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At least 1,297 records · Page 72

Fluorine as a constituent in lunar magmatic gases

Fluorine surface deposits on Apollo 15 green glass, Apollo 17 orange glass, and on vesicle linings from Apollo 15 basalts were studied by a resonant nuclear reaction technique. Surface layers of about 10 to the 15th F atoms/sq cm were observed on unbroken spheroidal glass surfaces, whereas thinner (about 10 to the 14th atoms/sq cm) deposits were found on the vesicle linings.

Goldberg, R. H.↗

The relative diffusion of strong magnetic fields and tenuous gases

General equations are given for treating the diffusion of a magnetic field in a fluid with electrical conductivity and a resistive diffusion coefficient. Consequences of nonnegligible gas motion are investigated by considering the one-dimensional problem where a tenuous isothermal gas with pressure expressed as a function of x-coordinate and time is enmeshed in a magnetic field in the y-direction. Approximate equations are obtained for the case of weak fluctuations in gas or field pressure, and the properties of a nonlinear diffusion equation are illustrated with the example of an initial thin slab of gas confined by a uniform field on either side. The advance of a gas front into a nonvanishing gas density is illustrated by using the progressive wave solution. Application of the results to the evolution of streamers and filaments observed in the solar corona is briefly discussed

Parker, E. N.↗

A few ways of calculating the similarity parameter kappa* for real gases

In connection with the question on the applicability of test results obtained from cryogenic wind tunnels to the large-scale model the similarity parameter is referred to. A simple method is given for calculating the similarity parameter. From the numerical values obtained it can be deduced that nitrogen behaves practically like an ideal gas when it is close to the saturation point and in a pressure range up to 4 bar. The influence of this parameter on the pressure distribution of a supercritical profile confirms this finding.

Lorenz-Meyer, W.↗

Toxicity of pyrolysis gases from synthetic polymers

The screening test method was used to investigate toxicity in polyethylene, polystyrene, polymethyl methacrylate, polyaryl sulfone, polyether sulfone, polyphenyl sulfone, and polyphenylene sulfide. Changing from a rising temperature program to a fixed temperature program resulted on shorter times to animal responses. This effect was attributed in part to more rapid generation of toxicants. The toxicants from the sulfur containing polymers appeared to act more rapidly than the toxicants from the other polymers. It was not known whether this effect was due primarily to difference in concentration or in the nature of the toxicants. The carbon monoxide concentration found did not account for the results observed with the sulfur containing polymers. Polyphenyl sulfone appeared to exhibit the least toxicity among the sulfur containing polymers evaluated under these test conditions.

Hilado, C. J.↗

Monte Carlo solution of Boltzmann equation for a simple model of highly nonequilibrium diatomic gases: Translational rotational energy relaxation

The semiclassical transition probability was incorporated in the simulation for energy exchange between rotational and translational energy. The results provide details on the fundamental mechanisms of gas kinetics where analytical methods were impractical. The validity of the local Maxwellian assumption and relaxation time, rotational-translational energy transition, and a velocity analysis of the inelastic collision were discussed in detail.

Yoshikawa, K. K.↗

Temporal and latitudinal variations of stratospheric trace gases - A critical comparison between theory and experiment

Global calculations of stratospheric HOx, Clx, and NOx are presented which include the effects of planetary albedo and diurnal and seasonal variations of the insolation. Comparisons are made with a wide range of atmospheric measurements at different latitudes and altitudes. Agreement between theory and observations is generally within a factor of 2. The theory appears to explain adequately the major features of latitude and seasonal distributions of NO2 and HNO3. The results indicate that mesospheric OH makes an appreciable contribution to the total OH column abundance and strongly suggest that nitrogen oxides exist principally in the form of HNO3 at high latitudes in winter. There are difficulties in reconciling OH, ClO, and O3 observations in the upper stratosphere.

Wofsy, S. C.↗

Mars - Regolith adsorption and the relative concentrations of atmospheric rare gases

Laboratory measurements of Kr and Xe adsorption on samples of ground montmorillonite, limonite and basalt at -77 C have been performed. Results suggest that (1) most degassed martian Xe could be adsorbed on a regolith with a large effective surface area, and (2) if this is the case the elemental composition of martian nonradiogenic rare gas (counting that in the regolith) may be virtually identical to that of ordinary chondrites.

Fanale, F. P.↗

Noble gases in the Murchison meteorite - Possible relics of s-process nucleosynthesis

The Murchison carbonaceous chondrite contains a new type of xenon component, enriched by up to 50 percent in five of the nine stable xenon isotopes, mass numbers 128 to 132. This component is released at 1200 to 1600 C from a severely etched mineral fraction. Krypton shows a similar but smaller enrichment in the isotopes 80 and 82. Neon and helium released in the same interval also are quite anomalous, being highly enriched in the isotopes 22 and 3. These patterns are strongly suggestive of three nuclear processes believed to take place in red giants: the s process (neutron capture on a slow time scale), helium burning, and hydrogen shell burning. If this interpretation is correct, then primitive meteorites contain yet another kind of alien, presolar material: dust grains ejected from red giants.

Srinivasan, B.↗

Rare gases and Ca, Sr, and Ba in Apollo 17 drill-core fines

Trapped gas isotopic compositions and spallation gas concentrations as functions of depth in the Apollo 17 drill core were determined from mass spectrometer studies by means of correlation techniques. The distribution of He, Ne, Ar, Kr, and Xe as well as Ca, Sr, and Ba was investigated, and rare-gas spallation and neutron capture profiles are compared with attention to proposed depositional models for the Taurus-Littrow regolith. The data exclude a sedimentation pattern similar to that found at the Apollo 15 site but are possibly compatible with long-term continuous accretion models or models of very recent rapid accumulation of regolith.

Pepin, R. O.↗

Inert gases in fines at three levels of the trench at Van Serg Crater

Inert-gas measurements were conducted with three soil samples collected from a trench of about 17 cm depth which had been dug at Station 9, approximately 60-m southeast of the rim of Van Serg Crater on the moon. The particular trench is interesting because it is located in the continuous ejecta blanket of a relatively young crater. The results of the inert-gas measurements are presented in a table. They confirm an earlier conclusion reported by Heymann et al. (1974) that fines from Station 9 are among the most gas rich in the whole landing site. The three fines are agglutinate rich and most of the trapped gas is contained in the constructional particles. Agglutinate contents of fines tend to decrease rapidly for particles greater than about 250 micrometers.

Jordan, J. L.↗

Interaction of gases with lunar materials - Revised results for Apollo 11

The surface properties of an Apollo 11 soil sample have been reinvestigated. The present study shows that the preliminary results for this sample (Fuller et al., 1971) are in error, principally because of incorrectly applied instrumental background effects. The surface properties of these Apollo 11 fines are very similar to those of fines from the other Apollo landing sites that we have examined. On the basis of results reported to date, the surface properties (specific surface area, porosity, and reactivity with water) of lunar soil samples are, to a first approximation, independent of bulk chemical composition and location on the lunar surface. Drastic alteration of the surface characteristics of lunar fines by adsorbed water continues to be the distinguishing feature of their surface chemistry.

Holmes, H. F.↗

Monitoring harmful gases

Instruments are developed for monitoring presence of hydrazine and nitrogen dioxide in air. Nitrogen dioxide and hydrazine are highly toxic and explosive substances used in propellants for rocket engines. Instruments discussed are inexpensive and most useful for detecting above substances in concentrations as low as few parts per million.

Helms, W. R.↗

Measuring the permittivity of gases and aerosols

Two-coupler microwave technique measures complex permittivity utilizing waveguide which encloses gas or aerosol. Using technique, blower continuously circulates substances to keep them homogeneous.

Trett, W. J.↗