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NASA NTRS2000

Chemistry and Properties of Imide Oligomers from Phenylethynyl-Containing Diamines

As an extension of work on pendent phenylethynlyl-containing imide oligomer, three new diamines containing pendent phenylethynyl groups were prepared and characterized. These diamines were used to prepare pendent and pendent and terminal phenylethynyl imide oliogomers via the amide acid route in N-methyl-2-pyrrolidinone at a calculated number average molecular weight of 5000 g mol (exp -1). The pendent phenylethynyl groups were randomly distributed along the oliogomer backbone and provided a means of controlling the distance between reactive sites. The imide oligomers were characterized and thermally cured, and the cured polymers evaluated as thin films and compared with materials of similar composition prepared from 3,5-diamino-4'-phenylethynylbenzophenone. This work was performed as part of a continuing research effort to develop structural resins for potential aeronautical applications.

Smith, J. G., Jr.↗
NASA NTRS2000

Fluid Inclusions in Extraterrestrial Samples Fact or Fiction?

Over the years there have been numerous reports of liquid inclusions in meteorites. Roedder reviews the reported occurrences of liquid inclusions in meteorites and states that "silicate-melt inclusions are expectable and apparently ubiquitous, but the presence of actual liquid inclusions (i.e., with moving bubbles at room temperature) would seem almost impossible." The reason for this conclusion is that meteorites (presumably) form in space at high temperatures and very low pressures where liquid water (or carbon dioxide) is not stable. Perhaps the most infamous report of fluid inclusions in meteorites was that of Warner et al. In that study, the authors reported the presence of two-phase, liquid-vapor inclusions in a diogenite from Antarctica. This report of fluid inclusions generated considerable interest in the meteorite community, and caused many to question existing models for the origin of the diogenites. This interest was short-lived however, as later investigations of the same samples showed that the inclusions were most likely artifacts. Rudnick et al. showed that many of the inclusions in meteorites prepared at the Johnson Space Center contained a fluid that fluoresced strongly under the laser beam on the Raman microprobe. They interpreted this to indicate that the inclusions contained Almag oil used in the preparation of thin sections. Presumably, the Almag oil entered empty vesicles along fractures that were opened intermittently during cutting. Here, the occurrence of unambiguous fluid inclusions that could not have been introduced during sample preparation are described in samples from two different extraterrestrial environments. One environment is represented by the SNC (martian) meteorites ALH 84001 and Nakhla. The second environment is represented by the Monahans 1998 meteorite that fell recently in the USA.

Bodnar, R. J.↗
NASA NTRS2000

Synthesis and Properties of Phenylethynyl-Terminated, Star-Branched, Phenylquinoxaline Oligomers

The primary objective of this work was to prepare readily melt and solution processable phenylquinoxaline (PQ) oligomers that could be thermally crosslinked to solvent-resistant resins. Thus, a mixture of 2-(4-hydroxyphenyl)-3-phenyl-6-fluoroquinoxaline and 3-(4-hydroxyphenyl)-2-phenyl-6-fluoroquinoxaline (HPFQ) was used to prepare star-branched PQ oligomers end-capped with 4-fluoro-4-phenylethynylbenzophenone (FPEB). 1,1,1-Tris(4-hydroxyphenyl)ethane (THPE) was used as the branching unit. The oligomer number-average molecular weights (M (bar) (sub n) S) as determined by size exclusion chromatography (SEC) were close to the calculated values of 2922, 4698, 6474, and 13,578 g/mol, and their intrinsic viscosities ranged from 0.16 to 0.57 dl/g (m-cresol at 30 C). The oligomers, which were quite soluble in common organic solvents, had glass transition temperatures (T (sub g) S) that ranged from 181 to 233 C (DSC, DELTA T = 20 C/min). They also underwent an exothermic cure with maxima from 377 to 443 C. The T (sub g) S of the cured oligomers ranged from 259 to 284 C depending on the oligomer M (bar) (sub n) and the curing conditions. The oligomers had low melt viscosities, e.g. an oligomer (SPQ-46) with an M (bar) (sub n) of 4816 g/mol (SEC) had a melt viscosity of 150 Pa s at 348 C. A cured thin film of SPQ-46, which was insoluble in common organic solvents, had a room temperature (RT) tensile strength of 100 MPa, a RT modulus of 2358 MPa, and a RT elongation of 5.9%. A cured sample of SPQ-46 displayed a RT titanium-titanium lap shear tensile strength of 35.2 MPa. SPQ-46/carbon fiber(IM-7) composites, were prepared that displayed a RT flexural strength of 1902 MPa, a RT modulus of 1.38 GPa and a RT open hole compressive strength of 433 MPa.

Ooi, I. H.↗
NASA NTRS2000

NASA's Hyper-X Program

This paper provides an overview of the objectives and status of the Hyper-X program which is tailored to move hypersonic, airbreathing vehicle technology from the laboratory environment to the flight environment, the last stage preceding prototype development. The first Hyper-X research vehicle (HXRV), designated X-43, is being prepared at the Dryden Flight Research Center for flight at Mach 7 in the near future. In addition, the associated booster and vehicle-to-booster adapter are being prepared for flight and flight test preparations are well underway. Extensive risk reduction activities for the first flight and non-recurring design for the Mach 10 X-43 (3rd flight) are nearing completion. The Mach 7 flight of the X-43 will be the first flight of an airframe-integrated scramjet-powered vehicle.

Rausch, Vincent L.↗
NASA NTRS1992

A Scenario for Human Exploration of the Moon and Mars

Following a meeting on May 31, 1989, NASA received a request from Vice President Dan Quayle to conduct a study in preparation for a presidential decision on July 20, 1989, that would establish a NASA exploration goal. NASA Administrator Richard Truly set up a Working Group under Frank Martin and Mark Craig, which met at the Johnson Space Center and put together the data necessary to brief the White House on a appropriate plan. The group met from June 4 through June 11 to study the issue and prepare briefing charts. Many of the charts that the group prepared follow. The charts were used to brief Admiral Truly and other high-ranking NASA officials on June 13, 1989.

Craig, Mark↗
NASA NTRS2002

STS-108 Mission Highlights Resource Tape

This is Part 1 of a three part video series which provides highlights of the STS-108 mission during which the Expedition Three crew (Commander Frank Culbertson) of the International Space Station (ISS) was relieved by the Expedition Four crew (Commander Yury Onfrienko). For the other parts of the series, refer to 'STS-108 Mission Highlights Resource Tape, Part 2 of 3' (Internal ID 2002049330) and 'STS-108 Mission Highlights Resource Tape, Part 3 of 3' (Internal ID 2002049329). During this video, the STS-108 crew of the Space Shuttle Endeavour (Commander Dom Gorie), as well as the Expedition Four crew, are shown preparing for liftoff at Kennedy Space Center (KSC). Preparations include preflight suiting up, and the strapping in of the crew by support staff. The launch is shown from the Launch Control Center. Following the orbital entry of Endeavour, there is an inspection of the shuttle's payload bay. There is some flight deck activity as the crew prepares for the rendezvous and docking of Endeavour with the ISS. Following the docking, the Expedition Three crew welcomes the others aboard the station, and both crews are briefed. There is an unobstructed view of the South Atlantic Ocean and the coast line of Argentina which includes Peninsula Valdes and Golfo Nuevo. The Raffaello Multipurpose Logistics Module (MPLM) is unberthed from the shuttle payload bay and attached to the ISS.

Source record↗
NASA NTRS2002

Development of Chemically and Thermally Robust Lithium Fast Ion Conducting Chalcogenide Glasses

In this project, a new research thrust into the development of an entirely new class of FIC glasses has begun that may lead to a new set of optimized thin-film lithium ion conducting materials. New chemically robust FIC glasses are being prepared that are expected to exhibit unusually high chemical and electrochemical stability. New thermally robust FIC glasses are being prepared that exhibit softening points in excess of 500 C which will dramatically expand the usable operating temperature range of batteries, fuel-cells, and sensors using such electrolytes. Glasses are being explored in the general compositional series xLi2S+ yGa2S3 + (1-x-y)GeS2. Li2S is added as the source of the conductive lithium ions. GeS2 is the base glass-forming phase and the trivalent sulfides, Ga2S3, is added to increase the "refractoniness" of the glass, that is to significantly increase the softening point of the glass as well as its chemical stability. By optimizing the composition of the glass, new glasses and glass-ceramic FIC materials have been prepared with softening points in excess of 500 C and conductivities above 10(exp -3)/Ohm cm at room temperature. These latter attributes are currently not available in any FIC glasses to date.

Martin, Steve W.↗
NASA NTRS2001

Lifetime of a Chemically Bound Helium Compound

The rare-gas atoms are chemically inert, to an extent unique among all elements. This is due to the stable electronic structure of the atoms. Stable molecules with chemically bound rare-gas atoms are, however, known. A first such compound, XePtF6, W2S prepared in 1962 and since then a range of molecules containing radon, xenon and krypton have been obtained. Most recently, a first stable chemically bound compound of argon was prepared, leaving neon and helium as the only elements for which stable chemically bound molecules are not yet known. Electronic structure calculations predict that a metastable species HHeF exists, but significance of the result depends on the unknown lifetime. Here we report quantum dynamics calculations of the lifetime of HHeF, using accurate interactions computed from electronic structure theory. HHeF is shown to disintegrate by tunneling through energy barriers into He + HF and H + He + F the first channel greatly dominating. The lifetime of HHeF is more than 120 picoseconds, that of DHeF is 14 nanoseconds. The relatively long lifetimes are encouraging for the preparation prospects of this first chemically bound helium compound.

Chaban, Galina M.↗
NASA NTRS1999

Electron Microscopy and Image Analysis for Selected Materials

This particular project was completed in collaboration with the metallurgical diagnostics facility. The objective of this research had four major components. First, we required training in the operation of the environmental scanning electron microscope (ESEM) for imaging of selected materials including biological specimens. The types of materials range from cyanobacteria and diatoms to cloth, metals, sand, composites and other materials. Second, to obtain training in surface elemental analysis technology using energy dispersive x-ray (EDX) analysis, and in the preparation of x-ray maps of these same materials. Third, to provide training for the staff of the metallurgical diagnostics and failure analysis team in the area of image processing and image analysis technology using NIH Image software. Finally, we were to assist in the sample preparation, observing, imaging, and elemental analysis for Mr. Richard Hoover, one of NASA MSFC's solar physicists and Marshall's principal scientist for the agency-wide virtual Astrobiology Institute. These materials have been collected from various places around the world including the Fox Tunnel in Alaska, Siberia, Antarctica, ice core samples from near Lake Vostoc, thermal vents in the ocean floor, hot springs and many others. We were successful in our efforts to obtain high quality, high resolution images of various materials including selected biological ones. Surface analyses (EDX) and x-ray maps were easily prepared with this technology. We also discovered and used some applications for NIH Image software in the metallurgical diagnostics facility.

Williams, George↗
NASA NTRS2002

Thermally Stable, Piezoelectric and Pyroelectric Polymeric Substrates and Method Relating Thereto

A thermally stable, piezoelectric and pyroelectric polymeric substrate was prepared, This thermally stable, piezoelectric and pyroelectric polymeric substrate may be used to prepare electromechanical transducers, thermomechanical transducers, accelerometers, acoustic sensors, infrared sensors, pressure sensors, vibration sensors, impact sensors. in-situ temperature sensors, in-situ stress/strain sensors, micro actuators, switches. adjustable fresnel lenses, speakers, tactile sensors, weather sensors, micro positioners, ultrasonic devices, power generators, tunable reflectors, microphones, and hydrophones. The process for preparing these polymeric substrates includes: providing a polymeric substrate having a softening temperature greater than 100 C; depositing a metal electrode material onto the polymer film; attaching a plurality of electrical leads to the metal electrode coated polymeric substrates; heating the metal electrode coated polymeric substrate in a low dielectric medium; applying a voltage to the heated metal electrode coated polymeric substrate to induce polarization; and cooling the polarized metal electrode coated polymeric electrode while maintaining a constant voltage.

Joycelyn O Simpson↗
NASA NTRS2002

Low Dielectric Polymers

This report summarizes results obtained from research funded through Research Cooperative Agreement No. NCC-1-01033-"Low Dielectric Polymers" (from 5/10/01 through 5/09/02). Results are reported in three of the proposed research areas (Tasks 1-3 in the original proposal): (1) Repeat and confirm the preparation and properties of the new alkyl-substituted PEK, 6HC17-PEK, (2) Prepare and evaluate polymers derived from a highly fluorinated monomer, and (3) Prepare and evaluate new silicon and/or fluorine-containing polymers expected to retain useful properties at low temperature.

Venumbaka, Sreenivasulu R.↗
NASA NTRS2002

STS-110 Flight Day 6 Highlights

On the sixth day of the STS-110 mission, Mission Specialists Jerry Ross and Lee Morin are seen in the second extravehicular activity (EVA) of this mission to the International Space Station (ISS). The video opens with the two astronauts preparing for the EVA, which will be Ross' eighth, thereby making him the most experienced space-walker in history. This pair of astronauts has been dubbed the Silver Team, largely because they both have grandchildren. As Ross and Morin prepare for the EVA by breathing pure oxygen and experiencing reduced pressure, Mission Specialist Ellen Ochoa maneuvers the robotic arm towards the hatch of the Space Shuttle Atlantis. There is video footage of the astronauts exiting the hatch and preparing their tools and work areas. During this EVA the astronauts will install two tripod-like struts, which will serve as structural attachments between the S-0 truss segment and the Destiny Laboratory Module. While the construction takes place, helmet mounted cameras on the spacesuits provide live video of the astronauts at work, most often using a pistol grip tool used as an electric ratcheting-type drill to loosen and tighten bolts. Following the installation of the struts, Ross and Morin remove the draglinks and keelpins that had functioned to hold the S0 truss structure securely in Atlantis' payload bay during the launch sequence of the mission. They move these to temporary storage positions, bolted on the outside of the ISS. They then install an umbilical system that will provide power to the Mobile Transporter (MT).

Source record↗
NASA NTRS2002

STS-111 Flight Day 5 Highlights

On Flight Day 5 of STS-111, the crew of Endeavour (Kenneth Cockrell, Commander; Paul Lockhart, Pilot; Franklin Chang-Diaz, Mission Specialist; Philippe Perrin, Mission Specialist) and the Expedition 5 crew (Valery Korzun, Commander; Peggy Whitson, Flight Engineer; Sergei Treschev, Flight Engineer) and Expedition 4 crew (Yury Onufrienko, Commander; Daniel Bursch, Flight Engineer; Carl Walz, Flight Engineer) are aboard the docked Endeavour and International Space Station (ISS). The ISS cameras show the station in orbit above the North African coast and the Mediterranean Sea, as Chang-Diaz and Perrin prepare for an EVA (extravehicular activity). The Canadarm 2 robotic arm is shown in motion in a wide-angle shot. The Quest Airlock is shown as it opens to allow the astronauts to exit the station. As orbital sunrise approaches, the astronauts are shown already engaged in their EVA activities. Chang-Diaz is shown removing the PDGF (Power and Data Grapple Fixture) from Endeavour's payload bay as Perrin prepares its installation position in the ISS's P6 truss structure; The MPLM is also visible. Following the successful detachment of the PDGF, Chang-Diaz carries it to the installation site as he is transported there by the robotic arm. The astronauts are then shown installing the PDGF, with video provided by helmet-mounted cameras. Following this task, the astronauts are shown preparing the MBS (Mobile Base System) for grappling by the robotic arm. It will be mounted to the Mobile Transporter (MT), which will traverse a railroad-like system along the truss structures of the ISS, and support astronaut activities as well as provide an eventual mobile base for the robotic arm.

Source record↗
NASA NTRS2002

STS-112 Flight Day 4 Highlights

On the fourth day of STS-112, its crew (Jeffrey Ashby, Commander; Pamela Melroy, Pilot; David Wolf, Mission Specialist; Piers Sellers, Mission Specialist; Sandra Magnus, Mission Specialist; Fyodor Yurchikhin, Mission Specialist) onboard Atlantis and the Expedition 5 crew (Valery Korzun, Commander; Peggy Whitson, Flight Engineer; Sergei Treschev, Flight Engineer) onboard the International Space Station (ISS) are seen preparing for the installation of the S1 truss structure. Inside the Destiny Laboratory Module, Korzun and other crewmembers are seen as they busily prepare for the work of the day. Sellers dons an oxygen mask and uses an exercise machine in order to purge the nitrogen from his bloodstream, in preparation for an extravehicular activity (EVA). Whitson uses the ISS's Canadarm 2 robotic arm to grapple the S1 truss and remove it from Atlantis' payload bay, with the assistance of Magnus. Using the robotic arm, Whitson slowly maneuvers the 15 ton truss structure into alignment with its attachment point on the starboard side of the S0 truss structure, where the carefully orchestrated mating procedures take place. There is video footage of the entire truss being rotated and positioned by the arm, and ammonia tank assembly on the structure is visible, with Earth in the background. Following the completion of the second stage capture, the robotic arm is ungrappled from truss. Sellers and Wolf are shown exiting the the Quest airlock hatch to begin their EVA. They are shown performing a variety of tasks on the now attached S1 truss structure, including work on the Crew Equipment Translation Cart (CETA), the S-band Antenna Assembly, and umbilical cables that provide power and remote operation capability to cameras. During their EVA, they are shown using a foot platform on the robotic arm. Significant portions of their activities are shown from the vantage of helmet mounted video cameras. The video closes with a final shot of the ISS and its new S1 truss.

Source record↗
NASA NTRS2002

Atmospheric Pressure Spray Chemical Vapor Deposited CuInS2 Thin Films for Photovoltaic Applications

Solar cells have been prepared using atmospheric pressure spray chemical vapor deposited CuInS2 absorbers. The CuInS2 films were deposited at 390 C using the single source precursor (PPh3)2CuIn(SEt)4 in an argon atmosphere. The absorber ranges in thickness from 0.75 - 1.0 micrometers, and exhibits a crystallographic gradient, with the leading edge having a (220) preferred orientation and the trailing edge having a (112) orientation. Schottky diodes prepared by thermal evaporation of aluminum contacts on to the CuInS2 yielded diodes for films that were annealed at 600 C. Solar cells were prepared using annealed films and had the (top down) composition of Al/ZnO/CdS/CuInS2/Mo/Glass. The Jsc, Voc, FF and (eta) were 6.46 mA per square centimeter, 307 mV, 24% and 0.35%, respectively for the best small area cells under simulated AM0 illumination.

Harris, J. D.↗
NASA NTRS2002

Integrated In-space Transportation Plan

The purpose of this report is to provide the reader with a readily accessible reference volume and history for the Integrated In-Space Transportation Plan (IISTP) phase I effort. This report was prepared by Gray Research, Inc. as a partial fulfillment of the Integrated Technology Assessment Center subcontract No. 4400037135 in support of the IISTP phase I effort within the In-Space Investment Area of the Advanced Space Transportation Program managed at Marshall Space Flight Center, Huntsville, Alabama. Much of the data used in the preparation of this report was taken from analyses, briefings, and reports prepared by the vast number of dedicated engineers and scientists who participated in the IISTP phase I effort. The opinions and ideas expressed in this report are solely those of the authors and do not necessarily reflect those of NASA in whole or in part.

Advanced space transportation↗
NASA NTRS2002

A Proposal to Investigate Outstanding Problems in Astronomy

During the period leading up to the spectacular launch of the Space Shuttle Columbia (STS-109) on 1 March 2002 6:22 am EST, the team worked hard on a myriad of tasks to be ready for launch. Our launch support included preparations and rehearsals for the support during the mission, preparation for the SMOV and ERO program, and work to have the science team's data pipeline (APSIS) and data archive (SDA) ready by launch. A core of the team that was at the GSFC during the EVA that installed ACS monitored the turn-on and aliveness tests of ACS. One hour after installation of ACS in the HST George Hartig was showing those of us at Goddard the telemetry which demonstrated that the HRC and WFC CCDs were cooling to their preset temperatures. The TECs had survived launch! After launch, the team had several immediate and demanding tasks. We had to process the ERO observations through our pipeline and understand the limitations of the ground based-based calibrations, and simultaneously prepare the EROs for public release. The ERO images and the SMOV calibrations demonstrated that ACS met or exceeded its specifications for image quality and sensitivity. It is the most sensitive instrument that Hubble has had. The ERO images themselves made the front page of all of the major newspapers in the US. During the months after launch we have worked on the SMOV observations, and are analyzing the data from our science program.

Ford, Holland↗
NASA NTRS2003

Novel Route to Transition Metal Isothiocyanate Complexes Using Metal Powders and Thiourea

A new synthetic route to isothiocyanate-containing materials is presented. Eight isothiocyanate- 4-methylpyridine (y-picoline) compounds were prepared by refluxing metal powders (Mn, Fe, Co, Ni, and Cu) with thiourea in y-picoline. With the exception of compound 5,prepared with Co, the isothiocyanate ligand was generated in situ by the isomerization of thiourea to NH4+SCN- at reflux temperatures. The complexes were characterized by x-ray crystallography. Compounds 1,2, and 8 are the first isothiocyanate- 4-methylpyridine anionic compounds ever prepared and structurally characterized. Compounds 1 and 2 are isostructural with four equatorially bound isothiocyanate ligands and two axially bound y-picoline molecules. Compound 8 is a five-coordinate copper(II) molecule with a distorted square-pyramidal geometry. Coordinated picoline and two isothiocyanates form the basal plane and the remaining isothiocyanate is bound at the apex. Structural data are presented for all compounds.

Harris, Jerry D.↗