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At least 1,279 records · Page 71

Technologies for Maintaining Animals in Space: Lighting, Air Quality, Noise, Food and Water

In the terrestrial environment multiple time cues exist. Zeitgebers have been identified and studied for their ability to convey temporal information to various physiological systems, In the microgravity experiment it is necessary to define time cues within the flight hardware prior to flight. During flight if changes in the Circadian System (e.g., mean, phase angle, period) occur this would indicate that the gravity vector is important relative to biological timing. This presentation is concerned with the environmental parameters to support rodent experiments in microgravity. The Animal Enclosure Module (AEM) provides solid food bars and water via lixits ad libitum. Flight animals (Sprague-Dawley rats, 60 - 300g) when compared to ground controls show similar growth (mean growth per day, g +/- SD; flight 5.4 +/- 2.0, ground 5.9 +/- 2.1). Current AEMs use incandescent lighting (approx. 5 Lux). Light emitting diode (LED) arrays are being developed that provide a similar light environment as cool-white fluorescent sources (40 Lux). In ground based tests (12L:12D), these arrays show normal circadian entrainment (Tau = 24.0) with respect to the behavioral responses. measured (drinking, eating, gross locomotor activity). A newly developed ultra high efficiency filter system can entrap all feces, urine and odors from 6 rats for 24 days. Maximum sound level exposure limits (per octave band 22 Hz - 179 kHz) have been established. The AEM will effectively support animal experiments in microgravity.

Winget, C. M.↗

Space Optical Communications Using Laser Beam Amplification

The Space Optical Communications Using Laser Beam Amplification (SOCLBA) project will provide a capability to amplify a laser beam that is received in a modulating retro-reflector (MRR) located in a satellite in low Earth orbit. It will also improve the pointing procedure between Earth and spacecraft terminals. The technology uses laser arrays to strengthen the reflected laser beam from the spacecraft. The results of first year's work (2014) show amplification factors of 60 times the power of the signal beam. MMRs are mirrors that reflect light beams back to the source. In space optical communications, a high-powered laser interrogator beam is directed from the ground to a satellite. Within the satellite, the beam is redirected back to ground using the MMR. In the MMR, the beam passes through modulators, which encode a data signal onto the returning beam. MMRs can be used in small spacecraft for optical communications. The SOCLBA project is significant to NASA and small spacecraft due to its application to CubeSats for optical data transmission to ground stations, as well as possible application to spacecraft for optical data transmission.

Laser↗

Coupled methane and NO x conversion on Pt + Pd/Al 2 O 3 monolith: Conversion enhancement through feed modulation and Mn 0.5 Fe 2.5 O 4 spinel addition

The performance of a dual-layer Pt-Pd/Al 2 O 3 washcoated monolith promoted by an Al 2 O 3 -supported Mn 0.5 Fe 2.5 O 4 spinel base layer was evaluated with the objective to develop a catalyst with a lower loading of Platinum group metal (PGM) for stoichiometric natural gas vehicle (NGV) emission control. Flow reactor results show that a combination of a lean/rich modulated feed and spinel addition gives enhanced methane and NO conversions compared to a steady-state feed having the same overall composition. Washcoated catalysts – PGM-only, spinel-only, PGM + spinel – were compared over a wide range of operating conditions. The results show a decrease in the methane conversion light-off temperature of up to 85 °C for an application-relevant feed (CH 4 + NO + H 2 + CO + O 2 + H 2 O + CO 2 ) while a moderate 40 °C decrease was observed for a simple feed (CH 4 + O 2 + H 2 O + CO 2 ). In the absence of spinel the modulation enhancement is negatively impacted at high methane conversion (> 80 %). The data show that the O 2 storage and release property of the spinel is needed to fully exploit the modulation enhancement. The mechanism responsible for the enhancement is linked to suppression of O 2 inhibition on the methane oxidation rate near the stoichiometric neutral point (λ = 1). Sufficiently fast cycling achieves a balance between a metallic and oxidic precious metal crystallites favorable for methane activation. The addition of spinel moves this balance closer to the λ = 1 feed, enabling a high oxidation efficiency with lower byproduct NH 3 selectivity. Enhancement in the NO conversion follows the methane conversion due to an easier NO reduction under the slightly rich of stoichiometric feed. Comparison of the PGM + spinel catalysts to PGM-only catalysts shows that the addition of spinel in combination with modulation can achieve the same activity with a lower PGM loading.

03 NATURAL GAS↗

Ionizing photon interactions modulate the optical properties of crystals with femtosecond scale temporal resolution

In this work, we continue our study of a new method for the detection of ionizing radiation with the potential for a dramatic improvement in coincidence time resolution (CTR) for time-of-flight positron emission tomography (ToF-PET) using the modulation of a material's optical properties instead of the scintillation mechanism. Our previous work has shown that for non-scintillation materials such as bismuth silicon oxide (BSO) and cadmium telluride (CdTe), their refractive index can be modulated by annihilation photon interactions. Additionally, the ultrafast nature of this process however remains unexplored. The ionizing radiation-induced charge carriers alter the local band structure in these materials, thus changing the complex refractive index. This mechanism is routinely used at the linac coherent light source (LCLS) facility of the SLAC National Accelerator Laboratory to measure x-ray pulse arrival times with femtosecond scale resolution for photon energies between 0.5 and 10 keV. The method described here follows that example by using a frequency chirped visible continuum pulse to provide a monotonic wavelength-to-time mapping by which one can measure the time-dependent refractive index modulation. In addition, we describe an interference-based measurement setup that allows for significantly improved sensitivity while preserving a timing precision of approximately 10 fs (σ) when measuring the arrival time of below 10 keV x-ray pulses with yttrium aluminum garnet (YAG) crystal. The method is presented in the context of ToF-PET application with further discussions on the potential CTR achievable if a similar detection concept is adopted for detecting 511 keV photons. Semi-empirical analysis indicates that the predicted CTR achievable is on the order of 1 ps (FWHM).

59 BASIC BIOLOGICAL SCIENCES↗

Probabilistic Assessment of Radiation Risk for Astronauts in Space Missions

Accurate predictions of the health risks to astronauts from space radiation exposure are necessary for enabling future lunar and Mars missions. Space radiation consists of solar particle events (SPEs), comprised largely of medium energy protons, (less than 100 MeV); and galactic cosmic rays (GCR), which include protons and heavy ions of higher energies. While the expected frequency of SPEs is strongly influenced by the solar activity cycle, SPE occurrences themselves are random in nature. A solar modulation model has been developed for the temporal characterization of the GCR environment, which is represented by the deceleration potential, phi. The risk of radiation exposure from SPEs during extra-vehicular activities (EVAs) or in lightly shielded vehicles is a major concern for radiation protection, including determining the shielding and operational requirements for astronauts and hardware. To support the probabilistic risk assessment for EVAs, which would be up to 15% of crew time on lunar missions, we estimated the probability of SPE occurrence as a function of time within a solar cycle using a nonhomogeneous Poisson model to fit the historical database of measurements of protons with energy > 30 MeV, (phi)30. The resultant organ doses and dose equivalents, as well as effective whole body doses for acute and cancer risk estimations are analyzed for a conceptual habitat module and a lunar rover during defined space mission periods. This probabilistic approach to radiation risk assessment from SPE and GCR is in support of mission design and operational planning to manage radiation risks for space exploration.

Kim, Myung-Hee↗

Developmental Hardware Testing Results and Forward Plans for the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM)

We present testing results for developmental hardware of the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM). SWIM-OWM will monitor spacecraft potable water and system water for trace organic contaminants. The system will detect and identify the specific organic chemical that makes up a given total organic carbon reading. We have built a first development unit (1DU) for SWIM-OWM, which directly injects aqueous water samples and detects chemicals with both a thermal conductivity detector and mass spectrometer sensor. The gas chromatography mass spectrometer (GCMS) system that comprises SWIM-OWM draws on the success of ISS-proven mass spectrometer hardware, and the demonstration of GCMS detection of trace organic contaminants in ISS cabin air. SWIM-OWM benefits from the excellent sensitivity and specificity afforded by GCMS. We have demonstrated detection of a set of chemicals relevant to both crew health and performance as well as system monitoring; these target chemicals range from light, volatile organics such as acetone and ethanol, to heavier, very non-volatile compounds such as dimethyl sulfone and o-phthalaldehyde. Direct aqueous injection was chosen for the general applicability of the technique to clean water sampling and to preclude sample pre-processing, which facilitates an on-line implementation of the SWIM-OWM when deployed in a spacecraft or habitation module. A specific advantage of direct aqueous injection when coupled with appropriate methods is that both the light, volatile organics and heavier non-volatiles can be detected from a single injection, in a single chromatogram. Results from 1DU testing will be discussed, and forward plans will be outlined for continued maturation of SWIM-OWM with the goal of implementing a technology demonstration for the purposes of maturing the engineering design and operations in an environment relevant to NASA’s future goals of exploring and setting up habitation on the Moon and Mars.

Water Monitoring↗

Developmental Hardware Testing Results and Forward Plans for Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM)

We present testing results for developmental hardware of the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM). SWIM-OWM will monitor spacecraft potable water and system water for trace organic contaminants. The system will detect and identify the specific organic chemical that makes up a given total organic carbon reading. We have built a first development unit (1DU) for SWIM-OWM, which directly injects aqueous water samples and detects chemicals with both a thermal conductivity detector and mass spectrometer sensor. The gas chromatography mass spectrometer (GCMS) system that comprises SWIM-OWM draws on the success of ISS-proven mass spectrometer hardware, and the demonstration of GCMS detection of trace organic contaminants in ISS cabin air. SWIM-OWM benefits from the excellent sensitivity and specificity afforded by GCMS. We have demonstrated detection of a set of chemicals relevant to both crew health and performance as well as system monitoring; these target chemicals range from light, volatile organics such as acetone and ethanol, to heavier, very non-volatile compounds such as dimethyl sulfone and o-phthalaldehyde. Direct aqueous injection was chosen for the general applicability of the technique to clean water sampling and to preclude sample pre-processing, which facilitates an on-line implementation of the SWIM-OWM when deployed in a spacecraft or habitation module. A specific advantage of direct aqueous injection when coupled with appropriate methods is that both the light, volatile organics and heavier non-volatiles can be detected from a single injection, in a single chromatogram. Results from 1DU testing will be discussed, and forward plans will be outlined for continued maturation of SWIM-OWM with the goal of implementing a technology demonstration for the purposes of maturing the engineering design and operations in an environment relevant to NASA’s future goals of exploring and setting up habitation on the Moon and Mars.

Water Monitoring↗

Light-induced Kondo-like exciton-spin interaction in neodymium(II) doped hybrid perovskite

Abstract Tuning the properties of a pair of entangled electron and hole in a light-induced exciton is a fundamentally intriguing inquiry for quantum science. Here, using semiconducting hybrid perovskite as an exploratory platform, we discover that Nd 2+ -doped CH 3 NH 3 PbI 3 (MAPbI 3 ) perovskite exhibits a Kondo-like exciton-spin interaction under cryogenic and photoexcitation conditions. The feedback to such interaction between excitons in perovskite and the localized spins in Nd 2+ is observed as notably prolonged carrier lifetimes measured by time-resolved photoluminescence, ~10 times to that of pristine MAPbI 3 without Nd 2+ dopant. From a mechanistic standpoint, such extended charge separation states are the consequence of the trap state enabled by the antiferromagnetic exchange interaction between the light-induced exciton and the localized 4 f spins of the Nd 2+ in the proximity. Importantly, this Kondo-like exciton-spin interaction can be modulated by either increasing Nd 2+ doping concentration that enhances the coupling between the exciton and Nd 2+ 4 f spins as evidenced by elongated carrier lifetime, or by using an external magnetic field that can nullify the spin-dependent exchange interaction therein due to the unified orientations of Nd 2+ spin angular momentum, thereby leading to exciton recombination at the dynamics comparable to pristine MAPbI 3 .

36 MATERIALS SCIENCE↗

Direct neutron-diffraction-based measurement of magnetic order in brownmillerite SrCoO 2.5 and La 0.5 Sr 0.5 CoO 2.5 thin films

Epitaxial cobaltites have emerged as exemplary materials for electrochemical gating, in large part due to their topotactic perovskite (P) ↔ brownmillerite (BM) transformations. SrCoO 3-δ , for example, can be cycled between metallic ferromagnetic P SrCoO 3 and insulating BM SrCoO 2.5 , realizing exceptional modulation of electronic, thermal, and optical properties. It is often presumed that such cycling also generates ferromagnetic–antiferromagnetic (F-AF) modulation due to the G-type AF order in bulk SrCoO 2.5 . Little is understood about magnetism in thin-film BM SrCoO 2.5 , however, meaning that the true magnetic property modulation is unclear. We address this here through a neutron diffraction study of BM La 1-x Sr x CoO 2.5 films at x = 0.5 and 1.0. Lightly compressively strained SrCoO 2.5 films are shown to retain G-type AF order, albeit with suppressed Néel temperature (~340 K). Of high interest for AF spintronics, room-temperature F–AF cycling is thus possible across the SrCoO 3-δ P ↔ BM transformation. At x = 0.5, however, BM La 0.5 Sr 0.5 CoO 2.5 films are found to exhibit no detectable G-type AF order but instead weak F order (Curie temperature ~115 K), unveiling a La 0.5 Sr 0.5 CoO 3-δ phase diagram with two distinct F phases. These results thus uncover new, unanticipated magnetic phase behavior in these materials, in addition to being directly relevant to cobaltite-based magnetoionics.

36 MATERIALS SCIENCE↗

ROM-Based Surrogate Systems Modeling of EBR-II

We report the System Analysis Module (SAM), developed and maintained by Argonne National Laboratory, is designed to provide whole-plant transient safety analysis capabilities for a number of advanced non-light water reactors, including sodium-cooled fast reactor (SFR), lead-cooled fast reactor (LFR), and molten salt reactor (MSR)/fluoride-salt-cooled high-temperature reactor (FHR) designs. SAM is primarily constructed as a systems-level analysis tool, with the potential to incorporate reduced order models from three-dimensional computational fluid dynamics (CFD) simulations to improve characterization of complex, multidimensional physics. It is recognized that the computational expense associated with CFD can be intractable for various engineering analyses, such as uncertainty quantification, inference, and design optimization. This paper explores the reducibility of a SAM model using recent advances in randomized linear algebra techniques, which attempt to find recurring patterns in the various realizations generated by a model after randomly perturbing all its input parameters. The reduction is described in terms of fewer degrees of freedom (DOFs), referred to as the active DOFs, for the model variables such as input model parameters and model responses. The results indicate that there is significant room for additional reduction that may be leveraged for additional computational gains when employing SAM for engineering-intensive analyses that require repeated model executions. Different from physics-based reduction approaches, the proposed approach allows one to estimate upper bounds on the reduction errors, which are rigorously developed in this work. Finally, different methods for surrogate model construction, such as regression and neural network-based training, are employed to correlate the input and output active DOFs, which are related back to the original variables using matrix-based linear transformations.

42 ENGINEERING↗

Gaia: segmented germanium detector for high-energy X-ray fluorescence and spectroscopic imaging

We present Gaia, a monolithic array of 96 high-purity germanium pixel detectors integrated with a custom low-noise application-specific integrated circuit (ASIC) and a field-programmable gate array (FPGA)-based data acquisition system. The sensor operates at ∼100 K using a commercial closed-cycle cryocooler, with the in-vacuum electronics thermally isolated from the cold finger to ensure thermal stability. The system demonstrates an average energy resolution of 711 eV at 122 keV, measured using a 57 Co source, and 253 eV at 5.89 keV, measured with 55 Fe across all channels. The readout architecture incorporates a high-performance FPGA paired with a dual-core ARM processor, forming a complete embedded Linux-based computing platform. Communication between the processor and FPGA is handled via memory-mapped I/O, and data are streamed over high-speed gigabit Ethernet. A full-scale 384-pixel Gaia detector, based on this 96-element module, is currently under fabrication.

36 MATERIALS SCIENCE↗

SAM Code Validation on Frictional Pressure Drop through Pebble Beds

The System Analysis Module (SAM) is currently under development at Argonne National Laboratory as a modern system-level modeling and simulation tool for safety analyses of advanced non-light water reactors. This report presents a recent effort to validate the capability of SAM to predict the frictional pressure drop through pebble beds. Selected experimental data were used for code validation, including data from test facilities at Texas A&M University, Missouri University of Science and Technology, and North-West University of South Africa. SAM implements three empirical correlations to predict frictional pressure drop: the classical Ergun correlation; the KTA correlation, which is widely used in high-temperature gas-cooled reactor applications; and the Eisfeld and Schnitzlein correlation, which explicitly considers wall effect. Code validation was performed using all three correlations. For all selected experimental data, the KTA correlation shows the best performance and agrees very well with experimental measurement; the Eisfeld and Schnitzlein correlation, explicitly considering wall effects, shows acceptable accuracy, while there is no evidence that it is better than the KTA correlation; the Ergun correlation, however, over-predicts frictional pressure drop for most selected data points.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

SS Cygni as a hard X-ray source identified with the scanning modulation collimator on HEAO 1

Hard X-ray emission from a 15 min by 1.5 deg area containing SS Cygni had previously been reported and identified with SS Cygni. This paper reports a 0.4 sq arc min measurement of the position of the X-ray source with the HEAO 1 modulation collimator experiment which leads to an unequivocal identification of SS Cygni as an X-ray emitter in the 2-10 keV energy range. The historical light curve in hard X-rays was also investigated by analyzing relevant Uhuru data, and two instances of possible source detection in the 2-6 keV band were noted. From Ariel 5 observations it is calculated that the X-ray luminosity of SS Cygni in the 2-10 keV energy range is of the order of 10 to the 33rd erg/sec in the optical low state and probably at least an order of magnitude less in the high state. By contrast, the soft X-ray luminosity increases by an order of magnitude between the optical low and high states. A coronal model or accretion onto the white dwarf can account for the inverse correlation of the soft and hard X-rays.

Fabbiano, G.↗

Controlling Electron-Beam-Weld Focus

Control loop measures weld-spot temperature to regulate focus current. Square-wave generator modulates current in electron-beam focus coil so that focal point is varied between points slightly above and below surface of weld. Sensor detects intensity of light emitted by weld, proportional to fourth power of temperature at hottest part of weld spot. Sensor signal is detected by chopper demodulator synchronized by square-wave generator, to determine whether average position of focal point is higher than, coincident with, or lower than optimum point; and focus coil current is adjusted accordingly.

Coate, F. M.↗

Pterodactyl: Integrated Control Design for Precision Targeting of Deployable Entry Vehicles

Deployable Entry Vehicles (DEVs) enable in-situ scientific exploration at destinations with atmospheres across the solar system. Because they stow in a compact form and deploy only when ready to enter the atmosphere, DEVs relax the volume constraint imposed by rigid aeroshells. This work seeks to do for a DEV what the Wright Brothers did to propel modern day aviation: develop the guidance and control (G&C) methods that will make maneuvering and precision landing of DEV a reality. The Pterodactyl project objective is to deliver an integrated G&C methodology for a DEV, based on a detailed analysis that utilizes a Multi-disciplinary, Design, Analysis and Optimization (MDAO) framework. The current state-of-the-art for blunt body entry, G&C is rooted in the precision landing of vehicles such as Mars Science Laboratory (MSL) and Apollo, which used a propulsive reaction control system (RCS) to steer. Recent research has taken a particular interest in non-propulsive control for DEVs, including direct force control (angle of attack modulation via control surfaces or mass movement) and drag modulation (discrete change in ballistic coefficient). Using the MDAO framework that includes a guidance and control model to explore multiple control concepts for a DEV will shed light on the best design approach for these vehicles. In Pterodactyl, we will complete this study for a novel DEV concept, and then we will fabricate a functional prototype to help validate the design. The project is expected to down-select to a final control architecture by the end of 2018, and complete fabrication of the prototype by the end of 2019.The DEV chosen for detailed study in this project is the Adaptable Deployable Entry and Placement Technology (ADEPT). ADEPT uses a revolutionary 3D-woven carbon fabric that is foldable, can serve as primary structure, and can survive the extreme heating environment of atmospheric entry. The specific configuration of ADEPT under investigation is called Lifting Nano-ADEPT (LNA). LNA is designed for secondary payloads missions that require precision landing either for scientific objectives at a target destination or for payload recovery at Earth.The MDAO framework being created through this research, called COBRA-Pt (Composite Beam Roll-Up Solar Array-Prototype), will combine three critical elements of the system design: a guidance algorithm with Monte Carlo, a parametric control model, and vehicle geometry details. Novel control models being studied are deployable aerodynamic surfaces as well as shape morphing. These concepts will be compared at the system level with a more traditional propulsive RCS by comparing several key performance parameters. Upon completion of the design study, a functional prototype of LNA will be fabricated that will include the integration of guidance software and relevant control actuators. We expect this study will provide critical data that could feed into the development of an Earth-based flight test of LNA. The COBRA-Pt framework will provide a modular system by which to study any DEV concept in any atmosphere.

Smith, Brandon↗

The development of inflatable array antennas

The deployable array antenna using an inflatable or thin-membrane structure has been identified as one of the enabling technologies to achieve low-mass, high packaging efficiency, low cost, and reliable deployment for future NASNJPL spacebome high-gain and large aperture antennas. Array antennas, when compared to parabolic reflectors, although suffering from limited bandwidth performance, offer wide-angle beam scanning capability and a more reliable flat “natural” aperture. To demonstrate the feasibility and capability of this low-mass array technology, three antenna concepts using inflatable and thin-membrane structures were initiated in 1997 at JPL and several breadboard units have been successfully developed. These three concepts are (1) the inflatable phased array, (2) the inflatable reflectarray, and (3) frame-supported thin membrane array antenna. All three concepts utilize the printed microstrip antenna technology. Although all three concepts will be briefly presented, this paper will discuss in more detail of the recent development of the second concept. The first concept of inflatable phased arrays that have been constructed are 3 to 5-meter size L-band dual-polarized synthetic aperture radar (SAR) arrays for Earth remote sensing application. They all consist of a rectangular configuration with inflatable cylindrical tubes that support and tension a multi-layer thin-membrane radiating aperture with microstrip patches and microstrip power divider lines. For the second concept, an inflatable reflectarray was developed for future deep-space telecom applications. It is a 3m Ka-band inflatable reflectarray (1.8 kg/m2). This reflectarray uses inflated torus tubes to support and tension a flat-membrane reflectarray surface. The reflectarray surface emulates a curved parabolic reflecting surface. However, because of its flat surface being a “natural surface”, it is much easier to achieve and more reliable to maintain the required surface tolerance than that of a curved parabola during long space flight. For the third concept, an L-band dual polarized SAR array with a 5m x 3m aperture and 2.5 kg/m2 of mass has recently been demonstrated. It consists of seven foldable panels each having a rectangular frame that supports a two-layer thinmembrane microstrip subarray aperture. Each frame is made of light-weight graphite composite material. The chief advantage of this deployable “frame” concept is that each frame is able to rigidly support an appropriate number of T/R modules and phase shifters to achieve the desired power distribution and beam scanning. Several technology challenges, such as the development of rigidizable inflatable tubes, a controlled deployment mechanism, thin-membrane thermal effects, a low-mass inflation system, membrane mounted T/R modules, means to counter surface tolerance issues, etc. are being investigated and will be discussed in the presentation. With foreseeable success in the development of these challenging areas, the inflatable/thin-membrane array antennas could be mature enough in a few years for actual space flight.

Lou, Michael↗