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At least 1,297 records · Page 72

Thermogravimetry system designed for use in dispersion strengthening studies.

A thermogravimetry system, designed to study the reduction of oxides in metal and alloy powders to be used in dispersion strengthened materials, is described. The apparatus was devised for use at high temperatures with controlled atmospheres. Experimental weight change and moisture evolution results for the thermal decomposition of calcium oxalate monohydrate in dry helium, and experimental weight change results for the reduction of nickel oxide in dry hydrogen and hydrogen containing 15,000 p.p.m. water vapor are presented. The system is currently being successfully applied to the evaluation of the reduction characteristics and the removal of impurities from metals and alloys to be used for dispersion strengthening.

Herbell, T. P.↗

Erosion, transportation and the nature of the maria.

Seismic evidence makes clear that there is no continuous sheet of bedrock at a shallow depth in the vicinity of the Apollo 12 site. A deep deposit of powder would match the seismic properties observed. Mascons require for their explanation a surface transportation process that tends to fill in the large impact basins after their formation. Surface transportation of lunar dust has been demonstrated in the laboratory to occur most readily as a result of electrostatic forces produced by electron bombardment in the energy range of a few hundred volts. Such bombardment happens on the moon predominantly when it is in the magnetic tail of the earth, and this may be the reason why mare ground is so remarkably dominant on the hemisphere facing the earth.

Gold, T.↗

Lineaments of the Apennine Front - Apollo 15 landing site.

The well-developed systems of lineaments that suggest regional fracturing or layering of the bedrock in the mountains at the Apollo 15 site may be illusions created by oblique lighting rather than expressions of true geologic structure. Supporting evidence includes: (1) occurrence of similar dominant lineament trends on many of the slopes even though the slope orientations differ widely; (2) presence of a thick mantling regolith that should conceal bedrock structures; (3) approximate symmetry of some of the lineament sets about the sun line; (4) lack of clear-cut topographic expression for many of the lineaments; and (5) general similarity of the lunar lineaments to lineament patterns produced by low oblique lighting on model surfaces mantled by fine sifted powder. Locally, as at Silver Spur, some lineament trends are related to distinct topographic features and are more confidently interpreted to reflect underlying geologic structures.

Wolfe, E. W.↗

Noble gases in eleven H-chondrites.

Review of the results of measurements of noble gases in powdered aliquots of 11 H-chondrites whose trace element contents have been previously determined by Laul et al. (1973). The measurements were made on a 4.5-inch radius, Reynolds-type mass spectrometer, using conventional techniques.

Ganapathy, R.↗

Ten-micron eclipse observations of Io, Europa, and Ganymede.

Eclipse observations of Jupiter's satellites Io, Europa, and Ganymede have been obtained in an 8 to 14-micron band pass during 1971. The simplest thermal model able to explain the data for each satellite is a two-layer surface structure with an upper layer, only a few millimeters thick, having low thermal conductivity consistent with fine rock powder or frost, and a subsurface having high thermal conductivity consistent with solid rock or dense ice. The upper layer on Io appears to be different from that on Europa and Ganymede, but the two-layer model fits all three satellites.

Hansen, O. L.↗

Oxidation of organic molecules by photoproduced holes of ZnO.

Two experimental techniques were developed. In the first, an electrochemical method was used with a single crystal ZnO electrode and with the material of interest dissolved in the electrolyte. In the other an electron spin resonance method was used so that measurements related to thermal control coatings could be made with the ZnO in the form of powder, either alone or in formulation of a binder. A simplified model regarding the relationship between the electron density and time is considered.

Sancier, K. M.↗

Conjectures about the evolution of the moon.

The principal questions about the derivation of the lunar surface have not yet been settled: is it the surface left over from the process of accumulation of the moon, or is it a surface generated by magmatic processes on the moon and subsequently altered by further infall from outside. The evidence derived from many sources now favors the former. Seismic data suggest an absence of bedrock down to a depth of several kilometers, and instead a compacted powder only. The 'mascon' evidence can be understood as a consequence of major impacts in a deep porous layer. The great abundance of cosmic ray tracks in most soil samples demands a much greater cosmic ray dosage than present rates would cause in the age of the moon, unless the dust represented infallen material previously irradiated.

Gold, T.↗

Effect of simulated lunar impact on the survival of bacterial spores.

In order to test the effect of impact on organisms, the survival of bacterial spores after being propelled at high velocity in Pyrex and plastic beads into crushed basalt was measured. The beads were fired into sterilized canisters by both a conventional powder and a light gas gun. Results indicate that at the minimum (2.4 km/sec) lunar capture velocity, the number of colony forming units (CFUs) decreased by five orders of magnitude, and at 5.5 km/sec, statistically a more probable capture velocity, no CFUs were found. The decrease in CFUs observed with increasing velocity indicates that the spores were most probably killed by the impact.

Whitfield, O.↗

Basic Behavior and Properties of W-UO2 Cermets

Thermal cycling studies on cermets prepared from tungsten and UO2 powder mixtures and cermets prepared using tungsten coated UO2 particles are discussed. The cermets were tested in hydrogen at high temperatures to determine the effects of temperature, thermal cycling, and hydrogen pressure. Basic mechanism studies of tungsten­-UO2 interactions in thermally cycled cermets are also described.

Baker, R. J.↗

A new nickel-base wrought superalloy for applications up to 1033 K (1400 F)

Alloy was melted from high purity raw materials and cast ingots extruded at 1422 K. Material was hot rolled to 0.013 m diameter bar stock. Partial solution heat-treatment followed by aging produced structure of fine gamma prime precipitate reinforcing gamma matrix containing coarser blocky gamma prime particles. Alloy can be processed by powder metallurgy.

Kent, W. B.↗

Economical technique for fragmentation testing

Automatic rifle was modified for remote, single-shot use. To simulate statistically--determined fragment size from rocket-motor casing blunt-nosed bullet was made of same alloy. Cartridge was loaded with enough powder to make bullet reach target at same estimated velocity as shrapnel from rocket casing.

Smith, T. H., III↗

Method of making pressure tight seal for super alloy

A procedure for forming a pressure tight seal along two edges of super alloy sheets is presented. The procedure consists of flame spraying a powdered aluminum-nickel composition on the joint. The use of frozen carbon dioxide and carbon dioxide gas to maintain a low temperature environment during the flame spraying is described.

Little, R. E.↗

HNS/Teflon, a new heat resistant explosive

HNS/Teflon (90/10) is a new pressed explosive developed for use in the Apollo program. The major advantages of HNS/Teflon are (1) excellent thermal stability at elevated temperatures, (2) superior resistance to sublimation at high temperatures and low pressures and (3) ease of molding powder preparation, pressing and machining. The impact sensitivity of HNS/Teflon is between that of Comp B and Comp A-3 while its explosive performance is about the same as TNT. Under the severe environmental conditions of the moon's surface, this explosive successfully performed its intended function of generating seismic waves in the Apollo ALSEP and LSPE experiments. (Modified author abstract)

Heller, H.↗

Effects of size, shape, and frequency on the antiferromagnetic resonance linewidth of MnF

The research concerning the properties and application of solid state materials at submillimeter frequencies is summarized. Work reported includes: far infrared Fourier spectroscopy; studies of the antiferromagnetic resonance line in MnF2 at millimeter wavelengths; numerical solution of the equations of motion of a general two-sublattice antiferromagnet; study of antiferromagnetic resonance line in NiO powder; and resonance investigations of several indium thisospinels at millimeter wavelengths.

Obrien, K. C.↗

A method for determining the preferred orientation of crystallites normal to a surface

Techniques representing the angular distribution of a particular direction in a crystallographic reference frame or analytical methods were developed. The data required by these techniques for displaying preferred orientation is obtained by measuring the orientation of a large number of crystallites. This may be done visually using etch-pit or Laue techniques which, experimentally, are both tedious and difficult. The intensities of X ray diffraction maxima are proportional to the number of crystallites whose crystallographic plane normals bisect the incident and diffracted beams. Parameters used in calculating powder patterns are also presented.

Snyder, R. L.↗

On the primordial condensation and accretion environment and the remanent magnetization of meteorites

In the context of various models for the early evolution of a solar nebula, the possible roles assigned to ambient magnetic fields and the paleointensities required to establish the stable natural remanent magnetization observed in meteorites, are discussed. It is suggested that the record of paleofields present during condensation, growth, and accumulation of grains is likely to have been preserved as chemical or thermochemical remanence in unaltered meteoritic material. Fine particle theories appear adequate for treating meteoritic remanence, if models based on corresponding types of permanent magnet materials, e.g., powder ferrites for chondrites and diffusion hardened alloys for iron meteorites, are adopted.

Brecher, A.↗

Major and trace element concentrations in samples from 72275 and 72255

Analytical data have been obtained for Co, Sc, Hf, Zn, Cr, Ga, Rb, Cs, Ni, major elements, and rare earth elements in eight samples from boulder 1. The data for trace elements were obtained by radiochemical neutron activation analysis. Major elements, except Na and Mn, were obtained by atomic absorption spectral photometry. Values for Na and Mn were obtained by neutron activation analysis of the same powder that was later dissolved to provide the atomic absorption analyses.

Haskin, L. A.↗

Solid state polymerization and crystallography of polyimide precursors

Although the production of crystallinity in a polymeric system has historically led to commerically useful properties, the polyimides, prized for their high temperature characteristics, as customarily synthesized by melt or solution casting, are amorphous. It is shown that polymide containing residual crystallinity can be synthesized by isothermal annealing of crystals of the salt of the diisopropyl ester of pyromellitic acid and phenylene diamine. The reaction is topochemical in that the geometry of the polymer product is dependent upon that of the crystalline precursor. Infrared spectroscopy reveals the presence of imide absorption in the polymer, while powder diffractometry suggests residual crystallinity. Single crystal X-ray analysis of the monomer yields a structure of chains of alternating acid and base suggesting that the monomer is amenable to polymerization with a minimum of geometrical disruption.

Wakelyn, N. T.↗