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DOE OSTI2022

Protein–Ligand Binding Free-Energy Calculations with ARROW–A Purely First-Principles Parameterized Polarizable Force Field

Protein–ligand binding free-energy calculations using molecular dynamics (MD) simulations have emerged as a powerful tool for in silico drug design. Here, we present results obtained with the ARROW force field (FF)–a multipolar polarizable and physics-based model with all parameters fitted entirely to high-level ab initio quantum mechanical (QM) calculations. ARROW has already proven its ability to determine solvation free energy of arbitrary neutral compounds with unprecedented accuracy. The ARROW FF parameterization is now extended to include coverage of all amino acids including charged groups, allowing molecular simulations of a series of protein–ligand systems and prediction of their relative binding free energies. We ensure adequate sampling by applying a novel technique that is based on coupling the Hamiltonian Replica exchange (HREX) with a conformation reservoir generated via potential softening and nonequilibrium MD. ARROW provides predictions with near chemical accuracy (mean absolute error of ~0.5 kcal/mol) for two of the three protein systems studied here (MCL1 and Thrombin). The third protein system (CDK2) reveals the difficulty in accurately describing dimer interaction energies involving polar and charged species. Overall, for all of the three protein systems studied here, ARROW FF predicts relative binding free energies of ligands with a similar accuracy level as leading nonpolarizable force fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1994

Obliquity-oblateness feedback: Are climatically sensitive values of obliquity dynamically unstable?

A new model is presented for feedback between rotational and climatic variations, operative on time scales of 10(exp 4) - 10(exp 7) years. Due to the combined effect of planetary perturbations to the Earth's orbit plane and luni-solar torques on the oblate figure of the Earth, the obliquity varies by approximately 1 deg on a 4 x 10(exp 4) year time scale. Associated changes in the seasonal and latitudinal pattern of incident solar radiation cause major glaciations. Mass transport from the oceans to the polar ice sheets during these glaciations can change the gravitational oblateness of the Earth by amounts approaching 1%. As the rate of spin axis precession is directly proportional to the oblateness, the climatically forced mass transport can by dynamically significant. A simple parameterization of this coupled orbital-rotational-climatic system suggests that there is a strong tendency for the system to evolve away from climatically sensitive values of the obliquity. This may explain the mid-Pleistocene transition from an obliquity dominated regime to the present regime in which most climatic variability is concentrated at longer (10(exp 5) year) periods.

Bills, Bruce G.↗

NASA NTRS2013

Net Influence of an Internally Generated Guasi-biennial Oscillation on Modelled Stratospheric Climate and Chemistry

A Goddard Earth Observing System Chemistry- Climate Model (GEOSCCM) simulation with strong tropical non-orographic gravity wave drag (GWD) is compared to an otherwise identical simulation with near-zero tropical non-orographic GWD. The GEOSCCM generates a quasibiennial oscillation (QBO) zonal wind signal in response to a tropical peak in GWD that resembles the zonal and climatological mean precipitation field. The modelled QBO has a frequency and amplitude that closely resembles observations. As expected, the modelled QBO improves the simulation of tropical zonal winds and enhances tropical and subtropical stratospheric variability. Also, inclusion of the QBO slows the meridional overturning circulation, resulting in a generally older stratospheric mean age of air. Slowing of the overturning circulation, changes in stratospheric temperature and enhanced subtropical mixing all affect the annual mean distributions of ozone, methane and nitrous oxide. Furthermore, the modelled QBO enhances polar stratospheric variability in winter. Because tropical zonal winds are easterly in the simulation without a QBO, there is a relative increase in tropical zonal winds in the simulation with a QBO. Extratropical differences between the simulations with and without a QBO thus reflect the westerly shift in tropical zonal winds: a relative strengthening of the polar stratospheric jet, polar stratospheric cooling and a weak reduction in Arctic lower stratospheric ozone.

stratosphere↗

DOE OSTI2020

Imaging grain microstructure in a model ceramic energy material with optically generated coherent acoustic phonons

Characterization of microstructure, chemistry and function of advanced energy materials remains a challenge for instrumentation science with tremendous opportunity for new discoveries. This active area of research is starting to make considerable strides with examples ranging from methodologies that employ bright X-rays, electron microscopy and optical spectroscopy. However, further development of instruments, capable of multimodal measurements, is necessary to fully reveal complex microstructure evolution in realistic environments and dynamical systems that are far from equilibrium. In this regard, laser-based instruments have a unique advantage as multiple measurement methodologies are easily combined into a single instrument using standard optics. A new pump-probe method that uses optically generated acoustic phonons is expanding standard optical characterization by providing depth resolved information. Here we report on a noteworthy extension of this pump-probe method to image grain microstructure in ceria. Rich information regarding the orientation of individual crystallites is obtained by monitoring acoustic phonon velocities and noting how the polarization of the probe beam influences the detected signal amplitude. When paired with other optical microscopies, this methodology will provide new perspectives for optical characterization of ceramic materials.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Southern Ocean latitudinal gradients of cloud condensation nuclei

Abstract. The Southern Ocean region is one of the most pristine in the world and serves as an important proxy for the pre-industrial atmosphere. Improving our understanding of the natural processes in this region is likely to result in the largest reductions in the uncertainty of climate and earth system models. While remoteness from anthropogenic and continental sources is responsible for its clean atmosphere, this also results in the dearth of atmospheric observations in the region. Here we present a statistical summary of the latitudinal gradient of aerosol (condensation nuclei larger than 10 nm, CN10) and cloud condensation nuclei (CCN at various supersaturations) concentrations obtained from five voyages spanning the Southern Ocean between Australia and Antarctica from late spring to early autumn (October to March) of the 2017/18 austral seasons. Three main regions of influence were identified: the northern sector (40–45∘ S), where continental and anthropogenic sources coexisted with background marine aerosol populations; the mid-latitude sector (45–65∘ S), where the aerosol populations reflected a mixture of biogenic and sea-salt aerosol; and the southern sector (65–70∘ S), south of the atmospheric polar front, where sea-salt aerosol concentrations were greatly reduced and aerosol populations were primarily biologically derived sulfur species with a significant history in the Antarctic free troposphere. The northern sector showed the highest number concentrations with median (25th to 75th percentiles) CN10 and CCN0.5 concentrations of 681 (388–839) cm−3 and 322 (105–443) cm−3, respectively. Concentrations in the mid-latitudes were typically around 350 cm−3 and 160 cm−3 for CN10 and CCN0.5, respectively. In the southern sector, concentrations rose markedly, reaching 447 (298–446) cm−3 and 232 (186–271) cm−3 for CN10 and CCN0.5, respectively. The aerosol composition in this sector was marked by a distinct drop in sea salt and increase in both sulfate fraction and absolute concentrations, resulting in a substantially higher CCN0.5/CN10 activation ratio of 0.8 compared to around 0.4 for mid-latitudes. Long-term measurements at land-based research stations surrounding the Southern Ocean were found to be good representations at their respective latitudes; however this study highlighted the need for more long-term measurements in the region. CCN observations at Cape Grim (40∘39′ S) corresponded with CCN measurements from northern and mid-latitude sectors, while CN10 observations only corresponded with observations from the northern sector. Measurements from a simultaneous 2-year campaign at Macquarie Island (54∘30′ S) were found to represent all aerosol species well. The southernmost latitudes differed significantly from both of these stations, and previous work suggests that Antarctic stations on the East Antarctic coastline do not represent the East Antarctic sea-ice latitudes well. Further measurements are needed to capture the long-term, seasonal and longitudinal variability in aerosol processes across the Southern Ocean.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2014

Assimilation of Dual-Polarimetric Radar Observations with WRF GSI

Dual-polarimetric (dual-pol) radar typically transmits both horizontally and vertically polarized radio wave pulses. From the two different reflected power returns, more accurate estimate of liquid and solid cloud and precipitation can be provided. The upgrade of the traditional NWS WSR-88D radar to include dual-pol capabilities will soon be completed for the entire NEXRAD network. Therefore, the use of dual-pol radar network will have a broad impact in both research and operational communities. The assimilation of dual-pol radar data is especially challenging as few guidelines have been provided by previous research. It is our goal to examine how to best use dual-pol radar data to improve forecast of severe storm and forecast initialization. In recent years, the Development Testbed Center (DTC) has released the community Gridpoint Statistical Interpolation (GSI) DA system for the Weather Research and Forecasting (WRF) model. The community GSI system runs in independently environment, yet works functionally equivalent to operational centers. With collaboration with the NASA Short-term Prediction Research and Transition (SPoRT) Center, this study explores regional assimilation of the dual-pol radar variables from the WSR-88D radars for real case storms. Our presentation will highlight our recent effort on incorporating the horizontal reflectivity (ZH), differential reflectivity (ZDR), specific differential phase (KDP), and radial velocity (VR) data for initializing convective storms, with a significant focus being on an improved representation of hydrometeor fields. In addition, discussion will be provided on the development of enhanced assimilation procedures in the GSI system with respect to dual-pol variables. Beyond the dual-pol variable assimilation procedure developing within a GSI framework, highresolution (≤1 km) WRF model simulations and storm scale data assimilation experiments will be examined, emphasizing both model initialization and short-term forecast of precipitation fields and processes. Further details of the methodology of data assimilation, the impact of different dual-pol variables, the influence on precipitation forecast will be presented at the conference.

Li, Xuanli↗

NASA NTRS2014

Assimilation of Dual-Polarimetric Radar Observations with WRF GSI

Li, Xuanli↗

NASA NTRS1976

A radio altimeter antenna for a planetary probe

The design of a 400 MHz directional radio altimeter antenna for use in a freely falling probe in a planetary atmosphere is described. It is required that the antenna be physically large to exploit the dependence of the return power on the square of the wavelength. The antenna must be deployable so that it can be stowed behind the heat shield during the phase of atmospheric penetration. The electrical requirement, imposed by the power available and the system noise, is that the gain in the direction of the probe be at least 3 dB over a dipole. The altimeter application imposes the requirement of linear polarization. Dipole elements are impractical because of the proximity of the heat shield, hence monopole elements using the heat shield as an integral part (the ground plane) of the antenna are used. A parasitic element is placed behind the driven element to increase both the front-to-back ratio and the directive gain. The antenna which has been selected has a gain of 4 dB over a dipole, a front-to-back ratio of 8 dB, and a -6 dB beam angle of 34 degrees. Experiments for evaluating the effects of element spacing, length, and tilt angle with respect to the probe axis were conducted on a 1/25 scale model of the antenna at 10 GHz, and impedance measurements were performed on a full scale antenna at 400 MHz.

Beyer, J. B.↗

DOE OSTI2025

Hunga Tonga–Hunga Ha′apai Volcano Impact Model Observation Comparison (HTHH-MOC) project: experiment protocol and model descriptions

The 2022 Hunga volcanic eruption injected a significant amount of water vapor and a moderate amount of sulfur dioxide into the stratosphere, causing observable responses in the climate system. We have developed a model–observation comparison project to investigate the evolution of volcanic water and aerosols and their impacts on atmospheric dynamics, chemistry, and climate, using several state-of-the-art chemistry climate models. The project goals are (1) to evaluate the current chemistry–climate models to quantify their performance in comparison to observations and (2) to understand atmospheric responses in the Earth system after this exceptional event and investigate the potential impacts in the projected future. To achieve these goals, we designed specific experiments for direct comparisons to observations, for example from balloons and the Microwave Limb Sounder satellite instrument. Experiment 1 consists of two sets of free-running ensemble experiments from 2022 to 2031: one with fixed sea-surface temperatures and sea ice and one with coupled ocean. These experiments will help to understand the long-term evolution of water vapor and aerosols; quantify HTHH effects on stratospheric and mesospheric temperatures, dynamics, and transport; understand the impact of dynamic changes on ozone chemistry; quantify the net radiative forcings; and evaluate any surface climate impact. Experiment 2 is a nudged-run experiment from 2022 to 2023 using observed meteorology. To allow participation of more climate models with varying complexities of aerosol simulation, we include two sets of simulations in Experiment 2: Experiment 2a is designed for models with internally generated aerosol, while Experiment 2b is designed for models using prescribed aerosol surface area density. This experiment will help to analyze H 2 O and aerosol evolution, quantify the net radiative forcings, understand the impacts on mid-latitude and polar O 3 chemistry, and allow close comparisons with observations.

Zhu, Yunqian [Univ. of Colorado, Boulder, CO (Unit↗

DOE OSTI2026

Enhancing dimensionality prediction in hybrid metal halides via feature engineering and class-imbalance mitigation

We present a machine learning (ML) framework for predicting the structural dimensionality of hybrid metal halides (HMHs), including organic-inorganic perovskites, using a combination of chemically-informed feature engineering and advanced class-imbalance handling techniques. This study is motivated by the small and highly imbalanced nature of experimentally available HMH datasets, which limits the applicability and reliability of conventional ML approaches. The dataset, consisting of 494 HMH structures, is highly imbalanced across dimensionality classes (0D, 1D, 2D, 3D), posing significant challenges to predictive modeling. To mitigate this limitation, the dataset was augmented to 1336 samples using the synthetic minority oversampling technique, enabling improved learning of underrepresented dimensionality classes while preserving chemically meaningful feature relationships. We developed interaction-based descriptors designed to capture coupled steric and polarity effects relevant to dimensionality prediction, which are not readily captured by standard single-parameter or composition-only descriptors. These descriptors are integrated into a multi-stage workflow combining feature selection, ensemble stacking, and performance optimization. Our approach significantly improves F1-scores for underrepresented classes, achieving robust cross-validation performance across all dimensionalities. This work demonstrates a generalizable strategy for extracting reliable and interpretable structure–dimensionality relationships from limited experimental data, enabling pre-synthesis screening of organic cations and providing a practical blueprint for small-data ML in hybrid materials systems.

36 MATERIALS SCIENCE↗

NASA NTRS1987

Rectification of terrain induced distortions in radar imagery

This paper describes a technique to generate geocoded synthetic aperture radar (SAR) imagery corrected for terrain induced geometric distortions. This algorithm transforms the raw slant range image, generated by the signal processor, into a map registered product, resampled to either Universal Transverse Mercator (UTM) or Polar Stereographic projections, and corrected for foreshortening. The technique utilizes the space platform trajectory information in conjunction with a digital elevation map (DEM) of the target area to generate an ortho-radar map with near-autonomous operation. The current procedure requires only two to three tie-points to compensate for the platform position uncertainty that results in translational error between the image and the DEM. This approach is unique in that it does not require generation of a simulated radar image from the DEM or a grid of tie-points to characterize the image-to-map distortions. Rather, it models the inherent distortions based on knowledge of the radar data collection characteristics, the signal Doppler parameters, and the local terrain height to automatically predict the registration transformation. This algorithm has been implemented on a minicomputer system equipped with an array processor and a large random-access memory to optimize the throughput.

Kwok, Ronald↗

NASA NTRS2017

Global Clear-Sky Surface Skin Temperature from Multiple Satellites Using a Single-Channel Algorithm with Angular Anisotropy Corrections

Surface skin temperature (T(sub s)) is an important parameter for characterizing the energy exchange at the ground/water-atmosphere interface. The Satellite ClOud and Radiation Property retrieval System (SatCORPS) employs a single-channel thermal-infrared (TIR) method to retrieve T(sub s) over clear-sky land and ocean surfaces from data taken by geostationary Earth orbit (GEO) and low Earth orbit (LEO) satellite imagers. GEO satellites can provide somewhat continuous estimates of T(sub s) over the diurnal cycle in non-polar regions, while polar T(sub s) retrievals from LEO imagers, such as the Advanced Very High Resolution Radiometer (AVHRR), can complement the GEO measurements. The combined global coverage of remotely sensed T(sub s), along with accompanying cloud and surface radiation parameters, produced in near-realtime and from historical satellite data, should be beneficial for both weather and climate applications. For example, near-realtime hourly T(sub s) observations can be assimilated in high-temporal-resolution numerical weather prediction models and historical observations can be used for validation or assimilation of climate models. Key drawbacks to the utility of TIR-derived T(sub s) data include the limitation to clear-sky conditions, the reliance on a particular set of analyses/reanalyses necessary for atmospheric corrections, and the dependence on viewing and illumination angles. Therefore, T(sub s) validation with established references is essential, as is proper evaluation of T(sub s) sensitivity to atmospheric correction source. This article presents improvements on the NASA Langley GEO satellite and AVHRR TIR-based T(sub s) product that is derived using a single-channel technique. The resulting clear-sky skin temperature values are validated with surface references and independent satellite products. Furthermore, an empirically adjusted theoretical model of satellite land surface temperature (LST) angular anisotropy is tested to improve satellite LST retrievals. Application of the anisotropic correction yields reduced mean bias and improved precision of GOES-13 LST relative to independent Moderate-resolution Imaging Spectroradiometer (MYD11_L2) LST and Atmospheric Radiation Measurement Program ground station measurements. It also significantly reduces inter-satellite differences between LSTs retrieved simultaneously from two different imagers. The implementation of these universal corrections into the SatCORPS product can yield significant improvement in near-global-scale, near-realtime, satellite-based LST measurements. The immediate availability and broad coverage of these skin temperature observations should prove valuable to modelers and climate researchers looking for improved forecasts and better understanding of the global climate model.

Scarino, Benjamin R.↗

NASA NTRSDate not supplied

Characterizing the Seasonal and Diurnal Aerosol Cycles using CATS Space-Based Lidar

The broader effects aerosols have on the earth and climate system is determined by a host of factors including their composition and vertical distribution. Characterizing the vertical distribution of clouds and aerosols is especially important considering it remains one of the greatest uncertainties in climate predictions. Space-based lidar, such as Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and Cloud-Aerosol Transport System (CATS), is especially well suited as a remote sensing tool in determining this vertical distribution. CALIOP has been used for over a decade to observe the global and vertical distribution of clouds and aerosols but is limited by Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations’ (CALIPSO’s) polar orbit to set equatorial crossing times of ~1:30AM/PM. This limited temporal sampling limits the use of CALIOP in determining the full diurnal variability of clouds and aerosols. On the International Space Station (ISS), with its inclined orbit and variable equatorial crossing times, the CATS lidar provided an opportunity to study the vertical profile of clouds and aerosols at a variety of local times. With this 33-month CATS record, we show that CATS captured the seasonal changes in global aerosol distributions and compares favorably with other instruments and models. Specifically targeting biomass burning regions, we also find CATS could observe the documented diurnal cycle in aerosol altitudes with some caveats. With the next generation of proposed space-based lidars including designs in similar orbits as the ISS and CATS, future studies of the aerosol diurnal and seasonal cycles would also be possible.

Kenneth Christian↗

NASA NTRS1973

Effects of the air breathing propulsion system on space shuttle orbiter subsonic stability and control characteristics (OA71A)

Experimental aerodynamic investigations were conducted on an 0.0405 scale representation of the -89B (2A) Space Shuttle Orbiter in a 7.75 x 11.00 ft low speed wind tunnel during the time period from July 27, 1973 to August 3, 1973. The primary test objective was to investigate the aerodynamic effects of engine nacelle grouping and location on the orbiter ferry mission configuration. Five nacelles were tested, both individually mounted as well as mounted in a podded configuration, at the baseline position and moved 45.0 in. aft (full scale). Orbiter control effectiveness, both with and without nacelles, was recorded at elevon deflections of 0 deg, 5 deg, 10 deg, -10 deg and -20 deg and aileron deflections, about 0 deg elevon, of 0 deg, 5 deg, 10 deg, and 15 deg. The model was sting mounted on a 2.5 inch diameter internal strain gage balance entering through the base region. The nominal angle of attack range was -4 deg or = alpha or = 30 deg. Yaw polars were recorded over the beta range of -10 deg or = beta or = at fixed angles of attack of 0 deg and 10 deg.

Mennell, R. C.↗

DOE OSTI2023

Quantum Dot–Organic Molecule Conjugates as Hosts for Photogenerated Spin Qubit Pairs

The inherent spin polarization present in photogenerated spin-correlated radical pairs makes them promising candidates for quantum computing and quantum sensing applications. The spin states of these systems can be probed and manipulated with microwave pulses using electron paramagnetic resonance spectrometers. However, to date, there are no reports on magnetic resonance-based spin measurements of photogenerated spin-correlated radical pairs hosted on quantum dots. In the current work, we prepare dye molecule-inorganic quantum dot conjugates and show that they can produce photogenerated spin-polarized states. The dye molecule, D131, is chosen for its ability to undergo efficient charge separation, and the nanoparticle materials, ZnO quantum dots, are chosen for their promising spin properties. Transient and steady state optical spectroscopy performed on ZnO quantum dot-D131 conjugates shows that reversible photogenerated charge separation is occurring. Transient and pulsed electron paramagnetic resonance experiments are then performed on the photogenerated radical pair, which demonstrate that (1) the radical pair is polarized at moderate temperatures and well modeled by existing theories and (2) the spin states can be accessed and manipulated with microwave pulses. In conclusion, this work opens the door to a new class of promising qubit materials that can be photogenerated in polarized states and hosted by highly tailorable inorganic nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Development of an x-ray radiography platform to study laser-direct-drive energy coupling at the National Ignition Facility

A platform has been developed to study laser-direct-drive energy coupling at the National Ignition Facility (NIF) using a plastic sphere target irradiated in a polar-direct-drive geometry to launch a spherically converging shock wave. To diagnose this system evolution, eight NIF laser beams are directed onto a curved Cu foil to generate Heα line emission at a photon energy of 8.4 keV. These x rays are collected by a 100-ps gated x-ray imager in the opposing port to produce temporally gated radiographs. The platform is capable of acquiring images during and after the laser drive launches the shock wave. A backlighter profile is fit to the radiographs, and the resulting transmission images are Abel inverted to infer radial density profiles of the shock front and to track its temporal evolution. Here, the measurements provide experimental shock trajectories and radial density profiles that are compared to 2D radiation-hydrodynamic simulations using cross-beam energy transfer and nonlocal heat-transport models.

47 OTHER INSTRUMENTATION↗

DOE OSTI2024

Magnetism and metallicity in moiré transition metal dichalcogenides

The ability to control the properties of twisted bilayer transition metal dichalcogenides in situ makes them an ideal platform for investigating the interplay of strong correlations and geometric frustration. Of particular interest are the low energy scales, which make it possible to experimentally access both temperature and magnetic fields that are of the order of the bandwidth or the correlation scale. In this manuscript, we analyze the moiré Hubbard model, believed to describe the low energy physics of an important subclass of the twisted bilayer compounds. We establish its magnetic and the metal–insulator phase diagram for the full range of magnetic fields up to the fully spin-polarized state. We find a rich phase diagram including fully and partially polarized insulating and metallic phases of which we determine the interplay of magnetic order, Zeeman-field, and metallicity, and make connection to recent experiments.

36 MATERIALS SCIENCE↗

DOE OSTI2024

R&D to Ensure a Scientific Basis for Qualification Tests and Standards (Final Report)

Project return on investment in a photovoltaic (PV) system depends increasingly on maintaining high energy yields, and the system lifetime is a major factor in levelized cost of electricity (LCOE). Thus, the rate of PV deployment and the success of these assets depends upon reliable long-term power generation. The overarching objective of this program is to improve photovoltaic (PV) module reliability via development of tests and standards. Where reliability problems or risk are discovered, we can design tests to ensure that these liabilities don't affect future generations of products. Customers can use these tests to understand which products are susceptible to certain degradation mechanisms, and manufacturers can use the tests to design unwanted characteristics out of their products. The work under this program identifies PV reliability needs, performs characterization that provides scientific understanding of targeted degradation mechanisms, and translates those data into practical and predictive test protocols and standards. Major accomplishments include: A model for polarization-type potential induced degradation (PID-p) was developed and validated against experimental data. NREL is currently leading a new edition of IEC 62804-1 for PID detection. PID-p can cause large losses in current and voltage for some module designs on cloudy days. Finite element modeling (FEM) and experiment was used to determine when cells crack in a module. It was shown that cells in landscape orientation are much more likely to crack than those on portrait orientation. Shortly thereafter, the first products with portrait-oriented cells were introduced. Studies of how to test for light and elevated temperature degradation (LeTID) culminated with the publication of IEC TS 63342. Software to predict the progression of LeTID was developed, validated, and made publicly available. Field validated tests and international standards for durability of PV module coatings abrasion, backsheets, and encapsulants were developed. Examples are IEC 62788-1-1, IEC 62788-2 ED2, IEC TS 62788-7-2, IEC 62788-7-3 ED1, IEC 63209-2. NREL led the development a high-temperature testing technical specification, and published guidelines that enable installers to determine whether higher-temperature testing is needed, simply based on location and mounting configuration. In a number of our case studies, variations in the bills of materials or workmanship have been associated with variations in reliability. These observations emphasize the importance of quality assurance to reliability. A framework for criticality (i.e. Pareto) analysis was developed and published. The framework helps us and other researchers determine what problems should be addressed for reliability research to have the biggest industry impact. NREL continues to participate actively in international standards development and stakeholder engagement activities, including organizing an annual PV Reliability Workshop. These activities are important for ensuring we address issues that are relevant and timely, and that we convey our results to those who may benefit.

14 SOLAR ENERGY↗