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At least 1,297 records · Page 72

Assessment of Potential Future Demands for Hydrogen in the United States

H2@Scale is a U.S. Department of Energy (DOE) initiative that brings together stakeholders to advance the affordable production, transport, storage, and utilization of hydrogen (H2) as an energy carrier to increase revenue opportunities in multiple energy sectors. The focus of the current work is to characterize the growth potential of diverse hydrogen industries in the United States, given research and development (R&D) advancements in hydrogen technologies. Current and emerging hydrogen production technologies utilize diverse energy sources, including natural gas (NG) reforming, as well as renewable and nuclear power for low-temperature and high-temperature water splitting. The produced hydrogen also enables emerging domestic industries that value conventional and renewable hydrogen as an energy carrier for intermediate and end use. The success of H2@Scale (Figure ES.1) depends not only on hydrogen demand from growing existing markets such as petroleum refining and ammonia (NH 3 ) production, but also on the development of new markets such as metals refining, synthetic fuel (synfuel) and chemical production, biofuels, light-duty (LD) and heavy-duty (HD) hydrogen fuel cell (FC) electric vehicles (FCEVs), and injection into NG pipelines, all of which can significantly increase hydrogen demand relative to current levels of approximately10 million metric tons [MMT] annually. This study focused primarily on five demand sectors — synfuels, upgrading of oil/biomass, NH 3 /fertilizer, metals refining, and hydrogen vehicles (transportation) — along with gas infrastructure. For each sector, a hydrogen demand potential was quantified, along with a “threshold price.” The hydrogen demand potential reflects a practical amount of hydrogen that could be used in that sector, barring economic considerations. The threshold price reflects the price at which the consumer would utilize hydrogen in lieu of an alternative that could supply the same performance.

08 HYDROGEN↗

Intracellular distributions and putative functions of calcium-binding proteins in the bullfrog vestibular otolith organs

Hair cells in the bullfrog vestibular otolith organs were immunolabeled by monoclonal and polyclonal antisera against calbindin (CaB), calmodulin (CaM), calretinin (CaR), and parvalbumin (PA). S-100, previously shown to immunolabel striolar hair cells in fish vestibular organs, only weakly immunolabeled hair cells in the bullfrog vestibular otolith organs. Immunolabeling was not detected in supporting cells. With the exception of CaR, myelinated axons and unmyelinated nerve terminals were immunolabeled by all of the above antisera. Immunolabeling was seen in all saccular hair cells, although hair cells at the macular margins were immunolabeled more intensely for CaB, CaM, and PA than more centrally located hair cells. As the macula margins are known to be a growth zone, this labeling pattern suggests that marginal hair cells up-regulate their calcium-binding proteins during hair cell development. In the utriculus, immunolabeling for CaM and PA was generally restricted to striolar hair cells. CaR immunolabeling was restricted to the stereociliary array. Immunolabeling for other calcium-binding proteins was generally seen in both the cell body and hair bundles of hair cells, although this labeling was often localized to the stereociliary array and the apical portion of the cell body. CaM and PA immunolabeling in the stereociliary array in saccular and utricular striolar cells suggests a functional role for these proteins in mechanoelectric transduction and adaptation.

NASA Discipline Number 40-10↗

Along-the-channel modeling and analysis of PEFCs at low stoichiometry: Development of a 1+2D model

Water management remains a key challenge in polymer-electrolyte fuel cells. In this paper, a pseudo 3-D (1+2D) model is developed to account better for changes of water management along the channel, as well as verify the possibilities of using differential cells for data capture and translation to integral cell performance. An accurate 2-D membrane-electrode-assembly model is developed for differential cell modeling, which is combined with an along-the-channel stepping algorithm to account for down the channel changes in pressure, temperature, reactant concentration, and relative humidity. Variations in cell performance along the channel due to changes in operating conditions are characterized quantitatively and optimized, where drier feed conditions demonstratively require such an approach. In conclusion, the study identifies gaps between differential and integral cells including those related to flow velocity and highlights the need for better models to understand and link integral cell performance and water management.

30 DIRECT ENERGY CONVERSION↗

Development of spatially and temporally resolved electron density measurements for the assessment of radiation hydrodynamics simulations of laboratory X-ray photoionized plasmas

The photoionized plasma gas cell experiment is an established platform we use to make at-parameter (ξ > > 1 ergs cm s –1 ) measurements of plasma properties with application to high-energy astrophysical systems. We model the experiments with 1D radiation hydrodynamics simulations using the HELIOS-CR code to inform our understanding and assist in the interpretation of results. The simulations predict that the bulk of the plasma is in a quasi-uniform and hydrodynamically unperturbed state throughout the duration of the experiment. To evaluate this prediction, we introduced a photonic Doppler velocimetry (PDV) diagnostic to measure spatially and temporally resolved plasma electron density. The initial measurements were successful but had limitations that made model-data comparisons challenging. To address this, we re-designed the gas cell PDV diagnostic and doubled the number of measurement locations to sample across two thirds of the depth of the cell. We also present a comparison of the results from the upgraded PDV diagnostic to the HELIOS-CR simulations for the first time. As a result, the experimental data confirms the prediction of an unperturbed region in the bulk of the plasma but reveals discrepancies in the time evolution and spatial distribution of the simulated electron density.

79 ASTRONOMY AND ASTROPHYSICS↗

Method of making a light weight battery plaque

A nickel plaque which may be coated with a suitable metal or compound to make an electrode for a fuel cell or battery is fabricated by directing nickel sensitizer, catalyst and plating solutions through a porous plastic substrate in the order named and at prescribed temperatures and flow rates. A boride compound dissolved in the plating solution decreases the electrical resistance of the plaque. Certain substrates may require treatment in an alkali solution to dissolve filler materials thereby increasing porosity to a required 65%.

Reid, M. A.↗

Microbial contributions to the Precambrian Earth

Life has existed on Earth for approximately 3.5 billion years. For most of this time, prokaryotic communities provided the major biological forces changing the Earth. Many changes in atmospheric gas composition occurred during the Archean and Proterozoic eons as a result of microbial activity. Extant microbial communities were used to help understand the dynamics which contributed to these atmospheric changes. The microbial mat communities were characterized according to the organismic constituents. Symbiosis in microbial communities is recognized as a major force in cell evolution. Among the evolutinary enigmas investigated is the problem of the origin of the undulipodia. Undulipodial microtubules are still deployed for major cellular processes such as mitosis and meiosis. Several prokaryotes were tested for the presence of the S1-type protein, so far only spirochetes were found to possess it. The S1-type protein is being sought in cyanobacteria reported to contain microtubules.

Margulis, L.↗

Characterizing the Relationships Among Lightning and Storm Parameters: Lightning as a Proxy Variable

We have gained important insights from prior studies that have suggested relationships between lightning and storm growth, decay, convective rain flux, vertical distribution of storm mass and echo volume in the region, and storm energetics. A study was initiated in the Summer of 1996 to determine how total (in-cloud plus ground) lightning observations might provide added knowledge to the forecaster in the determination and identification of severe thunderstorms and weather hazards in real-time. The Melbourne Weather Office was selected as a primary site to conduct this study because Melbourne is the only site in the world with continuous and open access to total lightning (LDAR) data and a Doppler (WSR-88D) radar. A Lightning Imaging Sensor Data Applications Demonstration (LISDAD) system was integrated into the forecaster's workstation during the Summer 1996 to allow the forecaster to interact in real-time with the multi-sensor data being displayed. LISDAD currently ingests LDAR data, the cloud-to-ground National Lightning Detection Network (NLDN) data, and the Melbourne radar data in f real-time. The interactive features provide the duty forecaster the ability to perform quick diagnostics on storm cells of interest. Upon selection of a storm cell, a pop-up box appears displaying the time-history of various storm parameters (e.g., maximum radar reflectivity, height of maximum reflectivity, echo-top height, NLDN and LDAR lightning flash rates, storm-based vertically integrated liquid water content). This product is archived to aid on detailed post-analysis.

Goodman, S. J.↗

Microbial detection with low molecular weight RNA

The need to monitor microorganisms in the environment has increased interest in assays based on hybridization probes that target nucleic acids (e.g., rRNA). We report the development of liquid-phase assays for specific bacterial 5S rRNA sequences or similarly sized artificial RNAs (aRNAs) using molecular beacon technology. These beacons fluoresce only in the presence of specific target sequences, rendering as much as a 27-fold fluorescence enhancement. The assays can be used with both crude cell lysates and purified total RNA preparations. Minimal sample preparation (e.g., heating to promote leakage from cells) is sufficient to detect many Gram-negative bacteria. Using this approach it was possible to detect an aRNA-labeled Escherichia coli strain in the presence of a large background of an otherwise identical E. coli strain. Finally, by using a longer wavelength carboxytetramethylrhodamine beacon it was possible to reduce the fraction of the signal due to cellular autofluorescence to below 0.5%.

NASA Discipline Life Sciences Technologies↗

Biomarkers Detection With the Autonomous and Remotely Operated SOLID-LDChip Instrument in A Mars Drilling Simulating Campaign

One of the main goals in Mars exploration is to determine whether life has ever existed on the red planet. To achieve this goal, it is important to verify the performance, robustness, and maturity of instrumentation devoted to life detection, for example through field-testing in Mars analog environments.The Atacama Desert is considered one of the best terrestrial analogs of the surface of Mars due to abrupt temperature shifts, dryness, high UV radiation, and extremely low biomass. This, together with the lack of vegetation and the geochemistry of the regolith, make it an ideal scenario for testing instrumentation, performance, and concepts of operations. The Atacama Rover Astrobiology Drilling Studies (ARADS) is a NASA PSTAR project conceived for maturing and testing life-detection instrumentation in the Atacama Desert(1). The project is based on the K-REX2 rover equipped with a robotic 1-meter arm that delivers samples toon board instruments. This includes SOLID3.1 (Signs of Life Detector), designed as a life-detection instrument for finding complex organic molecules by means of the LDCHip (Life Detector Chip), an antibody microarray sensor(2). The instrument can extract organic compounds from soil, rocks, and sediments into a liquid solvent in the extraction cell (EC), allowing the search for hundreds of microbial molecular biomarkers at once (3). The robustness and reliability of SOLID were tested in the 2019 ARADS Mars drilling simulating campaign and confirmed with other analytical methods.

M Moreno-Paz↗

Pressure-induced suppression of ferromagnetism in the itinerant ferromagnet LaCrSb 3

We have performed an extensive pressure-dependent structural, spectroscopic, and electrical transport study of LaCrSb 3 . The ferromagnetic phase (TC=120 K at p = 0 GPa) is fully suppressed by p = 26.5 GPa and the Cr moment decreases steadily with increasing pressure. The unit-cell volume decreases smoothly up to p = 55 GPa. We find that the bulk modulus and suppression of the magnetism are in good agreement with theoretical predictions, but the Cr moment decreases smoothly with pressure, in contrast to steplike drops predicted by theory. The ferromagnetic ordering temperature appears to be driven by the Cr moment.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Demixing kinetics of phase separated polymer solutions in microgravity

In preparation for performing cell partitioning in space the demixing behavior of aqueous two phase systems containing dextran and poly(ethylene glycol) in microgravity was modeled with an isopycnic system and studied on aircraft flights and on STS 51-D. In all types of experiments demixing occurs, eventually producing one phase localized around the wall of the container with the other internalized within it. The demixing kinetics were analyzed in each case.

Brooks, D. E.↗

Detection Limit of Smectite by Chemin IV Laboratory Instrument: Preliminary Implications for Chemin on the Mars Science Laboratory Mission

The CheMin instrument on the Mars Science Laboratory (MSL) is an miniature X-ray diffraction (XRD) and X-ray fluorescence (XRF) instrument capable of detecting the mineralogical and elemental compositions of rocks, outcrops and soils on the surface of Mars. CheMin uses a microfocus-source Co X-ray tube, a transmission sample cell, and an energy-discriminating X-ray sensitive CCD to produce simultaneous 2-D XRD patterns and energy-dispersive X-ray histograms from powdered samples. CRISM and OMEGA have identified the presence of phyllosilicates at several locations on Mars including the four candidate MSL landing sites. The objective of this study was to conduct preliminary studies to determine the CheMin detection limit of smectite in a smectite/olivine mixed mineral system.

Archilles, Cherie↗

Seasat scanning multichannel microwave radiometer - Results of the Gulf of Alaska workshop

Scanning multichannel microwave radiometer results obtained by the Gulf of Alaska Seasat Experiment Workshop are reported. The Seasat SMMR provided data from five channels operating at 6.6, 10.7, 18, 21, and 37 GHz at vertical and horizontal polarizations. Two preliminary algorithms were used to retrieve geophysical parameters from the data: the Wentz algorithm (Bierman et al., 1978) based on a theoretically derived function for computing brightness temperatures and the Wilheit algorithm, based on statistical relationships between brightness temperatures and the geophysical parameters obtained from an ensemble of realistic sea-surface temperature values, wind speeds, atmospheric temperature profiles, water vapor profiles and cloud models. In spite of the immaturity of the data-processing algorithms, results are encouraging. For open ocean, rain-free cells of high-quality surface truth wind determinations display standard deviations of 3 m/sec about a bias of 1.5 m/sec. The sea-surface temperature exhibits a standard deviation of about 1.5 deg C about a bias of 3 to 5 deg C under a variety of meteorological conditions.

Lipes, R. G.↗

Cellular and extracellular C contributions to respiration after wetting dry soil

Wetting of dry soil triggers a pulse of microbial respiration that has been attributed to two broad mechanisms: (1) recycling of microbial cellular carbon (C), and (2) consumption of extracellular organic C made available to microbes by wetting. We evaluated these two mechanisms by measuring cumulative CO 2 release, changes in the size and chemical composition of microbial biomass, and water-extractable organic carbon (WEOC) concentrations following artificial wetting of soil sampled from two depths at each of seven sites across California spanning a range of geologic parent materials. In samples collected from surface soil (0–10 cm depth), we found that cumulative CO 2 release after wetting in the laboratory was most strongly correlated with microbial biomass. In these samples, the relative abundance of trehalose—a putative microbial osmolyte—decreased from 25% (SD = 12) to 16% (SD = 7) of the chloroform-labile fraction of the microbial biomass after wetting. This suggested a role for osmolyte consumption in generating the respiration pulse. In subsoil (40–50 cm depth, or sampled at contact with rock), however, the cumulative CO2 release after wetting was unrelated to microbial biomass and more strongly related to WEOC. The concentrations of selected microbial biomass constituents (e.g. trehalose and amino acids) in WEOC were negligible (< 1%), suggesting that cell lysis was not important in generating WEOC in this study. The amount of WEOC relative to total organic C was greatest in subsoil, and negatively related to ammonium oxalate-extractable Fe (Pearson’s R = 0.42, p < 0.01), suggesting a role for soil mineralogical properties in controlling WEOC release. Together, these findings suggest that microbial cellular C and extracellular C jointly contribute to the respiration pulse, and that their relative contribution depends on depth.

59 BASIC BIOLOGICAL SCIENCES↗

Vibrational spectra and structure of azomethane and azomethane-d6.

The infrared and Raman spectra of azomethane and azomethane-d(6) were examined in detail. Vibrational data provided definitive verification of a trans-structure with C(2h) symmetry. A vibrational assignment is proposed for the 24 fundamental modes based upon the observed contours, isotopic shift ratios, and group frequency correlations. Spectra of the polycrystalline samples indicate that there are at least four molecules per unit cell, since a number of the bands were observed to be split into doublets. The crystal also appeared to have a center of symmetry, since mutual exclusion was clearly operative.

Durig, J. R.↗

Particle-in-cell simulations of burning inertial confinement fusion capsule implosions

Anomalies observed in the neutron spectral shift of high-yield shots at the National Ignition Facility (NIF) suggest the presence of suprathermal ions [E. P. Hartouni et al., Nat. Phys. 19, 72 (2023)], implying that kinetic effects play a significant role in burning inertial confinement fusion (ICF) plasmas. Furthermore, recent measurements of reaction-in-flight (RIF) neutrons offer a direct probe of the stopping power in the burning fuel region of high-energy alpha particles and up-scattered fuel ions. We have developed the particle-in-cell code PICNIC, an exactly energy-conserving particle-in-cell Monte-Carlo collision (PIC-MCC) code to simulate the burn stage in ICF. We present results from 1D spherical simulations of NIF shot N210808, which was the first to exceed the Lawson criterion for laser fusion. We find that the suprathermal ions generated by large-angle Rutherford and nuclear elastic scattering (NES) with fusion alphas produce an alpha knock-on neutron (AKN) signal consistent with the extent and relative yield of the AKN spectrum identified in ignition experiments at the NIF. Furthermore, we also find that the inclusion of large-angle scattering physics does not explain the anomalously large spectral shift observed in the experiment.

High-energy-density plasmas↗

Pattern of filling in the pulmonary capillary bed.

Artificially ventilated and perfused dog lungs were rapidly frozen under various physiological conditions. In 2-micron-thick sections the number of red blood cells (RBCs) per 10-micron length of alveolar septum was counted. Under conditions in which alveolar pressure exceeded venous pressure, variation in RBC concentration within areas supplied by single arterioles accounted completely for variation between areas supplied by different arterioles. Except at very high perfusion pressures when venous pressure exceeded alveolar pressure, there was no significant correlation between RBC concentrations of pairs of adjacent septa.

Warrell, D. A.↗

Advanced microbial check valve development

A flight certified assembly identified as a Microbial Check Valve (MCV) was developed and tested. The MCV is a canister packed with an iodinated anionic exchange resin. The device is used to destroy organisms in a water stream as the water passes through the device. The device is equally effective for fluid flow in either direction and its primary method of organism removal is killing rather than filtering. The MCV was successfully developed for the space shuttle to: disinfect fuel cell water; and prevent back contamination of the stored potable water supply. One version of the device consists of a high residual iodinated resin bed that imparts approximately 2 ppm of iodine to the fuel cell water as it flows to the potable water tanks. A second version of the device consists of a low residual iodinated resin bed. One of these low residual beds is located at each use port in the potable water system for the dual purpose of removing some iodine from the potable water as it is dispensed and also to prevent back contamination of the potable supply.

Colombo, G. V.↗