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At least 1,297 records · Page 72

Laser formation of luminescence bubble microstructures in polymer films

The results of laser-induced formation of luminescent structures on the surface of poly-2.2’-n-oxydiphenylene-5.5’-bis-benzimidazole films, obtained by the coating method from a formic acid solution, are presented. The structures are formed using cw 405-nm laser radiation with intensities of 10{sup 2} – 10{sup 4} W cm{sup –2}. It is shown (using methods of optical, atomic-force, and electron microscopy) that the structures formed on the surface are microbubble foam-like aggregations. Their formation is modelled as a sequence of the following processes: release of formic acid molecules, their condensation on matrix defects in the surface layer, and explosive boiling as a result of heating this layer of polymer film by the laser beam. The luminescence of these structures is due to the weakening of the concentration quenching from closely spaced luminescence centres in benzimidazole cycles during their emergence to the surface and the increase in the distance between them due to the extension on bubble aggregates on the surface. (interaction of laser radiation with matter. laser plasma)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of solvent/polymer infiltration and irradiation on microstructure and tensile properties of carbon nanotube yarns

Recently carbon nanotube (CNT) yarns have been gaining importance as an approach to harvest the excellent properties of the CNTs. However, the properties of CNT yarns at this stage are well below the expected value. Investigation of the structure of CNT yarns and possible approaches to enhance the strength and modulus are reported. Scanning electron microscopy and focused ion beam imaging reveal the inherently porous structure and poor orientation, emphasizing the need to enhance packing of CNT bundles in the yarns for increased strength and modulus. Densification of CNT yarn by toluene or polystyrene increases the strength by 140 or 172 % and modulus by 79 or 218 %, respectively, as compared to that of the pristine yarn. E-beam irradiation was investigated as a means to introduce crosslinking and enhanced internanotubes bonding to increase strength and modulus. However, the irradiation resulted in generation of defects and damages to the yarn contributing to reduction in strength and modulus. Raman spectroscopy studies on the irradiated samples reveal the change in bonding characteristics resulting in poor mechanical properties. As a result, denser packing of nanotubes and increased interaction without any damage is the key to improve the properties of CNT yarns.

36 MATERIALS SCIENCE↗

Modeling and simulations of hydrodynamic shocks in a plasma flowing across randomized ICF scale laser beams

High-energy laser beams interacting with flowing plasmas can produce a plasma response that leads to deflection of the beam, beam bending. Such beams have usually a speckle structure generated by optical smoothing techniques that reduce the spatial and temporal coherence in the laser field pattern. The cumulative plasma response from laser speckles slows down the velocity of the incoming flow by momentum conservation. For slightly super-sonic flow the cumulative plasma response to the ponderomotive force exerted by the beam speckle ensemble is the strongest, such that slowing down the flow to subsonic velocities leads eventually to the generation of a shock around the cross section of the beam. This scenario has been predicted theoretically and is confirmed here by our hydrodynamic simulations in two dimensions with speckled beams and in one dimension with a reduced model. The conditions of shock generation are given in terms of the ponderomotive pressure, speckle size and the flow velocity. The nonlinear properties of the shocks are analyzed using Rankine–Hugoniot relations. According to linear theory, temporally smoothed laser beams exhibit a higher threshold for shock generation. Numerical simulations with beams that are smoothed by spectral dispersion compare well with the linear theory results, diverging from those produced by beams with only a random phase plates in the nonlinear regime. The conditions necessary for shock generation and their effects on the laser plasma coupling in inertial confinement fusion (ICF) experiments are also discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Synthetic observations of the evolution of starless cores in a molecular cloud simulation: Comparisons with JCMT data and predictions for alma

Interpreting the nature of starless cores has been a prominent goal in star formation for many years. In order to characterize the evolutionary stages of these objects, we perform synthetic observations of a numerical simulation of a turbulent molecular cloud. We find that nearly all cores that we detect are associated with filaments and eventually form protostars. We conclude that observed starless cores that appear Jeans unstable are only marginally larger than their respective Jeans masses (within a factor of three). We note single dish observations such as those performed with the James Clerk Maxwell Telescope appear to miss significant core structure on small scales because of beam averaging. Finally, we predict that interferometric observations with Atacama Large Millimeter Array Cycle 1 will resolve the important small-scale structure, which has so far been missed by millimeter wavelength observations.

79 ASTRONOMY AND ASTROPHYSICS↗

Method of fabrication of fibers, textiles and composite materials

A method of growing a plurality of free-standing structures comprises providing a plurality of free-standing structures, each free-standing structure having a first end coupled to a substrate, and a terminal end; providing at least one laser beam, the laser beam having a beam waste at a point proximate to the terminal end of the free-standing structure; and moving one of the plurality of freestanding structures or the beam waste to provide a growth zone proximate to the terminal end of each of the free-standing structures such that the free-standing structures grow into the growth zones by addition of decomposing precursor components. The growth rates of each of the free-standing structures are substantially the same.

36 MATERIALS SCIENCE↗

The dynamic response of composite beams to axial impact

Large deformation response of simple composite structural elements to intense dynamic loadings is studied by focusing on the response of beams. Overall goals are to: design a simple test fixture to introduce crash related bending loads in beams; determine any difference between large deformation static and large deformation dynamic response; determine the influence of laminate stacking arrangements on the dynamic response, failure mode, and energy absorbed; and predict the dynamic response. Twelve different laminate orientations were investigated. Modeling of the response was done with an existing finite element program. The program computed nonlinear transient response analysis of a structure objected to a time varying load.

Derian, E. J.↗

Tuning the interaction between propagating and localized surface plasmons for surface enhanced Raman scattering in water for biomedical and environmental applications

With a view to biomedical and environmental applications, we investigate the plasmonic properties of a rectangular gold nanodisk array in water to boost surface enhanced Raman scattering (SERS) effects. To control the resonance wavelengths of the surface plasmon polariton and the localized surface plasmon, their dependence on the array period and diameter in water is studied in detail using a finite difference time domain method. A good agreement is obtained between calculated resonant wavelengths and those of gold nanodisk arrays fabricated using electron beam lithography. For the optimized structure, a SERS enhancement factor of 7.8 × 10{sup 7} is achieved in water experimentally.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Optically addressed spatial light modulators by MBE-grown nipi MQW structures

Promising approaches for achieving optically addressed spatial light modulators (O-SLMs) are investigated based on combining nipi and multiple quantum well structures. Theoretical aspects of photooptic effects achievable in such structures are treated. Test structures are grown by molecular beam epitaxy using two material systems. (In,Ga)As/GaAs and (Al,Ga)As/GaAs. Experiments show large optically controlled modulation of the absorption coefficient in the quantum well layers, a log power dependence on the control signal, millisecond and shorter time response, and generally predictable behavior. The results are encouraging for several different O-SLM device structures proposed.

Maserjian, Joseph↗

Evidence of a Love wave bandgap in a quartz substrate coated with a phononic thin layer

This paper presents a numerical and experimental study of Love wave propagation in a micro-fabricated phononic crystal (PC) structure consisting of a 2D, periodically etched silica film deposited on a quartz substrate. The dispersion characteristics of Love waves in such a phononic structure were analyzed with various geometric parameters by using complex band structure calculations. For the experiment, we adopted reactive-ion etching with electron-beam lithography to fabricate a submicrometer phononic structure. The measured results exhibited consistency with the numerical prediction. The results of this study may serve as a basis for developing PC-based Love wave devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Application of a robust linear control design to a truss structure with nonlinear joints

An efficient nonlinear equivalent beam finite-element method for the application of a full state feedback design is described, which is robust to plant uncertainties to a beamlike truss structure with nonlinear elements. The method may be extended to model nonlinear structures with other types of control systems, such as model-based compensators.

Webster, Mark↗

Strain and morphology of graphene membranes on responsive microhydrogel patterns

We study the configuration of atomically-thin graphene membranes on tunable microhydrogel patterns. The polyethylene oxide microhydrogel structures patterned by electron-beam lithography show increase in height, with a persistent swelling ratio up to ∼10, upon exposure to vapors of an organic solvent. We demonstrate that modifying the height fluctuations of the microhydrogel affects the strain and morphology of ultrathin graphene membrane over-layer. Raman spectroscopic investigations indicate that small lattice strains can be switched on in mechanically exfoliated few-layer graphene membranes that span these microhydrogel structures. In case of chemical-vapor deposited single-layer graphene, we observe Raman signatures of local depinning of the membranes upon swelling of microhydrogel pillars. We attribute this depinning transition to the competition between membrane-substrate adhesion energy and membrane strain energy, where the latter is tuned by hydrogel swelling.

36 MATERIALS SCIENCE↗

Transonic aeroelasticity analysis for rotor blades

A numerical method is presented for calculating the unsteady transonic rotor flow with aeroelasticity effects. The blade structural dynamic equations based on beam theory were formulated by FEM and were solved in the time domain, instead of the frequency domain. For different combinations of precone, droop, and pitch, the correlations are very good in the first three flapping modes and the first twisting mode. However, the predicted frequencies are too high for the first lagging mode at high rotational speeds. This new structure code has been coupled into a transonic rotor flow code, TFAR2, to demonstrate the capability of treating elastic blades in transonic rotor flow calculations. The flow fields for a model-scale rotor in both hover and forward flight are calculated. Results show that the blade elasticity significantly affects the flow characteristics in forward flight.

Chow, Chuen-Yen↗

Optimization for minimum sensitivity to uncertain parameters

A procedure to design a structure for minimum sensitivity to uncertainties in problem parameters is described. The approach is to minimize directly the sensitivity derivatives of the optimum design with respect to fixed design parameters using a nested optimization procedure. The procedure is demonstrated for the design of a bimetallic beam for minimum weight with insensitivity to uncertainties in structural properties. The beam is modeled with finite elements based on two dimensional beam analysis. A sequential quadratic programming procedure used as the optimizer supplies the Lagrange multipliers that are used to calculate the optimum sensitivity derivatives. The method was perceived to be successful from comparisons of the optimization results with parametric studies.

Pritchard, Jocelyn I.↗

Study of Dislocation-Ordered In(x)Ga(1-x)As/GaAs Quantum Dots

A report describes an experimental study of dislocation-induced spatial ordering of quantum dots (QDs) comprising nanometer-sized In(x)Ga(1-x)As islands surrounded by GaAs. Metastable heteroepitaxial structures were grown by molecular-beam epitaxy of In(x)Ga(1-x)As onto n+ GaAs and semi-insulating GaAs substrates. Then the structures were relaxed during a post-growth annealing/self-organizing process leading to the formation of surface undulations that acted as preferential sites for the nucleation of QDs. Structural effects of annealing times and temperatures on the strain-relaxed In(x)Ga(1-x)As/GaAs and the subsequent spatial ordering of the QDs were analyzed by atomic-force microscopy and transmission electron microscopy. Continuous-wave spectral and time-resolved photoluminescence (PL) measurements were performed to study the effects, upon optical properties, of increased QD positional ordering, increased QD uniformity, and proximity of QDs to arrays of dislocations. PL spectral peaks of ordered QD structures formed on strain-relaxed In(x)Ga(1-x)As/GaAs layers were found to be narrower than those of structures not so formed and ordered. Rise and decay times of time-resolved PL were found to be lower at lower temperatures -- apparently as a consequence of decreased carrier-transport times within the barriers surrounding the QDs.

Leon, Rose↗

Micromagnetic and Magnetooptical Properties of Ferromagnetic/Heavy Metal Thin Film Structures

The magnetic properties of CoPt, CoPd, and FePd thin films with different contents of a ferromagnetic material fabricated by electron beam evaporation have been compared. The micromagnetic structure investigations have shown a decrease in the magnetic domain size with an increase in the Co content in the CoPt and CoPd films, which has been attributed to the presence of two magnetic phases in the films. The magnetooptical studies have shown anomalously large Faraday angles and the absence of Kerr effect in the CoPt films, which make them attractive for application in optics. In the FePd films, the minimum coercivity values have been obtained from the magnetic-field dependences of the magnetization, which has also been related to the magnetic structure features.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Record quantum efficiency from strain compensated superlattice GaAs/GaAsP photocathode for spin polarized electron source

Photocathodes based on GaAs and other III–V semiconductors are capable of producing highly spin-polarized electron beams. GaAs/GaAsP superlattice photocathodes exhibit high spin polarization; however, the quantum efficiency (QE) is limited to 1% or less. To increase the QE, we fabricated a GaAs/GaAsP superlattice photocathode with a Distributed Bragg Reflector (DBR) underneath. This configuration creates a Fabry–Pérot cavity between the DBR and GaAs surface, which enhances the absorption of incident light and, consequently, the QE. These photocathode structures were grown using molecular beam epitaxy and achieved record quantum efficiencies exceeding 15% and electron spin polarization of about 75% when illuminated with near-bandgap photon energies.

47 OTHER INSTRUMENTATION↗

Nonlinear equations for dynamics of pretwisted beams undergoing small strains and large rotations

Nonlinear beam kinematics are developed and applied to the dynamic analysis of a pretwisted, rotating beam element. The common practice of assuming moderate rotations caused by structural deformation in geometric nonlinear analyses of rotating beams was abandoned in the present analysis. The kinematic relations that described the orientation of the cross section during deformation are simplified by systematically ignoring the extensional strain compared to unity in those relations. Open cross section effects such as warping rigidity and dynamics are ignored, but other influences of warp are retained. The beam cross section is not allowed to deform in its own plane. Various means of implementation are discussed, including a finite element formulation. Numerical results obtained for nonlinear static problems show remarkable agreement with experiment.

Hodges, D. H.↗