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NASA NTRS1986

The ortho-para H2 distribution on Uranus: Constraints from the collision-induced 3-0 dipole band and 4-0 S(0) and S(1) quadrupole line profiles

Recent high quality spectral observations have allowed the derivation of constraints on the atmospheric structure of Uranus. The present analysis, which is based on the detailed modeling of a broadband geometric albedo spectrum and high resolution observations of the H2 4-0 quadrupole and 6818.9-A CH4 features, yields (1) a family of models which parameterize an upper tropospheric haze layer, (2) a lower, optically infinite cloud at a given pressure level, (3) the cloud-level methane molar fraction, and (4) the mean ortho/para ratio in the visible atmosphere. The single scattering albedo of atmospheric aerosols exhibits a steep darkening between 5890 and 6040 A.

Baines, K. H.↗

NASA NTRS1986

Radiative-convective equilibrium models of Uranus and Neptune

The present study of Uranus and Neptune radiative-convective equilibrium models gives emphasis to such aspects of the stratospheric energy balance as the influence of aerosol heating and convective penetration. The results obtained for Uranus imply that a continuum absorber may be a significant factor in the stratosphere despite the great distance from the sun. The results obtained for Neptune show that such a continuum absorber could significantly contribute to the energy balance within a localized stratospheric region, although it probably cannot furnish sufficient power to account for the observed IR spectrum irrespective of its vertical distribution. Attention is accordingly given to the convective penetration that could arise under such rapid vertical mixing that CH4's condensation cannot occur before the gas is carried above the condensation region.

Appleby, J. F.↗

NASA NTRS1986

The HD/H2 ratio in the atmosphere of Uranus

High resolution spectra of HD and H2 were brought together to derive the D/H ratio for Uranus. The deuterium concentration in the dominant molecular hydrogen phase is least susceptible to the effects of isotope fractionation in the planetary atmosphere, and the determination of relative abundances of HD and H2 is unambiguous due to nearness and relative weakness of the chosen spectral lines. The HD 5-0 R(0) and R(1) dipole lines and the H2 4-0 S(0), S(1), and S(2) quadrupole lines were obtained with a PEPSIOS instrument at the Palomar 5-meter telescope. The H2 spectra, which resolve the asymmetric line profiles resulting from pressure shifts in the deep stratified Uranus atmosphere, unambiguously define the line-of-sight hydrogen abundance for comparison with the HD spectra. The 5-0 band of HD was chosen to minimize interference from blended CH4 lines. However, weak interfering lines were found in the 5-0 bands from Uranus as well, and some uncertainties remain regarding the intrinsic line strengths in molecular hydrogen, complicating the analysis of the HD/H2 data. Nevertheless, it is established that the D/H ratio in the atmosphere of Uranus is smaller than the Jovian value, and is significantly smaller than recent theoretical predictions for Uranus based on estimates of isotope fractionation in the pre-planetary solar nebulae.

Trauger, J. T.↗

NASA NTRS1987

Lidar measurements from space for tropospheric chemistry investigations: Summary of workshop overview presentation

Over the past decade, NASA has played a lead role in defining the scientific objectives and technology requirements for spaceborne lidar investigations of the atmosphere. An assessment of the potential for conducting lidar measurements from space for investigations that pertain specifically to tropospheric chemistry is presented. A description of potential lidar measurement techniques is given, and the scientific requirements for tropospheric chemistry are reviewed. The current status of airborne lidar measurements of aerosols, O3, and H2O is discussed, and a brief description of the evolution of lidar technology to space is given. Also, the measurement of tropospheric gases with a spaceborne lidar system is evaluated for a wide range of gas species. From this general assessment, it appears feasible to measure aerosols, H2O, O3, NH3, CO, CH4, NO2, atmospheric pressure and temperature, and wind with a lidar from space provided that the appropriate laser and receiver technology is available. For the mid-1990's, it is expected that lidar technology will be available for the measurement of aerosols, H2O, and O3 from a space platform.

Browell, Edward V.↗

NASA NTRS1987

Parametrization of electron impact ionization cross sections for CO, CO2, NH3 and SO2

The electron impact ionization and dissociative ionization cross section data of CO, CO2, CH4, NH3, and SO2, measured in the laboratory, were parameterized utilizing an empirical formula based on the Born approximation. For this purpose an chi squared minimization technique was employed which provided an excellent fit to the experimental data.

Srivastava, Santosh K.↗

NASA NTRS1987

Properties of planetary fluids at high pressure and temperature

In order to derive models of the interiors of Uranus, Neptune, Jupiter and Saturn, researchers studied equations of state and electrical conductivities of molecules at high dynamic pressures and temperatures. Results are given for shock temperature measurements of N2 and CH4. Temperature data allowed demonstration of shock induced cooling in the the transition region and the existence of crossing isotherms in P-V space.

Nellis, W. J.↗

NASA NTRS1986

Opposed jet burner studies of silane-methane, silane-hydrogen and hydrogen diffusion flames with air

An atmospheric pressure tubular opposed jet burner technique was used to characterize certain diffusion-flame transitions and associated burning rates for N2-diluted mixtures of highly-reactive fuels. Presented are: (1) details of the technique, with emphasis on features permitting the study of flames involving pyrophoric gases and particle-forming combustion reactions: (2) discoveries on the properties of these flames which correspond to physically and chemically distinct stages of silane and hydrogen combustion; and (3) unburnt gas velocity data obtained from flames based on SiH4-CH4-N2, SiH4-H2-N2, and H2-N2 fuel mixtures, and plotted as functions of combustible-fuel mole fraction and fuel/oxygen molar input flow ratios. In addition, these burning velocity results are analyzed and interpreted.

Pellett, G. L.↗

NASA NTRS1987

Atlas of Absorption Lines from 0 to 17900 Cm (sup)-1

Plots of logarithm (base 10) of absorption line strength versus wavenumber from 0 to 17900/cm(sup)-1 are shown for the 28 atmospheric gases (H2O, CO2, O3, N2O, CO, CH4, O2, NO, SO2, NO2, NH3, HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, H2CO, HOCl, N2, HCN, CH3Cl, H2O2, C2H2, C2H6, PH3), which appear in the 1986 Air Force Geophysics Laboratory high-resolution transmission molecular absorption data base (HITRAN) compilation, and for O(P-3), O-18 isotopic ozone, and HO2 from the 1984 JPL compilation in the 0- to 200/cm(sup)-1 region, and infrared solar CO lines at 4500 K. Also shown are plots of logarithm (base 10) of approximate infrared absorption cross sections of 11 heavy molecules versus wavenumber. The cross-section data cover 700 to 1800/cm(sup)-1 and are included as a separate data file in the 1986 HITRAN database.

Park, J. H.↗

NASA NTRS1986

Elemental, isotopic and molecular abundances in comets

The chemical composition of comet nuclei and the factors affecting it are discussed, summarizing the results of recent theoretical, experimental, and observational investigations. Consideration is given to the evidence supporting the view that the nucleus is radially differentiation (except for a thin outer layer), surface differentiation by heat processing and outgassing, and mantle buildup on an undifferentiated core. The nature of the refractory and volatile components is examined, and the elemental and isotopic compositions are given in tables and characterized. The uncertain (except for H2O) molecular composition of the volatile fraction is considered, and it is suggested that some oxides or aldehydes (such as CO, CO2, and H2CO), but no large amounts of fully hydrogenated compounds (such as CH4 and NH3) are included.

Delsemme, A. H.↗

NASA NTRS1986

Tracer transport by the diabatic circulation deduced from satellite observations

Nimbus-7 sensor data were used to track the diabatic circulation in the stratosphere to study the advective transport of CH4 and N2O as tracer species. Advective transport by the mean circulation was found to be a function of the temperature field and associated deviations from radiative equilibrium. A photochemical model was applied to account for the disappearance of the tracer species from the stratosphere. Comparisons between the SAMS data and modeling on the basis of the chemical loss rates of the tracers and the LIMS circulation data showed that the model predictions underestimated the resident abundances, although the global distributions and circulations exhibited a good match.

Solomon, S.↗

NASA NTRS1986

The geometric albedos of Uranus and Neptune between 2100 and 3350 A

Results are reported from large aperture IUE observations of the stratospheres of Uranus and Neptune. The data were collected using 16 Cyg A and B as solar analog stars. The spectra observed were similar to geometric albedos of the predicted in terms of Rayleigh-Raman scattering in the 2200-2800 A region. A falloff was observed near visible wavelengths, a factor which might be attributable to low-altitude haze absorbing in the 3000-4000 A interval. The data also indicated that the Uranus stratosphere does not strongly absorb UV radiation, and is not a good heating source. The stratospheric haze constituents over Uranus could therefore be condensates of CH4 and H2 photochemistry.

Wagener, R.↗

NASA NTRS1986

Submillimeter and millimeter observations of Uranus and Neptune

Neptune and Uranus were studied at submillimeter and millimeter wavelengths for 2 yr using the UK IR telescope and the NASA IR telescope at Mauna Kea and the 12 dish at Kitt Peak, AZ. The brightness temperatures of both planets are provided at various wavelengths over the 0.35-3.3 mm interval scanned in the study. The present data, in combination with data from the 17 microns-3 mm interval scanned in the study. The present data, in combination with data from the 17 microns-3 mm interval taken during previous campaigns, are employed to model the temperature structures in the atmospheres of the two planets over the vertical range 100 mbar-8 bar. The data support the presence of active convection processes at the 1 bar level and deeper in both atmospheres. A static equilibrium however, exists between para-H2 and ortho-H2, along with a constant CH4 fraction of 2 percent. Deficiencies in the current database are detailed.

Orton, G. S.↗

NASA NTRS1986

An approach for verifying clear-sky radiation models with ERBS scanner measurements

A technique is proposed for validating radiation models using Earth Radiation Budget Satellite (ERBS) top of the atmosphere longwave radiance exitance data. ERBS measures clear-sky fluxes in terms of reflected solar and emitted longwave radiation. The radiation model considered accounts for the effects of H2O, CO2, O3, CH4, and N2O. ERBS nighttime radiance data for the region 60 deg N to 60 deg S latitude for most of November 1984 are compared with radiances over 5/cm intervals predicted by the model by means of the Malkmus theory for transmittances for line absorption.

Ramanathan, V.↗

NASA NTRS1986

Mobilization of cryogenic ice in outer solar system satellites

Mechanisms to explain the mobilization of ice on the Uranian satellites Miranda and Ariel at the very low temperatures prevailing on those bodies are considered. A form of pressure solution creep is proposed in which very fine-grained water ice or clathrate hydrate is mobilized by a small amount of intergranular cryogenic fluid (CH4, CO, or N2). Viscosities as low as 10 to the 12th P are possible for a limited time, sufficient to allow flooding of rift valleys and perhaps even substantial lateral flows (glaciers).

Stevenson, D. J.↗

NASA NTRS1987

Remote sensing of the earth's biosphere - A tool for studies of the global atmospheric environment

Recent advances in remote sensing technology and its use for global studies of the biospheric processes are described. Special consideration is given to research related to two issues: (1) quantifying the impacts of natural vegetation and its changing patterns of occurrence on the atmospheric CO2 budget and (2) assessing wetlands (such as the swamps and marshes of Florida's Everglades) as sources of atmospheric CH4. The results include the data from NOAA-AVHRR sensors and from experiments in remote detection of plant growth rate.

Bartlett, David S.↗

NASA NTRS1987

Voyager 2 at Uranus - A synopsis of atmospheric science results

Knowledge of the Uranian atmosphere took a quantum leap when the Voyager 2 spacecraft made a close approach in January 1986. Among the highlights of the early results are measurements of the atmospheric composition (He mole fraction = 0.15; Ch4 mole fraction = 0.02), rotation period of the deep interior (17.24 h), thermal structure and dynamics (the planet is coldest at midlatitudes; retrograde equatorial winds are inferred), and upper-atmosphere processes (a phenomenon called electroglow is only partly understood and is recognized as an important process n all the major-planet atmospheres examined by Voyager).

West, Robert A.↗

NASA NTRS1986

Opposed jet burner studies of silane-methane, silane-hydrogen, and hydrogen diffusion flames with air

An atmospheric pressure tubular opposed jet burner technique was used to characterize certain diffusion-flame transitions and associated burning rates for N2-diluted mixtures of highly-reactive fuels. The paper presents: (1) details of the technique, with emphasis on features permitting the study of flames involving pyrophoric gases and particle-forming combustion reactions; (2) discoveries on the properties of these flames which correspond to physically and chemically distinct stages of silane and hydrogen combustion; and (3) unburnt gas velocity data obtained from flames based on SiH4-CH4-N2, SiH4-H2-N2, and H2-N2 fuel mixtures, and plotted as functions of combustible-fuel mole fraction and fuel/oxygen molar input flow ratios. In addition, these burning velocity results are analyzed and interpreted.

Pellett, G. L.↗

NASA NTRS1986

Balloon-borne cryogenic spectrometer for measurement of lower stratospheric trace constituents

A liquid-nitrogen cooled, multidetector Fourier transform spectrometer has been constructed to measure minor stratospheric constituents via high resolution, earth-limb emission spectroscopy from a balloon-borne platform. Cryogenic cooling, combined with the use of extrinsic silicon photoconductor detectors cooled to liquid-helium temperature, allows the detection of weak emission features of gaseous species. The spectrometer has two basic scan modes: the first mode records the continuous spectrum from 650-2100/cm with 0.2/cm resolution; the second simultaneously records four preselected narrow intervals (about 175/cm bandpass each) with 0.02/cm resolution, unapodized. Filtering of the interferogram signal is done by real-time, digital signal processing. The most important feature of this flat mirror Michelson system, with respect to remote balloon-borne operation, is the dynamic alignment system which maintains the relative parallelism of the two flat reflectors of the interferometer. Species identified to date in data obtained during a Nov. 6, 1984, flight include: CO2, O3, H2O, CH4, HNO3, N2O, NO2, NO, CCl3F (Freon-11) and CF2Cl2 (Freon-12).

Brasunas, J. C.↗