Results for “Model assignment” — Page 72

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

2017 Puget Sound Regional Travel Study

# 2017 Puget Sound Regional Travel Study The 2017 Puget Sound Regional Travel Study collected household- and person-level activity and travel pattern information from residents throughout the Puget Sound Regional Council's four-county region in Washington State. It followed the [2014-2015 Puget Sound Regional Travel Study](https://www.nrel.gov/transportation/secure-transportation-data/tsdc-puget-sound-travel-study), starting a planned six-year data collection that includes 2019 and 2021. The multiyear program's goal is to maintain an updated source of household travel behavior data that: - Supports modeling and planning needs - Facilitates trend analysis over time - Allows for regular study design updates to integrate evolving data collection methods and emerging travel behaviors and transportation issues. ## Data Collection Agency The Puget Sound Regional Council conducted the study. ## Methodology The 2017 study featured both the design and administration of a one-day household travel diary (approximately 80% of households before data cleaning) and a seven-day smartphone global positioning system (GPS) diary (approximately 20% of households before data cleaning). It combined data collection methods, including smartphone, online, and telephone. The survey design included several stages to recruit and collect data about households, their members, and their travel behaviors during the assigned travel period. ## Survey Records Survey records include a total of 6,254 participants. ## More Information For more information, see the [survey documentation](https://www.nrel.gov/media/docs/libraries/tsdc/zip/tsdc-2017-puget-sound-travel-study-documentation.zip?sfvrsn=45991f2f_1). ## Transportation Data The data set contains a demographic and socioeconomic composition of 6,254 people from 3,285 households in the Puget Sound regional area, as well as detailed information on the travel behavior of each household for a designated 24-hour period. The survey logged over 508 thousand vehicle miles of travel by participants during 52,492 trips. Transportation data are available as zipped files. [Download Winzip](http://www.winzip.com/downwz.htm).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS2000

An Indirect Mixed-Sensitivity Approach to Microgravity Vibration Isolation: The Exploitation of Kinematic Coupling In Frequency-weighting Design-Filter Selections

Many space-science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation systems planned for use with the International Space Station have been appropriately modeled using relative position relative velocity, and acceleration states. In theory, frequency-weighting design filters can be applied to these state-space models, in order to develop optimal H2 or mixed-norm controllers with desired stability and performance characteristics. In practice, however, the kinematic coupling among the various states can lead, through the associated frequency-weighting-filters, to conflicting demands on the Riccati design "machinery." The results can be numerically ill-conditioned regulator and estimator Riccati equations and/or reduced intuition in the design process. In addition, kinematic coupling can result in a redundancy in the demands imposed by the frequency weights. Failure properly to account for this type of coupling can lead to an unnecessary increase in controller dimensionality and, in turn, controller complexity. This paper suggests a rational approach to the assignment of frequency-weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, R. David↗

NASA NTRS2000

An Indirect Mixed-Sensitivity Approach to Microgravity Vibration Isolation: The Exploitation of Kinematic Coupling In Frequency-Weighting Design-Filter Selections

Many space science experiments need an active isolation system to provide them with the requisite microgravity environment. The isolation systems planned for use with the International Space Station have been appropriately modeled using relative position, relative velocity, and acceleration states. In theory, frequency design filters can be applied to these state-space models, in order to develop optimal H, or mixed-norm controllers with desired stability- and performance characteristics. In practice. however, the kinematic coupling among the various states can lead, through the associated frequency-weighting-filters, to conflicting demands on the Riccati design "machinery." The results can be numerically ill-conditioned regulator and estimator Riccati equations and/or reduced intuition in the design process. In addition, kinematic coupling can result in a redundancy in the demands imposed by the frequency weights. Failure properly to account for this type of coupling can lead to an unnecessary increase in controller dimensionality and, in turn, controller complexity. This paper suggests a rational approach to the assignment of frequency weighting design filters, in the presence of the kinematic coupling among states that exists in the microgravity vibration isolation problem.

Hampton, R. David↗

NASA NTRS2007

Lessons Learned from Deploying an Analytical Task Management Database

Defining requirements, missions, technologies, and concepts for space exploration involves multiple levels of organizations, teams of people with complementary skills, and analytical models and simulations. Analytical activities range from filling a To-Be-Determined (TBD) in a requirement to creating animations and simulations of exploration missions. In a program as large as returning to the Moon, there are hundreds of simultaneous analysis activities. A way to manage and integrate efforts of this magnitude is to deploy a centralized database that provides the capability to define tasks, identify resources, describe products, schedule deliveries, and generate a variety of reports. This paper describes a web-accessible task management system and explains the lessons learned during the development and deployment of the database. Through the database, managers and team leaders can define tasks, establish review schedules, assign teams, link tasks to specific requirements, identify products, and link the task data records to external repositories that contain the products. Data filters and spreadsheet export utilities provide a powerful capability to create custom reports. Import utilities provide a means to populate the database from previously filled form files. Within a four month period, a small team analyzed requirements, developed a prototype, conducted multiple system demonstrations, and deployed a working system supporting hundreds of users across the aeros pace community. Open-source technologies and agile software development techniques, applied by a skilled team enabled this impressive achievement. Topics in the paper cover the web application technologies, agile software development, an overview of the system's functions and features, dealing with increasing scope, and deploying new versions of the system.

O'Neil, Daniel A.↗

NASA NTRS2008

Building on 50 Years of Systems Engineering Experience for a New Era of Space Exploration

Over the past 50 years, the National Aeronautics and Space Administration (NASA) has delivered space transportation solutions for America's complex missions, ranging from scientific payloads that expand knowledge, such as the Hubble Space Telescope, to astronauts and lunar rovers destined for voyages to the Moon. Currently, the venerable Space Shuttle, which has been in service since 1981, provides the United States (US) capability for both crew and heavy cargo to low-Earth orbit to construct the International Space Station, before the Shuttle is retired in 2010. In the next decade, NASA will replace this system with a duo of launch vehicles: the Ares I crew launch vehicle and the Ares V cargo launch vehicle. The goals for this new system include increased safety and reliability coupled with lower operations costs that promote sustainable space exploration for decades to come. The Ares I will loft the Orion crew exploration vehicle, while the heavy-lift Ares V will carry the Altair lunar lander, as well as the equipment and supplies needed to construct a lunar outpost for a new generation of human and robotic space pioneers. NASA's Marshall Space Flight Center manages the Shuttle's propulsion elements and is managing the design and development of the Ares rockets, along with a host of other engineering assignments in the field of scientific space exploration. Specifically, the Marshall Center's Engineering Directorate houses the skilled workforce and unique facilities needed to build capable systems upon the foundation laid by the Mercury, Gemini, Apollo, and Shuttle programs. This paper will provide details of the in-house systems engineering and vehicle integration work now being performed for the Ares I and planned for the Ares V. It will give an overview of the Ares I system-level testing activities, such as the ground vibration testing that will be conducted in the Marshall Center's Dynamic Test Stand to verify the integrated vehicle stack's structural integrity and to validate computer modeling and simulation, as well as the main propulsion test article analysis to be conducted in the Static Test Stand. Ultimately, fielding a robust space transportation solution that will carry international explorers and essential payloads will pave the way for a new era of scientific discovery now dawning beyond planet Earth.

Dumbacher, Daniel L.↗

NASA NTRS2015

Magnetogram Forecast: An All-Clear Space Weather Forecasting System

Solar flares and coronal mass ejections (CMEs) are the drivers of severe space weather. Forecasting the probability of their occurrence is critical in improving space weather forecasts. The National Oceanic and Atmospheric Administration (NOAA) currently uses the McIntosh active region category system, in which each active region on the disk is assigned to one of 60 categories, and uses the historical flare rates of that category to make an initial forecast that can then be adjusted by the NOAA forecaster. Flares and CMEs are caused by the sudden release of energy from the coronal magnetic field by magnetic reconnection. It is believed that the rate of flare and CME occurrence in an active region is correlated with the free energy of an active region. While the free energy cannot be measured directly with present observations, proxies of the free energy can instead be used to characterize the relative free energy of an active region. The Magnetogram Forecast (MAG4) (output is available at the Community Coordinated Modeling Center) was conceived and designed to be a databased, all-clear forecasting system to support the operational goals of NASA's Space Radiation Analysis Group. The MAG4 system automatically downloads nearreal- time line-of-sight Helioseismic and Magnetic Imager (HMI) magnetograms on the Solar Dynamics Observatory (SDO) satellite, identifies active regions on the solar disk, measures a free-energy proxy, and then applies forecasting curves to convert the free-energy proxy into predicted event rates for X-class flares, M- and X-class flares, CMEs, fast CMEs, and solar energetic particle events (SPEs). The forecast curves themselves are derived from a sample of 40,000 magnetograms from 1,300 active region samples, observed by the Solar and Heliospheric Observatory Michelson Doppler Imager. Figure 1 is an example of MAG4 visual output

Barghouty, Nasser↗

NASA NTRS2018

Radar Measurements of the LEO Orbital Debris Environment

Access to space and the preservation of the near-Earth space environment is of critical significance. Increased interest in issues surrounding space traffic management and the continued assessment and discussion of orbital debris at the United Nations Committee on the Peaceful Uses of Outer Space (COPUOS) illustrates the significance of the topic of orbital debris. There are currently over 20,000 tracked objects in the publicly available satellite catalog on Space-Track.org. The catalog is maintained by the US Air Force Space Command using a network of optical and radar ground-based sensors and is believed to be complete for a characteristic size of 10 cm or larger in low Earth orbit (LEO). Based on the work of the NASA Orbital Debris Program Office (ODPO) over approximately the past 40 years it is understood that the small debris population (< 10 cm) increases by orders of magnitude as characteristic size decreases. With population estimates ranging from 500,000 to 1,000,000 small debris objects (> 5 mm) in orbit, it is currently not practical to track and maintain precision orbits on every object. Instead the NASA ODPO uses powerful ground-based radars to sample the low Earth Orbit (LEO) environment and assign approximate orbits to each detection. This poses an interesting signal processing challenge as we are trying to detect the smallest objects possible on the edge of the radar's sensitivity. For approximately the last 30 years, NASA ODPO has partnered with the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL) to utilize the Haystack Ultra-wideband Satellite Imaging Radar (HUSIR - formerly the Long-Range Imaging Radar or simply Haystack) and the Haystack Auxiliary (HAX) radar to collect orbital debris radar data. Additionally, the ODPO collaborates with the NASA Jet Propulsion Laboratory (JPL) to use the Goldstone Solar System Radar. The orbital debris detections from these radars serve as inputs for statistical risk models used by the human spaceflight and satellite communities to assess risk to spacecraft posed by orbital debris. In this paper, we will describe the history of orbital debris radar measurements conducted by NASA, provide an overview of current radar measurements techniques and facilities, discuss the signal processing software used for orbital debris measurements and the inference of debris size and orbital parameters from these measurements, and discuss how orbital debris radar measurements are validated for use in models that are used throughout the aerospace industry.

Blackwell, Chris↗

DOE OSTI2023

Differentiable Neural Architecture, Mixed Precision and Accelerator Co-Search

Quantization, effective Neural Network architecture, and efficient accelerator hardware are three important design paradigms to maximize accuracy and efficiency. Mixed Precision Quantization is a process of assigning different precision to different Neural Network layers for optimized inference. Neural Architecture Search (NAS) is a process of automatically designing the neural network for a task and can also be extended to search for the precision of each weight and activation matrix. In this paper, we develop the following three methods: (i) Fast Differentiable Hardware-aware Mixed Precision Quantization Search method to find optimal precision, (ii) Joint Differentiable hardware-aware Architecture and Mixed Precision Quantization Co-search, (iii) Joint Accelerator, Architecture, and Precision triple co-search to find best possibilities in all the three worlds. We demonstrate the effectiveness of our proposed methods targeting Bitfusion accelerator by searching mixed precision models on MobilenetV2. We achieve better accuracy-latency trade-off models than the manually designed and previously proposed search methods.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2024

Ameloblastin binding to biomimetic models of cell membranes – A continuum of intrinsic disorder

A 37-residue amino acid sequence corresponding to the segment encoded by exon-5 of murine ameloblastin (Ambn), AB2 (Y67-Q103), has been implicated with membrane association, ameloblastin self-assembly, and amelogenin-binding. Here, our aim was to characterize, at the residue level, the structural behavior of AB2 bound to chemical mimics of biological membranes using NMR spectroscopy. To better define the structure of AB2 using NMR-based methods, recombinant 13 C- and 15 N-labelled AB2 (*AB2) was prepared and data collected free in solution and with deuterated dodecylphosphocholine (dPC) micelles, deuterated bicelles, and both small and large unilamellar vesicles. Amide chemical shift and intensity perturbations observed in 1 H- 15 N HSQC spectra of *AB2 in the presence of bicelles and dPC micelles suggest that a region of *AB2, S6-E36 (murine Ambn S68 – E98), associates with the membrane biomimetics. A CSI-3 analysis of the NMR chemical shift assignments for *AB2 free in solution and bound to dPC micelles indicated the peptide remains disordered except for the adoption of a short, 12-residue α-helix, F10-G21 (murine Ambn F72-G83). In dPC micelles, the NOE NMR data was void of patterns characteristic of long-lived helical structure indicating this helix was transient in nature. A continuum of intrinsic disorder in the membrane-bound state may be responsible for ameloblastin’s ability to dynamically interact with multiple partners at the same site during amelogenesis.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2024

Phenalenyl growth reactions and implications for prenucleation chemistry of aromatics in flames

The energetics and kinetics of phenalene and phenalenyl growth reactions were studied theoretically. Rate constants of phenalene and phenalenyl H-abstraction and C 2 H 2 addition to the formed radicals were evaluated through quantum-chemical and rate-theory calculations. The obtained values, assigned to all π radicals, were tested in deterministic and kinetic Monte Carlo simulations of aromatics growth under conditions of laminar premixed flames. Kekulé and non-Kekulé structures of the polycyclic aromatic hydrocarbons (PAHs) evolving in the stochastic simulations were identified by on-the-fly constrained optimization. The numerical results demonstrated an increased PAH growth and qualitatively reproduced experimental observations of Homann and co-workers of non-decaying PAH concentrations with nearly equal abundances of even and odd carbon-atom PAHs. The analysis revealed that the PAH growth proceeds via alternating and sterically diverse acetylene and methyl HACA additions. Furthermore, the rapid and diverse spreading in the PAH population supports a nucleation model as PAH dimerization, assisted by the non-equilibrium phenomena, forming planar aromatics first and then transitioning to the PAH–PAH stacking with size.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRSDate not supplied

The Evolution of the Impact Evidence Library Methods – What We Learned

During fiscal years 2020-2022 NASA’s Human Research Program, Exploration Medical Capability Element has worked to source this evidence for the model. During the process several lessons learned have been identified and drive recommendations for future efforts. The ICL 1.0: Spaceflight Medical Operational expertise should be consulted regarding the addition of future conditions. A clinician experienced with the nuances of spaceflight is recommended to have a minimum of 20 hours per condition to adequately source the evidence. Condition definitions should be carefully crafted to maintain mutual exclusivity. Common side effects from medications, common and consequential incidental findings in laboratory studies, and consequential side effects of diagnostic and procedural capabilities should be considered for inclusion as unique conditions in future iterations of the ICL 1.0. Incidence: Spaceflight incidence, although based on small population sizes, is the gold standard. Terrestrial incidence should be applied cautiously. Probability of minor vs. severe cases of the condition: Data informing severity probability of the medical condition are nearly always terrestrial. Special attention should be paid to this metric as it drives outcomes in the model and terrestrial data often overestimate severity of expected cases in spaceflight. Condition duration: Three clinical phases currently exist in the model. They represent the time necessary for diagnosis, treatment/convalescence/recurrence, and the remaining duration of the mission after maximal recovery, respectively. Further subdivision of acute and convalescent treatment/recurrence is recommended. Probability of need for evacuation: Surrogates for “Return to Definitive Care” were chosen prior to data collection. In most cases these surrogates were “need for hospitalization” or “need for surgery.” For many conditions these may not be realistic drivers of “Return to Definitive Care” and should be re-examined. Probability of Crew Mortality: Terrestrial mortality data is difficult to apply to astronauts who, invariably, have less comorbidities than terrestrial subjects. It must be applied judiciously. The proportion of mission tasks impaired by the condition: “Task Impairment” was assigned to each condition prior to the condition duration data becoming available. Future efforts should assign Task Impairment as the final step in sourcing the evidence.

A.J. Kreykes↗

DOE OSTI2023

FY23 Status Report on MOOSE-Based Approaches to Modeling Core Bowing in Fast Reactors

Under the U.S. Department of Energy Office of Nuclear Energy’s Advanced Modeling and Simulation (NEAMS) Program, an integrated multiphysics approach is being developed to model the core bowing phenomena important to liquid metal-cooled fast reactors. Core bowing is an important passive safety mechanism whereby increased power (which leads to temperature and flux gradients) influences the core to bow into less reactive configurations when the restraint system is properly designed. The phenomenon includes a complex interplay of radiation transport, duct temperature calculations involving fluid flow and heat transfer, and thermo-mechanical responses to the induced temperature and flux gradients. Structural material properties are also important to determining inelastic response to longer term flux gradients which cause irradiation creep and swelling. While core bowing provides a strong negative reactivity feedback when the restraint system is designed properly, it also results in additional forces between assemblies which increase the loads required to extricate them during refueling or control rod movement. Therefore, the restraint system must be designed with these tradeoffs in mind. The first stage of the work, which commenced in FY21 and continues through FY23, assesses thermo-mechanical modeling tools for producing core bowing predictions consistent with conventional tools. The Multiphysics Object Oriented Simulation Environment (MOOSE) Tensor Mechanics and Contact Modules are employed. This status report describes work on additional thermo-mechanical benchmark verification problems with increased complexity from the examples demonstrated in FY21 and FY22. Several benchmark verification examples were selected from the IAEA verification and validation report with increased number of ducts and more complex contact interaction behavior. These examples involve a full symmetric sector with restraint rings at multiple load pad locations to simulate a limited free-bow restraint system concept, as well as irradiation induced swelling and creep effects in a sector. In addition, improvements to the contact module sideset assignment were assessed and compared with previous MOOSE results to verify the contact behavior. The MOOSE-based results were compared to IAEA benchmark participants’ results. In every case, the MOOSE results agreed with other simulations results for estimating bowing behavior, providing additional verification basis of the tools for this particular physics application. Estimation of contact forces were mostly in agreement, with a few outlier results. A plan was suggested for dealing with the discrepancies with estimating contact force values. In addition, a 1-way coupling demonstration was performed using subchannel analysis code Pronghorn-SC and MOOSE on an ABR-1000-design sodium-cooled fast reactor assembly to evaluate coolant and duct wall temperatures.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗