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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,297 records · Page 72
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Optical Design of the MOSES Sounding Rocket Experiment

The Multi-Order Solar EUV Spectrograph (MOSES) is a sounding rocket payload now being developed by Montana State University in collaboration with the Goddard Space Flight Center, Lockheed Martin Advanced Technology Center, and Mullard Space Science Laboratory. The instrument utilizes a unique optical design to provide solar EUV measurements with true 2-pixel resolutions of 1.0 arcsec and 60 mA over a full two-dimensional field of view of 1056 x 528 arcsec, all at a time cadence of 10 s. This unprecedented capability is achieved by means of an objective spherical grating 100 mm in diameter, ruled at 833 gr/mm. The concave grating focuses spectrally dispersed solar radiation onto three separate detectors, simultaneously recording the zero-order as well as the plus and minus first-spectral-order images. Data analysis procedures, similar to those used in X-ray tomography reconstructions, can then disentangle the mixed spatial and spectral information recorded by the multiple detectors. A flat folding mirror permits an imaging focal length of 4.74 m to be packaged within the payload's physical length of 2.82 m. Both the objective grating and folding flat have specialized, closely matched, multilayer coatings that strongly enhance their EUV reflectance while also suppressing off-band radiation that would otherwise complicate data inversion. Although the spectral bandpass is rather narrow, several candidate wavelength intervals are available to carry out truly unique scientific studies of the outer solar atmosphere. Initial flights of MOSES, scheduled to begin in 2004, will observe a 10 Angstrom band that covers very strong emission lines characteristic of both the sun's corona (Si XI 303 Angstroms) and transition-region (He II 304 Angstroms). The MOSES program is supported by a grant from NASA's Office of Space Science.

Thomas, Roger J.↗
NASA NTRS2013

Advanced Colloids Experiment (ACE) Science Overview

The Advanced Colloids Experiment is being conducted on the International Space Station (ISS) using the Light Microscopy Module (LMM) in the Fluids Integrated Rack (FIR). Work to date will be discussed and future plans and opportunities will be highlighted. The LMM is a microscope facility designed to allow scientists to process, manipulate, and characterize colloidal samples in micro-gravity where the absence of gravitational settling and particle jamming enables scientists to study such things as:a.The role that disordered and ordered-packing of spheres play in the phase diagram and equation of state of hard sphere systems,b.crystal nucleation and growth, growth instabilities, and the glass transition, c.gelation and phase separation of colloid polymer mixtures,d.crystallization of colloidal binary alloys,e.competition between crystallization and phase separation,f.effects of anisotropy and specific interactions on packing, aggregation, frustration and crystallization,g.effects of specific reversible and irreversible interactions mediated in the first case by hybridization of complementary DNA strands attached to separate colloidal particles,h.Lock and key interactions between colloids with dimples and spheres which match the size and shape of the dimples,i.finding the phase diagrams of isotropic and interacting particles,j.new techniques for complex self-assembly including scenarios for self-replication, k.critical Casimir forces,l.biology (real and model systems) in microgravity,m.etc. By adding additional microscopy capabilities to the existing LMM, NASA will increase the tools available for scientists that fly experiments on the ISS enabling scientists to observe directly what is happening at the particle level. Presently, theories are needed to bridge the gap between what is being observed (at a macroscopic level when photographing samples) with what is happening at a particle (or microscopic) level. What is happening at a microscopic level will be directly accessible with the availability of the Light Microscopy Module (LMM) on ISS. To meet these goals, the ACE experiment is being built-up in stages, with the availability of confocal microscopy being the ultimate objective. Supported by NASAs Physical Sciences Research Program, ESAESTEC, and the authors respective governments.

Microgravity Biology Research↗
NASA NTRS2019

Design, Prototyping, and Testing of a Novel Flowpath with an Array of Six 3D Matrix Vitvo Bioreactors for the NASA Bioculture System

The NASA Bioculture System is an advanced cell culture closed-loop system containing highly automated flowpaths designed to conduct long term biology experiments on ISS with earth remote controllable medium flow, temperature, gas composition, medium exchange, cell sampling and fixation. This technology was already demonstrated with successful cardiomyocyte and osteocyte cultures experiments onboard the ISS and is now supporting NASA PI science. The Bioculture System, however, can only support 10 cassettes with disposable flowpaths, each containing a single hollow fiber bioreactor with a culture capacity of about 2ml. This constraint not only severely limits the number of investigators that can conduct experiments in space, but also subjects the experiments to limitations in the number of replicates and conditions that can be studied. To address these limitations, we sought a novel design solution to maximize the number of separate bioreactor cultures and volume that can be conducted simultaneously. To this end we designed, prototyped, and are now testing a six-Vitvo 3D Matrix 2ml bioreactor insert that replaces the conventional Bioculture System hollow fiber bioreactor. This design will allow the Bioculture System to support up to 60 different bioreactors and samples at once. Specifically, the novel gas-tight containment housing insert contains six COTS Rigenerand VITVO bioreactors stacked on each side of a heat sink powered by the existing heating element and pair of temperature sensors. Medium will be distributed into each bioreactor's cell-free chamber via its built-in Luer connector, then across the 3D matrix to the cell chamber, dissipating laminar flow and limiting fluid shear stresses that might mechanostimulate cell cultures. Gas (5% CO2 in air) will be supplied directly to the bioreactor gas-tight housing for exchange via the bioreactor flat-surface gas-permeable membranes, eliminating the need for the existing Bioculture System cassette oxygenator. If successfully implemented on ISS, this new multi-bioreactor insert for the Bioculture System has the potential to make real-time cell science experimentation in space more efficient and accessible to more investigators.

Ma, Kristin R.↗
NASA NTRS2021

Aerocapture Trajectories for Earth Orbit Technology Demonstration and Orbiter Science Missions at Venus, Earth, Mars, and Neptune

The use of aerocapture to provide the delta-V needed to capture a spacecraft into orbit can provide significant fuel savings compared to a propulsive orbit insertion. The aerocapture guidance method described in this paper uses drag modulation, which deploys a drag skirt in the atmosphere until the amount of delta-V needed to capture into the desired orbit is obtained, at which time the drag skirt is separated from the spacecraft. By modulating the time of drag skirt jettison, the vehicle can target a specific orbit apoapsis in the presence of uncertainties such as entry targeting errors and unknown atmospheric conditions.

Jadusingh, Matt↗
DOE OSTI2021

Efficient loading of reduced data ensembles produced at ORNL SNS/HFIR neutron time-of-flight facilities

We present algorithmic improvements to the loading operations of certain reduced data ensembles produced from neutron scattering experiments at Oak Ridge National Laboratory (ORNL) facilities. Ensembles from multiple measurements are required to cover a wide range of the phase space of a sample material of interest. They are stored using the standard NeXus schema on individual HDF5 files. This makes it a scalability challenge, as the number of experiments stored increases in a single ensemble file. The present work follows up on our previous efforts on data management algorithms, to address identified input output (I/O) bottlenecks in Mantid, an open-source data analysis framework used across several neutron science facilities around the world. We reuse an in-memory binary-tree metadata index that resembles data access patterns, to provide a scalable search and extraction mechanism. In addition, several memory operations are refactored and optimized for the current common use cases, ranging most frequently from 10 to 180, and up to 360 separate measurement configurations. Results from this work show consistent speed ups in wall-clock time on the Mantid LoadMD routine, ranging from 19% to 23% on average, on ORNL production computing systems. The latter depends on the complexity of the targeted instrument-specific data and the system I/O and compute variability for the shared computational resources available to users of ORNL’s Spallation Neutron Source (SNS) and the High Flux Isotope Reactor (HFIR) instruments. Nevertheless, we continue to highlight the need for more research to address reduction challenges as experimental data volumes, user time and processing costs increase.

Godoy, William↗
DOE OSTI2021

University of Nebraska unmanned aerial system (UAS) profiling during the LAPSE-RATE field campaign

Abstract. This paper describes the data collected by the University of Nebraska-Lincoln (UNL) as part of the field deployments during the Lower Atmospheric Process Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE-RATE) flight campaign in July 2018. The UNL deployed two multirotor unmanned aerial systems (UASs) at multiple sites in the San Luis Valley (Colorado, USA) for data collection to support three science missions: convection initiation, boundary layer transition, and cold air drainage flow. We conducted 172 flights resulting in over 21 h of cumulative flight time. Our novel design for the sensor housing onboard the UAS was employed in these flights to meet the aspiration and shielding requirements of the temperature and humidity sensors and to separate them from the mixed turbulent airflow from the propellers. Data presented in this paper include timestamped temperature and humidity data collected from the sensors, along with the three-dimensional position and velocity of the UAS. Data are quality-controlled and time-synchronized using a zero-order-hold interpolation without additional post-processing. The full dataset is also made available for download at https://doi.org/10.5281/zenodo.4306086 (Islam et al., 2020).

Islam, Ashraful (ORCID:000000022826269X)↗
NASA NTRS1974

The Penn State ORSER system for processing and analyzing ERTS and other MSS data

The author has identified the following significant results. The office for Remote Sensing of Earth Resources (ORSER) of the Space Science and Engineering Laboratory at the Pennsylvania State University has developed an extensive operational system for processing and analyzing ERTS-1 and similar multispectral data. The ORSER system was developed for use by a wide variety of researchers working in remote sensing. Both photointerpretive techniques and automatic computer processing methods have been developed and used, separately and in a combined approach. A remote Job Entry system permits use of an IBM 370/168 computer from any compatible remote terminal, including equipment tied in by long distance telephone connections. An elementary cost analysis has been prepared for the processing of ERTS data.

Mcmurtry, G. J.↗
NASA NTRS1994

Voyager observations of O(+6) and other minor ions in the solar wind

The plasma science (PLS) experiments on the Voyager 1 and 2 spacecraft began making measurements of the solar wind shortly after the two launches in the fall of 1977. In reviewing the data obtained prior to the Jupiter encounters in 1979, we have found that the large dynamic range of the PLS instrument generally allows a clean separation of signatures of minor ions (about 2.5% of the time) during a single instrument scan in energy per charge. The minor ions, most notably O(+6), are well separated from the protons and alpha particles during times when the solar wind Mach number (ratio of streaming speed to thermal speed) is greater than approximately 15. During the Earth to Jupiter cruise we find that the average ratio of alpha particle number density to that of oxygen is 66 +/- 7 (Voyager 1) and 71 +/- 17 (Voyager 2). These values are consistent with the value 75 +/- 20 inferred from the Ion Composition Instrument on ISEE 3 during the period spanning 1978 and 1982. We have inferred an average coronal temperature of (1.7 +/- 0.1) x 10(exp 6) K based on the ratio of O(+7) to O(+6) number densities. Our observations cover a period of increasing solar activity. During this time we have found that the alpha particle to proton number density ratio is increasing with the solar cycle, the oxygen to proton ratio increases, and the alpha particle to oxygen ratio remains relatively constant in time.

Villanueva, Louis↗
NASA NTRS2001

Aspect-Oriented Programming

Computer science has experienced an evolution in programming languages and systems from the crude assembly and machine codes of the earliest computers through concepts such as formula translation, procedural programming, structured programming, functional programming, logic programming, and programming with abstract data types. Each of these steps in programming technology has advanced our ability to achieve clear separation of concerns at the source code level. Currently, the dominant programming paradigm is object-oriented programming - the idea that one builds a software system by decomposing a problem into objects and then writing the code of those objects. Such objects abstract together behavior and data into a single conceptual and physical entity. Object-orientation is reflected in the entire spectrum of current software development methodologies and tools - we have OO methodologies, analysis and design tools, and OO programming languages. Writing complex applications such as graphical user interfaces, operating systems, and distributed applications while maintaining comprehensible source code has been made possible with OOP. Success at developing simpler systems leads to aspirations for greater complexity. Object orientation is a clever idea, but has certain limitations. We are now seeing that many requirements do not decompose neatly into behavior centered on a single locus. Object technology has difficulty localizing concerns invoking global constraints and pandemic behaviors, appropriately segregating concerns, and applying domain-specific knowledge. Post-object programming (POP) mechanisms that look to increase the expressiveness of the OO paradigm are a fertile arena for current research. Examples of POP technologies include domain-specific languages, generative programming, generic programming, constraint languages, reflection and metaprogramming, feature-oriented development, views/viewpoints, and asynchronous message brokering. (Czarneclu and Eisenecker s book includes a good survey of many of these technologies).

Elrad, Tzilla↗
NASA NTRSDate not supplied

CERES Fast Longwave And SHortwave Radiative Flux (FLASHFlux): Research to Operation

The Clouds and Earth’s Radiant Energy System (CERES) project provides satellite-based observations of how Earth’s energy flows are varying in time and space and how clouds and aerosols are affecting the Earth’s radiation budget. Nominally, CERES data products require months of validation and calibration before releasing a climate quality data. The Fast Longwave and Shortwave Radiative Flux (FLASHFlux) data product was developed as to provide key data for applied science research involving the renewable energy and agricultural sectors within a week of observations. FLASHFlux achieves this by using simplified calibration, an operation meteorology product from Global Modeling and Assimilation Office (GMAO), and its own surface parameterizations model. The CERES FLASHFlux provides two data products: 1) an hourly Level 2 Single Scanner Footprint (SSF) data separately for Aqua and Terra observations, and 2) a daily Level 3 Time Interpolated and Spatially Averaged (TISA) 1ox 1ogridded data that combines Aqua and Terra observations. We inter-compared of FLASHFlux Version4A calibration to the climate quality CERES Edition4A data product over time. In addition, we also inter-compared the impact of the fluxes by using the near real-time GMAO GEOS FP-IT instead of GMAO G5-CERES meteorology data. We also compare both SSF overpass and TISA radiative flux products to a set of surface measurement sites that are globally distributed and assess agreement.

P. C. Sawaengphokhai↗
NASA NTRS2023

The Earth in Living Color - NASA’s Surface Biology and Geology Designated Observable

The Surface Biology and Geology (SBG) Designated Observable will transform our understanding of the global land surface, inland and coastal aquatic ecosystems through visible-to-shortwave infra-red imaging (VSWIR) spectroscopy and thermal infra-red (TIR) imaging. SBG is one of four high-priority observables recommended in the 2017 NASA Earth Science Decadal Survey t o address science questions on vegetation and aquatic ecosystem health, snow-cover dynamics, volcanic activity, and minerology. With a planned launch readiness date of 2028, SBG is currently in Pre-Phase A, with Level 1 requirements being developed for a two-spacecraft architecture, including an additional constellation pathfinder. The recommended architecture emerged from an extensive study (2018-2021) that engaged the research and applications community to consider the science questions and measurement objectives of the Decadal Survey. A Science and Applications Traceability Matrix was used as a basis for scoring candidate architectures, with inputs from four working groups that covered algorithms, applications, calibration and validation, and modeling. Two pathfinder studies, Modeling End-to-End Traceability in support of SBG (MEET-SBG) and Space-based Imaging Spectroscopy and Thermal pathfindER (SISTER) are providing pre-launch modeling tools and data for algorithm development to support science value trades. The architecture consists of one spacecraft hosting a wide-swath VSWIR imaging spectrometer providing 30-m ground-sample distance (GSD), a spectral range of 380-2500 nm (at 10 nm resolution), 16-day revisit with 400 signal-to-noise for VNIR and 250 for SWIR (at 25% reflectance). A separate spacecraft will host a wide swath thermal imager, with five to seven bands placed between 4-12 μm), with 60-m (GSD), 3- day revisit, and 0.2K noise-equivalent differential temperature (NeDT). A VNIR compact camera will be hosted on the TIR spacecraft to enable coincident TIR and VNIR observations. A constellation pathfinder will evaluate options for enabling VSWIR mission continuity using Small Sats or data buys. Partnerships with international space agencies contribute technology as well as improvements to temporal revisit. SBG, when launched, will be the first dedicated mission collecting the full spectra of the Earth’s ‘living color’ and will play a critical role in NASA’s Earth System Observatory.

David S Schimel↗
DOE OSTI2025

Proton Selective Nanoporous Atomically Thin Graphene Membranes for Vanadium Redox Flow Batteries

Angstrom-scale proton-selective pores in atomically thin 2D materials present fundamentally new opportunities for advancing proton exchange membranes (PEMs). Vanadium Redox Flow Batteries (VRFBs) for grid-scale energy storage require PEMs with high areal proton conductance (>1 S cm −2 ) and minimal vanadium ion (VO 2+ ) crossover. However, state-of-the-art Nafion 212 membranes (N212 ≈50 µm thick), suffer from persistent VO 2+ crossover reducing performance and efficiency. Here, a layered PEM is demonstrated, comprising monolayer CVD graphene with Angstrom-scale proton-selective pores introduced via Ar plasma, integrated with an ultra-thin ≈300 nm polybenzimidazole (PBI) layer and sandwiched between two Nafion 211 (25 µm thick) layers. The layered architecture facilitates scalable membrane fabrication by mitigating defects while processing and facile stacking of graphene layers allows stochastic non-selective defect isolation enabling exceptionally low VO 2+ crossover (selectivity (H + areal conductance / VO 2+ permeability) ≈6709 × 10 6 S min cm −4 ), with proton conductance >8 S cm −2 . Systematic transport experiments supported by resistance-based transport modelling elucidate the role of defect size, defect isolation, and sealing, as well as layering/stacking, to enable orders of magnitude (>671× over N212) improvements in selectivity, along with areal proton conductance >8 S cm −2 . This work highlights the potential of atomic-scale proton-selective defect engineering in 2D materials, in conjunction with facile stacking and layering of materials as strategies for scalable, high-performance advances in PEMs for energy, electrochemical, and separation applications beyond VRFBs.

Chaturvedi, Pavan [Vanderbilt Univ., Nashville, TN↗
DOE OSTI2023

Sequential Separation of Linear, Mono–, and Di–Branched Hexane Isomers on a Robust Coordination Polymer with Nonbonding Flexibility

Efficient separation of hexane isomers is a crucial process for upgrading gasoline. Herein, the sequential separation of linear, mono-, and di-branched hexane isomers by a robust stacked 1D coordination polymer termed as Mn-dhbq ([Mn(dhbq)(H 2 O) 2 ], H 2 dhbq = 2,5-dihydroxy-1,4-benzoquinone) is reported. The interchain space of the activated polymer is of optimal aperture size (5.58 Å) that could exclude 2,3-dimethylbutane, while the chain structure can discriminate n-hexane with high capacity (1.53 mmol g –1 at 393 K, 6.67 kPa) by high-density open metal sites (5.18 mmol g –1 ). With the temperature- and adsorbate-dependent swelling of interchain spaces, the affinity between 3-methylpentane and Mn-dhbq can be deliberately controlled from sorption to exclusion, and thus a complete separation of ternary mixture can be achieved. Column breakthrough experiments confirm the excellent separation performance of Mn-dhbq. Furthermore, the ultrahigh stability and easy scalability further highlight the application prospect of Mn-dhbq for separation of hexane isomers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Persistence of crystal orientations across sub-micron-scale "super-grains" in self-organized Cu-W nanocomposites

We use precession electron diffraction to investigate the crystallographic character of copper (Cu)-tungsten (W) nanocomposites fabricated via physical vapor co-deposition at 400 oC. We observe sub-micron-scale regions, where apparently disconnected Cu and W grains have near identical crystallographic orientations. This persistence of grain orientations suggests Cu and W grains within these regions are interconnected in 3-D when they first form and may be considered as intercalated, sub-micron-scale "super-grains". Indeed, atom probe tomography provides direct evidence of 3-D interconnectivity of W domains. Our findings shed light on the structure and self organization mechanisms of nanocomposites formed by spontaneous phase separation of co-deposited metals.

Yadav, Digvijay↗
DOE OSTI2022

Hermetically sealed porous-wall hollow microspheres enabled by monolithic glass coatings: Potential for thermal insulation applications

Thermal insulation materials are crucial to improve the energy performance of buildings and industrial applications. We report an approach to create hermetically vacuum-sealed silica-based hollow microspheres that can lower the thermal conductivity of closed-cell insulation materials. The wall structure of these hollow microspheres includes a reticulated network of pores or channels that extend through the thickness of the wall. When a thin layer of glass material is applied to the wall exterior, followed by a vacuum-assisted thermal treatment process, the coated microsphere surfaces display a highly dense conformal coverage and near-complete elimination of surface porosity. The sealing efficiency of these microspheres is verified by trapping argon within their cavities as well as through evacuating their hollow cores. Notably, incorporating the evacuated microspheres into a polymer matrix resulted in ~27% enhancement in its thermal insulation performance and no notable loss of performance was observed following three months of exposure to ambient conditions. Thus, we believe that the present study offers a commercially viable strategy that opens the door to applications of such inorganic hollow particles in areas ranging from vacuum-based thermal insulation systems to catalysis, separation technologies, and medical fields.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Coupling nitrate capture with ammonia production through bifunctional redox-electrodes

Abstract Nitrate is a ubiquitous aqueous pollutant from agricultural and industrial activities. At the same time, conversion of nitrate to ammonia provides an attractive solution for the coupled environmental and energy challenge underlying the nitrogen cycle, by valorizing a pollutant to a carbon-free energy carrier and essential chemical feedstock. Mass transport limitations are a key obstacle to the efficient conversion of nitrate to ammonia from water streams, due to the dilute concentration of nitrate. Here, we develop bifunctional electrodes that couple a nitrate-selective redox-electrosorbent (polyaniline) with an electrocatalyst (cobalt oxide) for nitrate to ammonium conversion. We demonstrate the synergistic reactive separation of nitrate through solely electrochemical control. Electrochemically-reversible nitrate uptake greater than 70 mg/g can be achieved, with electronic structure calculations and spectroscopic measurements providing insight into the underlying role of hydrogen bonding for nitrate selectivity. Using agricultural tile drainage water containing dilute nitrate (0.27 mM), we demonstrate that the bifunctional electrode can achieve a 8-fold up-concentration of nitrate, a 24-fold enhancement of ammonium production rate (108.1 ug h −1 cm −2 ), and a >10-fold enhancement in energy efficiency when compared to direct electrocatalysis in the dilute stream. Our study provides a generalized strategy for a fully electrified reaction-separation pathway for modular nitrate remediation and ammonia production.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2024

p14 ARF forms meso-scale assemblies upon phase separation with NPM1

NPM1 is an abundant nucleolar chaperone that, in addition to facilitating ribosome biogenesis, contributes to nucleolar stress responses and tumor suppression through its regulation of the p14 Alternative Reading Frame tumor suppressor protein (p14 ARF ). Oncogenic stress induces p14 ARF to inhibit MDM2, stabilize p53 and arrest the cell cycle. Under non-stress conditions, NPM1 stabilizes p14 ARF in nucleoli, preventing its degradation and blocking p53 activation. However, the mechanisms underlying the regulation of p14 ARF by NPM1 are unclear because the structural features of the p14 ARF -NPM1 complex were elusive. Here we show that p14 ARF assembles into a gel-like meso-scale network upon phase separation with NPM1. This assembly is mediated by intermolecular contacts formed by hydrophobic residues in an α-helix and β-strands within a partially folded N-terminal portion of p14 ARF . These hydrophobic interactions promote phase separation with NPM1, enhance p14 ARF nucleolar partitioning, restrict NPM1 diffusion within condensates and nucleoli, and reduce cellular proliferation. Our structural analysis provides insights into the multifaceted chaperone function of NPM1 in nucleoli by mechanistically linking the nucleolar localization of p14 ARF to its partial folding and meso-scale assembly upon phase separation with NPM1.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Linking optical spectra to free charges in donor/acceptor heterojunctions: cross-correlation of transient microwave and optical spectroscopy

The primary photoexcited species in excitonic semiconductors is a bound electron–hole pair, or exciton. An important strategy for producing separated electrons and holes in photoexcited excitonic semiconductors is the use of donor/acceptor heterojunctions, but the degree to which the carriers can escape their mutual Coulomb attraction is still debated for many systems. Here, we employ a combined pump–probe ultrafast transient absorption (TA) spectroscopy and time-resolved microwave conductivity (TRMC) study on a suite of model excitonic heterojunctions consisting of mono-chiral semiconducting single-walled carbon nanotube (s-SWCNT) electron donors and small-molecule electron acceptors. Comparison of the charge-separated state dynamics between TA and TRMC photoconductance reveals a quantitative match over the 0.5 microsecond time scale. Charge separation yields derived from TA allow extraction of s-SWCNT hole mobilities of ca. 1.5 cm 2 V -1 s -1 (at 9 GHz) by TRMC. We find that the correlation between the techniques conclusively demonstrates that photoinduced charge carriers separated across these heterojunctions do not form bound charge transfer states, but instead form free/mobile charge carriers.

36 MATERIALS SCIENCE↗