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At least 1,297 records · Page 72

Experimental investigation of a reverse osmosis desalination system directly powered by wave energy

Powering desalination processes with renewable energy is a promising solution to address the global issue of water shortage with minimum carbon footprint and environmental impact. Here, we experimentally investigate a sustainable reverse osmosis (RO) desalination system directly powered by wave energy. In this system, seawater is pressurized and pumped to a RO desalination module via a piston pump directly driven by an oscillating surge wave energy converter (OSWEC). An accumulator is adopted on the feed inlet to mitigate the pressure fluctuations under time-varying ocean conditions. Meanwhile, a needle valve on the brine outlet is used to adjust the system pressure and water recovery. A 1:10 scaled model was designed, fabricated, and tested in a wave tank based on the Froude scaling law. Further, the optimal specific water productivity (SWP) obtained in the tank tests with 3.5 g/L feed salinity was 2.23m 3 /kWh, indicating a full-scale specific water productivity of 0.22m 3 /kWh for 35g/L seawater salinity. The influence of needle valve tuning on the specific water productivity was experimentally investigated and analyzed. Under a specific operational condition, tuning this valve improved specific water productivity by about 17% and reduced the system pressure by 24%, thereby avoiding extreme pressure and improving the system’s capability. This pilot study demonstrates that ocean wave energy is a promising source to sustainably power reverse osmosis desalination and provide freshwater water for coastal regions.

16 TIDAL AND WAVE POWER↗

Effects of transient thermal shock on the microstructures and corrosion properties of a reduced activation high-entropy alloy

The devices would subject transient thermal shocks (TTS) during operation under extremely harsh conditions of nuclear fusion reactors, which inevitably exert significant impact on the microstructure and performance of structural materials. Here, a reduced activation VCrFeTa 0.2 W 0.2 high-entropy alloy (HEA) was developed by vacuum arc melting. The effects of electron beam induced TTS on its microstructure, microhardness, and corrosion properties were investigated. The results indicate that the weight fraction of each phase changes after TTS, showing a significant decrease in the content of BCC1 phase and an increase in the content of BCC2 and Laves phases. The content of BCC1 phase continues to decrease slightly with increasing the power of TTS. Besides, the microhardness of the alloy increases from ~673 HV to ~714 HV after TTS treatments. In the reduced activation HEA, TTS results in a relatively low corrosion current density of ~0.472 μA/cm 2 in 3.5 wt% NaCl solution, around one-third of the current density observed in the as-cast sample. Furthermore, the VCrFeTa 0.2 W 0.2 HEA after TTS exhibits a pitting potential of ~1.165 V SCE , which is much higher than that of the as-cast sample. The refined composite multiscale entropy method is employed to analyze the influence of TTS on current fluctuation behavior during the corrosion process. The reduced activation VCrFeTa 0.2 W 0.2 HEA exhibits excellent properties in harsh environments after TTS, thereby showing advantageous property in the field of nuclear structural materials. Furthermore, TTS is an efficient and controllable strategy for the improvement of the HEAs’ microstructures and performances.

36 MATERIALS SCIENCE↗

Exploring the Role of the Central Carbide of the Nitrogenase Active-Site FeMo-cofactor through Targeted 13 C Labeling and ENDOR Spectroscopy

Mo-dependent nitrogenase is a major contributor to global biological N 2 reduction, which sustains life on Earth. Its multi-metallic active-site FeMo-cofactor (Fe 7 MoS 9 C-homocitrate) contains a carbide (C 4– ) centered within a trigonal prismatic CFe 6 core resembling the structural motif of the iron carbide, cementite. The role of the carbide in FeMo-cofactor binding and activation of substrates and inhibitors is unknown. Here, to explore this role, the carbide has been in effect selectively enriched with 13 C, which enables its detailed examination by ENDOR/ESEEM spectroscopies. 13 C-carbide ENDOR of the S = 3/2 resting state (E 0 ) is remarkable, with an extremely small isotropic hyperfine coupling constant, C a = +0.86 MHz. Turnover under high CO partial pressure generates the S = 1/2 hi-CO state, with two CO molecules bound to FeMo-cofactor. This conversion surprisingly leaves the small magnitude of the 13 C carbide isotropic hyperfine-coupling constant essentially unchanged, C a = –1.30 MHz. This indicates that both the E 0 and hi-CO states exhibit an exchange-coupling scheme with nearly cancelling contributions to C a from three spin-up and three spin-down carbide-bound Fe ions. In contrast, the anisotropichyperfine coupling constant undergoes a symmetry change upon conversion of E 0 to hi-CO that may be associated with bonding and coordination changes at Fe ions. In combination with the negligible difference between CFe 6 core structures of E 0 and hi-CO, these results suggest that in CO-inhibited hi-CO the dominant role of the FeMo-cofactor carbide is to maintain the core structure, rather than to facilitate inhibitor binding through changes in Fe-carbide covalency or tretching/breaking of carbide–Fe bonds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

How Do Climate Model Resolution and Atmospheric Moisture Affect the Simulation of Unprecedented Extreme Events Like the 2021 Western North American Heat Wave?

Abstract Although the 2021 Western North America (WNA) heat wave was predicted by weather forecast models, questions remain about whether such strong events can be simulated by global climate models (GCMs) at different model resolutions. Here, we analyze sets of GCM simulations including historical and future periods to check for the occurrence of similar events. High‐ and low‐resolution simulations both encounter challenges in reproducing events as extreme as the observed one, particularly under the present climate. Relatively stronger amplitudes are observed during the future periods. Furthermore, high‐ and low‐resolution short initialized GCM simulations are both able to reasonably predict such strong events and their associated high‐pressure ridge over the WNA with a 1 week forecast lead time. Moisture sensitivity experiments further indicate a drier atmospheric moisture condition results in substantially higher near‐surface temperatures in the simulated heat events.

54 ENVIRONMENTAL SCIENCES↗

Failure Analysis–Informed Risk Assessment Framework for Geological Carbon Storage Using Numerical Simulation and Machine Learning

Geological carbon storage (GCS) is recognized as a critical technology for achieving large-scale reductions in anthropogenic carbon dioxide (CO 2 ) emissions. Ensuring long-term containment and safety requires robust risk assessment frameworks that account for geological uncertainty and identify potential failure scenarios. Among various indicators, the area of review (AoR) serves as a key metric for evaluating storage performance, regulatory compliance, and monitoring design, as it delineates the spatial extent impacted by pressure buildup and plume migration. However, conventional AoR-based risk assessments typically perturb parameters within narrow uncertainty bounds, potentially overlooking rare but high-impact events arising from extreme geological conditions. In this study, we present a failure analysis–informed risk assessment framework for large-scale GCS projects to improve site prescreening and monitoring design. A suite of 300 numerical simulations was generated using stochastic geological models that vary five key parameters: net-to-gross ratio, anisotropy azimuth, porosity multiplier, permeability multiplier, and vertical-to-horizontal permeability ratio. Among these, 200 realizations represent normal geological uncertainty, while 100 additional cases explore extreme yet plausible conditions for failure-case analysis. The AoR was simulated and computed from pressure and CO 2 saturation fields, where the baseline AoR boundary, representing the extent predicted under typical geological uncertainty, was defined as the union of 200 normal-range simulations, and failure was identified when extreme-range cases exceeded this baseline. Results show that incorporating broader parameter uncertainty produces significantly larger AoR extents, underscoring the potential underestimation of risk under conventional uncertainty ranges. Furthermore, spatial probability maps derived from failure-induced AoR exceedance identify regions requiring enhanced monitoring attention. Various machine learning (ML)–based classifiers were developed to predict failure occurrence from geological parameters, with the random forest model achieving the highest performance (F1-score of 0.986). Consistent findings from correlation coefficient, feature importance, and Sobol sensitivity analyses reveal that low net-to-gross ratios and permeability multipliers are the dominant risk drivers, reflecting reduced reservoir connectivity and limited pressure dissipation. Altogether, these results provide a novel framework for risk-informed site prescreening and monitoring design that explicitly considers rare but high-impact geological scenarios in GCS projects.

25 ENERGY STORAGE↗

Study of mesoscale phenomena, winter monsoon clouds and snow area based on LANDSAT data

The author has identified the following significant results. Most longitudinal clouds which appear as continuous linear clouds are composed of small transversal clouds. There are mountain waves of different wavelength in a comparatively narrow area indicating complicated orographical effects on wind and temperature distribution or on both dynamical and static stability condition. There is a particular shape of cirrus cloud suggestive of turbulence in the vicinity of CAT in the upper troposphere near jet stream level and its cold air side. Thin cirrus of overcast condition can be distinguished by MSS; however, extremely thin cirrus of partly cloudy condition cannot be detected even in LANDSAT data. This presents a serious problem in the interpretation of satellite thermal infrared radiation data since they affect the value.

Tsuchiya, K.↗

Filter development for the extreme ultraviolet explorer

Thin film filters with extreme ultraviolet bandpasses unattainable with previously available filter materials were developed. Titanium and antimomy were identified as the most promising materials for providing the scientifically important 350-500 A bandpass heretofore unattainable with thin film filters. Titanium foils and titanium-antimony sandwich foils of the required uniformity and durability were fabricated. Transmission measurements and optimization studies indicate that the titanium-antimony combination provides an ideal bandpass for scientifically valuable, high-sensitivity observations with EUVE. Environmental testing of the mechanical strength, moisture sensitivity and aging characteristics of the newly developed filter materials demonstrate flightworthy performance.

Kimble, R.↗

SAMSI: An orbiting spatial interferometer for micro-arc second astronomical observations

The concept and performance of (SAMSI) Spacecraft Array for Michelson Spatial Interferometry, an orbiting spatial interferometer comprised of three free-flying spacecraft, two collector telescopes and a central mixing station are described. In the one-dimensional interferometry mode orbits exist which provide natural scanning of the baseline. These orbits place extremely small demands on thrusters and fuel consumption. Resolution of 0.00001 arcsecond and magnitude limits of mv = 15 to 20 are achievable in a single orbit. In the imaging mode, SAMSI could synthesize images equivalent to those produced by equal diameter filled apertures in space, making use of the fuel resupply capability of a space station. Simulations indicate that image reconstruction can be performed with milliarcsecond resolution to a visual magnitude 12 in 12 hr of spiral scanning integration time.

Stachnik, R. V.↗

A unified process for systems identification based on performance assessment

Many modern spacecraft are complex multi-body dynamic systems where the bodies are connected by several active control systems for pointing and isolation. Mission requirements indicate that many structural modes and possibly some nonlinear effects will require characterization. Thus, even characterization at the subsystem level will become more difficult than usual. System level characterization difficulties will be compounded by the fact that only limited ground testing will be possible on the full up system, and flight testing will be restricted by an extremely limited measurements set. The object of the present discussion is the application of matrix majorant theory to the problem of assessing dynamic system performance when knowledge of the system is uncertain. We show how majorants provide an effective tool to relate required performance output to system identification test quality in terms of residual uncertainty in input-output relations, parameter values, nonlinearities, and interactions. The underlying machinery consists of the block-norm matrix which is a nonnegative matrix each of whose elements is the norm of a block of a suitably partitioned matrix. A matrix which bounds the block-norm matrix in the sense of nonnegative matrices, i.e., element by element is known as a majorant.

Hyland, C.↗

North African savanna fires and atmospheric carbon dioxide

The effect of north African savanna fires on atmospheric CO2 is investigated using a tracer transport model. The model uses winds from operational numerical weather prediction analyses and provides CO2 concentrations as a function of space and time. After a spin-up period of several years, biomass-burning sources are added, and model experiments are run for an additional year, utilizing various estimates of CO2 sources. The various model experiments show that biomass burning in the north African savannas significantly affects CO2 concentrations in South America. The effect is more pronounced during the period from January through March, when biomass burning in South America is almost nonexistent. During this period, atmospheric CO2 concentrations in parts of South America typically may increase by 0.5 to 0.75 ppm at 970 mbar, the average pressure of the lowest model layer. These figures are above the probable uncertainty level, as model runs with biomass-burning sources estimated from independent studies using distinct data sets and techniques indicate. From May through September, when severe biomass burning occurs in South America, the effect of north African savanna fires over South America has become generally small at 970 mbar, but north of the equator it may be of the same magnitude or larger than the effect of South American fires. The CO2 concentration increase in the extreme northern and southern portions of South America, however, is mostly due to southern African fires, whose effect may be 2-3 times larger than the effect of South American fires at 970 mbar. Even in the central part of the continent, where local biomass-burning emissions are maximum, southern African fires contribute to at least 15% of the CO2 concentration increase at 970 mbar. At higher levels in the atmosphere, less CO2 emitted by north African savanna fires reaches South America, and at 100 mbar no significant amount of CO2 is transported across the Atlantic Ocean. The vertical structure of the CO2 concentration increase due to biomass burning differs substantially, depending on whether sources are local or remote. A prominent maximum of CO2 concentration increase in the lower layers characterizes the effect of local sources, whereas a more homogeneous profile of CO2 concentration increase characterizes the effect of remote sources. The results demonstrate the strong remote effects of African biomoass burning which, owing to the general circulation of the atmosphere, are felt as far away as South America.

Iacobellis, Sam F.↗

Biomolecular Effects of Cold Plasma Exposure

The effects of cold plasma exposure on Deinococcus radiodurans, plasmid DNA and model proteins were assessed using microbiological, spectrometric and biochemical techniques. Exposure of D. radiodurans, an extremely radiation resistant microbe, to O2 plasma (less than or equal to 25 W, approx. 45 mTorr, 90 min) yielded a approx. 99.999 % sterilization and the sterilization rate was increased approx. 10-fold at 100 W and 500 mTorr. AFM images shows that the exposed cells are significantly deformed and possess 50-70 nm concavities. IR analysis indicates the chemical degradation of lipids, proteins and carotenoids of the cell wall and membrane. Intracellular damage was indicated by major absorbance loss at 1245, 1651 and 1538/cm corresponding to degradation of DNA and proteins, respectively. Biochemical experiments demonstrate that plasmas induce strand scissions and crosslinking of plasmid DNA, and reduction of enzyme activity; the degradation is power dependent with total sample loss occurring in 60 s at 200 W and 500 mTorr. Emission spectroscopy shows that D. radiodurans is volatilized into CO2, CO, N2 and H2O confirming the removal of biological matter from contaminated surfaces. The O2 plasma impacts several cellular components predominantly through chemical degradation by atomic oxygen. A CO2, plasma, however, was not effective at degrading D. radiodurans, revealing the importance of plasma composition, which has implications for planetary protection and the contamination of Mars.

Mogul, Rakesh↗

Sizing Up the Situation

Hailstorm damage to the Space Shuttle's External Tank inspired a NASA innovation with extensive photography applications. In order to measure the defects caused by the storm, Kennedy Space Center used telephoto lenses to zoom in on the tank and view the damage clearly. However, since there was no reference object in the image, the engineers could not determine the scale of the damage. In photographic situations similar to this, an object, such as a ruler, is placed within the field of view. This allows a person to look at a photograph and have a visual indication of the scale of the objects in it. In the External Tank situation, however, this procedure was not possible. As a solution, Kennedy developed the Scaling and Measurement Device for Photographic Images, which provides a non-intrusive means of adding a scale to a photograph. In addition to meeting Kennedy's needs, scaling images is extremely important in crime and accident scene investigations, oil and chemical tank monitoring, and aerial photography. The innovation consists of a tool that attaches directly to a camera or charge coupled device using a standard screw. Two lasers fitted to the device provide parallel beams that are set 1 inch apart. These lasers enable the device to project a pattern into the field of view. When a photograph is taken, the image of the laser pattern appears, along with the image of the object under investigation, allowing the viewer quantifiable information as to the size of the object. The laser beams are accurate to approximately 200 feet. Windows-based software was developed to work with the scaling device tool. The software provides further techniques to measure objects in photographs and digital images. By using the software, any object in the image can be measured diagonally, vertically, and horizontally. The device and its software enable the user to determine two-dimensional measurements within a photograph.

Source record↗

Satellite Orbital Drag During Magnetic Storms

We investigate satellite orbital drag effects at lowEarth orbit associated with thermosphere heating during magnetic storms caused by coronal mass ejections. CHAllenge Minisatellite Payload (CHAMP) and Gravity Recovery And Climate Experiment (GRACE) neutral density data are used to compute orbital drag. Stormtoquiet density comparisons are performed with background densities obtained by the JacchiaBowman 2008 (JB2008) empirical model. Our storms are grouped in different categories regarding their intensities as indicated by minimum values of the SYMH index. We then perform superposed epoch analyses with storm main phase onset as zero epoch time. In general, we find that orbital drag effects are larger for CHAMP (lower altitudes) in comparison to GRACE (higher altitudes). Results show that storm time drag effects manifest first at high latitudes, but for extreme storms, particularly observed by GRACE, stronger orbital drag effects occur during early main phase at low/equatorial latitudes, probably due to heating propagation from high latitudes. We find that storm time orbital decay along the satellites' path generally increases with storm intensity, being stronger and faster for the most extreme events. For these events, orbital drag effects decrease faster probably due to elevated cooling effects caused by nitric oxide, which introduce modeled density uncertainties during storm recovery phase. Errors associated with total orbit decay introduced by JB2008 are generally the largest for the strongest storms and increase during storm times, particular during recovery phases. We discuss the implication of these uncertainties for the prediction of collision between space objects at lowEarth orbit during magnetic storms.

Oliveira, D. M.↗

Radar Observations of Asteroid 1620 Geographos

Goldstone radar observations of Geographos from Aug. 28 through Sep. 2, 1994, yield over 400 delay-Doppler images whose linear spatial resolutions range from ~75 m to ~151 m, and 138 pairs of dual-polarization (OC, SC) spectra with one-dimensional resolution of 103 m. Each data type provides thorough rotational coverage. The images contain an intrinsic north/south ambiguity, but the equatorial view allows accurate determination of the shape of the radar-facing part of the asteroid's pole-on silhouette at any rotation phase. Sums of co-registered images that cover nearly a full rotation have defined the extremely elongated shape of that silhouette (Ostro et al. 1995, Nature 375, 474-477). Here we present individual images and co-registered sums over ~30û of rotation phase that show the silhouette's structural characteristics in finer detail and also reveal numerous contrast features "inside" the silhouette. Those features include several candidate craters as well as indications of other sorts of large-scale topographic relief, including a prominent central indentation. Protuberances at the asteroid's ends may be related to the pattern of ejecta removal and deposition caused by the asteroid's gravity field. The asteroid's surface is homogeneous and displays only modest roughness at centimeter-to-meter scales. Our estimates of radar cross section and the currently available constraints on the asteroid's dimensions are consistent with a near-surface bulk density between 2 and 3 g cm-3. The delay-Doppler trajectory of Geographos' center of mass has been determined to about 200 m on Aug. 28 and to about 100 m on Aug. 31, an improvement of two orders of magnitude over pre-observation ephemerides.

Asteroid↗

X-ray Quasi-Periodic Eruptions from Two Previously Quiescent Galaxies

Quasi-Periodic Eruptions (QPEs) are extreme high-amplitude bursts of X-ray radiation recurring every few hours and originating near the central supermassive black holes in galactic nuclei. It is currently unknown what triggers these events, how long they last and how they are connected to the physical properties of the inner accretion flows. Previously, only two such sources were known, found either serendipitously or in archival data, with emission lines in their optical spectra classifying their nuclei as hosting an actively accreting supermassive black hole. Here we present the detection of QPEs in two further galaxies, obtained with a blind and systematic search over half of the X-ray sky. The optical spectra of these galaxies show no signature of black hole activity, indicating that a pre-existing accretion flow typical of active nuclei is not required to trigger these events. Indeed, the periods, amplitudes and profiles of the newly discovered QPEs are inconsistent with current models that invoke radiation-pressure driven accretion disk instabilities. Instead, QPEs might be driven by an orbiting compact object. Furthermore, their observed properties require the mass of the secondary object to be much smaller than the main body and future X-ray observations may constrain possible changes in the period due to orbital evolution. This scenario could make QPEs a viable candidate for the electromagnetic counterparts of the so-called extreme mass ratio inspirals, with considerable implications for multi-messenger astrophysics and cosmology.

R Arcodia↗

One Planet or Two Planets? The Ultra-sensitive Extreme-magnification Microlensing Event KMT-2019-BLG-1953

We present the analysis of a very high-magnification (A ∼ 900) microlensing event KMT-2019-BLG-1953. A single-lens single-source (1L1S) model appears to approximately delineate the observed light curve, but the residuals from the model exhibit small but obvious deviations in the peak region. A binary-lens (2L1S) model with a mass ratio of q ∼ 2 × 10{sup −3} improves the fits by Δχ {sup 2} = 181.8, indicating that the lens possesses a planetary companion. From additional modeling by introducing an extra planetary lens component (3L1S model) and an extra source companion (2L2S model), it is found that the residuals from the 2L1S model further diminish, but claiming these interpretations is difficult due to the weak signals with Δχ {sup 2} = 16.0 and 13.5 for the 3L1S and 2L2L models, respectively. From a Bayesian analysis, we estimate that the host of the planets has a mass of M{sub host}=0.31{sub −0.17}{sup +0.37} M{sub ⊙} and that the planetary system is located at a distance of D{sub L}=7.04{sub −1.33}{sup +1.10} kpc toward the Galactic center. The mass of the securely detected planet is M{sub p}=0.64{sub −0.35}{sup +0.76} M{sub J}. The signal of the potential second planet could have been confirmed if the peak of the light curve had been more densely observed by follow-up observations, and thus the event illustrates the need for intensive follow-up observations for very high-magnification events even in the current generation of high-cadence surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

The Energy Transition: Advanced Nuclear Needed but Address Climate Vulnerabilities Now

The term “Energy Transition” is an attempt to capture an elaborate set of activities related to the modernization and decarbonization of energy grids. Performed concurrently and often in an ad hoc manner across local, state, regional and national boundaries, it is bringing chaos to what should arguably be one of the most conservatively managed of all critical infrastructure sectors. What’s more, with climate change producing an increasing tempo of extreme events, confidence in the intended resilient and redundant structure of the electric grids is likely to ebb. Even without these climate induced stressors, the nation’s electric grid was built for an earlier century. In addition to a drive towards greater efficiency via digitization and a continuing price decline in distributed energy resources (DERs), one could argue that climate change concerns are the primary driver of the energy transition. Non-CO2 emitting generation sources like wind and solar have become an important part of the overall generation fleet, albeit ones that cannot be counted upon to provide dispatchable power. Current projections indicate deployment of even larger percentages of DERs in coming years. Until far better storage capabilities arrive, the variability of wind and solar, inconsistent performance of traditional thermal generation plants, and energy delivery failures associated with natural gas pipelines will reinforce mounting reliability concerns. This pertains to both electric transmission and distribution. The recent shuttering of nuclear power plants in Germany, Japan, the US and elsewhere are also putting more downward pressure on dispatchable generation. Russia’s attack on Ukraine has roiled energy markets worldwide and forced some countries to return to coal as a primary fuel. In view circumstances such as these, it is essential that significant changes be made to policies and planning criteria, and to the standards and code on which they are based. Given the accelerating pace of extreme weather events, this needs to occur as soon as possible.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A microstructural signature of the coesite-quartz transformation: New insights from high-pressure experiments and EBSD

Ultra-high pressure (UHP) metamorphism is difficult to identify in continental crust as few petrological barometers are suitable for dominantly felsic lithologies. In such cases, burial to extreme depths is commonly identified through the preservation of coesite, a high-pressure polymorph of SiO 2 that typically forms at depths exceeding ∼ 100 km (i.e., > 2 GPa pressure). Unfortunately, coesite readily transforms to quartz upon exhumation, meaning that UHP terranes may often be overlooked. While some studies have suggested that quartz may inherit an orientation signature indicative of former coesite, both the specific nature of this signature and the conditions favouring its development remain uncertain. Here, to address this problem, we combine electron backscatter diffraction analysis of natural and experimental samples to explore microstructural evolution across the coesite-quartz phase transformation. We demonstrate that neighbouring domains of quartz commonly feature an 84 ± 4° rotation of [c] axes around the pole of a common {m} plane. This orientation relationship is a product of epitaxy, whereby the {$11\bar{2}2$} Japan twin plane in quartz nucleates on the (010) plane in coesite. In supercell simulations, the nucleation of Japan twins can be explained by the energetically favourable alignment of quartz tetrahedra on parental coesite tetrahedra. Through experiments, we demonstrate that this signature emerges over a broad range of conditions, regardless of the availability of nucleation sites (e.g., grain boundaries) or the density of crystal lattice defects (e.g., dislocations). Overall, our work provides a quantitative and unambiguous tool for identifying UHP terranes from quartz in isolation.

Coesite↗