radiosondes. While increases in accuracy were made and additional increases are expected to result from increased instrument capabilities, it was recognized that the production of level temperatures is not consistent with the average temperature that is represented by the radiances.

Mcmillin, L.↗

Initialization of a mesoscale model for April 10, 1979, using alternative data sources

A 35 km grid limited area mesoscale model was initialized with high density SESAME radiosonde data and high density TIROS-N satellite temperature profiles for April 10, 1979. These data sources were used individually and with low level wind fields constructed from surface wind observations. The primary objective was to examine the use of satellite temperature data for initializing a mesoscale model by comparing the forecast results with similar experiments employing radiosonde data. The impact of observed low level winds on the model forecasts was also investigated with experiments varying the method of insertion. All forecasts were compared with each other and with mesoscale observations for precipitation, mass and wind structure. Several forecasts produced convective precipitation systems with characteristics satisfying criteria for a mesoscale convective complex. High density satellite temperature data and balanced winds can be used in a mesoscale model to produce forecasts which verify favorably with observations.

Kalb, M. W.↗

High temperature (900-1300 C) mechanical behaviour of dendritic web grown silicon ribbons - Strain rate and temperature dependence of the yield stress

The mechanical behavior of dendritic web Si ribbons close the melting point was studied experimentally. The goal of the study was to generate data for modeling the generation of stresses and dislocation structures during growth of dendritic web Si ribbons, thereby permitting modifications to the production process, i.e., the temperature profile, to lower production costs for the photovoltaic ribbons. A laser was used to cut specimens in the direction of growth of sample ribbons, which were then subjected to tensile tests at temperatures up to 1300 C in an Ar atmosphere. The tensile strengths of the samples increased when the temperature rose above 1200 C, a phenomena which was attributed to the diffusion of oxygen atoms to the quasi-dislocation sites. The migration to the potential dislocations sites effectively locked the dislocations.

Mathews, V. K.↗

Laminar friction and heat transfer at Mach numbers from 1 to 10

Velocity and temperature profiles and laminar boundary-layer characteristics have been computed for Mach numbers from 1 to 10, utilizing experimental values of the heat capacity, viscosity, and conductivity. The analysis shows that effective temperature, which is a function of the surface temperature and stream conditions, arises naturally and is the proper reference temperature to be used in heat-transfer calculations. The effective temperature and the recovery temperature become identical for the condition of zero heat transfer.

Klunker, E B↗

From the Cluster Temperature Function to the Mass Function at Low Z

This XMM project consisted of three observations of the nearby, hot galaxy cluster Triangulum Australis, one of the cluster center and two offsets. The goal was to measure the radial gas temperature profile out to large radii and derive the total gravitating mass within the radius of average mass overdensity 500. The central pointing also provides data for a detailed two-dimensional gas temperature map of this interesting cluster. We have analyzed all three observations. The derivation of the temperature map using the central pointing is complete, and the paper is soon to be submitted. During the course of this study and of the analysis of archival XMM cluster observations, it became apparent that the commonly used XMM background flare screening techniques are often not accurate enough for studies of the cluster outer regions. The information on the cluster's total masses is contained at large off-center distances, and it is precisely the temperatures for those low-brightness regions that are most affected by the detector background anomalies. In particular, our two offset observations of the Triangulum have been contaminated by the background flares ("bad cosmic weather") to a degree where they could not be used for accurate spectral analysis. This forced us to expand the scope of our project. We needed to devise a more accurate method of screening and modeling the background flares, and to evaluate the uncertainty of the XMM background modeling. To do this, we have analyzed a large number of archival EPIC blank-field and closed-cover observations. As a result, we have derived stricter background screening criteria. It also turned out that mild flares affecting EPIC-pn can be modeled with an adequate accuracy. Such modeling has been used to derive our Triangulum temperature map. The results of our XMM background analysis, including the modeling recipes, are presented in a paper which is in final preparation and will be submitted soon. It will be useful not only for our future analysis but for other XMM cluster observations as well.

Mushotzky, Richard↗

Comparing Velocity Profiles Along the Rod Length of a Helical Coil Steam Generator Model

A model of a specific type of tube and shell heat exchanger, the helical coil steam generator (HCSG), was designed and constructed to study multiple fluidic properties that attribute to the efficiency of the heat transfer it provides. Tube and shell heat exchangers are currently used throughout industry in chemical, power and petroleum engineering. Most commonly, a primary flow is circulated through a shell, while the secondary flow is run through several small tubes that are bundled together. Methods to increase the heat transfer between the two flows include adding baffles to force shell side flow over more tubes, fins added in-between layers of tubes and passing tubes multiple times through the shell to increase heat exchanger effectiveness. The HCSG incorporates many of the proposed methods but also relies on a complex geometry to increase the heat transfer between tube and shell side flow. In an area where cost effectiveness is favorable, such as inside a nuclear reactor, helically banked steam generators makes extensive use of the room with no sharp tube bends. This increases the pressure loss on the secondary flow and can solve potential temperature manufacturing issues at the welds of junctions. Additionally, they have exhibited pure cross flow behaviors with high heat transfer coefficients and axial temperature profiles that correspond to pure counter-flow with high mean temperature differences. Early work showed that helical banks can have a significant increase of 16 to 43% higher heat transfer coefficient than straight pipe heat exchangers. While many previous studies have looked at the heat transfer, pressure drop and flow fields of a tube and shell heat exchanger, they all focus on tube bundles that are either in-line or staggered. The early flow visualization studies on these types of bundle arrangements reported that attached eddies were formed alternatively behind each of the rods and were occasionally dragged into the main stream of shell side flow. Later studies suggested that observable periodic vortex shedding was dependent on geometry. Experimental data taken using techniques such as laser Doppler anemometry (LDV) by Simonin and Barcouda (1986) as mentioned in Hassan (2002), hot-wire anemometry with Tsuchida (1982) and particle image velocimetry (PIV) conducted by researchers as late as 2007 have been used to characterize turbulent flow and distinguish flow field structures within in-line and staggered tube bundles. By studying these flow field structures, their contribution to fluidic properties such as heat transfer efficiency and pressure drop can be characterized effectively. Literature review lead to a design that incorporated five layers of coils wrapped around one another. The outermost and middle layers of tubes coiled at a specific pitch in a clockwise direction while the other two layers coiled counterclockwise. The proposed design incorporates a constantly changing lateral pitch ratio, a, between adjacent rods. The constructed test section isolates a single interface between two adjacent coiling rod bundles of twelve rods. Three distinct cross sectional planes along the rod bundles were looked at to study the effect of the local geometry to flow fields, Section A, B and C. Particle Image Velocimetry (PIV) frames of 896 x 848 pixels were captured at each section across a specific height. Profiles of mean velocity fields for each section are compared and discussed as possible features of the changing lateral pitch ratio.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Viscosity profile of the lower mantle

The viscosity of the earth's mantle is an important factor in studies of mantle convection and other problems in geodynamics. The present investigation is concerned with a determination of the variation of effective viscosity across the lower mantle from models of the Gibb's free energy of activation G(asterisk) and the adiabatic temperature profile. The variation of G(asterisk) with depth is calculated using both an elastic strain energy model, in which G(asterisk) is related to the seismic velocities, and a model which assumes G(asterisk) is proportional to the melting temperature.

Ellsworth, K.↗

Using distributed temperature sensing to detect CO 2 leakage along the injection well casing

The objective of this study is to evaluate the sensitivity of Distributed Temperature Sensing (DTS) data to detect CO 2 leakage along an injection well casing. This paper describes the relationship between the CO 2 leakage rate and temperature response at DTS locations, and the method and numerical model used for understanding such a relationship. The uncertainties in the parameters are propagated to the interpretation of DTS measurements, which may lead to false positive and false negative identifications of CO 2 leakage. We propose to identify CO 2 leakage by analyzing both temperature history plots at selected vertical locations as well as the vertical temperature profiles at different times. The analysis should be combined with numerical simulations for the estimation of leakage rates. In addition, leakage needs to be confirmed by data from a warm-up test (temperature recovery after injection of cold CO 2 is stopped) to minimize the probability of false identifications.

42 ENGINEERING↗

Reconstruction of magnetic island electron temperature in mixed second and third harmonic electron cyclotron emission conditions

Here we develop a method to use the mixed third and second harmonic electron cyclotron emission (ECE) signal in the DIII-D tokamak to reconstruct the electron temperature profile of a rotating magnetic island. The third harmonic ECE is removed by extracting the rotating-island-associated fluctuations in the mixed signal, and the extracted fluctuation is combined with the equilibrium temperature obtained from other diagnostics after correcting for the third harmonic reabsorption. The accuracy of the reconstruction is studied by considering a DIII-D shot where an unmixed signal from an island is available on the low field side of the plasma and a mixed signal from the same island is available from the high field side. It is found that the reconstruction method successfully reproduces the island shape and temperature perturbation magnitude without the distortion caused by third harmonic ECE mixing. However, the radial location of the reconstructed island is somewhat displaced relative to the location of the q = 2 surface in the axisymmetric equilibrium reconstruction, resulting in a corresponding inaccuracy in the absolute temperature of the island. It is conjectured that this may arise from an inaccuracy of the reconstructed axisymmetric equilibrium in this region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Development of APCVD BSG and POCl 3 Codiffusion Process for Double-Side TOPCon Solar Cell Precursor Fabrication

This paper presents a commercially viable process for fabricating a high-quality double-side tunnel oxide passivating contact (DS-TOPCon) cell precursor using APCVD-deposited boron silicate glass and ex-situ POCl 3 diffusion in a single high-temperature step, eliminating the need for additional masking and diffusion processes. A two-tier temperature profile was developed, involving a pre-annealing at above 900°C in nitrogen (N2) ambient followed by POCl 3 diffusion at 840°C. We investigated the effect of varying pre-annealing temperatures, ranging from 875°C to 950°C, on the passivation quality and metal-Si contact properties of both n-TOPCon and p-TOPCon layers. The resultant DS-TOPCon cell precursor after silicon nitride (SiNX) passivation exhibited an excellent iV OC of close to 730 mV. In addition, a rapid asymmetric poly-Si thinning technique, developed in this work, enabled adjustment of the front n + poly-Si thickness while maintaining the rear p + poly-Si thickness. Two types of DS-TOPCon cell architectures can be fabricated: i) full-area thin (≈40nm) n-TOPCon layer on the front and ii) selective-area thick (≈200nm) n-TOPCon fingers underneath the metal grid. Device simulations suggest that full-area DS-TOPCon cell with 40 nm n + poly-Si and selective-area DS-TOPCon cell with 200 nm n + poly fingers on the front, fabricated from our current DS-TOPCon cell precursor, can achieve cell efficiencies of 22.1 and 23.5%, respectively. Detailed power loss analysis and device simulation reveal that further improvements in material and device parameters have potential to push the cell efficiencies of DS-TOPCon cell structure beyond 25%, making it a promising alternative to fabricate a high-efficiency next-generation solar cells at low cost.

14 SOLAR ENERGY↗