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At least 1,297 records · Page 72

Ion beam sputter deposited zinc telluride films

Zinc telluride is of interest as a potential electronic device material, particularly as one component in an amorphous superlattice, which is a new class of interesting and potentially useful materials. Some structural and electronic properties of ZnTe films deposited by argon ion beam sputter depoairion are described. Films (up to 3000 angstroms thick) were deposited from a ZnTe target. A beam energy of 1000 eV and a current density of 4 mA/sq. cm. resulted in deposition rates of approximately 70 angstroms/min. The optical band gap was found to be approximately 1.1 eV, indicating an amorphous structure, as compared to a literature value of 2.26 eV for crystalline material. Intrinsic stress measurements showed a thickness dependence, varying from tensile for thicknesses below 850 angstroms to compressive for larger thicknesses. Room temperature conductivity measurement also showed a thickness dependence, with values ranging from 1.86 x to to the -6/ohm. cm. for 300 angstrom film to 2.56 x 10 to the -1/ohm. cm. for a 2600 angstrom film. Measurement of the temperature dependence of the conductivity for these films showed complicated behavior which was thickness dependent. Thinner films showed at least two distinct temperature dependent conductivity mechanisms, as described by a Mott-type model. Thicker films showed only one principal conductivity mechanism, similar to what might be expected for a material with more crystalline character.

Gulino, D. A.↗

Ion beam sputter deposited zinc telluride films

Zinc telluride is of interest as a potential electronic device material, particularly as one component in an amorphous superlattice, which is a new class of interesting and potentially useful materials. Some structural and electronic properties of ZnTe films deposited by argon ion beam sputter deposition are described. Films (up to 3000 angstroms thick) were deposited from a ZnTe target. A beam energy of 1000 eV and a current density of 4 mA/sq cm resulted in deposition rates of approximately 70 angstroms/min. The optical band gap was found to be approximately 1.1 eV, indicating an amorphous structure, as compared to a literature value of 2.26 eV for crystalline material. Intrinsic stress measurements showed a thickness dependence, varying from tensile for thicknesses below 850 angstroms to compressive for larger thicknesses. Room temperature conductivity measurement also showed a thickness dependence, with values ranging from 1.86 x 10 to the -6th/ohm cm for 300 angstrom film to 2.56 x 10 to the -1/ohm cm for a 2600 angstrom film. Measurement of the temperature dependence of the conductivity for these films showed complicated behavior which was thickness dependent. Thinner films showed at least two distinct temperature dependent conductivity mechanisms, as described by a Mott-type model. Thicker films showed only one principal conductivity mechanism, similar to what might be expected for a material with more crystalline character.

Gulino, D. A.↗

Telescope structures - An evolutionary overview

A development history is presented for telescope structural support materials, design concepts, equatorial and altazimuthal orientational preferences, and mechanical control system structural realizations. In the course of 50 years after Galileo, the basic configurations of all reflecting telescopes was set for the subsequent 300 years: these were the Cassegrain, Gregorian, and Newtonian designs. The challenge of making a lightweight ribbed pyrex glass primary mirror for the 5-m Palomar telescope was met by von Karman's use of finite element analysis. Attention is given to the prospects for a 20-m deployable space-based reflecting telescope.

Meinel, Aden B.↗

Centers for the commercial development of space

In 1985, NASA initiated an innovative effort called Centers for the Commercial Development of Space (CCDS). The CCDS program was designed to increase private-sector interest and investment in space-related activities, while encouraging U.S. economic leadership and stimulating advances in promising areas of research and development. Research conducted in the Centers handling the following areas is summarized: materials processing; life sciences; remote sensing; automation and robotics; space propulsion; space structures and materials; and space power.

Walker, Susan E.↗

A perspective on technical needs in computational structures technology

The wide spectrum of needs and applications are demonstrated of computational structural mechanics. The spectrum ranges from micro structural mechanics to the optimization of the performance of aerovehicles. Critical high leveraged technologies will require engineering process modernization and automation, affordable structures and materials, and advanced computational technology. Recent advances at Rockwell International in computational structural mechanics addressed these issues and improve the ability to achieve advanced aircraft objectives.

Abdi, Frank F.↗

Vibration suppression using smart structures

The control of structures for vibration suppression is discussed in the context of using smart materials and structures. Here the use of smart structures refers to using embedded piezoelectric devices as both control actuators and sensors. Using embedded sensors and actuators allows great improvements in performance over traditional structures (both passive and active) for vibration suppression. The application of smart structures to three experimental flexible structures is presented. The first is a flexible beam, the second is a flexible beam undergoing slewing motion, the third is a ribbed antenna. A simple model of a piezoelectric actuator/sensor is presented. The equations of motion for each structure is presented. The control issues considered as those associated with multi-input, multi-output control, PID control and LQR control implementation. A modern control analysis illustrates the usefulness of smart structures for vibration suppression.

Garcia, Ephrahim↗

Overview of CMC Development Activities in NASA's Ultra-Efficient Engine Technology (UEET) Program

The primary objective of the UEET (Ultra-Efficient Engine Technology) Program is to address two of the most critical propulsion issues: performance/efficiency and reduced emissions. High performance, low emissions engine systems will lead to significant improvement in local air quality, minimum impact on ozone depletion and level to an overall reduction in aviation contribution to global warming. The Materials and Structures for High Performance project will develop and demonstrate advanced high temperature materials to enable high-performance, high efficiency, and environmentally compatible propulsion systems.

Brewer, Dave↗

Structurally Integrated Antenna Concepts for HALE UAVs

This technical memorandum describes work done in support of the Multifunctional Structures and Materials Team under the Vehicle Systems Program's ITAS (Integrated Tailored Aero Structures) Project during FY 2005. The Electromagnetics and Sensors Branch (ESB) developed three ultra lightweight antenna concepts compatible with HALE UAVs (High Altitude Long Endurance Unmanned Aerial Vehicles). ESB also developed antenna elements that minimize the interaction between elements and the vehicle to minimize the impact of wing flexure on the EM (electromagnetic) performance of the integrated array. In addition, computer models were developed to perform phase correction for antenna arrays whose elements are moving relative to each other due to wing deformations expected in HALE vehicle concepts. Development of lightweight, conformal or structurally integrated antenna elements and compensating for the impact of a lightweight, flexible structure on a large antenna array are important steps in the realization of HALE UAVs for microwave applications such as passive remote sensing and communications.

Cravey, Robin L.↗

Lattice-Matched Semiconductor Layers on Single Crystalline Sapphire Substrate

SiGe is an important semiconductor alloy for high-speed field effect transistors (FETs), high-temperature thermoelectric devices, photovoltaic solar cells, and photon detectors. The growth of SiGe layer is difficult because SiGe alloys have different lattice constants from those of the common Si wafers, which leads to a high density of defects, including dislocations, micro-twins, cracks, and delaminations. This innovation utilizes newly developed rhombohedral epitaxy of cubic semiconductors on trigonal substrates in order to solve the lattice mismatch problem of SiGe by using trigonal single crystals like sapphire (Al2O3) as substrate to give a unique growth-orientation to the SiGe layer, which is automatically controlled at the interface upon sapphire (0001). This technology is different from previous silicon on insulator (SOI) or SGOI (SiGe on insulator) technologies that use amorphous SiO2 as the growth plane. A cubic semiconductor crystal is a special case of a rhombohedron with the inter-planar angle, alpha = 90 deg. With a mathematical transformation, all rhombohedrons can be described by trigonal crystal lattice structures. Therefore, all cubic lattice constants and crystal planes (hkl) s can be transformed into those of trigonal crystal parameters. These unique alignments enable a new opportunity of perfect lattice matching conditions, which can eliminate misfit dislocations. Previously, these atomic alignments were thought to be impossible or very difficult. With the invention of a new x-ray diffraction measurement method here, growth of cubic semiconductors on trigonal crystals became possible. This epitaxy and lattice-matching condition can be applied not only to SiGe (111)/sapphire (0001) substrate relations, but also to other crystal structures and other materials, including similar crystal structures which have pointgroup rotational symmetries by 120 because the cubic (111) direction has 120 rotational symmetry. The use of slightly miscut (less than plus or minus 10 deg.) sapphire (0001) substrate can be used to improve epitaxial relationships better by providing attractive atomic steps in the epitaxial process.

Choi, Sang↗

Carbon Nanotubes for Human Space Flight

Single-wall carbon nanotubes offer the promise of a new class of revolutionary materials for space applications. The Carbon Nanotube Project at NASA Johnson Space Center has been actively researching this new technology by investigating nanotube production methods (arc, laser, and HiPCO) and gaining a comprehensive understanding of raw and purified material using a wide range of characterization techniques. After production and purification, single wall carbon nanotubes are processed into composites for the enhancement of mechanical, electrical, and thermal properties. This "cradle-to-grave" approach to nanotube composites has given our team unique insights into the impact of post-production processing and dispersion on the resulting material properties. We are applying our experience and lessons-learned to developing new approaches toward nanotube material characterization, structural composite fabrication, and are also making advances in developing thermal management materials and electrically conductive materials in various polymer-nanotube systems. Some initial work has also been conducted with the goal of using carbon nanotubes in the creation of new ceramic materials for high temperature applications in thermal protection systems. Human space flight applications such as advanced life support and fuel cell technologies are also being investigated. This discussion will focus on the variety of applications under investigation.

Scott, Carl D.↗

Making Activated Carbon by Wet Pressurized Pyrolysis

A wet pressurized pyrolysis (wet carbonization) process has been invented as a means of producing activated carbon from a wide variety of inedible biomass consisting principally of plant wastes. The principal intended use of this activated carbon is room-temperature adsorption of pollutant gases from cooled incinerator exhaust streams. Activated carbon is highly porous and has a large surface area. The surface area depends strongly on the raw material and the production process. Coconut shells and bituminous coal are the primary raw materials that, until now, were converted into activated carbon of commercially acceptable quality by use of traditional production processes that involve activation by use of steam or carbon dioxide. In the wet pressurized pyrolysis process, the plant material is subjected to high pressure and temperature in an aqueous medium in the absence of oxygen for a specified amount of time to break carbon-oxygen bonds in the organic material and modify the structure of the material to obtain large surface area. Plant materials that have been used in demonstrations of the process include inedible parts of wheat, rice, potato, soybean, and tomato plants. The raw plant material is ground and mixed with a specified proportion of water. The mixture is placed in a stirred autoclave, wherein it is pyrolized at a temperature between 450 and 590 F (approximately between 230 and 310 C) and a pressure between 1 and 1.4 kpsi (approximately between 7 and 10 MPa) for a time between 5 minutes and 1 hour. The solid fraction remaining after wet carbonization is dried, then activated at a temperature of 500 F (260 C) in nitrogen gas. The activated carbon thus produced is comparable to commercial activated carbon. It can be used to adsorb oxides of sulfur, oxides of nitrogen, and trace amounts of hydrocarbons, any or all of which can be present in flue gas. Alternatively, the dried solid fraction can be used, even without the activation treatment, to absorb oxides of nitrogen.

Fisher, John W.↗

Overview of Heatshield for Extreme Entry Environment Technology (HEEET)

The Heatshield for Extreme Entry Environment Technology (HEEET) projects objective is to mature a 3-D Woven Thermal Protection System (TPS) to Technical Readiness Level (TRL) 6 to support future NASA missions to destinations such as Venus and Saturn. The scope of the project, status of which will be discussed, encompasses development of manufacturing and integration processes, fabrication of a prototype 1m diameter engineering test unit (ETU) that will undergo a series of structural tests, characterizing material aerothermal performance including development of a material response model, and structural testing and analysis to develop tools to support design and establish system capability.

Driver, David M.↗

Thermal History Mapping Technology for Turbine Engine Diagnostics

The infusion of ceramic matrix composites (CMCs) in next generation gas turbines represents daunting challenges as the failure of protective coating, known as Environmental Barrier Coating (EBC), means little remnant life of CMC components. Consequently reliable lifing is critical to the success of CMC components. Accurate thermal mapping of EBC in rig and engine test is of paramount importance because temperature is the most critical variable for EBC life. Current temperature measurement technologies include thermocouples, pyrometers, IR cameras, and thermal paints. Thermocouples require a passage to access the components and pyrometers and IR cameras require line-of-sight. Thermal paints are based on color-sensitive pigments that visually indicate the temperature that a component experienced. Thermal paints do not require line-of-sight, however, they have a low resolution and a limited temperature capability (~1400°C). Thermal history coating is based on oxide ceramic which luminesces when excited with a light source. The luminescence changes when the material's structure changes triggered by heat impact. The maximum temperature to which the material was exposed can be determined from the luminescence change. This paper describes the principles of this new technique and demonstrates its capabilities for EBCs exposed to excess of 1500°C.

Lee, Kang N.↗

Goniometric and Polarized Imaging Spectroscopic Lab Measurements ofSpacecraft Materials

To better characterize the spectral response of common spacecraft materials, the following laboratory measurements are presented to support the Space Situational Awareness community in the analysis of remotely sensed observational data. Of interest is classifying material reflective properties using spectral bidirectional reflectance distribution function (BRDF) data and spatially resolved polarized imaging spectroscopy, allowing laboratory data to be applicable to ground-based optical telescope observations. The team acquired a typical CubeSat solar panel and a sample of multi-layer insulation commonly used on spacecraft for initial measurements. The data were collected at the Goniometer of the Rochester Institute of Technology (GRIT) laboratory with a field and laboratory goniometer housing two Analytical Spectral Device (ASD) spectrometers and a Headwall micro-Hyperspec E-Series imaging spectrometer with an adjustable linear polarizer. The goniometer provides spectral reflectance over a broad spectral range from 350-2500 nm at 1 nm spacing with 3 nm spectral resolution in the visible and near infrared and 8 nm in the shortwave infrared. The Headwall imager covers a spectral range from 400-1000 nm with 1.6 nm spectral resolution. We present the results from these initial measurements that show highly reflective regions at various locations in the angular domain for both materials. In addition, the solar cell spectra exhibited strong interference effects typically observed with thin films. Our team is pursuing a variety of typical solar cells to assess variations in product type. The spatially resolved polarization ratio maps show variability across the materials due to surface structure and varying material composition. Based on these results, we outline a plan for simulating spectral radiance light curves of the materials in various orbital configurations as they would be measured from ground- based telescopes for a clear observing sky during twilight. The paper will also present a plan for expanding ours of interest to determine if the results presented are unique to these samples and to categorize the spectral response for different material classes.

Chris H. Lee↗

Indigenous lunar construction materials

The utilization of local resources for the construction and operation of a lunar base can significantly reduce the cost of transporting materials and supplies from Earth. The feasibility of processing lunar regolith to form construction materials and structural components is investigated. A preliminary review of potential processing methods such as sintering, hot-pressing, liquification, and cast basalt techniques, was completed. The processing method proposed is a variation on the cast basalt technique. It involves liquification of the regolith at 1200-1300 C, casting the liquid into a form, and controlled cooling. While the process temperature is higher than that for sintering or hot-pressing (1000-1100 C), this method is expected to yield a true engineering material with low variability in properties, high strength, and the potential to form large structural components. A scenario for this processing method was integrated with a design for a representative lunar base structure and potential construction techniques. The lunar shelter design is for a modular, segmented, pressurized, hemispherical dome which could serve as habitation and laboratory space. Based on this design, estimates of requirements for power, processing equipment, and construction equipment were made. This proposed combination of material processing method, structural design, and support requirements will help to establish the feasibility of lunar base construction using indigenous materials. Future work will refine the steps of the processing method. Specific areas where more information is needed are: furnace characteristics in vacuum; heat transfer during liquification; viscosity, pouring and forming behavior of molten regolith; design of high temperature forms; heat transfer during cooling; recrystallization of basalt; and refinement of estimates of elastic moduli, compressive and tensile strength, thermal expansion coefficient, thermal conductivity, and heat capacity. The preliminary design of the lunar shelter showed us that joining is a critical technology needed for building a structure from large segments. The problem of joining is important to the design of any structure that is not completely prefabricated. It is especially important when the structure is subjected to tensile loading by an internal pressure. For a lunar shelter constructed from large segments the joints between these large segments must be strong, and they must permit automated construction. With a cast basalt building material which is brittle, there is the additional problem of connecting the joint with the material and avoiding stress concentration that would cause failure. Thus, a well-defined project which we intend to pursue during this coming year is the design of joints for cast basalt structural elements.

Rogers, Wayne P.↗

Analysis of a Landing System for Planetary Payloads Utilizing Passive Energy Absorbing Composite Structure

Delivery of a payload from space to a planetary surface currently requires the development of an application specific landing system to protect the payload from forces imparted during impact with the planet surface. Often, active energy attenuating systems such as retro-rockets, deployable parachutes, and airbags are utilized within these landing systems to reduce landing impact energy. Unfortunately, these active systems come at a cost; active energy attenuating systems are susceptible to system faults which may limit or completely negate their energy attenuating capability. Additionally, components needing to be stowed such as fuel, parachutes, and airbags increase design complexity, cost, and weight. To overcome these limitations, this study examines the potential of passive energy attenuation through energy absorbing structural design and composite materials to mitigate landing loads for small payload planetary delivery. Researchers at the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) have conducted extensive research into developing energy absorbing structures and components for the attenuation of impact energy under various loading conditions including aircraft crash and spacecraft impact. The current study leverages this research to design a lightweight planetary delivery system which utilizes unique outer mold line (OML) geometry and passive energy absorbing structural design to limit landing loads across potential planetary surface environments. The OML geometry is designed to control impact orientation and provide self-righting capabilities for slopped impact surfaces. The internal structure is composed of composite material structures arranged to provide energy absorption which is robust to impact angle and impact velocity. The developed planetary delivery design concept will be evaluated using finite element (FE) model analysis. Simulations of landing impacts with representative soil surface environments will be used to characterize the energy absorbing capabilities of the landing system. Sensitivity of predicted impact force to landing environment, impact angle, and impact velocity will be assessed to identify capabilities and limitations of the initial structural design. Results will be used to determine the feasibility of a lightweight composite structure to passively absorb landing energy for robust planetary payload delivery.

Crashworthiness↗

Processing and Characterization of Basalt Fiber Reinforced Ceramic Composites for High Temperature Applications Using Polymer Precursors

The development of high temperature structural composite materials has been very limited due to the high cost of the materials and the processing needed. Ceramics can take much higher temperatures, but they are difficult to produce and form in bulk volumes. Polymer Derived Ceramics (PDCs) begin as a polymer matrix, allowing a shape to be formed, to be cured, and be pyrolized in order to obtain a ceramic with the associated thermal and mechanical properties. The two PDCs used in this development are polysiloxane and polycarbosilane. Polysiloxanes contain a silicon oxycarbide backbone when pyrolized up to 1000degC. Polycarbosilane, an organosilicon polymer, contain a silicon-carbon backbone; around 1200degC, -SiC begins to crystallize. The use of basalt in structural and high temperature applications has been under development for over 50 years, yet there has been little published research on the incorporation of basalt fibers as a reinforcement in composites. Basalt is a naturally occurring material found in volcanic rock. Continuous basalt fiber reinforced PDCs have been fabricated and tested for the applicability of this composite system as a high temperature structural composite material. Testing for this included thermal and mechanical testing per ASTM standard tests.

High Temperature Composites↗

Load Diffusion in Composite and Smart Structures

The research carried out here builds on our previous NASA supported research on the general topic of edge effects and load diffusion in composite structures. Further fundamental solid mechanics studies were carried out to provide a basis for assessing the complicated modeling necessary for the multi-functional large scale structures used by NASA. An understanding of the fundamental mechanisms of load diffusion in composite subcomponents is essential in developing primary composite structures. Some specific problems recently considered were those of end effects in smart materials and structures, study of the stress response of pressurized linear piezoelectric cylinders for both static and steady rotating configurations, an analysis of the effect of pre-stressing and pre-polarization on the decay of end effects in piezoelectric solids and investigation of constitutive models for hardening rubber-like materials. Our goal in the study of load diffusion is the development of readily applicable results for the decay lengths in terms of non-dimensional material and geometric parameters. Analytical models of load diffusion behavior are extremely valuable in building an intuitive base for developing refined modeling strategies and assessing results from finite element analyses.

Horgan, Cornelius O.↗