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NASA NTRSDate not supplied

Calcium and Magnesium Distribution Between Sulfide and Silicate Melts: Thermodynamic Modeling and Insights into Mercury's Mantle-Crust Differentiation

Mercury stands out as the terrestrial planet with the lowest degree of oxidation among all planets of our solar system. It is characterized by a high abundance of sulfur, which is expected to replace oxygen in silicate melts. This sulfur enrichment could lead to sulfide saturation in its mantle, potentially resulting in the formation of sulfides rich in calcium and magnesium. Utilizing experimental data from the literature, we constructed a thermodynamic model to explore the partitioning of calcium and magnesium between sulfide and silicate melts. This model aims to improve our comprehension of the chemical equilibria driving the process of mantle-crust differentiation on Mercury. Our models indicate that increased temperature, decreased pressure, and low concentrations of iron, oxygen, and carbon within the sulfide phase, along with low sulfur concentrations in the silicate phase, favor calcium’s partitioning into the sulfide. Additionally, magnesium partitioning into the sulfide melt is favored with decreased pressure, decreased temperature, low concentrations of iron and calcium within the sulfide, and low concentrations of sulfur within the silicate. Our results suggest that up 9.4% and 5.6% Ca and Mg, respectively, can be present in sulfides equilibrated with sulfide-saturated silicate melts during mantle-crust differentiation. Further investigation will focus on the distribution of sulfide phases within the mantle and crust to better constrain Mercury’s internal structure.

Taylor McCombs↗
NASA NTRS1991

An ion microprobe study of corundum in the Murchison meteorite - Implications for Al-26 and O-16 in the early solar system

Results are presented from measurements of O, Mg, and Ti isotopes and the abundances of Mg, Ca, Sc, Ti, V, Sr, Y, Zr, La, and Ce in 26 individual corundum grains from the Murchison CM2 chondrite. The results provide further evidence for live Al-26 in the early solar system and set strict upper limits on the amounts of fossil Mg-26. The analyses suggest that corundum in this chondrite formed from two components with live Al-26 and a mass fraction of 43 percent dead Al.

Virag, Alois↗
NASA NTRSDate not supplied

Preliminary XANES Analysis of Laboratory Analogs of Titan Tholins

Titan, the largest moon of Saturn, is a fascinating object. It is the only other object in the Solar System, besides Earth, with a dense (1.5 bar at the surface) atmosphere whose composition is dominated by N2, with CH4 as the second most abundant gas. A complex organic chemistry between N2 and CH4, induced by solar UV photons and energetic particles, results in the formation of a large variety of organic compounds, including hydrocarbons (e.g., C2H2, C2H4, C2H6, C3H4, C6H6), nitriles (e.g., HCN, HNC, HC3N, CH3CN, C2N2), as well as larger molecules that include aromatic and heteroaromatic compounds [1]. This complex organic chemistry also leads to the formation of aerosols that play an important role in Titan’s atmospheric dynamics, climate, as well as surface composition and processes. Because of its N2-based dense atmosphere, and its CH4 cycle that resembles the hydrological cycle on Earth, Titan is often considered to be an analog of early Earth. In recent years, Titan’s atmosphere and surface were monitored in detail by the NASA Cassini mission, which orbited the Saturnian system from 2004 to 2017, as well as the ESA Huygens probe, which plunged into Titan’s atmosphere and landed on its surface in 2005.

Titan↗
NASA NTRSDate not supplied

First N 2 Profile for Venus’ Deep Lower Atmosphere

We present the first N 2 profile for Venus’ deep lower atmosphere (<15 km) and a constrained isotopic composition for cloud N 2 [1]. This work directly addresses unresolved questions for Venus using legacy observations. Prior to this work, there were no reported measurements for N 2 abundances at <15 km and the isotopic composition remained unconstrained [2]. The N 2 parameters are critical to understanding the evolution and thermal properties of the atmosphere [3-7]. Our N 2 results were obtained by re-analysis of data acquired in 1978 by the Pioneer Venus Large Probe Neutral Mass Spectrometer (LNMS) [8]. The archived mass spectra from 64.2 to 0.2 km were treated using the analytical procedures specifically developed for the LNMS [9-11]. Judicious peak fitting permitted disambiguation of (A) N 2 + and CO + at 28 u and (B) 14 N 15 N+, 13 CO + , and C 2 H 5 + at 29 u. Quality controls included comparing the (A) LNMS CO + /CO 2 + ratios to the NIST database and literature and (B) fitted counts for CO + to the expected counts of CO + calculated from C 18 O + and 13 CO + using the LNMS 16 O/ 18 O and 12 C/ 13 C ratios (obtained from CO 2 ). Our results show that N 2 is uniformly mixed across the deep lower atmosphere between ~0.2 and 15 km (2.49 ± 0.10 v%). In contrast, N 2 is non-uniformly mixed across the sub-cloud atmosphere and clouds (~15–59 km), where N 2 abundances increase by ~ 2-fold between ~15 km (2.45 ± 0.32 v%) and ~59-51 km (5.21 ± 0.18 v%). Using the cloud data, we also obtained a constrained 15 N/ 14 N ratio (2.93×10 -3 ± 0.13×10 -3 ) and δ 15 N value (-204 ± 35‰). Thus, the LNMS results [1] suggest that (A) the atmosphere is unstable at <15 km, (B) N 2 is not well-mixed >15 km, and (C) the cloud δ 15 N falls between Earth and the solar wind [12, 13]. Comparisons of the N 2 abundances and isotopic compositions for nitrogen, carbon, and oxygen to other Venus measurements will be discussed.

deep lower atmosphere↗
NASA NTRS1972

Composition and energy spectra of heavy nuclei with 0.5 less than E less than 40 MeV per nucleon in the 1971 January 24 and September 1 solar flares.

Measurement of energy spectra of O, Si, and Fe between 0.5 and 40 MeV per nucleon with stacks of plastic detectors exposed in a rocket during the Jan. 24, 1971 flare. The Fe/Si ratio decreases from 1.8 plus or minus 0.3 to 0.42 plus or minus 0.14 with energy. In both the January 24 flare and the September 1 flare, the abundances of elements 10 less than or equal to Z less than or equal to 28 at approximately 15 MeV per nucleon are similar to high-energy cosmic-ray source abundances; S, Ne, and Ar are significantly lower than current solar values.

Crawford, H. J.↗
NASA NTRS2007

The Abundance and Distribution of Presolar Materials in Cluster IDPS

Presolar grains and remnants of interstellar organic compounds occur in a wide range of primitive solar system materials, including meteorites, interplanetary dust particles (IDPs), and comet Wild-2 samples. Among the most abundant presolar phases are silicate stardust grains and molecular cloud material. However, these materials have also been susceptible to destruction and alteration during parent body and nebular processing. In addition to their importance as direct samples of remote and ancient astrophysical environments, presolar materials thus provide a measure of how well different primitive bodies have preserved the original solar system starting materials.

Messenger, Scott↗
NASA NTRS1984

Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

Cold, dark molecular clouds are particularly useful for the study of interstellar chemistry because their physical parameters are better understood than those of heterogeneous, complex giant molecular clouds. Another advantage is their relatively small distance from the solar system. The present investigaation has the objective to provide accurate abundance ratios for several cyanides and isocyanides in order to constrain models of dark cloud chemistry. The relative abundances of such related species can be particularly useful for the study of chemical processes. The cloud TMC-1 considered in the current study has a remarkably high abundance of acetylene and polyacetylene derivatives. Data at 3 mm, corresponding to the J = 1 to 0 transitions of HCN, H(C-13)N, HN(C-13), HC(N-15), and H(N-15)C were obtained.

Irvine, W. M.↗
NASA NTRS1984

Explosive nucleosynthesis in massive stars - Comparison with the Cassiopeia A fast-moving knots

If the ejecta of a Type II supernova do not undergo extensive mixing, then, based on the explosion of current presupernova models, only a small fraction approximately equal to or less than 0.1 solar mass of the mantle of a massive star can yield abundances similar to those observed in the fast-moving knots of Cas A. This is shown to be independent of the detailed structure of the mantle and the supernova energy. Lack of mixing in Cas A is indicated by strong upper limits on the abundance ratios Ne/O, and Fe/O. If this is confirmed by further observations, then either Cas A is not the result of a standard progenitor of approximately equal to or less than 25 solar masses disrupted by a Type II supernova, or the picture of the last stages of stellar evolution in massive stars needs to be modified substantially.

Johnston, M. D.↗
NASA NTRS1993

Comets and the origin of the solar system - Reading the Rosetta Stone

It is argued that, from the measured volatile abundances, comets formed at temperatures near or below about 60 K and possibly as low as about 25 K. Grains in Comet Halley were found to be of two types: silicates and organics. Isotopic evidence shows that Comet Halley formed from material with the same compositional mix as the rest of the solar system, and is consistent with comets having been a major contributor to the volatile reservoirs on the terrestrial planets. A variety of processes have been shown to modify and reprocess the outer layers of comets both during their long residence time in the Oort cloud and following their entry back into the planetary system. The most likely formation site for comets is in the Uranus-Neptune zone or just beyond, with dynamical ejection by the growing protoplanets to distant orbits to form the Oort cloud. A substantial flux of interstellar comets was likely created by the same process, and may be detectable if cometary formation is common in planetary systems around other stars.

Mumma, Michael J.↗
NASA NTRS1976

Chemistry of primitive solar material

The paper reviews chemical processes that occurred in the cooler outer regions of the primitive solar nebula (PSN) at the time of intimate chemical contact between the preplanetary condensate and the nebular gas. The elemental composition of the PSN is discussed, the 15 most abundant elements in it are listed, and numerical models of it are examined. Various condensation models are described and tested against observed properties of the planets, their satellites, and the asteroids. The chemistry of abundant volatile elements in the PSN is investigated along with stability limits of graphite in a solar-composition gas, regions of dominance of the most abundant carbon-containing gas species in the same gas, and implications of the moon's composition for its origin. Some theories that have been proposed as alternatives to the condensation models are noted.

Barshay, S. S.↗
NASA NTRS1993

Evolution of the Martian atmosphere

Evolution of Mars' noble gases through two stages of hydrodynamic escape early in planetary history has been proposed previously by the author. In the first evolutionary stage of this earlier model, beginning at a solar age of approximately 50 m.y., fractionating escape of a H2-rich primordial atmosphere containing CO2, N2, and the noble gases in roughly the proportions found in primitive carbonaceous (CI) chondrites is driven by intense extreme-ultraviolet (EUV) leads to a long (approximately 80 m.y.) period of quiescence, followed by an abrupt degassing of remnant H2, CO2, and N2 from the mantle and of solar-composition noble gases lighter than Xe from the planet's volatile-rich accretional core. Degassed H refuels hydrodynamic loss in a waning but still potent solar EUV flux. Atmospheric Xe, Kr, and Ar remaining at the end of this second escape stage, approximately 4.2 G.y. ago, have evolved to their present-day abundances and compositions. Residual Ne continues to be modified by accretion of solar wind gases throughout the later history of the planet. This model does not address a number of processes that now appear germane to Martian atmospheric history. One, gas loss and fractionation by sputtering, has recently been shown to be relevant. Another, atmospheric erosion, appears increasingly important. In the absence then of a plausible mechanism, the model did not consider the possibility of isotopic evolution of noble gases heavier than Ne after the termination of hydrodynamic escape. Subsequent non-thermal loss of N was assumed, in an unspecified way, to account for the elevation of N from the model value of approximately 250 percent at the end of the second escape stage to approximately 620 percent today. Only qualitative attention was paid to the eroding effects of impact on abundances of all atmophilic species prior to the end of heavy bombardment approximately 3.8 G.y. ago. No attempt was made to include precipitation and recycling of carbonates in tracking the pressure and isotopic history of CO2.

Pepin, R. O.↗
NASA NTRS2021

Low Total Abundances and a Predominance of n-ω-Amino Acids in Enstatite Chondrites: Implications for Thermal Stability of Amino Acids in the Inner Solar System

Investigating the organic contents of enstatite chondrite meteorites may offer insights into both early inner solar system and early Earth chemistry. Enstatite chondrite meteorites have highly reduced and anhydrous compositions, and their bulk isotopic compositions closely resemble terrestrial values, suggesting that their parent body asteroids accreted within the inner protoplanetary disk and were a primary contributor during Earth’s late accretion (Javoy et al., 1995; Piani et al., 2020). Here, we present the first report of amino acids in enstatite chondrite meteorite samples. Three EH3 meteorites were analyzed (Dominion Range 14021, Larkman Nunatak 12001, and Larkman Nunatak 06252). The acid-hydrolyzed water extracts of the meteorites contained low abundances (1.5 – 215.9 pmol/g) of n-ω-amino acids (glycine, β-alanine, γ-amino-n-butyric acid (γ-ABA), δ-amino-n-valeric acid (δ-AVA), and ε-amino-n-caproic acid (ε-ACA)), but amino acids were not present above detection limits in the non-hydrolyzed samples. The low amino acid abundances and the predominance of n-ω-amino acids resembles amino acid distributions previously observed for thermally altered chondrites. These results suggest that the parent body asteroid was not conducive to the synthesis and/or preservation of α-amino acids, or free amino acids in general, and that EH3 chondrite-like material may not have been a primary contributor of diverse or abundant free amino acids to the early Earth.

Danielle N Simkus↗
NASA NTRS2021

Low total abundances and a predominance of n-ω-amino acids in enstatite chondrites: Implications for thermal stability of amino acids in the inner solar system

Investigating the organic contents of enstatite chondrite meteorites may offer insights into both early inner solar system and early Earth chemistry. Enstatite chondrite meteorites have highly reduced and anhydrous compositions, and their bulk isotopic compositions closely resemble terrestrial values, suggesting that their parent body asteroids accreted within the inner protoplanetary disk and were a primary contributor during Earth’s late accretion (Javoy, 1995; Piani et al., 2020). Here, we present the first report of amino acids in enstatite chondrite meteorite samples. Three EH3 meteorites were analyzed (Dominion Range [DOM] 14021, Larkman Nunatak [LAR] 12001, and Larkman Nunatak 06252). The acid-hydrolyzed water extracts of the meteorites contained low abundances (1.5–215.9 pmol per g) of n-ω-amino acids (glycine, β-alanine, γ-amino-n-butyric acid [γ- ABA], δ-amino-n-valeric acid [δ-AVA], and ϵ-amino-n-caproic acid [ϵ-ACA]), but amino acids were not present above detection limits in the nonhydrolyzed samples. The low amino acid abundances and the predominance of n-ω-amino acids resemble amino acid distributions previously observed for thermally altered chondrites. These results suggest that the parent body asteroid was not conducive to the synthesis and/or preservation of α-amino acids, or free amino acids in general, and that EH3 chondrite-like material may not have been a primary contributor of diverse or abundant free amino acids to the early Earth.

Danielle N. Simkus↗
DOE OSTI2024

An Expanded Set of Los Alamos OPLIB Tables in MESA: Type-1 Rosseland-mean Opacities and Solar Models

Abstract We present a set of 1194 Type-1 Rosseland-mean opacity tables for four different metallicity mixtures. These new Los Alamos OPLIB atomic radiative opacity tables are an order of magnitude larger in number than any previous opacity table release, and span regimes where previous opacity tables have not existed. For example, the new set of opacity tables expands the metallicity range to Z = 10 −6 to Z = 0.2, which allows improved accuracy of opacities at low and high metallicity, increases the table density in the metallicity range Z = 10 −4 to Z = 0.1 to enhance the accuracy of opacities drawn from interpolations across neighboring metallicities, and adds entries for hydrogen mass fractions between X = 0 and X = 0.1 including X = 10 −2 , 10 −3 , 10 −4 , 10 −5 , 10 −6 that can improve stellar models of hydrogen deficient stars. We implement these new OPLIB radiative opacity tables in MESA and find that calibrated solar models agree broadly with previously published helioseismic and solar neutrino results. We find differences between using the new 1194 OPLIB opacity tables and the 126 OPAL opacity tables range from ≈20% to 80% across individual chemical mixtures, up to ≈8% and ≈15% at the bottom and top of the solar convection zone respectively, and ≈7% in the solar core. We also find differences between standard solar models using different opacity table sources that are on par with altering the initial abundance mixture. We conclude that this new, open-access set of OPLIB opacity tables does not solve the solar modeling problem, and suggest the investigation of physical mechanisms other than the atomic radiative opacity.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1993

Upper limit on Titan's atmospheric argon abundance

An analysis is conducted on the Voyager 1 UV Spectrometer solar-occultation data and a Titan flyby spectrum of the north polar region dayglow, in order to infer the tropopausal Ar mixing ratio's upper limit as a function of the CH4 mixing ratio, f(CH4). The mole-fraction upper limit of tropopausal Ar mixing ratio ranges from 0.01 to 0.1 at f(CH4) of 0.026 to as low as 0.08 at f(CH4) of 0.05. Since the best fits to the solar occultation data require f(CH4) of more than 0.26, the Ar mixing ratio must be lower than 0.1.

Strobel, Darrell F.↗
NASA NTRS1979

Jupiter's atmospheric composition and cloud structure deduced from absorption bands in reflected sunlight

The spectrum of sunlight reflected by Jupiter is analyzed by comparing observations of Woodman (1979) with multiple-scattering computations. The analysis yields information on the vertical cloud structure at several latitudes and on the abundance of CH4 and NH3 in the atmosphere of Jupiter. The abundances of CH4 and NH3 suggest that all ices and rocks are overabundant on Jupiter by a factor of 2 or more, providing an important constraint on models for the formation of Jupiter from the primitive solar nebula. The pressure level of the clouds, the gaseous NH3 abundance, the mean temperature profile, and the Clausius-Clapeyron relation suggest that these clouds are predominantly ammonia crystals with the cloud bottom at 600-700 mb. A diffuse distribution of aerosols exists between 150 and 500 mb, and the spectral variation of albedo reflects a changing bulk absorption coefficient of the material composing the aerosols and is diagnostic of the aerosol composition.

Sato, M.↗
NASA NTRS2009

The Herschel DUNES Open Time Key Programme

We will use the unique photometric capabilities provided by Herschel to perform a deep and systematic survey for faint, cold debris disks around nearby stars. Our sensitivity-limited Open Time Key Programme (OTKP) aims at finding and characterizing faint extrasolar analogues to the Edgeworth-Kuiper Belt (EKB) in an unbiased, statistically significant sample of nearby FGK main-sequence stars. Our target set spans a broad range of stellar ages (from 0.1 to 10 Gyr) and is volume-limited (distances < 20 pc). All stars with known extrasolar planets within this distance are included; additionally, some M- and A-type stars will be observed in collaboration with the Herschel DEBRIS OTKP, so that the entire sample covers a decade in stellar mass, from 0.2 to 2 solar masses. We will perform PACS and SPIRE photometric observations covering the wavelength range from 70 to 500 microns. The PACS observations at 100 microns have been designed to detect the stellar photospheres down to the confusion limit with a signal-to-noise ratio > 5. The observations in the other Herschel bands will allow us to characterize, model, and constrain the disks. As a result, it will be possible for us to reach fractional dust luminosities of a few times 10-7, close to the EKB level in the Solar System. This will provide an unprecedented lower limit to the fractional abundance of planetesimal systems and allow us to assess the presence of giant planets, which would play dynamical roles similar to those played by Jupiter and Neptune in the Solar System. The proposed observations will provide new and unique evidence for the presence of mature planetary systems in the solar neighbourhood and, in turn, will address the universality of planet/planetary system formation in disks around young stars.

Danchi, William C.↗
DOE OSTI2021

Transmission Spectroscopy for the Warm Sub-Neptune HD 3167c: Evidence for Molecular Absorption and a Possible High-metallicity Atmosphere

We present a transmission spectrum for the warm (500−600 K) sub-Neptune HD 3167c obtained using the Hubble Space Telescope Wide Field Camera 3 infrared spectrograph. We combine these data, which span the 1.125–1.643 μm wavelength range, with broadband transit measurements made using Kepler/K2 (0.6–0.9 μm) and Spitzer/IRAC (4–5 μm). We find evidence for absorption by at least one of H{sub 2}O, HCN, CO{sub 2}, and CH{sub 4} (Bayes factor 7.4; 2.5σ significance), although the data precision does not allow us to unambiguously discriminate between these molecules. The transmission spectrum rules out cloud-free hydrogen-dominated atmospheres with metallicities ≤100× solar at >5.8σ confidence. In contrast, good agreement with the data is obtained for cloud-free models assuming metallicities >700× solar. However, for retrieval analyses that include the effect of clouds, a much broader range of metallicities (including subsolar) is consistent with the data, due to the degeneracy with cloud-top pressure. Self-consistent chemistry models that account for photochemistry and vertical mixing are presented for the atmosphere of HD 3167c. The predictions of these models are broadly consistent with our abundance constraints, although this is primarily due to the large uncertainties on the latter. Interior structure models suggest that the core mass fraction is >40%, independent of a rock or water core composition, and independent of atmospheric envelope metallicity up to 1000× solar. We also report abundance measurements for 15 elements in the host star, showing that it has a very nearly solar composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗